• Journal of the Korean earth science society
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• v.22 no.2
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• pp.120-129
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• 2001

A sand shoal (1300 m long and 400 m wide) with an orientation of north-south is formed on the lower tidal flat of Gomso Bay, southwestern coast of Korea. Surface bedforms, sedimentary structures, sedimentation rate, grain size distribution and can-corer sediments have been measured and analysed along the sand shoal proper zone B and its offshore zone A and onshore zone C during the period of 14 months. These three zones can be differentiated based on sedimentological characteristics: A zone - fine sand (3${\varphi}$ mean), linguoid-type ripples, 70 mm/month in sedimentation rate and no bioturbation, B zone - medium sand (2.5${\varphi}$ mean), dunes (4${\sim}$5 m in wavelength), 30 mm/month in sedimentation rate and no bioturbation, and C zone - coarse silt (5${\varphi}$ mean), sinuous-type ripples, 10 mm/month in sedimentation rate and well-developed bioturbation. These characteristics indicate that the zone C represents a relatively low-energy regime environment whereas the zone A corresponds to a relatively high-energy environment. The zone B would play an important role for a barrier to dissipate the approaching wave energy, resulting in maintaining of low-energy conditions in the inner part of Gomso-Bay intertidal flat behind.

• Resources Recycling
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• v.27 no.2
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• pp.32-37
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• 2018

This study was conducted as a preliminary study for the recycling of palladium and palladium oxide. In this study, thermodynamic equations for the formation of palladium oxide (PdO) are established. Palladium chloride is dissolved into hydrochloric acid to generate a palladium chloride solution. Nanosized palladium oxide powder with an average particle size below 30 nm were generated from this raw material solution by means of a spray pyrolysis process. The palladium oxide particles were composed of a single solid crystal. The results of XRD analysis showed that only a PdO phase of the generated powder was formed. And, the specific surface area of the generated palladium powder was approximately $32m^2/g$.

• Economic and Environmental Geology
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• v.46 no.5
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• pp.425-444
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• 2013

This study was carried out in order to determine the remediation of total petroleum hydrocarbons (TPHs), trichloroethylene (TCE), perchloroethylene (PCE), benzene, toluene, ethylbenzene and xylenes (BTEX) compounds for non-aqueous phase liquids (NAPLs) using in-situ air sparging (IAS) / vapor extraction (VE) with the marine sediments of Mandol, Hajeon, Sangam and Busan, South Korea. Surface sediment of Mandol area had sand characteristics (average particle size, 1.789 ${\Phi}$), and sandy silt characteristics (average particle size, 5.503 ${\Phi}$), respectively. Sangam surface sediment had silt characteristics (average particle size, 5.835 ${\Phi}$). Sediment characteristics before experiment in the Busan area showed clay characteristics (average particle size, 8.528 ${\Phi}$). TPHs level in the B1 column of Mandol, Hajeon, Sangam, and Busan sediments were 2,459, 6,712, 4,348, and 14,279 ppm. B2 (3 L/min) to B5 (5 L/min) columns reduced 99.5% to 100.0% of TCE and 93.2% to 100.0% of PCE. Removal rates of TCE, PCE, and BTEX are closely correlated (0.90-0.99) with particle sizes and organic carbon concentrations. However, TPHs (0.76) and benzene (0.71) showed the poorer but moderate correlations with the same parameters.

• Resources Recycling
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• v.25 no.6
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• pp.41-49
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• 2016

The present study was intended to prepare cobalt oxide ($Co_3O_4$) powder of average particle size 50 nm or less by spray pyrolysis reaction using the raw cobalt chloride ($CoCl_2$) solution, in order to identify the change in the nature of the particles according to the change in the nozzle tip size. When the nozzle tip was 1 mm, it turned out that most of the droplets were spherical and the surface showed very tight structure. The average particle size of the finally formed particles was 20-30 nm. When the nozzle tip size was 2 mm, some of the droplets formed were spherical, but a considerable part of them showed severely disrupted form. particles formed showed an average particle size of 30 - 40 nm. For the nozzle tip size of 5 mm, spherical droplets were almost non-existent and most were in badly fragmented state. The tightness of surface structure of the droplets has greatly been reduced compared with other nozzle tip sizes. Average size of the formed particles was about 25 nm. As the nozzle tip size increased from 1 mm to 2 mm and 3 mm, the intensities of the XRD peaks have changed little, but significantly been reduced when the nozzle tip size increased to 5mm. As the nozzle tip size increased from 1 mm to 2 mm, the specific surface area of the particles decreased, but the nozzle tip size increased to 5mm, the specific surface area remarkably increased.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.41 no.1
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• pp.46-53
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• 2005

