• Journal of The Korean Society of Grassland and Forage Science
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• v.29 no.1
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• pp.51-62
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• 2009

This study was carried out development a new composting system to lower copper and zinc concentration in plg sludge compost and conduct an inquiry into the possibility of crop cultivation. The concentrations of nitrogen, phosphorus and pH averaged 4.4%, 6.3% and 7.57, respectively, which were higher concentrations than in commercial organic fertilizers, and the concentrations of copper and zinc averaged 805 and 1,704 mg/kg, respectively, which were beyond the heavy metal concentration limit in byproduct compost. Hydrated citric acid I lowered the concentrations of copper and zinc by 58% and 97%, respectively and hydrated oxalic acid II lowered the concentrations of copper and zinc by 48% and 56%, respectively in pig sludge compost. Lower concentrations of copper and zinc in pig sludge resulted from the enhanced hydrated-citric acid concentration in organic acid solution mixed with distilled water. The concentrations of copper and zinc were 330, and 41 mg/kg in the pig sludge treated with 100% hydrated citric acid. Agitation composting system stabilized the compost earlier than the stationary composting system, in which the stabilization condition was confirmed by higher temperature by $4^{\circ}C$ at highest temperature and 7 days earlier cooling down after highest temperature. The levels of germination index (G.I) 80 were obtained 15 and 20 days after composting in agitation and stationary composting system, respectively. The concentrations of copper and zinc were 2.4 and 4.26 mg/kg respectively in soils amended with pig sludge compost after removing process of heavy metals by citric acid, but 8.0 and 22.37 mg/kg, respectively in soils amended with Pig Sludge. The concentrations of heavy metals was highest in com cultivated in soils amended with pig sludge. The copper and zinc concentrations In corn leaves were 75.2 and 50.56 mg/kg respectively, which were 4 and 2 fold higher than the com cultivated in soils amended with pig sludge compost after heavy metal removing process by hydrated citric acid.

• Journal of the Korean Geotechnical Society
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• v.17 no.2
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• pp.143-150
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• 2001

최근 국내에서는 건설재료의 부족으로 건설부산물인 폐콘크리트를 새로운 토목재료로써 재활용 또는 자원화에 노력하고 있다. 이러한 차원에서 폐콘크리트의 재활용 및 자원화는 사용용도에 적합한 공학적 특성뿐만 아니라 환경적 특성을 분석하여 대상재료의 환경 안정성을 파악해야 한다. 따라서, 본 논문은 폐콘크리트에 대하여 pH시험, 용출시험, 중금속 흡착특성 등 일련의 환경특성 실험을 실시하여 폐콘크리트 사용에 따른 주변 환경에 미치는 영향을 분석하였다. 실험결과, 폐콘크리트의 pH는 11~12정도이고, 폐기물공정시험법과 TCLP법에 의한 용출시험은 법적기준에 모두 만족하는 것으로 나타났다. 또한 중금속 흡착시험은 폐콘크리트나 구리, 납, 카드늄의 제거능이 큰 것으로 나타났으나 반면, 크롬에 대해서는 제거율이 50%정도로 나타났다.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.3
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• pp.53-63
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• 2013

It is well known that problem for contaminated soil with heavy metals is mainly produced from agricultural land around abandoned metal mine and the cost to solve them is much higher than those of water and air pollution in addition, it takes much more time to clarify the contaminated soil. Until now, economical and practical many techniques to remediate contaminated soils with heavy metals have been developed and proposed. Therefore, in this study, characteristic, merit and weakness for various techniques which are developing and commercializing recently in domestic/foreign country will be reviewed.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.4
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• pp.90-96
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• 2011

In order to remediate contaminated soils with heavy metals, many techniques have been developed and proposed. However, weakness for the various techniques has been making application for actual process difficult. They have been led to the necessity for novel techniques. Therefore, in this study, novel techniques which are developing and commercializing recently in domestic/foreign country will be introduced, especially it will be focused on remediation technique for contaminated soil with heavy metals using magnetic material.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.4
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• pp.81-90
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• 2009

About 35 domestic incinerators are being operated currently. There is waste management policy to reuse waste efficiently and reduce waste through incineration which include reuse, recycling and energy recovery. However, there is a critical social issue that some heavy metals(Cu, Pb) were found in bottom ash from incineration of waste. After incineration, bottom ash is treated with chemicals to prevent second pollution of heavy metals from bottom ash and increase efficiency of heavy metal stabilization.

