• Title/Summary/Keyword: 철 나노입자

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An update technology trend in iron oxide (산화철산업의 개발동향)

  • Sohn Jin-Gun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.12a
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    • pp.17-26
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    • 2004
  • 산화철의 국제동향에 대하여 각 지역 간의 수출입동향과 최근에 급속하게 성장하고 있는 중국의 산화철업계 동향에 대하여 소개하였다. 특히 세게 산화철 교역량은 산화철업계의 기술발전과 각 국이 처한 환경에 따라 변화하며, 산화철의 주요용도중 하나인 안료용도의 경우 건축경기에 큰 영향을 받는다. 중국의 산화철업계는 전반적으로 크게 성장한 반면 다국적 기업의 진출에 따른 기술력 향상과 반대급부로 경쟁력 약한 중국내 기업정리 등이 수반되었다. 산화철산업의 발전을 위하여는 타 소재와의 가격경쟁력도 중요하지만 새로운 응용분야의 개척이 필요하다 본 기술자료에서는 최근에 관심이 집중되는 산화철 나노분말에 대하여 신용도 및 특성에 대하여 소개하였다.

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Photoelectrochemical Performance of Hematite Nanoparticles Synthesized by a DC Thermal Plasma Process (DC 열플라즈마를 이용하여 제조된 산화철 나노입자의 광 전기화학적 물분해 효율 증가연구)

  • Lee, Chulho;Lee, Dongeun;Kim, Sunkyu;Yoo, Hyeonseok;Choi, Jinsub
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.306-310
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    • 2015
  • In this research, hematite nanoparticles were synthesized by DC thermal plasma process to increase the overall surface area. The effect of binders on hematite electrodes was investigated by changing the type and composition of binders when preparing electrodes. Nitrogen gas was also added to the DC thermal plasma process in order to dope the hematite with N for enhancing photoelectrochemical properties of hematite nanoparticles. The efficiency of water splitting reaction was measured by linear sweep voltammetry (LSV) under solar simulator. In LSV measurements, the onset potential and maximum current density at a fixed voltage were measured. The durability of electrodes was checked by repeating LSV measurements. CMC (carboxymethyl cellulose) binder with 50 : 1 composition exhibits the highest current density of $12mA/cm^2$ and CMC binder with 20 : 1 composition, showing the initial current density of $3mA/cm^2$, endures 20 times of repetitive LSV measurements. Effects of nitrogen doping on hematite nanoparticles were proven to be insignificant.

Surface Mmodification of Poly(DL-lactide-co-glycolide) Nanoparticle (Poly(DL-lactide-co-glycolide) 나노입자의 표면 수식)

  • Oh, Yu-Mi;Jung, Taek-Kyu;Chi, Sang-Cheol;Shin, Byung-Cheol
    • Journal of the Korean Chemical Society
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    • v.47 no.6
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    • pp.601-607
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    • 2003
  • We studied on preparation of nanoparticles modified surface using biodegradable polymer, poly(DL-lactide-co-glycolide) (PLGA). Two kinds of PLGA nanoparticles were prepared by a spontaneous emulsification solvent diffusion (SESD) method using cetyltrimethylammonium chloride (CTAC) and tetradecyltrimethylammonium bromide (TTAB) as a cationic surfactant and polyethylene glycol-block-polypropylene glycol copolymer (Lutrol F68) as a nonionic surfactant. Model protein was coated on the surface of nanoparticles by the ionic complexation. The model protein was that influenza vaccine ($H_3N_2,\;H_1N_1$, B strain) labeled with NHS-fluorescein. The sizes of cationic nanoparticles were 140-160 nm and the surface charges were 50-60 mV. The sizes of nonionic nanoprticles were 80-90 nm and the surface charge was -10 mV. After coating vaccine on the surface of nanoparticles, the sizes of cationic nanoparticles were increased to 380-400 nm and the size of nonionic nanoparticles was not increased. The amount of coated vaccine on the cationic nanoparticles was 22.73 ${\mu}g$/mg.

An update technology trend in iron oxide (酸化鐵産業의 開發動向)

  • Sohn, Jin-Gun
    • Resources Recycling
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    • v.13 no.6
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    • pp.3-8
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    • 2004
  • From the world wide globalization of iron oxide industry, the global trend in iron oxide is changed rapidly and the production of iron oxide is increasing in China, currently. Iron oxide have a broad range of applications from construction materials to medical area. Therefore, it is expected that nanoparticulate iron oxides have many applications, too. A series of interesting applications in entirely different fields are introduced.

