• Title/Summary/Keyword: 질소산화물 농도

Search Result 170, Processing Time 0.027 seconds

A pilot study of NOx concentration emitted from cement industry (시멘트산업에서 배출되는 NOx의 환경영향 예비실태조사)

  • 김윤신;이태형;이철민;문정숙;이지철;전형진
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2003.05b
    • /
    • pp.235-236
    • /
    • 2003
  • 시멘트 업계에서 필연적으로 다량 배출되는 질소산화물(NOx)의 법적 규제치는 350ppm(산소 농도 13% 기준)이나 대부분의 시멘트 사업장에서 기준치를 초과하여 배출되고 있는 실정이다. 시멘트 산업은 석회소성로의 고온운전과 다량의 연료사용 등 시멘트 제조의 공정특성상 타 산업에 비해 많은 질소산화물을 배출하여 왔으나, 사업장 주변지역 환경에 질소산화물이 미치는 영향에 관한 연구가 전혀 이루어지지 않아 이에 대한 자료가 전무한 실정에 있다. (중략)

  • PDF

Experimental Study on Reduction of Emissions for Marine Diesel Engines with a Double Post Injection (선박용 디젤엔진에서 이단지연분사에 따른 배기 배출물 저감에 관한 실험 연구)

  • Lee, Won-Ju;Choi, Jae-Hyuk;Cho, Kwon-Hae
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.39 no.4
    • /
    • pp.418-424
    • /
    • 2015
  • Marine Environment Protection Committee of the International Maritime Organization has decided to reinforce the NOx emission standards for ships passing an ECA(Emission Control Area) with Tier III standards from January 1, 2016. In this study, real-time measurements of the exhaust gas, cylinder pressure and fuel consumption were conducted at each load of a T/S Hanbada main engine of Korea Maritime and Ocean University, which is controlled by single injection and double post injection for reducing NOx emissions. The results showed that the quantity of CO2 and NOx increased in proportion to the engine load, whereas the CO concentration was inversely proportional to the engine load. In addition, double post injection decreased 10 % of P-max and reduced 25~30 % of the NOx emissions compared to single injection, whereas there was a trade-off relation, such as increase 3~5 % of SFOC (Specific Fuel Oil Consumption).

NOx Reduction Characteristics of Ship Power Generator Engine SCR Catalysts according to Cell Density Difference (선박 발전기관용 SCR 촉매의 셀 밀도차에 따른 NOx 저감 특성)

  • Kyung-Sun Lim;Myeong-Hwan Im
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.28 no.7
    • /
    • pp.1209-1215
    • /
    • 2022
  • The selective catalytic reduction (SCR) is known as a very efficient method to reduce nitrogen oxides (NOx) and the catalyst performs reduction from nitrogen oxides (NOx) to nitrogen (N2) and water vapor (H2O). The catalyst, which is one of the factors determining the performance of the nitrogen oxide (NOx) ruduction method, is known to increase catalyst efficiency as cell density increases. In this study, the reduction characteristics of nitrogen oxides (NOx) under various engine loads investigated. A 100CPSI(60Cell) catalysts was studied through a laboratory-sized simulating device that can simulate the exhaust gas conditions from the power generation engine installed in the training ship SEGERO. The effect of 100CPSI(60Cell) cell density was compared with that of 25.8CPSI(30Cell) cell density that already had NOx reduction data from the SCR manufacturing. The experimental catalysts were honeycomb type and its compositions and materials of V2O5-WO3-TiO2 were retained, with only change on cell density. As a result, the NOx concentration reduction rate from 100CPSI(60Cell) catalyst was 88.5%, and IMO specific NOx emission was 0.99g/kwh satisfying the IMO Tier III NOx emission requirement. The NOx concentration reduction rate from 25.8CPSI(30Cell) was 78%, and IMO specific NOx emission was 2.00g/kwh. Comparing the NOx concentration reduction rate and emission of 100CPSI(60Cell) and 25.8CPSI(30Cell) catalysts, notably, the NOx concentration reduction rate of 100CPSI(60Cell) catalyst was 10.5% higher and its IMO specific NOx emission was about twice less than that of the 25.8CPSI(30Cell) catalysts. Therefore, an efficient NOx reduction effect can be expected by increasing the cell density of catalysts. In other words, effects to production cost reduction, efficient arrangement of engine room and cargo space can be estimated from the reduced catalyst volume.

Effect of Ozone Injection into Exhaust Gas on Catalytic Reduction of Nitrogen Oxides (촉매 공정의 배기가스 질소산화물 저감 성능에 미치는 오존주입의 영향)

  • Yun, Eun-Young;Mok, Young-Sun;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.27 no.3
    • /
    • pp.330-336
    • /
    • 2005
  • The ozone injection method was proposed to improve the catalytic process for the removal of nitrogen oxides ($NO_x$). Nitric oxide (NO) in the exhaust gas was first oxidized to nitrogen dioxide ($NO_2$) by ozone produced by dielectric barrier discharge, and then the exhaust gas containing the mixture of NO and $NO_2$ was directed to the catalytic reactor where both NO and $NO_2$ were reduced to $N_2$ in the presence of ammonia as the reducing agent. A commercially available $V_2O_5-WO_3/TiO_2$ catalyst was used as the catalytic reactor. The $NO_2$ content in the mixture of NO and $NO_2$ was changed by the amount of ozone added the exhaust gas. The effect of reaction temperature, initial $NO_x$ concentration, feed gas flow rate, and ammonia concentration on the removal of $NO_x$ at various $NO_2$ contents was examined and discussed. The increase in the content of $NO_2$ by the ozone injection remarkably improved the performance of the catalytic reactor, especially at low temperatures. The present ozone injection method appears to be promising for the improvement of the catalytic reduction of $NO_x$.

