• 분석과학
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• 제11권3호
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• pp.151-155
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• 1998

100 mM NaCl+27 mM $MgCl_2$ 용액에서, 도데실황산나트륨 (SDS)의 유무에 따른 1.0 mM 메틸비올로겐 ($MV^{2+}$)의 전기화학적 거동을 연구하였다. ${\Delta}E_p$(산화와 환원 봉우리전위 값의 차이) 대 - log[SDS]로 도시한 그림에서 두 선의 교차점을 임계미셀농도 (CMC)로 결정하였다. $Mg^{2+}$가 첨가되면, 유리탄소전극에 대한 효과적인 $MV{\cdot}^+$의 접근이 가능해지고 미셀형성도 지연되었다.

• 한국전기전자재료학회논문지
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• 제19권9호
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• pp.849-854
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• 2006

In this study, the hybrid electrodes, composed of the activated carbon powders and $LiCoO_{2}$ powders, were prepared as a cathode for the high-capacitance type hybrid capacitor, and the electrochemical properties of the hybrid electrodes were examined in terms of the weight composition and the milling time of $LiCoO_{2}$ powders. The specific volumetric capacities were increased with increasing of the composition of $LiCoO_{2}$ powders in the hybrid electrodes. On the other hand the coin cell capacitors, using the hybrid electrodes with $LiCoO_{2}$ poweders milled for 200 h, have exhibited the lower internal resistivities and the better capacity retention after 100 charge-discharge cycle than those of the coin cell capacitors using the hybrid electrodes with raw $LiCoO_{2}$ powders.

• 한국응용과학기술학회지
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• 제20권2호
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• pp.130-140
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• 2003

In order to improve the lithium ion battery's performance, the carbon nanofibers were introduced to the anode electrode fabricated with natural graphite particles. The influence of structural adjustment of the particles by the introduction method of carbon nanofibers and the content of carbon nanofibers on the electrical property and charge/discharge characteristics of the electrode were investigated. The electrode fabricated with the mixture of 10 wt% of carbon nanofibers grown separately and 90 wt% of graphite particles showed an excellent discharge capacity of 400 mAh/g and the improved cycle performance. The improved performance could be explained by that the carbon nanofibers shortened and uniformly distributed on the surface of graphite particles by ball milling increased the stability for the intercalation/deintercalation of lithium ion and increased the electrical conductivity due to the closed packing between graphite particles.

• 자원리싸이클링
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• 제12권2호
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• pp.45-53
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• 2003

2001년 국내에서는 총 491만톤의 석탄회가 발생되어, 이중 약 63.3%가 재활용되고 있으나 이들의 대부분은 콘크리트 혼합물과 시멘트 산업에 사용되고 있다. 그러므로 본 연구에서는 석탄회의 활용도를 높이기 위한 새로운 용도개발을 위한 목적으로 마찰대전법 대신 정전유도법을 사용하였다. 정전유도법을 적용하여 석탄회로부터 1%LOI 이하의 고순도 석탄회와 70%LOI 이상의 고탄소질 석탄회를 얻을 수 있음을 확인하였으며, 본 실험에서 두 전극간의 전위차는 8～16kV 범위로 적용하였다.

• 반도체디스플레이기술학회지
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• 제11권2호
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• pp.13-16
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• 2012

Zinc oxide (ZnO) films were deposited by an RF magnetron sputtering system with the RF power of 200W and 300W and flow rate of oxygen gases of 20 and 30 sccm, in order to research the growth of ZnO on carbon doped silicon oxide (SiOC) thin film. The reflectance of SiOC film on Si film deposited by the sputtering decreased with increasing the oxygen flow rate in the range of long wavelength. In comparison between ZnO/Si and ZnO/SiOC/Si thin film, the reflectance of ZnO/SiOC/Si film was inversed that of ZnO/Si film in the rage of 200~1000 nm. The transmittance of ZnO film increased with increasing the oxygen gas flow rate because of the transition from conduction band to oxygen interstitial band due to the oxygen interstitial (Oi) sites. The low reflectance and the high transmittance of ZnO film was suitable properties to use for the front electrode in the display or solar cell.

