• Title/Summary/Keyword: 철부식

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Development and Application of Anti-Corrosive Steel Using Electro-Deposition of Sea Water (1) -Development of Electro-Deposition System Using Sea Water (해수전착 코팅을 이용한 내부식성 철근의 개발 및 적용성에 대한 연구 (1) -해수전착 코팅 시스템 개발)

  • Kwon, Seung Jun;Lee, Myeong Hoon;Park, Sang Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.5
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    • pp.78-87
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    • 2012
  • This study is for developing a system for electro-deposition utilizing sea water containing various ions like calcium and magnesium. This is the first step research for the final goal which is a development of anti-corrosive steel for RC structure, so that this paper is mainly focused on the development for electro-deposition system. Optimum conditions for steel coating is obtained through various tests considering anode type, temperature, duration time, and current density. The composition of electro-deposition is analyzed through SEM, EDS, and XRD and it is evaluated to be $CaCO_3$ and $Mg(OH)_2$. Through measuring polarization potential and current density in the coated steel, the coating layer from the developed system is evaluated to have high resistance to steel corrosion. Additional tests and discussions on durability and structural performance in the coated steel from this work will be performed for the second step research.

Conservation of the Metal ball fired by a cannon (창녕 화왕산성 출토 비격진천뢰(飛擊震天雷)의 보존)

  • Gwak, Hongin;Hwang, Jungsoon;Yu, Heisun;Chung, Kwangyong
    • Conservation Science in Museum
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    • v.7
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    • pp.25-31
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    • 2006
  • We performed the conservation treatment for Bigyeokchinjeonnoe (A kind of time bomb in the Joseon Dynasty) excavated from Hwawangsanseong Fortress in Changnyeong-gun, Gyeongsangnam-do Province. Part of the Bigyeokchinjeonnoe has been lost; we did not restore the lost part so that one can observe the inside through it. The results of X-ray investigation and C. T (Computed Tomography) scan proved the generation of many blowholes around the molding line during the casting process; a hole in the casting mold to maintain inner mold during casting was identified on the surface and traces of fortifying this part with iron plate were also identified. The main ingredients of the blue corrosion on the surface were identified as O, Fe, P, Si and Al by SEM/EDS analysis. The result of XRD analysis identified the blue corrosion as vivianite [Fe3(PO4)2·8H2O]. The metal structure clarified its material was gray cast iron.

Effect of Induction Heat Bending Process on the Corrosion Properties of 316 Stainless Steel Pipes for Nuclear Power Plant (원자력발전소용 316 스테인리스강 배관의 부식특성에 미치는 유도가열벤딩공정의 영향)

  • Shin, Mincheol;Kim, Young Sik;Kim, Kyungsu;Chang, Hyunyoung;Park, Heungbae;Sung, Giho
    • Corrosion Science and Technology
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    • v.13 no.3
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    • pp.87-94
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    • 2014
  • Recently, the application of bending products has been increased since the industries such as automobile, aerospace, ships, and plants greatly need the usage of pipes. For facility fabrication, bending process is one of key technologies for pipings. Induction heat bending process is composed of bending deformation by repeated local heat and cooling. Because of local heating and compressive strain, detrimental phases may be precipitated and microstructural change can be induced. This work focused on the effect of induction heat bending process on the properties of ASME SA312 TP316 stainless steel. Evaluation was done on the base metal and the bended areas before and after heat treatment. Microstructure analysis, intergranular corrosion test including Huey test, double loop electropotentiokinetic reactivation test, oxalic acid etch test, and anodic polarization test were performed. On the base of microstructural analysis, grain boundaries in bended extrados area were zagged by bending process, but there were no precipitates in grain and grain boundary and the intergranular corrosion rate was similar to that of base metal. However, pitting potentials of bended area were lower than that of the base metal and zagged boundaries was one of the pitting initiation sites. By re-annealing treatment, grain boundary was recovered and pitting potential was similar to that of the base metal.

