• Title/Summary/Keyword: 질소산화물(NOx)

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The characteristics of temperature distribution, NOx and CO formation in a MILD combustor with the variation of equivalence ratio (당량비 변화에 따른 MILD 연소로의 온도 분포 및 NOx, CO 생성 특성)

  • Ha, Ji-Soo;Yu, Sang-Yeol;Sim, Sung-Hoon;Kim, Tae-Kwon
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.4
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    • pp.485-490
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    • 2010
  • MILD (Moderate and Intense Low Oxygen Dilution) combustion is a technique which is able to reduce NOx formation and to uniform temperature distribution in the furnace by recirculating the exhaust gas to the fresh air and fuel. This study focuses on finding optimal condition of MILD combustor by changing equivalence ratio with fuel and air flow. The present experiment employs six thermocouple sensors in the furnace, and two concentration probes of NOx and CO at the exhaust exit pipe respectively. The MILD combustion phenomena have been observed at the condition of equivalent ratios of 0.71~0.73, and the temperature uniformity, NOx and CO concentration are also examined at the MILD combustion condition.

Reaction Mechanism of Low Temperature NH3 SCR over MnOx/Sewage Sludge Char (MnOx/Sewage Sludge Char를 이용한 저온 NH3 SCR의 반응 메커니즘)

  • Cha, Jin-Sun;Park, Young-Kwon;Park, Sung Hoon;Jeon, Jong-Ki
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.308-311
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    • 2011
  • The reaction mechanism of selective catalytic reduction of NOx over sewage sludge char impregnated with MnOx using $NH_3$ as the reducing agent was investigated. The active Mn phase was shown to be $Mn_3O_4$ from the XRD analysis. Adsorption was the dominant NOx removal mechanism at low temperatures below $150^{\circ}C$ although reduction reaction also contributed partly to the NOx removal at $100{\sim}150^{\circ}C$. The reaction rate constants of NOx removal over non-impregnated and MnOx-impregnated active chars were compared based on experimental results. The MnOx-impregnated char was shown to have a higher reaction rate constant and a higher NOx removal efficiency due to a higher collision coefficient and a lower activation energy. The activation energy for both chars was shown to be relatively low (10~12 kJ/mol) under the experimental conditions of this study.

A Study on the Installation of SCR System for Generator Diesel Engine of Existing Ship (기존 선박의 디젤발전기용 SCR 시스템 설치에 관한 연구)

  • Ryu, Younghyun;Kim, Hongryeol;Cho, Gyubaek;Kim, Hongsuk;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.412-417
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    • 2015
  • The IMO MEPC has been increasingly strengthening the emission standard for marine environment protection. In particular, nitrogen oxide (NOx) emissions of all ocean-going ships built from 2016 will be required to comply with the Tier-III regulation. In this study, a vanadia based SCR (Selective Catalytic Reduction) system developed for ship application was installed on a diesel engine for power generation of the training ship T/S SAENURI in Mokpo National Maritime University. For the present study, the exhaust pipeline of the generator diesel engine was modified to fit the urea SCR system. This study investigated the NOx reduction performance according to the two kind of injection method of urea solution (40%): Auto mode through the PLC (Programable Logic Control) and Manual mode. We were able to find the ammonia slip conditions when in manual mode method. So, the optimal urea injection quantity can be controlled at each engine load (25, 35, 50%) condition. It was achieved 80% reduction on nitrogen oxide. Furthermore, we found that the NOx reduction performance was better with the load up-down (while down to 25% from 50%) than the load down-up (while up to 50% from 25%) test.

A Study on the Flame Structure and NOx Distribution In Coaxial Diffusion Combustor (동축확산연소기 화염구조와 NOx 분포에 관한 연구)

  • Kim, K.S.;Lee, W.S.;Kang, I.G.;Lee, D.H.
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.35-41
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    • 1999
  • The purpose of this study is to establish the flame structure and NOx emission characteristics of the swirl flow coaxial diffusion combustion in the model gas turbine combustor. The mean temperature, ion currents and NOx emission measurement technique showed the effect of equivalence ratio into flame length and flame stability. As a result of this study, NOx emission was increased by increasing the equivalence ratio, and the peak value of the NOx was appeared near the flame front.

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A Study on the Effects of NOx Reduction for the Tandem System (Tandem 시스템의 NOx 저감 효과에 관한 연구)

  • Nam Jeong-Gil
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.645-653
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    • 2005
  • The effects of a WI(Water Injection) at the intake Pipe and an urea injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine were investigated experimentally The water quantity was controlled by temperature of intake manifold and MAF(Manifold Air Flow). In addition, the urea quantify was controlled by NOx quantify and MAF. Effects of WI system, urea-SCR system and tandem system were investigated for with and without EGR(Exhaust Gas Recirculation). As the results. the SUF(Stoichiometric Urea Flow) and NOx map were obtained. In addition, NOx results can be visualized with engine speed and engine load. It was concluded. therefore, that the NOx reduction effects of the tandem system without the EGR were more than those with the EGR base engine.

