• Title/Summary/Keyword: 탄산화도

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Liming Materials and Desalinization of Marine Originated Tidal Soil (석회(石灰)의 종류(種類)와 해성간척지(海成干拓地) 토양(土壤)의 제염(除鹽))

  • Oh, Wang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.2
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    • pp.107-113
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    • 1990
  • In comparision with calcium sulphate, the effect of calcium-carbonate, -silicate and -hydroxide on desalinization of tidal saline soil was investigated in a continuous leaching column experiments after mixing with an equivalent amount of Ca to sodium plus magnessium in the saline soil. One half of liming materials was mixed to the top one-tenth of column soil and the remainder was spread on the surface. Results obtained are as follows ; 1. Gypsum made easy to percolate and desaline (Na) tidal marine soil but accumulated magnessium in subsoil. 2. $Ca(OH)_2$, $CaCO_3$, and $CaSO_3$ precipitated Mg in the soil which limes were mixed, but they washed down magnessium more severely from the immediate bellow the limed soil and less from the subsequent soil layers. This leaching was more severer at the treatment of $Ca(OH)_2$and lowest at the treatment of $CaSiO_3$. 3. The alkalinity of lime in addition to the dissociation of exchangeable Na raised pH of limed leached tidal soil and slowed down the percolation rate which retarded desalining Na from limed saline soils. This effect was most severe in the $Ca(OH)_2$ treated soil. 4. pH of leached soils was correlated possitively with exchangeable Na and negatively with exchangeable Mg giving follwing relationship pH= 7.77+0.489 Na/Mg r = 0.845.

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An Analysis of Consumer's Behavior of Milk Products Containing Human Lactoferrin (사람락토페린 함유 유제품의 젖소의 소비자행태분석)

  • 현병환;이경광
    • Proceedings of the Korea Technology Innovation Society Conference
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    • 1998.05a
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    • pp.10-10
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    • 1998
  • 생명공학의 혁신적 발명성을 매우 잘 보여주는 성공사례의 하나가 사람락토페린을 함유한 형질전환 젖소의 개발이다. 우유의 모유화를 내걸고 있는 본 연구는 국내·외에 막대한 잠재시장 규모가 예상되고 있다. 그러나 생명공학 제품은 ‘생물 재해(Bio Hazard)’에 대한 우려와 윤리문제를 제기할 수 있기 때문에 대중인식(Public Acceptance)에 대한 연구가 매우 중요한 의미를 가지는 것이다. 이러한 상황인식하에 사람락토페린을 함유한 유제품에 대한 소비자행태분석(Consumer Behavior Analysis)을 수행하게 되었다. 본 연구에 사용된 연구방법은 비시장가치평가법 중 임의가치평가법(CVM)을 사용하고 있다. 임의가치평가법은 선진국 특히 본 이론의 발상지인 미국에서 환경재기 가치를 측정하는 방법으로 사용되어 오고 있는데 이를 신상품 및 과학기술의 가치평가법으로 확대하여 연구하여온 필자의 일련의 연구중의 한 시도이다. 좋은 CVM 연구를 수행하기 위해서는 CVM이 요구하는 가치평가방법에 맞추어 설문서가 구성되고 분석되는 일이 무엇보다도 중요한 일이다. 본 연구에서는 CVM의 연구방법에 맞추어 사람락토페린 강화우유에 대한 소비자지불의향(Consumer Willingness to Pay) 조사와 더불어 사람락토페린 강화우유에다가 DHA, 칼슘 등 새로운 기능성 물질을 추가하여 더욱 좋은 기능을 첨가한 경우의 구입할 용의와 지불의향에 대한 조사를 수행하였다. 본 연구에서는 과학기술에 의해 탄생된 신상품에 대한 임의가치평가법의 적용이라는 새로운 시도의 연구라는점을 감안하여 본 연구를 바탕으로 더욱 새로운 문제제기와 추가적인 연구가 필요하다고 생각된다.적인 자세를 견지한다. 한편, 적응의 원리에 입각한 교육은 문화와 전통에 대한 피동적 전승을 넘어서 사회의 변화에 따라 교육체제와 내용을 바꾸는 등 적극적으로 변화에 대응하고, 이러한 변화를 주도할 인간육성에 힘을 기울이는 교육방식을 취한다. 시대적 변화의 소용돌이 속에서 교육은 이제 기왕의 많은 교육적 신화들을 타파하고 뉴 밀레니엄을 준비해야할 기로에 서 있다. 현재의 변화를 슬기롭게 대처하고 미래의 변화에 능동적으로 적응하는 인간을 육성하기 위한 오늘날 교육의 사명은 우선 미래사회를 위한 교육정책의 방향을 수립하는 일이다. 교육정책은 국가의 교육방침으로서 현실 교육문제의 해결도 중요하지만 미래의 발전을 기약할 수 있는 장기적인 비젼과 목표 속에서 정립될 필요가 있다. 이러한 의도하에 본 연구는 21세기를 대비한 교육정책의 방향을 탐색하고 그에 따른 정책적 과제를 제시하는 데 그 목적이 있다. 이러한 목적하에 본고는 \circled1 과거 우리 나라의 교육정책을 반성적으로 회고하고, \circled2 미래사회에 대한 전망과 교육적 시사점을 분석하며, \circled3 마지막으로 21세기의 변화에 적응하기 위한 교육정책의 방향과 과제를 내용으로 제시하고자 한다.탄산염으로의 전환이 진행되고 있다. 이러한 배경으로부터 Uchida그룹에서 개발한 FeiCr/AVTi재료와 현재 분리판 재료로 사용증인 SUS 310, S SUS 316재료에 대해. 산화성 분위기의 5기압까지의 가압하에서, Li-K, Li-Na탄산염에 대하여 부 식거동을 검토한 결과, 가압하에서 내식성이 향상되는 것이 발견되었다. 이유로서는 가압하에서 용융탄산엽의 증가된 산화력으로 보다 치밀한 내식성 산화물 피막

