• Title/Summary/Keyword: 질소 순환

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The Estimation of N, P mass Balance in Masan Bay using a Material Cycle Model (물질순환 모델을 이용한 마산만의 질소, 인 수지 산정)

  • 김동명;박청길;김종구
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.833-843
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    • 1998
  • It is noted that the red tides and the oxygen-deficient water mass are extensively developed in Masan Bay during summer. The nutrients mass balance was calculated in Masan Bay, using the three-dimensional numerical hydrodynamic model and the material cycle model. The material cycle model was calibrated with the data obtained on the field of the study area in June 1993. The nutrients mass balance calculated by the combination of the residual currents and material cycle model results showed nutrients of surface and middle levels to be transported from the inner part to the outer part of Masan Bay, and nutrients of bottom level to be transported from outer part to inner part of Masan Bay. The uptake rate of DIN in the box A1(surface level of inner part) was found to be 337. 5mg/$m^3$ㆍday, the largest value in all 9 boxes and that of DIP was found to be 18.6mg/$m^3$ㆍday in box A1, and the regeneration rate of DIN was found to be 78.2mg/$m^3$ㆍday in the box A3(bottom level of inner part), and that of DIP was found to be 18.6mg/$m^3$ㆍday in box A1. The regenerations of DIN and DIP in the water column of the entire Bay were found to be 7.66ton/day and 760kg/day, respectively. And the releases of DIN and DIP from the sediments of the entire Bay were found to be 2.86ton/day and 634kg/day, respectively. The regeneration rate was 2.5 times as high as the release rate in DIN, and 1.2 times in DIP. The results of mass balance calculation showed not only the nutrients released from the sediments but the nutrients regenerated in water column to be important in the control and management of water quality in Masan Bay.

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Experimental Study on Thermal NOx and CO Emission in a Laboratory-Scale Incinerator with Reversed Secondary Air Jet Injection (역방향 2차 공기 주입 방식을 적용한 소각 연소로의 Thermal NOx 및 CO 배출특성에 대한 축소모형실험 연구)

  • Choi, Chonggun;Choi, Woosung;Shin, Donghoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.8
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    • pp.503-510
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    • 2016
  • Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

Characteristics of Red Pepper (Capsicum Annuum L.) Powder Using $N_2-Circulated$ Low Temperature Drying Method (저온질소순환 건조방법에 의해 제조된 고춧가루의 품질 특성)

  • Kim, Chung-Hee;Ryu, Seung-Hee;Lee, Min-Ja;Baek, Jong-Won;Hwang, Hong-Cheol;Moon, Gap-Soon
    • Korean Journal of Food Science and Technology
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    • v.36 no.1
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    • pp.25-31
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    • 2004
  • Characteristics of good-quality red pepper powder produced using $N_{2}$-circulated low-temperature drying method were compared with those made through conventional sun and hot-air drying methods. Kimchi and kochujang were prepared with different types of red pepper powder, and their physicochemical and sensory properties were compared. Results revealed Hunter L (lightness), a (redness), and b (yellowness) values of $N_{2}$-circulated low temperature-dried red pepper were highest. Absorbance of crude capsanthin in hot air-dried red pepper powder ($0.584{\pm}0.001$) was significantly lower than sun-dried ($0.848{\pm}0.001$) and $N_{2}$-circulated low temperature-dried products ($0.832{\pm}0.002$. Use of $N_{2}$-circulated low-temperature drying method resulted in the highest amounts at reducing sugar and total vitamin C. Capsaicin content of $N_{2}$-circulated low temperature-dried products were higher than hot air-dried ones. The aL values of kochujaug made with sun-and low temperature-dried red peppers were higher than that of kochujang made with hot-dried red peppers. Physicochemical and sensory evaluation results showed red pepper powders made using $N_{2}$-circulated low-temperature drying method have the best quality among all samples tested.

Material Budgets in the Nakdong River Estuary with Simple Box Model (낙동강 하구해역에서의 단순 박스모델에 의한 물질수지)

  • Hong Suk-Jin;Lee Dae-In;Kim Dong-Myung;Park Chung-Kil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.3
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    • pp.50-57
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    • 2000
  • Budgets of fresh water, salt, DIN and DIP in the Nakdong river estuary were estimated in order to clarify the characteristics of material cycling and fluxes of nutrients with a simple box model. Freshwater inflow into this system was approximately 1.1E+10m³/y, water exchange was 3.3E+10m³/y and water residence time was 2.03 day assumed with salinity between estuary and adjacent ocean. Nutrients loadings were 3.2E+09mol DIN/y3.7×10³, 2.7E+07mo1 DIP/y, respectively. net ecosystem metabolism was 2.4E+07mo1 C/y. Although the Nakdong river discharge was the main source of nutrients but Jang-rim sewage treatment plant effluent take parts of 16% of nitrogen and 10.2% of phosphorus loadings.

