• Resources Recycling
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• v.12 no.4
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• pp.38-43
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• 2003

Phosphate is an essential material for the growth of organisms. However. since relatively small amount is required. a large amount of phosphate is abandoned in wastes and wastewater. which contaminate the ecological environment including aquatic system. Purpose of this study is to treat especially high concentrated phosphate wastewater by use of calcium precipitation method. The pH range considered was from 6 to 12 and the maximum removal of phosphate was attained at pH 12. The con-centration of phosphate was observed to decrease rapidly until a half amount of calcium ion to its equivalent for the formation of calcium phosphate precipitate was added. which resulted in the decrease of the remaining concentration of phosphate down to 0.0027 mM. The effect of fluoride ion was examined and the concentration ratio between the phosphate and fluoride ion did not have any significant influence on the removal efficiency of phosphate. The effect of pH was also investigated. With the increasing of the pH in solution, the removal rate of phosphate was increased. Also it was investigated that the effect of fluoride on the phosphate removal was not significant.

• Journal of Biomedical Engineering Research
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• v.19 no.5
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• pp.449-454
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• 1998

It is well known that new tissue or blood vessel is grown into a porous calcium phosphate ceramics used as a bone graft substitute due to their excellent biocompatibility. In this study, the most chemically stable porous $\beta$-crystalline form in various forms of calcium metaphosphate, Ca(PO$_3$)$_2$is prepared by the controlled thermolysis of monocalcium phosphate, Ca(H$_2$PO$_4$)$_2$.The diameter of cylindrical pores formed during cooling was controlled by a holding time at the melting point of a monocalcium phosphate and by the change of a crystallization temperature, to obtain the most appropriate size (about 200$\mu$m) of pores for the application of bone substitutes and matricuts. It was observed that the increasing holding time at the melting point of monocalcium phosphate results in the decreases of cylindrical pore sizes.

• Clinics in Shoulder and Elbow
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• v.12 no.1
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• pp.84-88
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• 2009

Purpose: Calcium pyrophosphate dihydrate crystal deposition disease(CPPD) is a disease of the elderly and extremely rare in young individuals. If young people develop CPPD crystal deposition disease, it may be associated with metabolic diseases, such as hemochromatosis, hyperparathyroidism, hypophosphatasia, hypomagnesemia, Wilson's disease, hypothyroidism, and gout. Materials and Methods: Therefore, in young-onset CPPD crystal deposition disease, an investigation of any predisposing metabolic conditions is warranted. Conclusion: We report a case of a young female patient who presented with idiopathic CPPD crystal deposition disease at 25 years of age.

• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.2
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• pp.196-202
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• 2018

In this study, we investigated phosphate removal efficiency according to pretreatment (pyrolysis temperature, pyrolysis time, particle size) of oyster shells as a basic study for their recycling. And XAFS analysis and isothermal adsorption experiments were performed to investigate the phosphate removal characteristics of oyster shells. As a result, the removal efficiency was good at $600^{\circ}C$ pyrolysis temperature with 6 hour pyrolysis time and 0.355 ~ 0.075 mm particle size. Isothermal adsorption experiments showed that the Langmuir model is suitable for adsorption of oyster shells. XAFS analysis showed that calcium phosphate formed on the oyster shell pyrolyzed at $600^{\circ}C$. In other words, it was confirmed that the formation of calcium phosphate by the calcium ion elution of the oyster shell contributes to the decrease of phosphate concentration.

• KOREAN POULTRY JOURNAL
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• v.29 no.4 s.330
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• pp.147-151
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• 1997

칼슘과 인은 닭이나 돼지가 요구하는 무기물의 대부분을 차지하며 또한, 무기물공급에 소요되는 비용의 거의를 차지한다. 어린동물에서의 골격성장, 성장한 동물에서의 난질과 골격강도는 경제적으로 매우 중요하듯이, 수많은 연구가 인공급원 이용률의 중요성을 주지했다. 반면에 칼슘공급원의 이용률에 대한 연구는 다소 미약했다. 사료용 인산염의 생체이용률에 관한 일반적인 경향을 이끌어 낼수 있음에도 불구하고, 상업적으로 이용가능한 인공급원에는 커다란 변이가 관찰되기 때문에 고품질의 사료제품을 유지하기 위해서는 인공급원의 꾸준한 평가제도가 요구된다. 현재로는 단위동물을 위한 인 이용률을 추정할 수 있는 실험실적 방법은 없고 동물 실험만이 유일한 방법으로 남아 있다. 인산염공급원의 칼슘 이용률은 인 이용률과 유사한 형태를 보인다. 석회석류와 굴껍질류 칼슘공급원의 입자크기에 크게 영향을 받는다. 사료내 칼슘수준이 적당할 경우에는 차이가 감소된다. 산란계에서 큰입자 석회석이나 굴껍질의 사용은 사료내 칼슘수준의 부적당, 사료 섭취감소 등과 같은 스트레스 상황에서는 난질 향상 효과가 있다. 산성용액에서의 용해도는 칼슘원마다 다르지만, 칼슘공급원에 따른 바람직한 용해속도에 관한 특별한 제안은 할 수가 없다.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.4
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• pp.241-248
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• 2009