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Production of High purity $Mn_3O_4$Powder by Precipitation of Calcium fluoride in the Manganese Leaching Solution (망간침출액에서 불화칼슘화에 의한 高純度 망간酸化物의 製造)

  • 한기천;이계승;최재석;신강호;조동성
    • Resources Recycling
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    • v.11 no.1
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    • pp.3-8
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    • 2002
  • In order to make the high purity Mn$_3$O$_4$powder for the raw material of soft ferrite, Mn is extracted from the dust and the extracted solution is refined. The dust is generated in producing a medium-low carbon ferromanganese and contains 90% Mn$_3$O$_4$. Mn$_3$O$_4$in the dust was reduced into MnO by roasting with charcoal. Injection of the 180g/L of the reduced dust into 4N HCI solution increased pH of the leaching solution higher than 5 and then a ferric hydroxide was precipitated. Because the ferric hydroxide co-precipitates with Si ion etc, Fe and Si ion was removed from the solution and the about 10% Mn solution was obtained. The solution was diluted with water to Mn-15000 ppm and $NH_4$F was injected into the diluted solution at $70^{\circ}C$ to the F-3000 ppm. As a result, Ca ion is precipitated as $CaF_2$and the residual concentration of Ca was 14 ppm. Injection of the equivalent (NH$1.5M_4$)$_2$$CO_3$solution as 2 L/min at $25^{\circ}C$ into the above solution precipitated a fine and high purity $MnCO_3$powder. The deposition was filtrated and roasted at $1000^{\circ}C$ for 2 hours. As a result, $MnCO_3$powder is converted into $Mn_3$$O_4$powder and it had $8.2\mu$m of median size. The final production is above 99% $Mn_3$$O_4$powder and it satisfied the requirement of high purity $Mn_3$$O_4$powder for a raw material of soft ferrite.

Synthesis and Crystal Structure of Amorphous Calcium Carbonate by Gas-Liquid Reaction of System CaO-$C_2 H_5 OH$-$CO_2$ (CaO-$C_2 H_5 OH$-$CO_2$계의 기.액반응에 의한 비정질 탄산칼슘의 합성 및 결정구조)

  • Im, Jae-Seok;Im, Goeng
    • The Journal of Engineering Research
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    • v.6 no.1
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    • pp.97-109
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    • 2004
  • The synthesis and crystal structure of amorphous calcium carbonate obtained from gas-liquid reaction of CaO-$C_2 H_5 OH$-$CO_2$ system according to change of added amount of calcium oxide by blowing $CO_2$ gas and reaction time using ethanol and ethylene glycol were investigated by electric conductivity, X-ray diffraction, and scanning electron microscope. The powdery or gelatinous phases were prepared by passing $CO_2$ gas at a flow rate of 1$\ell$/min into the suspensions containing 10~40g of CaO in mixing solutions 900ml of $C_2 H_5 OH$- and 100ml of ethylene glycol. By rapid filtration and drying the both phases at $60^{\circ}C$ under reduced pressure, the phases converted to the spherical vaterite and amorphous phase. The stable phase of amorphous calcium carbonate(ACC) was formed in the region pH 7-9 but the formation regions of amorphous phase were remarkably affected by pH in the mother liquor. It seems that a part of ACC changed into chain calcite as an intermediate products. The initial reactants prior to the formation of precipitated calcium carbonate is ACC. And ACC is unstable in the aqueous solution and crystallizes finally to calcite by the through-solution reaction. Especially ACC was produced or gelatinous phase which precipitated from the reaction of CaO-$C_2 H_5 OH$-$CO_2$ system.