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Simultaneous Removal of Carbon and Ammonia Nitrogen from Recirculation Water in High Density Seawater Aquaculture Farm (고밀도 해산어 양식장 순환수로부터 유기물 및 암모니아질소 동시 제거)

  • 정병곤;김문태;이헌모
    • Journal of environmental and Sanitary engineering
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    • v.18 no.1
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    • pp.15-22
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    • 2003
  • Treatability tests were conducted using EMC process to study the feasibility of applying this process as recycling-water treatment system in high density seawater aquaculture farm. To study the effect of organic and ammonia nitrogen loading on system performance, hydraulic retention time of reactor was reduced gradually from 12hr to 10min. The conclusions are can be summarized as follows. When the system HRT was reduced from 12hr to 10 min gradually, there was little noticeable change(reduction) in ammonia nitrogen removal efficiencies until 2hr of HRT, however, removal efficiencies were decreased dramatically when the system was operated under the HRT of less than 2hr. In case of organics(COD), there was no dramatic deterioration in removal efficiencies depending on HRT reduction. More than 90% of removal efficiencies were maintained successfully when the system was operated at the HRT of 10 min. In case of system performance depending on media packing ratio in reactor, there was little difference in each reactor performance depending on media packing ratio in reactor when the reactors were operated under the HRT of longer than 1hr, however, differences in reactor performances were considerably evident when the reactors were operated under the HRT of shorter than 1hr. That is, the more reactor was packed, the better reactor performed. When comparing reactor performance among 25%, 50%, 75% packed reactor, it can be judged that media packing ratio more than 50% plays no significant role in increasing reactor performance. For this reason, packing the media less than 50% is more reasonable way in view of economic. Such a tendency well agreed with the variation of ammonia-nitrogen removal efficiencies according to the media packing ratio in reactors at each HRT. Difference in effluent ammonia-nitrogen concentration between 50% media packing reactor and 75% media packing reactor was negligible. When comparing with the results of 25% packing reactor, difference was not so great.

Effect of KOH Activation on Electrochemical Behaviors of Graphite Nanofibers (KOH 활성화 효과에 의한 흑연나노섬유의 전기화학적 거동)

  • Yoo, Hye-Min;Min, Byung-Gak;Lee, Kyu-Hwan;Byun, Joon-Hyung;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.321-325
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    • 2012
  • In this work, we prepared the activated graphite nanofibers (A-GNFs) via chemical activation with KOH/GNFs ratios in a range of 0 to 5. The effect of KOH activation was studied in the surface and pore properties of the samples for electrochemical performance. The surface properties of A-GNFs were characterized by XRD and SEM measurements. The textural properties of the A-GNFs were investigated by $N_2$/77 K adsorption isotherms using Brunauer-Emmett-Teller (BET) equation. Their electrochemical behaviors were investigated by cyclic voltammetry and galvanostatic charge-discharge performance. From the results, electrochemical performances of the A-GNFs were improved with increasing the ratio of KOH reagent. It was found that specific surface area and total pore volume of the A-GNFs were increased by KOH activation.

Effect of the Mechanochemical Pretreatment on Antioxidant Material Extraction from Pu'er Tea Leaf (Camellia sinensis var. assalnlca) (보이차잎 항산화 물질추출에 메카노케미스트리 전처리 효과분석)

  • Park, Keum-Joo;Song, Won-Seob
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2011.10a
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    • pp.13-13
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    • 2011
  • 보이차의 주요산지는 중국 운남성이며 특히 란창강 유역이 그 중심지이다. 천연 사포닌과 미네랄류를 풍부하게 포함하고, 지방의 용해, 다이어트 효과, 소화 촉진, 정장 작용, 숙취 해소, 위가 더부룩할 증상 개선, 혈당치 상승 억제, 혈액 순환 촉진에 효과가 있는 것으로 알려져 있다.또한, 면역력 강화 효과와 노화예방, 암 예방효과도 있는 것으로 알려져 있다. 보이차의 기능성 물질은 일반적으로 메탄올 또는 에탄올 용매에 의하여 추출한다. 용매에 의하여 추출하기 전에 메카노케미스트리 분쇄기술을 적용하여 전처리하면 재료의 표면적을 증가시키고 부분적으로 화학적 성분을 변화시켜 기능성 물질의 추출효율을 증가시킬 수 있다. 본 연구에서는 메카노케미스트리 분쇄기술을 적용하여 보이차를 전처리한 다음 메탄올과 에탄올 용매에 의하여 기능성 물질을 추출하여 메카노케미스트리 전처리가 항산화 물질의 추출효율에 미친 효과를 분석하였다. 보이차는 메탄올과 에탄올 추출 전에 유성밀에 의하여 분쇄되었으며 분쇄 후의 형상을 SEM 현미경으로 분석하였다. 아질산성질소 소거능은 pH 1.2에서 메탄올 용매추출을 했을 때 전처리하지 않는 경우 63.0-83.0%로부터 메카노케미스트리 분쇄기술을 적용한 전처리를 한 경우에 74.0-92.0%로 증가하였다. 전자공여능은 DPPH(1,1-diphenyl-2-pycrylhydrazyl)를 이용한 방법으로 측정하였으며, 메탄올 용매추출의 경우에 13.12-49.29%로부터 메카노케미스트리 전처리 후에 15.12-64.29%로 증가하였다. DPPH radical 50% 소거능을 나타내는 $IC_{50}$은 전처리하지 않는 경우 164 ug/mL로부터 전처리한 경우에 151ug/mL로 감소하였다.

