• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.6
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• pp.411-416
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• 2020

An optical arrangement has been set inside a photo-spectrometer to measure the reflectance of IR optics materials in mid IR range. The optical arrangement consists of equally spaced 4 gold coated full reflecting mirrors with the incidence angle of 45°. Baseline beam intensity I_B has been measured while the beam proceeds through the 4 mirrors. Reflectance of a mirror has been estimated from the I_B. And the beam intensity I_S with the specimen in the optical path has been measured with the 4th mirror replaced with the specimen. Reflectance of the specimen has been estimated from the value of I_S/I_B. Then the estimated reflectance has been put in Fresnel equation relating reflectance and refractive index(RI) to estimate the RI of the material. Measurement has been made for sapphire, germanium, magnesium fluoride, and zinc sulfide. The estimated RI of the materials are closely matching with reference data and the maximum difference less than 2% over the wavelength range 3-5㎛ for all materials tested. As an FT-IR photo-spectrometer with a broadband wavelength infrared light source is used, this method has the advantage of measuring the refractive index at multiple wavelengths in a single measurement.

• Journal of the Korean Chemical Society
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• v.42 no.3
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• pp.306-314
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• 1998

Acetolactate synthase (ALS) is the common enzyme in the biosynthesis of branched chain amino acids, Val, Leu, and Ile in bacteria, yeast, and higher plants. The enzyme is target site of several classes of structually diverse herbicides, including the sulfonylureas, the imidazolinones, the triazolopyrimidines, and the primidyl-oxy-benzoates. We have synthesized new triazolopyrimidine (TP) derivatives, and determined their inhibitory activities on barley ALS. $lC_{50}$ values for the active compounds were 3.2 nM-0.62 mM, and some of them appeared to be potent inhibitors. The progress curves for inhibition of ALS by TP4, a representative derivative, indicated that the extent of inhibition increased with incubation time. The inhibition of ALS by TP4 showed mixed-type inhibition with respect to pyruvate. Dual inhibition analyses of TP4 versus imidazolinone Cadre and feedback inhibitor Leu suggested that three different classes of inhibitors bind to ALS in a mutually exclusive manner. Chemical modification of tyrosyl residues of ALS decreased sensitivity of ALS to TP4, while modification of tryptophan and cysteine did not affect the sensitivity.

• Journal of the Korean Chemical Society
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• v.38 no.11
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• pp.827-832
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• 1994

The crystal structure of bis(N-methylphenazinium) bis(oxalato)palladate(II) has been determined by X-ray crystallography. Crystal data: ((C_{13}H_{11}N_2)_2[Pd(C_2O_4)_2]) $M_w$ = 672.93, Triclinic, Space Group P1 (No = 2), a = 7.616(8), b = 9.842(3), c = $20.335(7)\AA$, $\alpha$ = 103.53(3), $\beta$ = 90.00(5), $\gamma$ = $112.38(5)^{\circ}$, Z = 2, $V = 1363(2){\AA}^3\;D_c = 1.639\;gcm^{-3},\;{\mu} = 7.3\;cm^{-1},\;F(000) = 680.0$. The intensity data were collected with $Mo-K\alpha$ radiation (${\lambda}$= 0.7107\;\AA)$ on an automatic four-circle diffractometer with a graphite monochromater. The structure was solved by Patterson method and refined by full matrix least-square methods using Killean & Lawrence weights. The final R and S values were $R = 0.069,\;R_w = 0.050,\;R_{all} = 0.069$ and S = 5.45 for 3120 observed reflections. Both cation and anion complexes are essentially planar and have dihedral angles of 6.3(6) and $57.06(6)^{\circ}$ between their planes. The planar complex anions are sandwiched between slightly bent cations. The interplanar separations of two triads are 3.328 and 3.463 $\AA$, respectively. The triads are stacked along b-axis, but their orientations are different based on dihedral angle $59.08(9)^{\circ}$ of two complex anions.

• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.627-634
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• 1995

Layered double hydroxides ($Mg-Al-CO_3$ systems, LDH), which are hydrotalcite-like anionic clay minerals, having different $Mg^{2+}\;to\;Al^{3+}$ ratio were synthesized by coprecipitation method. The subsequent products were characterized by the following methods; elemental analysis, X-ray powder diffraction, thermal analysis (DSC and TGA), FT-IR and $^{27}$Al-MAS NMR. X-ray powder patterns showed that the products formed were layered structure materials. Two heat absorption peaks were observed around 20 ∼280$^{\circ}C$ (surface water and interlayer water) and 280∼500$^{\circ}C$ (water from lattice hydroxide and carbon dioxide from interlayer carbonate) in DSC diagrams, and they were quantitatively analyzed by TGA diagrams (in case LDH4 16.2% and 28.6% respectively). FT-IR spectra indicate that the interlayer carbonate ions occupied symmetrical sites between two adjacent layers in a parallel direction. $^{27}$Al-MAS NMR spectra show only single resonance (8.6 ppm) of the octahedrally coordinated aluminum similar magnesium. When LDH4 was calcined at 560$^{\circ}C$ for 3 hours in air, its layered structure was destroyed giving a mixed metal oxide. However it readily became rehydrated in aqueous chromate solution to its original structure.

• The Journal of Korean Academy of Sensory Integration
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• v.16 no.1
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• pp.25-34
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• 2018

Objective : This study aims to figure out the effect that sensory integration group therapy has on the fine motor, social interaction and playfulness of preschool children with intellectual disability. Methods : Participants were four children from three to five years old who were diagnosed with intellectual disabilities and they participated in twelve sessions of sensory integration group therapy, sixty minutes per session and once a week. Sensory integration group therapy was composed of parallel and peer play-centered gross motor activities, art activities and sensory plays that were related to each theme. Erhardt Developmental Prehension Assessment (EDPA), Penn Interactive Peer Play Scale (PIPPS) and Test of Playfulness (ToP) were used to evaluate participants' fine motor, social interaction and playfulness before and after the intervention. Results of fine motor, social interaction and playfulness before and after the intervention were compared using Wilcoxon matched-pair signed rank test. Results : After sensory integration group therapy intervention, the fine motor skills of participants did not show significant increases, but social interaction and playfulness showed significant increases (p< .05). Conclusion : Although sensory integration group therapy with preschool children with intellectual disability did not show positive improvement in fine motor skills, it showed positive effect on social interaction and playfulness. Group sensory integration therapy might be an intervention approach for all children with disabilities.

• The Journal of Engineering Geology
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• v.19 no.3
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• pp.351-363
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• 2009

Two orthogonal joint sets develop well only in sandstone beds in the sandstone-mudstone sequences of Gumi and Dasa outcrops within Cretaceous Gyeongsang Basin. And various joint data are similar in the beds of the same thickness in both outcrops, meaning that the joint sets were homogeneously produced by extensional deformation in the same regional stress field. Most of joints in the sandstone beds are orthogonal to, and confined by bed boundaries, which are believed to be formed by hydrofracturing during consolidation after burial. Two orthogonal joint sets are considered to be almost coeval on the basis of mutual abutting relationship which makes up fracture grid-lock and a product of rapid switching of ${\sigma}_2$ and ${\sigma}_3$ axes with constant ${\sigma}_1$ direction oriented to vertical. The joint sets in the sandstone beds show planar surfaces, parallel orientations and regular spacing, with joint spacing linearly proportional to bed thickness. The spacing distributions of the joints seem to correspond to log-normal to almost normal distribution in most of the beds. But multilayer joints do not display regular spacing and dominant size. Either joint set in this study is characterized by a high level of joint density and a saturated spacing distribution as indicated by the mode/mean ratio values and the Cv(coefficient of variance) values. Joint aperture tends to increase with the vertical length of the joints controlled by bed thickness.

• Journal of the Korean earth science society
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• v.21 no.3
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• pp.323-336
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• 2000

Ultramafic rocks in Choongnam area are mainly serpenitinites which are parent rock of talc and asbestos ore deposits. About 10 $^{\circ}$ NNE-trending parallel serpentinites masses occur as discontineous isolated lenticular intrusive bodies in Precambrian gneiss complex between Hongseong-Kwangcheon line and Onyang-Cheongyang line. The sizes of serpentinites vary from several centimeters to 1 kilometer in width and from several meters to 5 kilometers in length. The serpentinites show high SiO$_2$(39.99wt.% in average), MgO(38.46wt % in average), Cr(>1011ppm), Ni(>1660ppm), and Co(>80ppm). Most serpentinites contain serpentine more than 50%. Some serpentines contain original minerals such as olivine, pyroxene and chromite. Also, serpentinites body may contain a little serpentinized peridotite, and some talc and asbestos ore deposits. The original rocks of the serpentinites interpreted as Alpine type ultramafic rocks, and dunite and/or harzburgite which were originated from slightly depleted upper mantle(30${\sim}$40km deep), and emplaced in the crust through the large fault zones. It seems that main serpentinization from the original rocks was occurred during greenschist and/or amphibolite facies regional metamorphism in Choongnam area.