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Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

Extraction of Micro Filler from Bio-waste Material (Bio waste 소재로부터의 마이크로 필러 추출)

  • Nam, Gibeop;Song, Jung-Il
    • Composites Research
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    • v.31 no.5
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    • pp.209-214
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    • 2018
  • This paper explain about the development of environmental friendly, low cost and stable supply material i.e., rice husk and shell were used as micro incorporating bio waste filler. Those were processed by ball mill and analyzed through micro observation by FE-SEM, EDS and particle size distribution. The obtained filler was mixed with epoxy resin for the manufacturing of CFRP composite and study tensile properties. In EDS analysis main contents of rice husk and rice husk ash are C, O and Si. When rice husk was burned C and Si ration were increased. Shell powder has C, O and Ca. It caused $CaCO_3$ from shell. Surface weighted mean of rice husk powder is $6.19{\mu}m$ and volume weighted mean is $14.77{\mu}m$. And it has rod type particles which caused hair and husk structure parts. Surface weighted mean of rice husk ash powder is $1.55{\mu}m$ and volume weighted means is $8.20{\mu}m$. Surface weighted mean of shell powder is $2.53{\mu}m$ and volume weighted mean is $5.79{\mu}m$. The tensile decreased with increasing the content of micro filler in CFRP composites. In case of rice husk, the significant decrement of tensile strength was observed. and in case of shell powder, there is no effect of changes take place in tensile strength.

Effect of Redox Processes and Solubility Equilibria on the Behavior of Dissolved Iron and Manganese in Groundwater from a Riverine Alluvial Aquifer (만경강 하천변 충적 지하수의 용존 Fe와 Mn 거동에 대한 산화-환원 과정과 용해 평형의 효과)

  • Choi, Beom-Kyu;Koh, Dong-Chan;Ha, Kyoo-Chul;Cheon, Su-Hyun
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.29-45
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    • 2007
  • Biogeochemical characteristics involving redox processes in groundwater from a riverine alluvial aquifer was investigated using multi-level monitoring wells (up to 30m in depth). Anaerobic conditions were predominant and high Fe ($14{\sim}37mg/L$) and Mn ($1{\sim}4mg/L$) concentrations were observed at 10 to 20 m in depth. Below 20 m depth, dissolved sulfide was detected. Presumably, these high Fe and Mn concentrations were derived from the reduction of Fe- and Mn-oxides because dissolved oxygen and nitrate were nearly absent and Fe and Mn contents were considerable in the sediments. The depth range of high Mn concentration is wider than that of high Fe concentration. Dissolved organics may be derived from the upper layers. Sulfate reduction is more active than Fe and Mn reduction below 20 m in depth. Disparity of calculated redox potential from the various redox couples indicates that redox states are in disequilibrium condition in groundwater. Carbonate minerals such as siderite and rhodochrosite may control the dissolved concentrations of Fe(II) and Mn(II), and iron sulfide minerals control for Fe(II) where sulfide is detected because these minerals are near saturation from the calculation of solubility equilibria.