• 반도체디스플레이기술학회지
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• 제13권1호
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• pp.19-25
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• 2014

This study demonstrates transparent electrodes with characteristics desirable for touch screen panels using carbon nanotubes (CNTs). This has been accomplished by depositing CNTs on glass substrates via spray coating and then depositing thin conductive polymer films on the CNTs via spin coating. For all of the samples, such as CNTs, conductive polymers, and polymer-coated CNTs, the surface morphologies, sheet resistances, visible transmittances, chromatic properties are characterized as functions of their preparation conditions, such as the spray times for CNTs and the spin speeds for conductive polymers. The experimental results confirm that only the polymer-coated CNTs can satisfy all of the requirements that are required for electrodes of touch screen panels, such as the sheet resistance lower than $100{\Omega}/sq$, the visible transmittance higher than 80 %, and the yellowness smaller than 1.

• 반도체디스플레이기술학회지
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• 제13권1호
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• pp.7-12
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• 2014

In this study, we investigate the effects of corona-discharge pre-treatment on the properties of carbon nanotubes (CNTs) which are used as flexible transparent electrodes. The CNTs are deposited on PET (polyethylene terephthalate) substrates using a spray coating method. Prior to the deposition of CNTs, the PET substrates are corona-treated by varying the feeding directions of the PET substrate and the numbers of treatments. The variations in the surface morphologies and roughnesses of the PET substrates due to corona-treatment are characterized via atomic force microscopy (AFM). Dynamic contact angles (DCAs) of the corona-treated PET substrates are measured and analyzed as functions of the treatment conditions. Also, the sheet resistances and visible-range transmittances of the CNTs deposited on PET substrates are measured before and after bending test. The experimental results obtained in this study provide strong evidences that the adhesive forces between CNTs and PET substrates can be substantially enhanced by corona-discharge pretreatment.

• 한국환경보건학회지
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• 제26권4호
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• pp.110-114
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• 2000

Determination of mercury(II) using Nafion-EDTA-modified glassy carbon electrodes is proposed. it is based on the chemical reactivity of an immobilized modifier, Nafion-EDTA. Differential pulse voltammetry is employed, and the oxidation of complexes, at +0.43V vs. Ag/AgCl, is observed. For a 5-min preconcentration period, a linear calibration curve is obtained for mercury(II) concentrations ranging from 1.0$\times$ 10$^{-8}$ to 1.0$\times$10$^{-6}$ M. Further, when an approximate amount of copper(II) is added to the test solution, We demonstrate that at a preconcentration time of 5 min the Nafion-EDTA-modified glassy carbon electrode has a dynamic range of 2 orders of magnitude(from 10$^{-10}$ to 10$^{-8}$ M) and the detection limit is as low as 0.5$\times$ 10$^{-10}$ M(0.01 ppb). This method is applied to the determination of mercury(II) in sea water(4.0$\times$10$^{-10}$ M, 0.08ppb). The result agrees satisfactorily with the value(below 0.1 ppb) measured by using ICP/MS.

• 자원리싸이클링
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• 제25권3호
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• pp.82-87
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• 2016

차세대 이차전지로서 주목받고 있는 리튬-공기 전지와 소듐-공기 전지를 에테류계 전해질을 이용하였을 시 방전 후 생성물을 분석 하였다. FESEM을 통하여 확인한 결과 리튬-공기 전지와 소듐-전지의 방전 후 생성된 입자의 형태는 좁쌀 모양을 보였으며, 두 전지 시스템에서 큰 차이를 보이지 않았다. 하지만 XRD를 통하여 확인 하였을 시 리튬-공기 전지는 비정질 형태의 $Li_2O_2$ 그리고 소듐-공기에서는 결정질의 $NaO_2$가 생성되는 것을 확인 할 수 있었다. 본 연구를 통하여 차세대 전지 시스템으로 주목받고 있는 리튬-공기 전지와 소듐-공기 전지의 기본적인 구동 원리를 이해할 수 있었다.

• 한국표면공학회지
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• 제50권2호
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• pp.108-113
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• 2017

We investigated the effect of graphite electrode geometry and combination on nanocarbon material synthesis using underwater discharge plasma(UDP). The UDP system consists of two graphite electrodes and beaker filled with de-ionized water. A high voltage of 15 kV with a frequency of 25 kHz is applied to produce UDP using an alternating-current power source. The UDP system with conical electrodes produced the largest amount of products due to the concentration of electrical fields between electrodes. In addition, hollow-shaped stationary electrode and conical-shaped moving electrode stores discharge-induced bubbles and maintains longer reaction time. We found from Raman spectroscopy and electron microscopy that high quality carbon nanomaterials including carbon nanotubes are synthesized by the UDP system.