• Journal of the Korean Society of Groundwater Environment
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• v.6 no.4
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• pp.206-212
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• 1999

In order to evaluate the applicability of steel mill slag as a AMD (Acid Mine Drainage) neutralizer and to compare capacity of slag with that of limestone lab scale experiments were conducted. The fixed treatment experiments of AMD with slag and limestone separately for 24 hours under the stagnant condition showed that slag has higher capacity of pH increase and removal of Fe. Al and other trace elements. During the 10 days continuous step experiment the pH has been maintained and any decrease in the removal capacity of Fe and Al has not bun observed. In the trace element removal experiment slag showed higher capacity for removal of Ni, Co. Cu and Zn than limestone. The removal of trace element was more effective in AMD than in distilled water that the pH was adjusted to the same level of AMD (synthetic acid solution). It means that Fe and Al in AMD adsorbed trace elements during or after precipitation as oxide forms. In the size effect experiment, the slag of the smaller size with larger specific surface area exhibited higher capacity of pH increase and removal efficiencies of Fe. Al and other trace elements.

• Korean Journal of Optics and Photonics
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• v.14 no.3
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• pp.306-311
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• 2003

In this paper, we modeled the incident beam in order to analyze and evaluate the optical thin film device for wavelength division multiplexing in optical telecommunication network. As applied ray tracing method to the optical path, we were compared the accuracy of coupling efficiency simulated by two modeling methods. In the results of sinulation, ceil modeling method was preferred to annual modeling method in micro-optic device because of accuracy for coupling efficiency and Gaussian intensity distribution. In the results of optimal simulation for optical device using thin film filter, the distance (d1) between optical fiber and GRIN lens, the distance (d2) between GRIN lens and thin film filter and the coupling efficiency were 0.24 mm, 0.25 mm and -0.11 ㏈ respectively. As d2 was displaced at 0.25 mm and d1 was varied in order to evaluate the optimal value, d1 and maximum coupling efficiency were 0.24 mm and -0.35㏈, respectively. Then the results of experiment were corresponded to that of optimal simulation by cell modeling and it was possible to analyze the performance for optical device using thin film filter by the simulation.

• Journal of the Korean Applied Science and Technology
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• v.38 no.1
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• pp.300-308
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• 2021

In this study, 3D networked poly(sodium acrylate) gel was polymerized and controlled with the crosslinking environment to evaluate the mechanical properties and swelling behavior. In general, as the degree of crosslinking in a pre-gelled solution increases, the swelling ratio of the 3D networked gel decrease while the mechanical strength of the gel increases. Interestingly, this study demonstrates that the polymerization and crosslinking efficiency in gelling process could be depended on the crosslinking environment by evaluating the number of elastically cross-links in 3D networked gel. As a result, the number of elastically corss-links would be changed with 3.6 times as varying of the crosslinking environment while keeping the degree of crosslinking. It is expected that the 3D networked gel would be optimized as an effective absorbing agent for VOCs by using the gel evaluation method based on the number of elastically cross-links.

• Korean Journal of Environmental Agriculture
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• v.24 no.3
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• pp.215-221
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• 2005

Numerous abandoned or closed mines are present in the steep mountain valleys in Korea due to the depression of the mining industry since the late 1980s. From the mines, enormous amounts of wastes were dumped on the slopes causing sedimentation and acid mine drainage to be discharged directly into streams causing detrimental effects on surrounding environment. Objective of this research was to evaluate the feasibility of the lime cake by-product from the soda ash production (Solvay process) to neutralize the pyrophyllite mine wastes, which have discharged the acid drainage to soil and stream in the watershed. The pH of mine wastes was strongly acidic at pH 3.67 containing over 16% of $Al_2O_3$ and 11% of $Fe_2O_3$. Whereas the lime cake by-product was strongly basic at pH 9.97 due to high contents of CaO, MgO and $CaCl_2$ as major components. Column experiments were conducted to test the neutralizing capacity of the lime cake by-product for the acidic pyrophyllite mine wastes. The column packed with the wastes (control) was treated with the lime cake by-product, calcium carbonate, the dressing soil or combination. The distilled water was eluted statically through the column and the leachate was collected for the chemical analyses. Treatments of the mine wastes with the lime cake by-product (or calcium carbonate) as mixtures increased pH of the leachate from $3.5{\sim}4.0\;to\;7{\sim}8$. Concentrations of Fe and Al in the leachate were also decreased below 1.0 mg $L^{-1}$. A Similar result was observed at the combined treatments of the mine waste, the lime by-product (or calcium carbonate) and the dressing soil. The results indicated that the lime cake by-product could sufficiently neutralize the acid drainage from the pyrophyllite mine wastes without dressing soils.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1071-1079
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• 2011