This paper describes the mean grain size and shear strength properties related to subsidence characteristics using sediment samples and acoustic images obtained from artificial reef areas in Tongyoung and Jangsungpo offshore. The acoustic images collected from chirp sonar and side scan sonar show well the attitude/orientation, the distribution pattern, and the degree of subsidence of artificial reefs, suggesting the possibility of suitable site investigation and the management of the reefs using acoustic sonar. The sediments were largely composed of clayey silt and silty clay. The mean grain sizes in Tongyoung and Jangsungpo offshore show the ranges of 5${\sim}$9${\Phi}$ and 8${\sim}$9${\Phi}$, respectively. The shear strength was significantly increased at the depths of 20cm in Tongyoung offshore and 80cm in Jangsungpo offshore, corresponding to the subsidence depth of artificial reefs. The relationship between mean grain size and shear strength did not show a correlation, suggesting the shear strength does not totally depend on mean grain size. Provided subsidence characteristics with respect to various artificial reefs and seabed condition are investigated in more details, the constructing area of the reef can be more extended.

• Journal of Adhesion and Interface
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• v.3 no.2
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• pp.9-16
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• 2002

In the synthesis of water-based polyurethane using self-emulsification process, after being neutralized, polyurethane pre-polymers containing ionic pendant groups are dispersed by simple convective mixing. Preparation of dispersion is followed by chain extension reaction, which is considered as important step for growth of the molecular weight of polyurethane. In this work, pH variations in the aqueous phase were monitored during the chain extension process in the presence of water-soluble diamines. The optimum degree of chain extension and the average particle size in the polyurethane dispersions were examined with varying ionic pendent group contents, type of chain extenders, and feed rate of chain extenders, The initial pH value in the aqueous phase linearly increased and the optimum chain extension point could be obtained from the intersection of two linear lines having different slopes, All average particle sizes before chain extension reaction were almost same, however, the final average particle size increased as feed rates of chain extenders increased, In addition, as the ionic pendant group contents increased, the particle size decreased since the hydrophilicity and hydrodynamic volume increased. As carbon numbers of the chain extenders increased, the final particle size increased significantly. From the results, it was concluded that the chain extension reaction took place among the particles not only in a particle.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.24 no.1
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• pp.54-63
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• 2019

As a part of the national marine ecosystem monitoring program, the temporal and spatial variation of sedimentary environment and pollution of organic matters and trace metals from four major tidal flats, i.e., Ganghwa Is., Garolim bay, Jeung Is., Suncheon bay, was investigated for 3 yerars from 2015 to 2017. The mean grain size of the sediment was $5.0-5.3{\varnothing}$ at Ganghwa Is, $4.5-4.8{\varnothing}$ at Garolim bay, $6.1-6.5{\varnothing}$ at Jeung Is, and $8.6-8.7{\varnothing}$ at Suncheon bay. The mean grain size (Mz) tended to decrease from the north (Ganghwa Is.) to the south (Suncheon bay). The ignition loss (IL) was 15.5% in Suncheon bay in 2015, which was relatively high compared to other sites, but gradually decreased over time from 8.3% in 2016 to 7.0% in 2017. In Jeung Is. and Suncheon bay, the concentration of Zn and As exceeded the threshold effect level (TEL) at some stations, but the range of trace metals in the other sites was below the level. In Jeung Is., the Mz and concentration of trace metals except Hg was positively correlated (r= 0.40-0.88, P<0.05). On the other hand, Mz was negatively correlated with trace metals (P<0.05) in Suncheon bay. The geoaccumulation index ($I_{geo}$) to evaluate contamination status of sediments for trace metal was less than 1(not contaminated) for Cu, Zn, Pb, Cd and Hg, and 2-3 (moderately to strongly polluted) for As at several stations in Suncheon bay and Jeung Is.

