• Applied Chemistry for Engineering
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• v.25 no.4
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• pp.430-436
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• 2014

Allura Red (AR) is a water-soluble harmful tar-based food colorant (FD & C Red 40). Batch adsorption studies were performed for the removal of AR using bituminous coal based granular activated carbon as adsorbent by varying the operation parameters such as adsorbent dosage, initial concentration, contact time and temperature. Experimental equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherms. The equilibrium process was described well by Freundlich isotherm. From determined separation factor ($R_L$), adsorption of AR by granular activated carbon could be employed as effective treatment method. Temkin parameter, B was determined to 1.62~3.288 J/mol indicating a physical adsorption process. By estimation of adsorption rate experimental data, the value of intraparticle diffusion rate constant ($k_m$) increased with the increasing adsorption temperature. The adsorption process were found to confirm to the pseudo second order model with good correlation. Thermodynamic parameters like change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The negative Gibbs free energy change (${\Delta}G$ = -2.16~-6.55 kJ/mol) and the positive enthalpy change (${\Delta}H$ = + 23.29 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.551-558
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• 2005

The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the convection heat transfer coefficient which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind, curing condition and ambient temperature. At initial stage, the convection heat transfer coefficient is overestimated by the evaporation quantity. So it is essential to modify the thermal equilibrium considered with the boiling effect. From experimental results, the convection heat transfer coefficient was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent convection heat transfer coefficient including effects of velocity of wind, curing condition, ambient temperature and boiling effects was theoretically proposed. The convection heat transfer coefficient in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with curing condition. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the convection heat transfer coefficient by this model was well agreed with those by experimental results.

• Journal of fish pathology
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• v.26 no.2
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• pp.65-75
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• 2013

Population growth equation of scuticociliate Miamiensis avidus was obtained from the experimental results of in vitro culture condition to estimate the growth rate and carrying capacity from the growth equation. In addition, intraperitoneal infections into olive flounder Paralichthys olivaceus were carried out into 2 different conditions: different concentrations of M. avidus in same water temperature and same concentration of M. avidus in different water temperatures. Olive flounder mortality was threshold dependent with both the temperature and M. avidus density parameters. In this paper, we propose a mathematical model to study M. avidus growth in olive flounder based upon the interactions between parasite and host. The mathematical model was logistic growth differential equation (1.2). The parameters were found with Matlab program through the Levenberge-Marquardt method. In theorem, equilibrium values between the infected fish population and dead population could found. Our equilibrium points were a stable equilibrium and an unstable equilibrium. From the equation (1.6), it was possible to predict the amount of cumulative mortality of olive flounder along with the time after M. avidus infection.

• Analytical Science and Technology
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• v.24 no.5
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• pp.378-386
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• 2011

The goal of this study is to understand the influence of temperature on phosphorus release rate from soil into water. As the temperature increases, $PO_4$-P reaches equilibrium more quickly and the equilibrium concentration increases, and thus the $PO_4$-P concentration increases, and pH decreases. The $PO_4$-P concentration affects pH. $PO_4$-P released from turbidity is not adsorbed onto the turbidity. $PO_4$-P was independent on the turbidity and yet $PO_4$-P was steadily increasing. However, $PO_4$-P was dependent upon the turbidity concentration as the turbidity releases $PO_4$-P. The total phosphorous (T-P) and turbidity were directly linked because T-P changed with the turbidity. T-P includes the $PO_4$-P content of water and the phosphorus content of the turbidity. As the temperature decreases, density of water increases, and the precipitation of turbidity decreases, resulting in an increases in T-P concentration. As the temperature increases, the T-P concentration decreases, but the PO4-P release rate from turbidity increases. At the same time, even at different temperatures, the T-P concentrations of the samples were about the same. When the lake gets deepened, the water temperature decreases, hence, the phosphorus release rate from soil into water was decreased. This mechanism is of great interest because phosphorus is released from soil sediment into the lake water.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1045-1053
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• 2000

The adsorption and desorption of herbicides such as napropamide and pendimethalin was studied in three kinds of soil. sandy loam. silty clay and loam. The results of batch tests performed with various shaking time, pH, organic matter content and temperature in soil were summarized as follows. The shaking times reached to the equilibrium of the adsorption and desorption for napropamide and pendimethalin in soil were 12 and 6 hours. respectively. For each soil. the adsorption rates of napropamide were 23.35%. 31.57% and 25.95%, the desorption rates of them were 18.42%, 13.42% and 15.89%, respectively. And the adsorption rates of pendimethalin were 59.61%, 77.26% and 64.02%, and the desorption rates of them were 3.23%, 2.93% and 3.07%, respectively. The adsorption isotherms with the Freundlich equation showed better consistency than those with the Langmuir one. The adsorption was affected by the organic matter content when it exceed 2.0%. But if the organic matter content is below 2.0%, it was affected by the clay content. When the organic matter content is 0.95~7.45%, the adsorption coefficients ($K_{fa}$) of napropamide and pendimethalin were 1.17~2.50 and 4.74~16.08 and the desorption coefficients($K_{fd}$) of them were 5.33~34.06 and 24.25~134.00, respectively. Because of the physical adsorption between herbicide molecules and soil surface, little effect of pH variation of soils was appeared for the adsorption and desorption. Because of the solubility of herbicide is related to the temperature, the adsorption rate was decreased and the desorption rate was increased with the temperature increase, respectively.

