• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.251-252
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• 2002

지속적인 산업의 발달과 인구의 밀집, 자동차등의 급증으로 인한 환경오염은 다양한 유해물질로 나타나고 있다. 최근 인구 및 교통밀집지역인 서울지역의 대기 중 미세먼지(PM$_{10}$) 및 중금속에 관한 농도 증가를 여러 매체들을 통해 쉽게 접할 수가 있다. (중략)

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11b
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• pp.623-628
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• 1996

핵주기 공정 및 원전 2차 계통 증기발생기의 화학 세정시 배출되는 액체 폐기물 및 산업 폐수등에 존재하는 구리, 우라늄, 납 및 카드늄 등의 중금속들은 일반환경 및 공중보건상에 심각한 문제를 야기할 수 있다. 본 연구에서는 사과 주스공정에서 나오는 폐 사과 껍질을 이용하여 용액의 pH, 이온강도, 유기, 무기 ligands 존재, 및 화학적 처리등에 따른 페수중 구리의 제거 특성에 대하이 연구하였다.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.3
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• pp.357-364
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• 2007

This research is to set a direction on the recycle of Discarded Automotive tires reforming them into heavy metal adsorbents by developing a particular functional group inducing formation of Chelate complexes with heavy metal ion in the water, on the surface of the used tire conventionally turned into powdered form. For this purpose, through FT-IR, XRD, XRF, SEM, elution test we confirmed and analyzed the property of newly reformed scrapped tires, and functional group. Also, by Kinetics Study we produced an invariable value applying to absorption models. Conclusively the absorption preference of heavy metal is determined to be $Pb^{2+}>Cu^{2+}>Cd^{2+}$, and it reached absorption balance within first 30 minutes, also the absorption reaction time increased from 0.27 to $1.78\sim3.15(g/mg{\cdot}min)$, and showed more than 80% of removal efficiency. This result proved that the efficiency increased by 10 times compared with the conventional powdered Discarded Automotive tires, and the Discarded Automotive tire which implemented the Functional group can exhibit a great efficiency as heavy metal adsorbent.

• Analytical Science and Technology
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• v.6 no.5
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• pp.435-442
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• 1993

Carboxymethylated polyamine-polyurea resin loaded with rubeanic acid (RCCPPI resin) was obtained by 1 step chemical reaction between chlorocarboxymethylated polyamine-polyurea(CCPPI) resin as matrix polymer and rebeanic acid. This resin was confirmed with infrared spectrometry, elemental analysis, and thermal analysis(DSC). The adsorption characteristics of the heavy metal's on the resin were studied by measuring distribution coefficient($K_d$) with changing pH of the solutions and frontal chromatography. The enrichment, recovery, and analysis of trace heavy metals, such as cadmium, cerium, copper, nikel, lead, and zinc, in the presence of high concentrations of sodium, calcium, and acetate salts was possible quantitatively by a column packed with the resin at each optimum pH. Preconcentration factors were more than 25. To elute the adsorbed heavy metals on the resin, 0.025M EDTA solution(pH 9.0) was used.

• Journal of Environmental Science International
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• v.6 no.1
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• pp.61-67
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• 1997

Heavy metal adsorption by microbial cells is an alternative to conventional methods of heavy metal removal and recovery from metal-bearing wastewater The waste Sac-chuomyces cerevisiae is an inexpensive, relatively available source of biomass for heavy metal biosorption. Biosorption was investigated by free and immobilized-S. cerevisiae. The order of biosorption capacity was Pb>Cu>Cd with batch system. The biosorption parameters had been determined for Pb with free , cells according to the Freundlich and Langmuir model. It was found that the data fitted reasonably well to the Freundlich model. The selective uptake of immobilized-S. cerevisiae was observed when all the metal ions were dissolved in a mixed metals solution(Pb, Cu, Cr and Cd). The biosorption of mixed metals solution by immobilized-cell was studied in packed bed reactor. The Pb uptake was Investigated in particular, as it represents one of the most widely distributed heavy metals in water. We also tested the desorption of Pb from immobilized-cell by us- ing HCI, $H_2SO_4$ and EDTA.