Serviceability Assessment of Corroded Subsea Crude Oil Pipelines (부식된 해저 원유 파이프라인의 사용적합성 평가)

  • Cui, Yushi;Kim, Dong Woo;Seo, Jung Kwan;Ha, Yeon Chul;Kim, Bong Ju;Paik, Jeom Kee
    • Journal of the Society of Naval Architects of Korea
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    • v.52 no.2
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    • pp.153-160
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    • 2015
  • Pipelines are one of the most important structures in subsea equipment. It is the main equipment for transportation of crude oil and natural gas to the downstream facilities. Crude oil and natural gas leak will be carry out not only political and financial issues but also pollution to the environment. Inaccurate predictions of corrosion behavior will make hazardous consequences. The serviceability assessment of corroded structures is essential especially for subsea pipelines. As corrosion is concerned, the effects of failure due to significant reduction will make it hard to the pipeline operator to maintain the serviceability of pipelines. In this paper, the serviceability assessment of corroded crude oil pipeline is performed using the industry design code (Shell92, DNV RP F101, ASME B31G, BS 7910, PCORRC) and FEA depending on corrosion area. In last step, the future integrity of the subsea crude oil pipeline is assessed to predict the remaining year in service of crude oil pipelines.

Nondestructive Analysis on Miniature Pagoda of Sarira Reliquary (Treasure No. 259-2) from Sujong-sa Temple (수종사(水鍾寺) 석조(石造) 부도내(浮屠內) 금동제구층탑(金銅製九層塔)(보물(寶物) 제(第)259-2호(號))의 비파괴(非破壞) 분석조사(分析調査))

  • Kwon, Hyuknam;Yu, Heisun;Kang, Hyungtae
    • Conservation Science in Museum
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    • v.4
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    • pp.57-61
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    • 2003
  • From the stupa of Sujongsa-Temple, located in Yangpyeong, Gyeonggi-do province, was excavated a celadon jar with lid, a gilt-bronze nine-storied miniature pagoda and a silver-plate hexagonal miniature shrine, etc. Among them, the gilt-bronze miniature pagoda has been known as a gilt-bronze product since most of its surface has copper tint and the base part has bronze corrosion. Its formal title registered on the Cultural Properties Administration also begins with "a gilt-bronze". However, it was supposed to be a gold product in many aspects: the color and status of the surface, degree of the bronze corrosion creation and the metal thread joining the wind bell. So the necessity to prove its material by a scientific analysis was raised. We examined it with nondestructive method. The results were traces of open-working on many parts of the surface, but no traces of gilding. Moreover, as we perform an XRF analysis, the main component were gold and silver(16%) and some impurities such as copper and iron were found. Therefore, it could be inferred that this miniature pagoda is a gold product.

Development of Torsion Bar for Antiroll-Bar Assembly for Express Train (고속철도용 안티롤바 어셈블리의 토션바 개발)

  • Tominaga, Yasutoshi;Pyun, Young-Sik;Kim, Dong-Il;Choe, Do-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.9
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    • pp.979-984
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    • 2012
  • An antiroll-bar assembly is a precision component that is designed to control the rolling of railway cars. It is important for ensuring a safe and comfortable ride. A torsion bar is the main part of the antiroll-bar assembly. Now, this part is classified as a consumable, and it is imported into Korea from France. Therefore, there is a strong need to domestically develop a torsion bar suitable for Korean conditions and to reduce cost and improve quality. In this study, an antiroll bar is developed, and it is analyzed and tested by using a road histogram measured on Korean railroads. This bar shows satisfactory results in a comparison with the imported bar. It has a novel design featuring a ring cover made of SUS steels to prevent the corrosion of the torsion bar. Its safety is examined through CAE analysis and wear tests. It is found that its design does not result in a significant difference in static and fatigue safety. Two different SUS steels were investigated in terms of their wear resistance, and the best one was adopted.

Comparing Erosion-Corrosion Behaviors of Carbon Steel and Hadfield Steel According to Pipe Forming (탄소강 및 해드필드강의 파이프 조관에 따른 침식부식 거동에 대한 비교연구)

  • Yun, Duck Bin;Park, Jin Sung;Lee, Sang Cheol;Choi, Jong Gyo;Hwang, Joong Ki;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.21 no.3
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    • pp.209-220
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    • 2022
  • Erosion-corrosion behaviors of Hadfield steel under a neutral aqueous environment with fine SiO2 particles were examined and compared with those of conventional carbon steel. A range of electrochemical experiments (potentiodynamic polarization, linear polarization, and impedance), immersion test, and slurry pot test (i.e., erosion-corrosion test) were performed. Results showed that the Hadfield steel composed of austenitic matrix with (Fe,Mn)-based carbide had lower corrosion potential and higher corrosion current density than carbon steel with a typical ferrite/pearlite structure. In addition, pipe forming increased total corrosion rates (i.e., pure corrosion and erosion-enhanced corrosion rates). Nevertheless, the erosion-corrosion rate of Hadfield steel was much smaller. Morphological observation showed that local damage in the form of a crater by erosion-corrosion was more noticeable in carbon steel. The higher resistance of Hadfield steel to erosion-corrosion was attributed to its lower total erosion rates (i.e., pure erosion and corrosion-enhanced erosion rates) highly depending on surface hardness. This study suggests that Hadfield steel with higher resistances to flowing erosion-corrosion in an aqueous environment can be applied widely to various industrial fields.