A Study on NOx Pollutant Reduction and Combustion Characteristics of Impinging-Jet-Flame Combustion Process( II ) (대향분출염(對向噴出焰) 연소방법(燃燒方法)에 의(依)한 NOx 생성저감(生成低減)과 연소특성(燃燒特性) 연구(硏究)( II ))

  • Jeung, I.S.;Cho, K.K.
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.2 no.2
    • /
    • pp.124-131
    • /
    • 1994
  • 자동차엔진의 연소과정에 상사하는 밀폐정적연소실을 주연소실과 대향 2개 부연소실로 분할하고 오리피스로 연결하였다. 이때 부연소실로부터 주연소실로 분출하는 대향분출염 연소에 의한 질소산화물 배출저감특성을 연소방식, 연소실형상 그리고 연료종류를 변경한 수종의 실험으로 조사하였다. 질소산화물농도, 연소실 최고압력, 화염전파과정의 고속도슐리렌사진 가시화를 수행한 결과, 대향분출염 연소방식을 도입하연 연소실의 중앙부공간이 상대적으로 넓은 경우에 고부하운전과 동시에 질소산화물의 배출량도 저감할 수 있었다. 그러나 연료의 종류는 질소산화물생성에 매우 영향이 적었다.

  • PDF

A Study for NOx Discharge Characteristics of Diesel Engines (디젤엔진의 NOx 배출 특성에 관한 연구)

  • 남정길;최주열
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.27 no.3
    • /
    • pp.373-380
    • /
    • 2003
  • According to the NOx regulations of annex Vi to IMO MARPOL 73/78, all diesel engines with a power output of more than 130 kW should be delivered so as to comply with the IMO speed dependent NOx limit. It is inevitable to adopt this regulations for marine engines Therefore, most of diesel engines which are being currently built should be designed and tested in accordance with the NOx technical code In this study, NOx concentrations of 4 type engines were measured with portable NOx measuring system recommended by ISO-8178. As the results NOx concentrations of each engine by variation of engine speed and engine load were visualized Also these results can be utilized for the basic design and development of diesel engine for NOx reduction.

DeNOx Characteristics of Hybrid SNCR-SCR Process in a Pilot Scale Flow Reactor (파일럿 규모 반응기에서 Hybrid SNCR-SCR 공정의 질소산화물 저감 특성)

  • Eom, Won-Hyun;Yoo, Kyung-Seun;Kim, Sung-June
    • Korean Chemical Engineering Research
    • /
    • v.49 no.1
    • /
    • pp.89-94
    • /
    • 2011
  • DeNOx characteristics of hybrid SNCR-SCR process have been investigated in a pilot scale flow reactor. DeNOx efficiency of SNCR reaction was about 80% at $970^{\circ}C$ and hybrid SNCR-SCR process showed 92% at $940^{\circ}C$ with NSR = 2.0. Compared to SNCR process alone, hybrid SNCR-SCR process was more effective at cool side, which is lower than $940{^{\circ}C}$. It should be also noted that ammonia slip from hybrid SNCR-SCR process was below 1ppm at the condition of higher space velocity and the required catalyst volume can be decreased to 2/3 of SCR process. Key factors for DeNOx efficiency of hybrid SNCR-SCR process were found to be $NH_3$ concentration and NOx selectivity of urea injected in SNCR process.

Study on Computational Fluid Dynamics(CFD) simulation for NOx dispersion around combined heat and power plant (열병합발전소 질소산화물 확산에 관한 전산유체역학 simulation 연구)

  • Kim, Ji-Hyun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
    • /
    • v.32 no.1
    • /
    • pp.62-71
    • /
    • 2015
  • In order to deal with the globally increasing electric power demand and reduce $CO_2$ emission, complex thermoelectric power plants are being constructed in densely populated downtown areas. As the environmental regulations are continuously strengthened, various facilities like low NOx burner and SCR are being installed to reduce NOx emission. This study is applied using the TMS emission of $NO_2$ from combined heat and power plant located in Goyang-si Gyeonggi-do. Applying data to the computational fluid dynamics(CFD), and compared with the actual measurement results. It is judged that even though there might be differences between actual measurements and CFD results due to the instant changes of wind direction and wind speed according to measurement time during measurement period, modeling results and actual measurement results showed similar concentration at most forecasting areas and therefore, the forecasting concentration could be deducted which is close to actual measurement by calculating the contribution concentration considering the surrounding concentration in the future.