$\beta$-Mercaptoethanol이 돼지 체외수정란의 생산에 미치는 영향

  • 한만희;구덕본;이경광;박창식;서길웅;정영채;이규승
    • Proceedings of the Korean Society of Embryo Transfer Conference
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    • 2002.11a
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    • pp.81-81
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    • 2002
  • $\beta$-Mercaptoethanol($\beta$-ME)은 일반적으로 황화합물(thiol compounds)의 일종으로, 배양액 중에서 이황화결합(disulfide bonds)을 분해하여 일정한 물질의 산화.환원반응에 관여하며, 특히 cysteine이 cystine으로 산화되는 것을 차단함으로서 cysteine의 이용능력을 증대시키고, GSH의 합성을 촉진 및 증대시키는 것으로 알려져 있고, 각종 활성산소로부터 세포를 보호하는 역할을 수행하는 것으로 보고되었다. 특히, 돼지수정란의 체외배양체계에 유의적인 영향을 미치는 것으로 보고되었다(Abebydeera 등, Theriogenol., 50:747-756, 1998). 따라서 본 실험에서는 돼지난포란의 체외성숙시 $\beta$-ME의 첨가배양이 체외수정과 배발달에 미치는 영향에 관하여 조사하였다. 돼지난포란을 10% PFF, 0.1mg/ml cysteine, 10IU/m1 PMSG, 10IU/m1 hCG 및 10ng/m1 EGF가 첨가된 NCSU23 배양액에 $\beta$-ME를 각각 0, 25, 50 및 100uM을 처리하여 22시간 동안 배양을 실시하고, 성선자극호르몬이 배제된 배양액에서 추가로 22시간을 배양하여 체외성숙을 유도하였다. 체외성숙이 유기된 난자는 난구세포를 제거하고, 2.5mM caffeine과 0.1% BSA가 첨가된 mTBM배양액에 정자를 1.25 $\times$ $10^{5}$cells/ml의 농도로 5-6시간 동안 공동배양을 실시하여 체외수정을 유도하였다. 체외수정후 일부의 수정란은 12시간에 난자 급속 염색방법으로 염색하여 다정자침입률 및 자.웅전핵형성률 등을 확인하였다. 그리고 나머지1-세포기의 수정란은 0.4mg/ml BSA가 함유된 NCSU23 배양액에 30 embryos/50ul 소적으로하여 38.8$^{\circ}C$, 5% $CO_2$의 탄산가스 배양기에서 각각 7일간 배양을 실시하였다. 조사된 결과는 SAS/STAT를 이용하여 통계분석을 실시하였다. 체외수정 12시간 후에 난자 급속 염색법으로 염색을 실시한 결과, 모든 처리구에서 핵성숙률(76.4~95.2%), 정자침투율(51.1~66.9%), 웅성전핵형성률(95.2~100%), 다정자침입률(18.2~25.6%) 및 평균침입정자수(1.2~l.4개)에서 유의적인 차이가 인정되지 않았다. 체외배양 48시간 난할률을 조사한 결과, 처리구별 차이(53.9~67.9%)는 인정되지 않았으나, 배양 7일째 배반포형성률은 각각 14.5, 25.4, 17.3 및 12.4%로서 25uM의 $\beta$-ME처리구가 유의적(P<0.05)으로 높은 배발달률을 나타내었고, 총세포수에 있어서는 대조구와 처리구간 유의적인 차이가 인정되지 않았다. 따라서 돼지 난포란을 성숙배양할 때, 25uM $\beta$-ME를 첨가배양하는 것이 양질의 돼지체외수정란을 생산하는 하나의 방법으로 조사되었다.다.

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Carbonation Mechanism of Hydrated Cement Paste by Supercritical Carbon Dioxide (초임계 이산화탄소에 의한 시멘트 페이스트의 중성화 반응 메커니즘)

  • Park, Jeong-Won;Kim, Ji-Hyun;Lee, Min-Hee;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.5
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    • pp.403-412
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    • 2018
  • Recently, needs for utilization of recycled aggregate have been increasing. However, its utilization has been limited due to its high alkalinity, which mostly came from the unremoved cement paste particles that were attached at the surface of recycled aggregate. Various efforts has been made to reduce its alkalinity by using $CO_2$, but currently available methods that uses $CO_2$ generate the problem with pH recovery. Considering the fact that supercritical $CO_2$ ($scCO_2$) can provide more rapid carbonation of cement paste than by normal $CO_2$, $scCO_2$ was utilized in this work. The reaction between $scCO_2$ and hydrated cement paste has been systematically evaluated. According to the results, it was found that powder type showed higher carbonation compared to that of cube specimens. It seems the carbonation by $scCO_2$ has occurred only at the surface of the specimen, and therefore still showed some amount of $Ca(OH)_2$ calcium aluminates after reaction with $scCO_2$. With powder type specimen, all $Ca(OH)_2$ was converted into $CaCO_3$. Moreover, additional calcium that came from both calcium aluminate hydrates and calcium silicate hydrates reacted with $scCO_2$ to form $CaCO_3$. After carbonation with $scCO_2$, the powder type specimen did not show pH recovery, but cube specimens did show due to the presence of portlandite.

Development and Application of Anti-Corrosive Steel Using Electro-Deposition of Sea Water (2)- Evaluation of Application Rebar with Electro-Deposition Using Sea Water (해수전착 코팅을 이용한 내부식성 철근의 개발 및 적용성에 대한 연구 (2) -해수전착된 구조용 철근의 적용성 평가)

  • Kwon, Seung Jun;Lee, Sang Min;Park, Sang Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.155-162
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    • 2012
  • When RC (Reinforced Concrete) structures are exposed to sea water, steel corrosion can occur and this leads a degradation of structural performance. Referring the electro-deposition system with sea water from the 1st step research, durability and structural performance are evaluated in coated steel and RC members containing it in the 2nd research. In the durability performance test, Half Cell Potential test is performed and the coated steel is evaluated to have the high resistance to corrosion, which shows only 35% of corrosion velocity in normal (bare) steel. In the structural performance test, tensile strength, adhesive strength, and flexural/shear in RC member are performed. For the electro-deposit coated steel, increasing ratios of 3.2% and 8.8% are evaluated in the test of tensile strength and adhesive strength, respectively. For the structural test in RC member, there is no big difference between RC members with coated and non-coated steel in ultimate load and failure pattern It is evaluated that the chemical compound with $CaCO_3$ and $Mg(OH)_2$ from electro-deposition causes slightly increased structural performance. The electro-deposit coated steel can be more widely applied after performance verification from several tests like fatigue, resistance to impact, and long term-submerging test.