In this study, coal combustion ash (CCA) was evaluated for its stabilization effect on acidic mine waste with column experiment. Total of six treatments were installed depending on mixing ratio between coal wastes and CCA (0, 20, 40%) and mixing method (completely mixing and layered). Artificial acidic rain (pH 5.6) was used for feeding solution with flow rate of $0.05mL\;min^{-1}$. Result showed that higher pH of leachate was observed as more CCA was mixed. The highest pH in leachate was measured when 40% of CCA was mixed with coal waste (pH of 5.8). Also, complete mixing with CCA and coal waste was more effective to increase the pH of leachate than layered treatment. Regarding the reduction of soluble Fe amount, the highest efficiency (78%) was observed when 20% of coal ash was completely mixed with mine waste. Based on those result, optimum mixing ratio of coal ash with mine waste can be ranged 20-40% depending on environmental circumstances in the field.

• Proceedings of the Korea Water Resources Association Conference
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• 2008.05a
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• pp.859-863
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• 2008

축산폐수, 침출수 등의 고농도 폐수를 생물학적으로 처리할 경우 최종 방류수는 강한 색도를 띠며 고분자량의 유기물질을 다량 함유한다. 이는 생물학적으로 분해하기 어려운 유기성 복합체와 생화학적 반응에 의한 중간생성물로 색도를 띠는 천연유기물질(NOM)을 포함한다. 생물학적 처리수의 색도는 심미적인 불안감, 방류수역의 수질오염 및 공중보건상의 잠재적 위해성을 갖는다. 또한, 수자원 이용측면에서 정수처리공정에서의 약품투입량 증가와 특히, 소독부산물 생성이라는 잠재적 문제점이 뒤따른다. 따라서 이러한 문제점을 해소하기 위한 생물학적 2차 처리수의 후속처리가 요구되며, 실제로 난분해성 유기물과 색도를 제거하기 위한 흡착, 막 분리, 고급산화(AOP) 및 화학적 응집 등의 물리-화학적 공정에 대한 연구가 수행되어왔다. 특히, 화학적 응집은 무기응집제 또는 고분자중합체(Polymer)를 이용하여 콜로이드성 입자와 색도를 띠는 난분해성 유기물을 전기적 불안정화를 유도함으로서 흡착 및 응집과정을 통해 제거하는 공정으로 많은 연구자들에 의해 연구되어왔다. 그러나 난분해성 유기물과 색도제거는 대상원수의 성상과 화학적 특성 등에 따라 각각의 제거효율과 최적 운전조건이 상이하게 나타난다. 화학적 응집공정은 비교적 높은 제거효율을 보이지만, 운전 및 유지관리의 기술적 어려움, 경제적 비효율성 등으로 인하여 적용에 어려움을 겪고 있는 실정이다. 본 논문에서는 생물학적 혐기-호기성 공정에서 방류되는 축산폐수의 2차 처리수를 대상으로 화학적 응집에 의한 색도 및 난분해성 유기물의 제거거동을 고찰하였다. 대상 처리수의 $TCOD_{Cr}$ 농도는 평균 410 mg/L인 반면, $BOD_5$는 7-15 mg/L 범위로 난분해성 유기물을 다량 함유하고 있음을 알 수 있었다. 이에 황산알루미늄(Aluminium sulfate; $Al_2(SO_4){\cdot}14H_2O$)과 염화철(ferric chloride)의 무기응집제를 이용하여 자 테스트(jar test)를 수행한 결과, 동일한 응집제 주입량에서 염화철의 유기물 제거 효율이 높은 것으로 나타났다. 황산알루미늄과 염화철의 경우 각각의 응집제 주입율 5.85mM에서 89%, 7.03mM에서 97.5%의 최대 유기물 제거효율을 보여주었으며, 이 때 최종 pH는 4.0-5.6 범위이었다. 한편, 대상 원수 내의 콜로이드성 입자 또는 용존성 유기물의 작용기(functional group)는 일반적으로 음으로 하전 되어 있어 응집에 의해 잘 제거되지 않는 특성을 가지고 있다. 따라서 과량의 응집제를 주입하여 다가의 양이온성 금속염을 흡착시켜 전기적으로 중화시키고, 생성된 침전성 수화물 내에 포획 또는 여과시켜 제거하게 된다. 이 때, 금속염 수화종의 전하밀도가 응집효율에 영향을 주는 것으로 알려져 있는데, 다가의 양이온은 전기적 이중층(Double layer) 압축에 의한 불안정화를 향상시킬 수 있기 때문에다. 또한, 2가 금속염은 색도유발물질과 흡착하여 humate 또는 fulvate 등의 착화합물(complex)을 형성시켜 응집효율을 향상시킬 수 있다. 따라서 본 연구에서는 생물학적 2차 처리수의 화학적 응집처리에 있어서 알루미늄염 등의 다가이온 첨가가 응집에 미치는 영향을 관찰하고, 후속되는 플록형성 및 침전공정에 의한 제거효율을 비교, 평가함으로써 2차 처리수로부터 난분해성 유기물과 색도를 보다 효과적이고 경제적으로 제거할 수 있는 최적인자를 도출하고자 하였다.