• Tunnel and Underground Space
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• v.18 no.1
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• pp.20-32
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• 2008

The study shows a method called a square-inventory method, which is a better and faster method than scanline survey and window method for an analysis of slope stability. The study area is located in the Changri area, Boeun-Gun, Chungbuk, and consists of many formations of the Okcheon Supergroup. Various types of failure are observed from the phyllite including the rocks in the study area. The physical properties of meta-sedimentary rocks are that minerals of the rocks are composed of microcrystalline quartz and sericite, which are arranged parallel to bedding (or schistosity) and crenulation cleavage. Therefore, such properties affect geotechnical ones of the rock. The slope stability are analyzed by selecting 3 areas, each of which are divided into 2 or 3 slopes of $1m{\times}1m$ area that represent each of 3 investigation sites. The possibility of wedge and toppling failure is very high in all 3 areas by using square-inventory method. Although possibility of plane failure is weak in the investigation site 2, the plane failures are frequently found from the slope of site 2. The bedding (or schistosity) plane and cleavage, another types of discontinuity coexist in meta-sedimentary rocks uulike igneous rocks, and therefore are important factors to be considered together with joint structures in th ε analysis of slope stability.

• 한국해양학회지
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• v.22 no.1
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• pp.43-56
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• 1987

A study on sedimentation, geochemical behavior and seismic stratigrapht of the continental shelf sediments along the Korea Strait and a part of south and southeast offshore area of the Korea Peninsula was carried out. In the inner shelf floor with depth ranging up to 80m zonal distribution patterns of mud, sandy silt, and silty sand were observed. In the outer shelf, however, coarse sandy sediments are dominant, and shills and gravels were frequently observed. These observations seem to confirm the Holocene sedimentary processes on the continental shelves off the south, south to east coasts of Korea discussed by Park (1985 and 1986) and Park and Choi (1986). The suface sediments (upper most 5cm thick)from selected 9 stations were analyzed for Al,Mn, Fe,Cr,Ni,Cu,Zn and Pb in order to study geochemical behavior of the sediments in the study area. All data were normalized to Al to com,pensate the size effect of the sediments.In general,inner shelf sediments show slight enrichment compared to the outer shelf sediments.In particular,Pb and Zn show heavy enrichment in most of the sediments.to degrees comparable to those observed at the polluted Kwangyang and Masan Bay sediments.Thus,it is considered that rapid migration or movement of fine-grained sediments in the study area does exist. Three seismic stratigraphic units were analyzed based on the seismic records.The acoustic basement the lower sedimentary deposit(B)and the upper deposit(A)were observed.The strong reflectivity R,in particular, between unit A and B is considered to be an erosinal unconformity during the last Glacial time.

• Journal of the Korean Society of Radiology
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• v.2 no.2
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• pp.31-38
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• 2008

Line scan diffusion weighted imaging (LSDI) pulse sequence for 0.32 T magnetic resonance imaging (MRI) system was developed. In the LSDI pulse sequence, the imaging volume is formed by the intersection of the two perpendicular planes selected by the two slice-selective $\pi$/2-pulse and $\pi$-pulse and two diffusion sensitizing gradients placed on the both side of the refocusing $\pi$-pulse and the standard frequency encoding readout was followed. Since the maximum gradient amplitude for the MR system was 15 mT/m the maximum b value was $301.50s/mm^2$. Using the developed LSDI pulse sequence, the diffusion weighted images for the aqueous NaCl solution phantom and triacylglycerol solution phantom calculated from the line scan diffusion weighted images gives the same results within the standard error range (mean diffusivities = $963.90{\pm}79.83({\times}10^{-6}mm^2/s)$ at 0.32 T, $956.77{\pm}4.12({\times}10^{-6}mm^2/s)$ at 1.5 T) and the LSDI images were insensitive to the magnetic susceptibility difference and chemical shift.