A farming area located near an abandoned copper mine in GuPo-ri, Choongchung province is heavily contaminated with heavy metals such as As, Pb, Cd, Cu and Zn of which concentrations are higher than the values typically detected in Korean soil environment. In this work, laboratory and field studies were conducted to examine feasibility of using Ca-citrate-phosphate solution in stabilizing heavy metals in the polluted soils. In laboratory batch experiments with field soil, the addition of Ca-citrate-phosphate solution resulted in decrease of aqueous phase concentration of phosphate and improvement of heavy metal stabilization, compared to those for sterilized soil samples. This indicates that microbial uptake of phosphate may have provided positive effects on availability of phosphate toward heavy metal stabilization. According to microbial community analysis for the field experiment, the use of Ca-citrate-phosphate led to increased diversity of microbial populations, and strict anaerobic microorganisms such as Anaerofilum and Treponema became the most dominant populations in the solution-amended field experiments. These findings suggest that, when Ca-citrate-phosphate is used for heavy metal stabilization in soils, microbial processes may have important roles in improving the stabilization of heavy metals by providing reducing conditions to the treatment locations or/and by making phosphate available to heavy metal stabilization.

• Journal of the Korea Institute of Building Construction
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• v.17 no.2
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• pp.135-140
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• 2017

As an elementary investigation to develop vegetation concrete with a relatively low pH value, magnesia-phosphate composites (MPC) were examined according to the phosphate types including Monoammonium, Monosodium, Monopotassium, Monocalcium, Diammonium, Disodium, Dipotassium, and Diacalcium phosphates. All of the MPC binders, the ratio of magnesia to phosphate was fixed to be 7:3. MPC mortars activated with Disodium, Dipotassium, and Diacalcium phosphates showed no compressive strength gain, even at age of 28 days. Meanwhile, MPC mortars with Monoammonium and Monosodium phosphates developed 28-day compressive strength of more than 34MPa, and showed a relatively low pH value below 9.8. Hence, Monoammonium and Monosodium phosphates have potentials as an activator for producing MPC-based vegetation concrete.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.9
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• pp.907-912
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• 2008

In order to reduce the availability of dissolved inorganic phosphorus in surface water, lakes, and estuaries, black shale and zero valent iron can be used as reacitve materials. Sorption of phosphate to sampled sediment, black shale, and zero valent iron was quantitatively evaluated in this research. Effect of coexistence of calcium was also tested, since coexisting ions can enhance the precipitation of phosphate. An empirical kinetic model with fast sorption(k$_t$), slow sorption(k$_s$), and precipitation(k$_p$) was well fitted to experiment data from this research. Langmuir and Freundlich sorption isotherms were also used to evaluated phosphate maximum sorption capacity. Calcium ions at 0, 1 and 5 mM affected the precipitation kinetic coefficient in empirical kinetic model but did not have impact on the maximum sorbed concentration.

• Proceedings of KOSOMES biannual meeting
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• 2017.11a
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• pp.76-76
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• 2017

• Journal of the Korean Ceramic Society
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• v.37 no.11
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• pp.1105-1113
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• 2000

Bioglass 조성 중 45S5 (46.1SiO$_2$.24.4$Na_2$O.26.9CaO.2.6P$_2$O$_{5}$ : 몰비)를 기본 조성으로 하여 46P4 (46.2SiO$_2$.49.5CaO.4.3P$_2$O$_{5}$ : 몰비), 46SF (46.1SiO$_2$24.4$Na_2$O.16.1CaO.2.6P$_2$O$_{5}$.10.8CaF : 몰비) 그리고 55SF (55.1SiO$_2$.9.2$Na_2$O.27.8CaO.3.4P$_2$O$_{5}$.4.5CaF : 몰비)를 제조하여 tris-완충용액 및 유사 생체용액(simulated body fluid)에서 반응시킨 후 생체활성유리의 표면에 생성되는 아파타이트 결정형에 관하여 연구하였다. 45S5 유리를 tris-완충용액에 반응시켰을 경우 6시간 반응시부터 수산화 아파타이트가 생성되었으나 유사 생체용액에 반응시켰을 경우에는 24시간까지도 수산화 아파타이트 결정이 생성되지 못하고 비정질 상태의 칼슘 인산염만 형성되었다. tris-완충용액에 각 조성의 유리를 200시간 반응시킨 경우 불소를 함유하지 않은 유리에서는 잎사귀 모양의 수산화 아파타이트가, 불소를 함유한 유리에서는 구상의 플루오르 아파타이트가 형성되었다. 그러나 유사 생체용액에 각 조성의 유리를 200시간 반응시켰을 경우 불소를 함유하지 않은 유리에서는 누에고치형의 수산화 아파타이트가 형성되었고 불소를 함유한 유리에서는 무정형의 칼슘 인산염이 생성되었다.