• Proceedings of the KIEE Conference
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• 2008.04a
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• pp.83-85
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• 2008

현행 지상파 DMB(Digital Multimedia Broadcasting)에서는 최대 CIF급 해상도의 동영상을 384 Kbps 정도의 비트율로 압축하여 비디오 CD급의 화질을 제공한다. 따라서 큰 화면을 통해 DMB 방송을 시청할 경우 해상도 부족 등으로 인한 화질 열화를 느낄 수 있다. 이와 같은 문제를 해결하기 위한 방안으로 계층적으로 부호화된 비트스트림을 서로 다른 채널로 전송하는 고품질 AT-DMB 시스템이 연구되고 있다. 더불어, 계층변조 기술을 이용하여 추가적인 전송대역폭을 확보하고, 계층적 비디오 부호화 기술을 이용하여 고품질 이동 멀티미디어 방송을 제공하는 고품질 T-DMB 방식이 개발되고 있다. 이와 같은 AT-DMB 방식으로 사용자에게 안정된 고품질 비디오 서비스를 제공하기 위해서는 계층적 비디오 부호화를 고려한 효율적인 AV다중화 및 동기화 구조에 대한 연구가 필수적으로 요구 된다. 본 논문에서는, 이와 같은 고품질 AT-DMB 시스템을 위해서 각 계층 ES(Elementary stream)을 MPEG-4 over MPEG-2 시스템과 Eureka-147 DAB 시스템을 통해 서로 다른 채널로 전송한다. 계층별 전송으로 인한 시간 지연에 대처하여 수신입력부에서는 각각의 계층으로 전송된 ES들이 동기화 되어 복호화 되도록 SVC의 계층적 비트스트림 구조와 적응적으로 동작되는 다중화 시스템구조를 제작하였다.

• Korean Journal of Optics and Photonics
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• v.14 no.4
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• pp.351-354
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• 2003

We present a 12.5-GHz interleaved bidirectional ultra-dense wavelength-division-multiplexing transmission over a conventional single mode fiber of 80 km achieving spectral efficiency as high as 0.8-bit/s/Hz. The beat-frequency-locking method is used to stabilize the channel frequency within $\pm$200 MHz error. To facilitate the identification of multiple beat frequency signals, we use a radio-frequency spectrum analyzer. The bidirectional transmission penalty is about 0.3 dB compared with the unidirectional transmission over the same fiber.

• Analytical Science and Technology
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• v.27 no.4
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• pp.196-200
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• 2014

Currently nonaqueous titration method for the assay method using the hazardous reagent, mercury acetate for difemerine hydrochloride has been used in Korean Pharmaceutical Codex. We developed an alternative titration assay method by substituting the use of the hazardous reagent, mercury acetate to the use of less toxic ones like ethyl alcohol. The linearity of the calibration curves in the desired concentration range was good (r>0.999). Precision was less than 0.64%. Accuracy was obtained with recoveries in range of 99.10% and 99.71%. The developed assay could be expected to become valuable tools for revising the Korean Pharmaceutical Codex.

• Journal of the Korean Institute of Telematics and Electronics D
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• v.36D no.6
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• pp.79-86
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• 1999

We propose a new photorefractive demultiplexer(DMUX) for WDM communicaytion system using a wavelength selectivity and demultiplexing properties of a volume holographic grating filters formed in $LinbO_3$ crystal doped with 0.015wt.% Fe. The wavelength selectivity properties of the filter are analyzed and experimentally investigated as a function of the following parameters : the crossing angle of the two writing beams, the reading-beam angle and writing-beam size. In addition, applying these wavelength selectivity properties and the multiplexing technique for recording multiple-exposure filters with equal diffraction efficiency, some preliminary experimental results are presented for use as DMUX.