Effect of Fluidized Bed Powdered Activated Carbon Impregnated by Iron Oxide Nano-particles on Enhanced Operation and NOM Removal of MF Membrane System (산화철 나노입자 표면개질 분말활성탄 유동층에 의한 MF 막 분리 공정의 운전 및 NOM 제거 효율 향상)

  • Kim, Sung-Su;Seo, Gyu-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.332-339
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    • 2011
  • Effects of powdered activated carbon impregnated by iron oxide nano particle (Impregnated PAC) on the microfiltration (MF) membrane system performance in NOM removal from water were investigated in this study. A fluidized bed column was employed as a pretreatment of MF membrane process. The Impregnated PAC bed was stably maintained at an upflow rate of 63 m/d without leakage of the Impregnated PAC particles, which provided a contact time of 29 minutes. A magnetic ring at the upper part of the column could effectively hold the overflowing discrete particles. The Impregnated PAC column demonstrated a significant enhancement in the MF membrane performance in terms of fouling prevention and natural organic matter (NOM) removal. Trans-membrane pressure of the MF membrane increased to 41 kPa in 98 hours of operation, while it could be maintained at 12 kPa with the Impregnated PAC pretreatment. Removal of NOM determined by dissolved organic carbon and UV254 was also enhanced from 46% and 51% to 75% and 84%, respectively, by the pretreatment. It was found that the Impregnated PAC effectively removed a wide range of different molecular-sized organic compounds from size exclusion analysis.

Spray Drying of Polymer-Adsorbed Drug Nanocrystal Particles (고분자가 흡착된 약물 나노결정입자의 분무 건조)

  • Choi, Ji-Yeun;Yoo, Ji Youn;Kim, Hwan Yong;Jung, Sang Young;Heo, Yoon Suk;Hong, Sung Chul;Lee, Jonghwi
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.106-110
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    • 2006
  • If drugs are made from nanoparticles, their formulations can be more effective than the conventional ones. Especially, water insoluble drugs having low absorption rates into our body could show improvement in their adsorption and bioavailability by decreasing their particle sizes to nanometers. In this study, polyvinylpyrrolidone (PVP) and various sugars were employed as stabilizers for the nanoparticles of a water insoluble drug, Itraconazole. Nanoparticles were successfully produced by the wet slurry process for five days. Then, spray drying converted the aqueous dispersions into dry powders, and the redispersibility of dried nanoparticles into water was investigated. The effects of temperature, pressure, and flow rate were studied to understand the importance of processing variables on redispersibility. It was found in particle size analysis that nanoparticles containing sugars have better redispersibility than those without sugars. Additionally, the mainly spherical morphology of dried nanoparticles was identified by SEM (Scanning Electron Microscopy) and AFM (Atomic Force Microscopy).

Preparation of Cellulose Nanoparticles Loaded with Retinyl Palmitate (레티닐 팔미테이트가 봉입된 셀룰로오스 나노입자의 제조)

  • Lee, Jeong-Soon;Ma, Sang-Chol;Kang, Ki-Choon;Pyo, Hyeong-Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.3
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    • pp.175-181
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    • 2008
  • Cellolose nanoparticles loaded with retinyl palmitate were prepared by modified spontaneous emulsification solvent diffusion method. We used polysorbate 20, polysorbate 60, and PPG-26-Buteth-26/PEG-40 Hydrogenated castor oil as dispersion medium. The optimum condition for particle size of cellulose nanoparticles was 1w/v% ethyl cellulose with, 3w/v% polysorbate 60 solution. And The optimum condition for leading amount of retinyl palmitate of cellulose nanoparticles was 2w/v% ethyl cellulose with 1w/v% polysorbate 60 solution. Also, we found that this optimum condition can be applicable to other active compounds.

Immobilization of As and Pb in Contaminated Soil Using Bead Type Amendment Prepared by Iron NanoparticlesImpregnated Biochar (철 나노 입자가 담지된 바이오차 기반 비드 형태 안정화제를 이용한 비소 및 납 오염토양의 안정화)

  • Choi, Yu-Lim;Kim, Dong-Su;Kang, Tae-Jun;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Environmental Impact Assessment
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    • v.30 no.4
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    • pp.247-257
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    • 2021
  • In this work, Iron Nano-Particles Impregnated BioChar/bead (INPBC/bead) soil amendment was developed to increase biochar's reactivity to As in soil and preventing possible wind loss. Prior to preparation of INPBC/bead, INPBC was produced utilizing lignocellulosic biomass and Fe(III) solution in a hydrothermal method, followed by a calcination process. Then, the bead type amendment, INPBC/bead was produced by cross-linking reaction of alginate with INPBC. FT-IR, XRD, BET, and SEM-EDS analyses were utilized to characterize the as-synthesised materials. The particle size range of INPBC/bead was 1-4 mm, and different oxygen-containing functional groups and Fe3O4 crystalline phase were produced on the surface of INPBC/bead, according to the characterization results. The soil cultivation test was carried out in order to assess the stabilization performance of INPBC/bead utilizing As and Pb-contaminated soil obtained from an abandoned mining location in South Korea. After 4 weeks of culture, TCLP and SPLP extraction tests were performed to assess the stabilization efficacy of the amendment. The TCLP and SPLP findings revealed that raising the application ratio improved stabilizing efficiency. The As stabilization efficiency was determined to be 81.56 % based on SPLP test findings for a 5% in (w/w) INPBC/bead treatment, and the content of Pb in extracts was reduced to the limit of detection. According to the findings of this study, INPBC/bead that can maintain pH of origin soil and minimize wind loss might be a potential amendment for soil polluted with As and heavy metals.