Analysis of Regional Relative Humidity Environment for Dehumidification System Efficiency of Suspension Bridge Cable (현수교 케이블 송기시스템 효율화를 위한 지역별 상대습도 환경 분석)

  • Seo, Dong-Woo;Kim, Ga Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.7
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    • pp.88-94
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    • 2018
  • This study examined the safety of a cable stayed bridge caused by damage to the cable system. Many cable-supported bridges, including cable-stayed bridges and suspension bridges, have been constructed on the Korean peninsula. This requires efficient maintenance and management because this structure has complex structural components and systems. This large structure also often faces risks either from manmade causes or natural phenomena. In 2015, the cables on one cable-stayed bridge in South Korea was struck by lightning, which led to a fire on the cables. These cables were damaged, which put the bridge at risk. This bridge was back in use after a few weeks of investigations and replacements of the cables but this was done at enormous social and economic expense. After this event, risk-based management for infrastructure is required by public demand. Therefore, this study examined the risks on the cable system due to potential damage. In this paper, a one cable-stayed bridge in South Korea was selected and its safety was investigated based on the damage scenarios of cable system for efficient and prompt management, and to support decision making. FEM analysis was conducted to evaluate the safety of the bridges after damage to the cable system.

The Effects of Barley Straw on the Eluviation of Components in the Submerged Paddy Soil (보릿짚시용(施用)이 논 토양성분(土壤成分)의 용탈(溶脫)에 미치는 영향(影響))

  • Suh, Jang-Sun;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.4
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    • pp.409-415
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    • 1988
  • This study was carried out to investigate the effects of barley straw application on the eluviation of components in submerged paddy soil percolated. The chemical components of soil, percolated water and humus fraction were as follows. $NH{^+}_4$-N in percolated water and soil, $NO{^-}_3$- N in soil were not detected after prime tillering stage by absorption of rice plant. Phosphate was not affected by the application but a little amount was eluviated through a whole period. Eluviation phase of $Ca^{{+}{+}}$ was similar to $Mg^{{+}{+}}$ and the changes of $K^+$, $Na^+$ and $Cl^-$ were almost same patterns, whereas the amount of these eluviated elements in plot applied was higher than non-applied. In the plot applied, eluviation of $SO{^{-2}}_4$ was low during the tillering stage but high after heading stage, whereas the whole amount of eluviation was high during the tillering stage. Eluviation of iron in the plot applied was increased rapidly. Humus type was almost same as type B in the plot applied or not after harvest, and contents of humic acid was about 60 percent.

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Reductive Degradation of hexachloroethane by using Iron Minerals: Kinetics studies (철 광물에 의한 헥사클로에탄의 환원적 분해: 반응 속도 연구)

  • Kim, Sung-Kuk;Park, Sang-Won
    • Journal of Soil and Groundwater Environment
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    • v.9 no.2
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    • pp.20-27
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    • 2004
  • Kinetic characteristics dependent on several factors such as iron mineral and organic solvents were investigated. When F $e^{0}$ , FeS and Fe $S_2$ were used as mediators, minerals affecting reaction rate were in the following order : $Fe_{0}$ 0/ > FeS > $FeS_2$ when in contact $C_2$C $l_{6}$ . The more chloride substituted, the higher reaction rate were observed. The reaction rates were dependent on pH, shaking rate, temperature and specific surface area. 1, 10-phenanthroline and EDTA degradation rates were fast, indicating that they adsorbed on the surface of the iron which makes the electron transfer reaction easy. Nitrate which has $\pi$* orbital of molecular can increase electron transfer rate because it is delocalized in its entity. The reaction rates were not affected by hydroquinone. Degradation rates were much enhanced with naturally occurring kaolinite because of the surface corrosion of Fe mineral. However, The reaction rate was not affected by F $e^{2+}$ or S $O_4$$^{2-}$ presented in solution.n.