Characteristics of Low NOx Plasma Burner Incorporating with Rotating Arc Plasma (회전 아크 적용 플라즈마 저 NOx 버너 연소특성)

  • Kim, Kwan-Tae;Kang, Hee-Seok;Lee, Dae-Hoon;Song, Young-Hoon;Park, Jae-Eon
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.934-941
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    • 2011
  • Characteristics of low NOx burner is investigated. Low NOx burner introduced in this paper adopts two staged combustion with plasma burner for the 1st stage combustion. Extensive parametric tests were done to figure out the effect of burner stoichiometry, staged thermal load, electric power for plasma generation. Overall NOx production by burner shows effective reduction by adopting plasma staged burner. and the aspects depends on the fuel stoichiometry of 1st stage burner or operating condition of plasma burner. It is promising to use plasma burner as an alternative tools of low NOx burner technology.

A removal characteristics of NOx at the cylinderical plasma reactor with magnetic field (자계가 인가된 원통형 플라즈마 반응기에서 질소산화물(NOx)의 제거특성)

  • Lee, Dong-Hoon;Lee, Tae-Geun;Oh, Jung-Min;Lee, Doo-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05b
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    • pp.104-108
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    • 2004
  • The effect of magnetic field was measured on NOx removal for cylinder-wire plasma reactor with magnetic field applied to electric field vertically. Power was supplied to plasma reactor using rotating spark gap switch. Consumption power increased with increasing discharge voltage. When magnetic field was applied to electric field vertically, consumption power was less than that without magnetic field because of lorenz's force. NOx removal rate of plasma reactor with magnetic field were higher, 10-15%, than that of plsama reactor without magnetic field. And NOx removal rate decreased with increasing gas flow rate.

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The Evaluation of NOx Emission Factor from Large Combustion Facilities in Seoul (서울지역 대형연소시설에서의 질소산화물 배출계수 산정)

  • 조기찬;최종욱;박후경;유병태
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.78-83
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    • 2000
  • The emission factor of nitrogen oxides(NOx) was evaluate to clarify the characteristics of NOx emitted from seven large combustion facilities in seoul area. The emission factors of NOx at A-1 and A-2 facilities of internal combustion engine were 66.957kgNOx/ton and 20.913kgNOx/ton, respectively. The emission factor of A-1 facility was higher than that of A-2 facility even same internal combustion engine, because A-1 facility adopted SCR(selective catalystic reactor) for reduction of NOx emission factor of A-2, A-4, and A-7 power generation boiler facilities were 4.300kgNOx/ton, 2.460kgNOx/ton and 1.796kgNOx/ton, respectively. The capacity of A-2 facility was about two times than that of A-4 and A-7. These emission factors were lower than those at facilities in other areas of korea, because of using low NOx burner of power generation boiler. The emission factors of NOx at A-3 and A-6 incinerator facilities were 0.147kgNOx/ton and 0.221kgNOx/ton which were lower than other facilities, respectively, because these facilities incinerate municipal solid waste of low heating value and uwe SCR for reducing NOx concentration.

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A Study of Improving Fuel Droplet Movement with Sonic Wave Radiation (음파를 이용한 연료 입자 운동성 향상에 관한 연구)

  • Min, Sunki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.608-613
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    • 2019
  • NOx (Nitrogen oxide) in the exhaust gas from vehicle engines is considered one of the most harmful substances in air pollution problems. NOx is made when combustion occurs under high temperature conditions and EGR (exhaust gas recirculation) is normally used to lower the combustion temperature. As the EGR ratio increases, the NOx level becomes low, but a high EGR ratio makes the combustion unstable and causes further air pollution problems, such as CO and unburned hydrocarbon level increase. This study showed that fuel droplets could move more freely by the radiation of sonic wave for the stable combustion. In addition, the engine performance improved with increasing EGR ratio. As a basic study, the effect of sonic wave radiation on the velocity of fuel droplets was studied using CFD software. The results showed that the velocity of small droplets increased more under high frequency sonic wave conditions and the velocity of the large droplets increased at low frequency sonic wave conditions. In addition, an engine analysis model was used to study the effects of the increased combustion stability. These results showed that a 15% increase in EGR ratio in combustion resulted in a 45% decrease in NOx and a 10% increase in thermal efficiency.

A Study on the Inlet NOx Estimation of SCR System in a Refuse Incineration Plant by Using General Structured Observer (일반 구조형 관측기를 이용한 소각장 SCR 시스템의 Inlet NOx 추정에 관한 연구)

  • Lee, Chung-Hwan;Kim, In-Gyu;Kim, Hwan-Seong;Kim, Sang-Bong
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.1
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    • pp.123-128
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    • 2001
  • The function of SCR system in refuse incineration plant is to reduce the harmful combustion gases especially NOx which make serious environmental pollution. The SCR system normally have a NOx measurement system such as inlet NOx analyzer and outlet T.M.S.(Tele Monitoring System) to control the outlet NOx in stack. The NOx measurement system is very important, however there are frequently happened sensing problems and it need maintenance periodically. In this paper, we propose an estimation method of inlet NOx of SCR system by using general structured observer. The inlet NOx is considered as an input disturbance and it is modelled by applying FFT method in frequency domains. Through the design of general structured observer, the outlet NOx can be estimated by using observation error between real outlet NOx and estimated outlet NOx. The effectiveness of the proposed method is shown by comparing to a measured inlet NOx data.

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