• Journal of the Korea Organic Resources Recycling Association
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• v.9 no.2
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• pp.45-51
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• 2001

Mackban-stone effectively removed heavy metals, such as Fe, Cu, Cd, and Zn, with best removal of Fe and Cu. And the removal of heavy merals related with ion exchange of Ca. Mackban-stone is also an efficient deodorant of hydrogen sulfide and ammonia and inhibited the growth of E coli. The degradation rare of 4-nitropheno1 by Nocardioides sp. PNP101 and 2,4-dinitrophenol by Strain CJ1 and Rhodococcus sp. DNP 505 are increased by Mackbane-srone.

• Journal of the Korea Organic Resources Recycling Association
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• v.22 no.2
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• pp.44-49
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• 2014

In order to remove the heavy metals from synthetic wastewater containing Pb, Cr, and Cd, the experiment was conducted with a variety of concentration and pH by using the washed and dried coffee grounds as adsorbent. Almost of the heavy metals were removed in thirty minutes and the removal efficiency was maximized to the 80 percents following the different pH conditions. Furthermore, in the case of Cr, the removal efficiency was declined with the increasing of pH. As a result of this study, coffee grounds is proved to be a very good adsorbent to remove the heavy metals.

• Resources Recycling
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• v.21 no.1
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• pp.75-81
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• 2012

Porous pellets for immobilizing heavy metals were manufactured from coal tailings and iron oxide powder. Coal tailings was pulverized and mixed with iron oxide powder. The mixed powder was granulated into spherical pellets and roasted. Over $1100^{\circ}C$, residual coal in coal tailings reduced iron oxide to ZVI(Zero-Valent Iron). The pellets have 34.63% of porosity, 1.31 g/mL of bulk density, and 9.82.urn median pore diameter. The pellets were reacted with synthetic solutions containing each heavy metals: arsenic(V), copper(II), chrome(VI), and cadmium(II), respectively. On the test of immobilizing heavy metal, the pellets made at $1100^{\circ}C$ were superior to the other pellets made under $1000^{\circ}C$. Immobilizing over 99.9% of 10ppm heavy metal solutions required I hour for arsenic, 2 hours for chrome, and 4 hours for copper. However, immobilizing capacity of cadmium was inferior to that of the other metals and it was decreased in reversely proportion to initial concentration of the solutions.

• Journal of the Korea Organic Resources Recycling Association
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• v.4 no.1
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• pp.23-31
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• 1996

The heavy metal concentration in mixed and separately collected household food waste, and their compost during the composting period was analysed. The mixed and separately collected food waste had Cd content of 8 mg/kg in spring and its content of 13 mg/kg in winter respectively. Its content was higher than by-product compost limit value(5 mg Cd/kg). Cd concentration in separately collected food waste in a house was higher in January, February, April and May than by-product compost limit value (5 mg Cd/kg). When Cd concentration in the initial composting material was higher than 5 mg/kg, its concentration in the compost of household food waste during the composting period was higher than by-product compost limit value, but it was not accumulated in the compost during the composting period. Fly ash was added to separately collected household food waste to adjust its moisture content for composting. Its addition had moisture conditioning and Cd concentration reducing effect in the compost. The average one month composted fresh compost from the mixed collected household food waste was matured in a pile out of doors for 7 months with turning the pile once a month and its heavy metal concentration was examined. Accumulation of the heavy metals in the compost did not occur during the composting period, because they were washed out during the rainfall.

• Journal of the Korea Organic Resources Recycling Association
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• v.22 no.2
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• pp.17-26
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• 2014

In this study, the adsorption efficiency of mixed heavy metals from an aqueous solution was examined using bentonite. The physical and chemical properties of bentonite was analyzed via scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR), Further, heavy metal adsorption was characterized using Freundlich and Langmuir equations. Equilibrium adsorption data were fitted well to the Langmuir model for bentonite. The adsorption uptake of heavy metals was high and followed the order $Pb^{2+}$ > $Cu^{2+}$ > $Cd^{2+}$ > $$Zn^{2+}{\sim_=}Ni^{2+}$$. The results also showed that adsorption uptake slightly increased as increasing pH from 6 to 10. The bentonite surface was observed viay SEM and FT-IR; Si-O and Si-O-Al were found to be the main functional groups by FT-IR analysis. From these results, the adsorption mechanisms of heavy metal were not only surface adsorption and ion exchange, but also surface precipitation. Thus, bentonite could be a useful adsorbent for treating heavy metal in aqueous solution.