• Clean Technology
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• v.7 no.4
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• pp.265-272
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• 2001

본 연구는 지구 온난화 현상의 주원인이 되는 $CO_2$ 를 화력발전소 연도가스로부터 분리 회수하기 위한 PSA 공정 개발용 기초자료를 습득하기 위하여 실시하였다. 연도가스와 유사한 조건하에서 국내에서 제조된 활성탄을 이용하여 이산화탄소 및 밸런스를 이루고 있는 질소 가스의 흡착평형 및 흡착속도 실험을 실시하였으며, 분석을 위하여 자체 제작한 장치(부피측정법) 및 TGA 장치를 각각 사용하였다. 이 연구에서 획득한 흡착등온선으로부터 사용된 흡착제가 이산화탄소의 분리에 적절한지 판단할 수 있었다. 또한, TGA에 의해 측정된 흡착속도 자료는 향후 사용될 흡착탑의 파과곡선 예측에 사용될 수 있다. 연구결과로부터 다음과 같은 사실을 알 수 있었다. 첫째, 낮은 흡착온도 일수록 흡착량이 많고 빠른 흡착속도를 나타내었다. 둘째, 압력이 높아질수록 흡착량은 증가하였다. 셋째, SGT활성탄이 SGA-100 및 SGP-100활성탄 보다 다소 많은 흡착량과 빠른 흡착속도를 보였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.103.2-103.2
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• 2015

10-3 Pa 이하의 고진공 환경과 $180^{\circ}C$ 이하의 극저온 환경에서 대형정지궤도위성의 고온 열평형 환경구현을 위한 열제어패널이 설계되었다. 열제어패널은 가로 2.2 m, 세로 2.6 m, 두께 2 mm의 구리판에 구리 튜브가 브레이징되어 있는 형태로 설계되었으며, 지상에서 6 m 이상의 높이에 설치되고 위성의 위치에 따라 이동이 가능해야 하기 때문에, 별도의 지지 구조물이 함께 설계되었다. 따라서, 열제어패널 설치 및 고정을 위한 지지구조물의 경우 160 kg의 무게를 견뎌내야 하며 이동 및 설치에 있어 구조적인 안전성이 확보 되어야 한다. 이에 본 연구에서는 상용유한요소해석 프로그램을 사용하여 열평형시험 시 위성체 상단부의 고온 환경모사를 위한 열제어패널 지지구조물에 대한 구조 안전성을 확인 하였다.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.1 no.1
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• pp.67-74
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• 1987

백열등의 POWER 평형 방정식을 통한 동작중의 필라멘트 온도와 광속 그리고 수명을 예측할 수 있는 이론이 제시되었다. POWER 평형 방정식을 설정함으로써 백열등 시스템을 모형화 하고, 방정식을 풀므로써 예측할 수 있는 형식으로 예측이론은 구성되었다. 가정용 110V전구에 대해 실측치와 비교해 본 결과, 충분한 타당성이 있음이 입증되었다. 본 이론의 정확한 예측성은 백열등을 해석, 이해하는 데 열쇠가 되는 제특성치를 제공할 수 있었는데 아직 생산단계에 있지 않은 크립톤가스등의 특성치도 추정할 수 있었다. 또 하나의 유용성은 백열등 설계를 위한 제 매개변수간의 관계식을 본 이론으로부터 도출하여 기존의 경험에만 의존하는 설계법을 보완하고 새로운 설계시 최적설계치를 선정할 수 있다는 점에 있다.

• Proceedings of the KAIS Fall Conference
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• 2010.11b
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• pp.684-687
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• 2010

본 논문은 복합사이클 발전플랜트의 폐열회수 보일러 최적운전 및 최적설계에 대한 새로운 접근 방법을 도출하기 위해 폐열회수 보일러에서 발생되는 증기로 증기터빈을 구동하는 하부사이클 효율을 검토하였다. 열역학 제1법칙 해석을 통해 하부사이클 에너지 평형을 검토하였고, 열역학 제2법칙을 통해 엑서지 평형을 검토하였다. 하부사이클 효율이 최대가 되는 폐열회수 보일러를 설계하기 위해서는 열역학 제1법칙을 해석할 경우 하부사이클 전체를 해석하여야 함을 알 수 있다. 하지만, 열역학 제2법칙을 통한 엑서지 해석을 행할 경우 하부사이클 효율이 최대가 되는 증발온도와 폐여회수 보일러에서 소모되는 엑서지가 최소가 되는 점이 일치함을 알 수 있었다. 따라서 본 논문을 통해 폐열회수 보일러에서 소모되는 엑서지 해석을 통해 하부사이클 효율이 최대가 되는 폐열회수 보일러 최적화가 가능함을 알 수 있다.

• Korean Journal of Food Science and Technology
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• v.27 no.2
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• pp.193-198
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• 1995

The changes in the rheological properties of soybean curd upon the various storage temperatures ($5{\sim}25^{\circ}C$) were measured by the stress-relaxation test and analysed by time-temperature superposition theory. As the storage temperature was lower, higher initial and equilibrium stress of soybean curd were observed. When the stress-relaxation curves were moved horizontally by using the shift-factor on the basis of reference temperature, the master curve was obtained. By applying master curve and shift-factor to the WLF (Williams-Landel-Ferry) equation, activation energy (30kcal/mol) was calculated and storage time at the specific temperature could be predicted, suggesting the equivalent shelf-life of soybean curd texture.