• Applied Chemistry for Engineering
• /
• v.34 no.5
• /
• pp.515-521
• /
• 2023

In this study, waste carbon fiber obtained by pyrolysis of carbon fiber reinforced plastic (CFRP) was used to produce carbon fluoride through vapor phase fluorination and recycled as a reducing electrode material for lithium primary batteries. First, the physicochemical properties of the waste carbon fiber obtained by pyrolysis were determined, and the structural and chemical properties of carbon fluoride were analyzed to evaluate the effect of vapor phase fluorination on the waste carbon fiber. XRD analysis confirmed that the hexagonal network carbon laminated structure (002 peak) of the waste carbon fiber was gradually converted into a carbon fluoride structure (CF_X, 001 peak) as the temperature of gas phase fluorination increased. The discharge capacity of the lithium primary battery produced using this carbon fluoride was up to 862 mAh/g. This was compared to the discharge capacity of carbon fluoride-based Li-ion batteries made of other carbon materials. These results suggest that carbon fluoride made from waste CFRP-based carbon fibers can be used as a reducing electrode material for Li-ion batteries.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.10 no.2
• /
• pp.102-106
• /
• 2007

While the effort has been made in recycling the FRP (Fiber Reinforced Plastic) used for the medium-to-small size ships, researchers try to find out the methods more favorable for the environments and more value-added. In respect to the fact that the FRP consists of two types of layers, roving and mat, differentiated by the 2-dimensional structure, our group was able to separate the layers of FRP instead of grinding it. The roving cloth was cut to the long glass fibers (about 50 mm long; calling it 'F-fiber' afterwards). F-fiber showed increasing tensile strength and chemical-resistance possibly due to the remained resin (about 25% by weight). In this experiment fiber-reinforced mortars are made of the F-fiber as a recycling method of FRP. The mortar containing 2% (v/v) F-fiber results in 34.6% increment of bending strength from the standard after 28 day curing. The resulting strength is similar to that of the mortar with imported polyvinyl fiber P-54. These results imply that F-fiber can be applied to the 'fiber reinforced mortar' and furthermore may be a substitute for the imported fibers.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.11 no.1
• /
• pp.46-49
• /
• 2008

Recycling glass fiber, 'F-fiber,' was obtained by the separation of the roving layer from waste FRP and the concrete products or structures were considered for its application. Experiment was carried out for the bending strength of aggregate (2.45 of cement) by weight and F-fiber (density of 1.45, volume ratio to all of the aggregate and the cement). Whereas the specimen containing 1% F-fiber showed the bending strength 23% higher than that without F-fiber after curing far 28 days, the one with 0.5% F-fiber did not give any change. It could be found, therefore, that the minimum mixing amount should be larger than 0.5% fur the strength reinforcement. One of the reinforcing concrete product, bench flume, containing 1% F-fiber showed 21% increment of bending strength In contrast to that without F-fiber.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.11 no.1
• /
• pp.42-45
• /
• 2008

It has been reported that FRP (fiber reinforced plastic) can be recycled by separating into layers instead of crushing into powder. F-fiber obtained from roving layer separated from FRP, has bigger tensile strength than the bundle of glass fibers of which FRP was made (more than 90%). SEM image of F-fiber shows the presence of some resin. Under the proposition of usage of F-fiber in the concrete material, tensile strength is examined after soaking in a basic solution (NaOH+KOH). The reaction mechanism of strength loss may be considered as an attack of hydroxide ion ($OH^-$) on a chemical bond of Si-O-Si of glass fiber. The simulation graph of the strength loss data implies certain reaction mechanism. While in the early stage kinetically controlled reaction results in a fast drop of tensile strength, after 30 days dispersion rate of hydroxide ion plays a major role in strength loss. This result is similar to the one for the AR glass. An extrapolation of the graph would make an assumption about the lift time of F-fiber possible.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.13 no.1
• /
• pp.43-46
• /
• 2010

As one of the methods for recycling the FRP used for the small and medium-sized waste ships, separation of the roving layer from the mat has some merit in a sense of the recycling energy and the environmental effects. Similar characteristics between the roving and the mat make the mechanically automatic differentiation difficult. They, however, contain different ratio of the resin and the glass and the thickness. In this study photo physical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer and (2) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring the FRP sample with water-soluble dye following the HF treatment makes the roving layer more distinguishable photophysically. The implementation of HF treatment has been successfully tested in this study.

• Journal of the Korean Society for Railway
• /
• v.12 no.6
• /
• pp.1059-1066
• /
• 2009

Recently, the amount of thermosetting plastic wastes has increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy resins, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that decompose epoxy resin and recover carbon fibers from carbon fiber reinforced epoxy composites applied to railway vehicles was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.12 no.1
• /
• pp.29-34
• /
• 2009

For several decades, many researchers have been involved in developing recycling methods for FRP boats. There are four basic classes of recycling covered in the literature. Despite of environmental problems(safety hazards), mechanical recycling of FRP boats, which involves shredding and grinding of the scrap FRP, is one of the simpler and more technically proven methods than incineration, reclamation or chemical ones. Because FRP is made up of reinforced fiber glass, it is very difficult to break into pieces. It also leads to secondary problem in recycling process, such as air pollution and unacceptable shredding noise level. Another serious problem of mechanical FRP recycling is very limited reusable applications for the residue. This study is to propose a new and efficient method which is more wide range applications and environment friendly waste FRP regenerating system. New system is added with the cyclone sorting machine for airborne pollutions and modified cutting system for several glass fiber chips sizes. It also has shown the FRP chip fiber-reinforced concrete and fiber-reinforced secondary concrete applications with the waste FRP boat to be more eligible than existing recycling method.

• Journal of the Korea Concrete Institute
• /
• v.14 no.2
• /
• pp.190-198
• /
• 2002

In this research the physical properties of polymer modified mortar containing pulverized FRP(Fiber-Reinforced Plastics) wastes fine powder as a part of fine aggregate were investigated. Styrene-butadiene rubber(SBR) latex, polyacrylic ester(PAE) emulsion and ethylene-vinyl acetate(EVA) emulsion were used as Polymer modifier. Polymer modified mortars containing FRP wastes fine powder were prepared with various FRP wastes fine powder replacement(5∼30 wt％) for fine aggregate and polymer-cement ratios(5∼20 wt％). The water-cement ratio, water absorption rates and hot water immersion test, compressive and flexural strengths of polymer modified mortars were tested and the results compared to those of ordinary portland cement mortar. As the results, compressive and flexural strengths of polymer modified mortar containing FRP wastes fine powder depend on the contents of FRP wastes fine powder, type and additional amounts of polymer modifier. Some of them showed higher compressive and flexural strengths than those of ordinary portland cement mortar. Especially, SBR-modified mortar showed the highest strengths properties among three types of polymer modifier. Also water absorption rates, compressive and flexural strengths of SBR-modified mortar were more superior than those of PAE or EVA-modified mortar. The optimum mix proportions of SBR-modified mortar was 20 wt％ of polymer-cement ratio and 20 wt％ of FRP wastes fine powder replacement. Otherwise heat cured polymer modified mortar accelerated the improvement of early compressive and flexural strengths.