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.288-288
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• 2018

점착성 유사는 응집 현상을 겪는 유사로, 응집 현상(Flocculation Process)는 응집 과정(Aggregation Process)와 파괴 과정(Breakup Process)의 경쟁으로 이루어진다고 여겨진다. 응집 현상을 통해 점착성 유사는 물과 점착성을 띠는 작은 입자들의 덩어리인 플럭(Floc)을 형성하여 흐름 내에서는 대부분이 플럭의 형태로 이동한다. 점착성 유사의 응집 모형 중 하나인 플럭 성장모형(Floc Growth Model, FGM)은 상미분 방정식으로 시간에 따른 플럭의 크기를 계산하는 모형이다. 응집과 파괴의 평형 상태에서 평균 입경을 얻는다. 이러한 FGM은 낮은 수치 계산 비용으로 합리적인 계산 결과를 얻을 수 있으며, 유사 이동 모형 혹은 흐름 모형과의 결합이 수월한 장점을 가진다. 또한, 닫힌 계(Closed System)에서 질량이 보존되는 특징이 있다. 반면, 결정론적인 특성을 띠면서 특정 플럭 크기만을 계산하기 때문에 점착성 유사의 입도 분포에 대한 정보를 얻을 수 없다. 결정론적 특성을 띠는 FGM에 추계학적 방법을 적용함으로써 특정 확률 분포형을 가지는 플럭의 입도 분포를 얻을 수 있다. 본 연구에서는 기 개발된 추계학적 FGM과 유사 이동 모형의 결합을 통해 변화하는 유수동역학적 조건에서 플럭의 입도 분포를 산정하고자 한다. 이전의 많은 실험실 실험 결과들은 부유가 발생한 상태를 유지하면서 수행되는 것으로, 특정 난류 특성(난류 소산 매개변수)와 특정 유사 농도 조건에서의 입도 분포를 얻는다. 그러나 하구부 및 하천의 하류는 조류의 영향을 받는 구간으로, 점착성 유사의 특성을 분석하기 위해서는 변화하는 유수동역학적 특성에 관한 고려가 필수적이라 할 수 있다. 결합된 점착성 유사 입도 분포 모형은 플럭의 침강과 재부유를 고려할 수 있는 특징을 가지며, 실측자료와의 비교를 통해 입도 분포를 합리적으로 모의하는 것으로 나타난다. 본 연구에서 개발된 점착성 유사 입도 분포 모형은 나아가 비점착성 유사의 입도 분포 모형과의 결합을 통해 두 종류의 유사가 혼재하는 구간에서도 합리적인 입도분포와 유사의 이동을 모의할 수 있을 것으로 예측된다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.7
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• pp.714-719
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• 2017

The controlled synthesis of inorganic materials with a specific size and morphology is an important factor in the development of new materials in many fields, such as nanoparticles, medicine, electronics, semiconductors, pharmaceutical sand cosmetics. Solution crystallization is one of the most widely used separation processes in the chemical and pharmaceutical industries. Calcium carbonate has attracted a great deal of attention in industry because of its numerous applications. The mean crystal size, crystal size distribution and morphology are important factors in the continuous crystallization process. In this study, the continuous crystallization of calcium carbonate by the calcium chloride process was investigated. The mean crystal size and crystal size distribution data were obtained by a particle size analyzer. The morphological imaging of the crystalswasper formed by SEM. Under steady state operation, the mean crystal size change was small, but increasing the input concentration and mixing rate increased the crystal size. In this operation, some aragonite was found, but the main crystal phase was calcite.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.5 no.2
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• pp.131-140
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• 2000

Heavy metals (Fe, Mn, Cr, Co, Cu, Ni, Zn, Pb) were determined in ninety-one surface sediments collected from Kwangyang Bay, south coast of Korea. The data show that the Fe, Cr, Ni, and Zn distribution in the bay can be described by metal vs. grain size relationship. However, the distribution pattern of Mn, Co, Cu and Pb were found to be changed because they are anthropogenically enriched to sediment. Correlation matrix and R-mode factor analyses revealed that two important factors controlling the distribution of metals in the bay are grain size and anthropogenic input.