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Production of Extracellular Laccase by Lignindegrading Basidiomycete Coriolus versicolor CV3 (리그닌 분해균 Coriolus versicolor CV3에 의한 Laccase의 생산)

  • Kwon, Soon Kyung;Yoon, Min Ho;Choi, Woo Young
    • Korean Journal of Agricultural Science
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    • v.18 no.2
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    • pp.157-163
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    • 1991
  • The cultural conditions in shake flasks were investigated under which maximum amounts of laccase produced by a strain of white-rot fungus Coriolus versicolor CV3. The enzyme yields on potato-malt extract medium by the fungus were higher than on other media consisted of onion infusion or malt extract, with maximum activity of $1.50unit/m{\ell}$ culture or 119.5 unit/g mycelium at 11 days of incubation. Maximum yields of laccase and growth were obtained by supplementation of yeast extract or potassium nitrate to the potato-malt extract medium. Addition of 2.5-xylidine at $4{\times}10^{-4}M$ concentration to the medium induced the laccase production 3.1-fold higher than the basal level, while the mycelial growth was somewhat repressed. The pH optimum for the growth and laccase formation by the fungus was between pH 4 to 4.5.

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Calibration of QUAL2E Reaction Coefficients by the Influence Coefficient Algorithm (영향계수(影響係數)를 이용한 QUAL2E 모형의 반응계수(反應係數) 추정(推定))

  • Jun, Kyung Soo;Lee, Kil Seong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.163-176
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    • 1993
  • A methodology based on the influence coefficient algorithm was established for the optimal calibration of QUAL2E reaction coefficients. It was applied to the stream sections from the Chungju Dam to the downstream end of the South Han River. A water budget analysis using the monthly records of reservoir inflows and outflows in 1990 was made to determine tributary inflows. Estimated tributary inflows were used, together with the monthly records of water quality measurements in 1990, for the calibration of reaction coefficients. Simulated quality constituents were chl.a. nitrogen cycles, phosphorus cycles. BOD and DO. A sensitivity analysis was made to determine significant reaction coefficients, and as a result 11 reaction coefficients were selected as calibration parameters. The influence coefficient algorithm applied to the calibration of QUAL2E reaction coefficients proved to be a useful one yielding a rapid convergence. Each calibration parameter converged to an optimum value within 3 iterations.

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Adaptations of Estuarine and Freshwater Phytoplankton to Urea Decomposition (기수 및 담수 식물플랑크톤의 요소 분해에 대한 적응)

  • PARK, MYUNG GIL;SHIM, JAE HYUNG;CHO, BYUNG CHEOL
    • 한국해양학회지
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    • v.28 no.4
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    • pp.323-331
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    • 1993
  • The concentration-dependence of and the effect of light on urea decomposition, and the suppression of urea decomposition by ammonium were studied to understand adaptations in phytoplankton to utilization of urea in the estuarine system of the Mankyung and Dongjin rivers and a hypertrophied pond. Results of size-fractionation showed that bacterial fraction played a minor role (14%) in urea decomposition in the estuary. However, the role of bacteria in urea decomposition seemed to increase in a hypertrophic pond. Natural phytoplankton communities exhibited a monophonic or biphasic kinetics of urea decomposition over a wide range of concentration (upto 7.7 mM). the addition of high concentration of ammonium and incubation of the euphotic samples in the dark caused reductions in the urea decomposition rates. It is suggested that understanding of adaptations in phytoplankton to urea decomposition would help to study the temporal and spatial variabilities of urea decomposition rates in the field and the significance of urea in nitrogen cycle.

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