• The Journal of Engineering Geology
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• v.18 no.3
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• pp.297-302
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• 2008

The main reason of the pollution caused by soils and tailings located at discussed mines is heavy metals and AMD(acid mine drainage). Human health is affected by these pollutants which are spreaded from the abandoned mines. In this study, we try a mathematical approach to predict the pollution level of heavy metals caused by the surrounding soils of abandoned mines. The new approach is established with the correlation between the distance and pH, ORP. The change of pH and ORP can be described by the rate of initial values to experimental values. We demonstrate a realistic possibility of the mathematical approach to assess an environmental impact from disused mines cause the rate range is 0.95 to 1.03 for 60 days. Therefore our proposed approach will be useful as a few promising method for the management of heavy metals in many mines.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.560-568
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• 2007

The aim of this study is to investigate the terminology of chemically unclear ‘heavy metals' which were expressed in the Korean secondary science textbook in terms of the definition, the type and the meaning. Initial results showed that six of ‘Chemistry I' textbooks among these texts defined a heavy metal with the density and described it as a metal which is hazardous and continuously accumulated in the human body. Specifically, cadmium, lead and mercury were presented as examples of the hazardous metal in all of the eight textbooks but non-metals such as arsenic and absolutely essential metals including chrome, manganese, iron, cobalt, nickel and copper were also given in the texts. Most of the texts described the hazardousness and toxicity of the metal too simple to understand the mechanism of its intoxication despite considering all of the factors including its oxidation state, residual amount and reactivity with biomolecules of the human body. Such an ambiguous definition and explanation may excluded in the textbook because the chemically undefined chemical vocabulary leads students to cause an alternative conception of the heavy metal, which means that the metal could be identical with toxins.

• The Korean Journal of Ecology
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• v.26 no.3
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• pp.91-96
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• 2003

To monitor the heavy metal exposure conditions of Feral Pigeons Columba livia, we collected them at commercial area, industrial area, park area and resident area in Seoul. In feathers, iron concentrations were significantly different among habitats(ANOVA, p<0.05), and were the highest at park area. Manganese concentrations were relatively higher at industrial and park area than other areas(ANOVA, p<0.05). In case of copper levels were the significantly highest at park area(ANOVA, p<0.05). Zinc, lead and cadmium had no difference among habitats. Correlation between livers and feathers concentrations were highly significant to copper(r²=0.983, p<0.01) and cadmium(r²=0.632, p<0.01), but iron, zinc, manganese and lead were not significantly different.

• Journal of the Korean GEO-environmental Society
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• v.9 no.4
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• pp.47-52
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• 2008

In this study, it was analyzed the soil components and elution characteristics of heavy metal ions in sediment samples to examine the effect of sediments embedded in Andong and Imha reservoirs on water quality. Major elements of sediments were shown to be Al, Si, K, and Fe by EDS analysis and major soil components of the collected 6 different sediments were illite (I), kaolinite (Ka), quartz (Q) and feldspar (F). And especially quartz took up a considerable part of sediments by XRD analysis. The total concentrations of Zn, As, Cr, Cu and Pb in sediments of Andong reservoir were relatively higher than those of Imha reservoir. The elution property of heavy metal from sediments had various aspects according to pH. Among the heavy metals in Andong reservoir sediments, As and Zn were significantly eluted at pH 6 compared with the other heavy metals. In the case of the adsorption tests using the sediments, the adsorptive capacities of Zn, Cd and Cu were very weak, on the while those of Pb and Cr were high.

• Economic and Environmental Geology
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• v.52 no.2
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• pp.141-158
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• 2019

The quantity of heavy metals in agricultural surface and subsurface soils around coal-fired power plants located in Samcheonpo and Hadong, Gyeongnam Province, were determined. The analytical results for 48 and 61 soils in Samcheonpo and Hadong, respectively, showed that the concentrations of Cu, Hg, Ni, Pb, and Zn were below the warning criteria regulated by Korean Soil Conservation Act; however, Cd in 38 and 13 soils in Samcheonpo and Hadong, respectively, exceeded the criterion. As a result of calculation of the geoaccumulation index and the enrichment factor, the soils were extremely contaminated with Cd and such high loading of Cd to the soils was due to anthropogenic source(s). Sequential extraction of the soils, however, showed that heavy metals including Cd existed as hardly extractable phases, which represented a low bioavailability of the heavy metals. Our results indicated that Cd contamination around the coal-fired power plants was due to artificial source(s) and may unlikely deteriorate nearby ecosystems.