• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.423-431
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• 2011

Recentincreasing awareness of the environmental damage caused by the $CO_2$ emission of fossil fuelsstimulated the interest in alternative and renewable sources of energy. Fuel cell is a representative example of hydrogen energy utilization. In this study, Molten Carbonate Fuel Cell system is simulated by using $Aspen^{TM}$. Stack model is consisted of equilibrium reaction equations using $ACM^{TM}$(Aspen Custom Modeler). Balance of process of fuel cell system is developed in Aspen $Plus^{TM}$ and simulated at steady-state. Analysis of performance of the system is carried out by using sensitivity analysis tool with main operating parameters such as current density, S/C ratio, and fuel utilization and recycle ratio.In Aspen $Dynamics^{TM}$, dynamics of MCFC system is simulated with PID control loops. From the simulation, we proposed operation range which generated maximum power and efficiency in MCFC power plant.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.516-521
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• 2012

This study developed a simple model to investigate effects of important operating parameters on performance of a bubbling-bed adsorber and regenerator system collecting $CO_2$ from flue gas. The chemical reaction rate was used with mean particles residence time of a reactor to determine the extent of conversion in both adsorber and regenerator reactors. Effects of process parameters - temperature, gas velocity, solid circulation rate, moisture content of feed gas - on $CO_2$ capture efficiency were investigated in a laboratory scale process. The $CO_2$ capture efficiency decreased with increasing temperature or gas velocity of the adsorber. However, it increased with increasing the moisture content of the flue gas or the regenerator temperature. The calculated $CO_2$ capture efficiency agreed to the measured value reasonably well. However the present model did not agree well to the effect of the solid circulation rate on $CO_2$ capture efficiency. Better understanding on contact efficiency between gas and particles was needed to interpret the effect properly.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.217-222
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• 2012

The synthesis of dimethyl carbonate(DMC) is a promising reaction for the use of naturally abundant carbon dioxide. DMC has gained considerable interest owing to its versatile chemical reactivity and unique properties such as high oxygen content, low toxicity, and excellent biodegradability. In this study, the synthesis of DMC through the transesterification of ethylene carbonate(EC) with methanol was investigated by using ionic liquid and metal oxide catalysts. The screening test of different catalysts revealed that choline hydroxide ([Choline][OH]) and 1-n-butyl-3-methyl imidazolium hydroxide([BMIm][OH]) had better catalytic performance than metal salts catalysts such as MgO, ZnO and CaO. The effects of reaction parameters such as reaction temperature, MeOH/EC mole ratio, and carbon dioxide pressure on the reactivity of [Choline][OH] catalyst were discussed. High temperature and high MeOH/EC mole ratio were favorable for high conversion of EC. However, the yield of DMC showed a maximum when carbon dioxide pressure was 1.34 MPa, and then it decreased for higher carbon dioxide pressure. Zinc chloride($ZnCl_2$) was used as co-catalyst with the ionic liquid catalyst. The mixed catalyst showed a synergy effect on the EC conversion and DMC yield probably due to the acid-base properties of the catalysts.

• Clean Technology
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• v.20 no.1
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• pp.13-21
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• 2014

Because of the water scarcity caused by the increase of salinity in the underground water, seawater desalination stands out as one of the most promising solution. As there are so much energy costs in operating desalination plants, new hybrid process which is more effective should be researched. A geothermal VMD (vacuum membrane distillation) hybrid process is a competitive alternative for seawater desalination. Because geothermal energy has significant characteristics of high capacity factor to operate the power plant at full capacity for 24 hour per day, it can be a priority heat source of VMD superior to any other renewable energies such as solar and wind power. In this study, we design a geothermal VMD hybrid process, analyze it economically and finally compare the result with a case of conventional VMD process. Geothermal VMD hybrid process generates $23,822,409 of NPV (net present value) more than the conventional VMD process in case of 5% discount rate. The break-even point between these processes is 5.36 year. Sensitivity analysis indicates that steam cost is the most decisive influence variable to the economic outcome.

• Clean Technology
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• v.13 no.2
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• pp.151-158
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• 2007

An experimental study to investigate the condensing heat transfer characteristics of small diameter horizontal double pipe heat exchangers with R-22 and R-410A was performed. Experimental facility was constructed to calculate and observe HTC(heat transfer coefficients), flow patterns and pressure drop. The main components include a liquid pump, an evaporator, a condenser(test section), a sight-glass, pressure taps and measurement apparatus. Two pipes of different diameters are tested; One 5.35 mm ID 0.5 mm thick, the other 3.36 mm ID 0.7 mm thick. The mass flow rate ranged from 200 to $500\;ks/m^2{\cdot}s$ and heating capacity were form 1.0 to 2.4 kW. The flow patterns of R-22 and R-410A were observed with a high speed camera through the sight-glass. The tests revealed that HTC of R-410A was higher than that of R-22 by maximum 5%. Annular pattern was observed for the most cases but stratified flow was also detected when x<0.2. The pressure drop in 3.36 mm ID pipe was higher than that of 5.35 mm by $30{\sim}50%$. Comparing with previous correlations such as Shah, Fujii and Soliman's, Fujii' showed the best good agreement with my data with a maximum deviation of 40%.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.21 no.2
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• pp.145-151
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• 2008

The research so far has primarily analyzed efficiency improvement but in this research, it analyzes the characteristics of earthquake behavior, with changed pier heights, through ordinary and seismic analysis. For this, the kind of bridge bearing has been changed against PSC I-shaped bridge, which is mostly used in practice, and at all times earthquake analysis has been performed with through height of pier. Especially considering sectional power resulting from earthquake analysis, displacement of PSC I-shaped bridge bearing, diameter of pier pillar by earthquake load, and upper spare gap have been analyzed. In case of high-pear, seismic isolated device is decided as proper for cars' driving and for management of bridge since it decreases movement of upper structure, than elastic bearing, reducing size of elastic connect device, and it's been analyzed it is effective for improvement of fine view and economic efficiency reducing section of lower bridge structure. Finally, when design PSC I-shaped bridge bearing, for the proper structure and high-pier side, applying seismic isolated device through precise inner analysis is proper than applying equal elastic bearing.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.31 no.5
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• pp.251-258
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• 2018

In construction site, conventional methods such as jackhammer or explosive methods(dynamite) have been often used for the demolition of structures. Use of those methods are more carefully treated in environmentally and historically sensitive area. For those reasons, use of Soundless Chemical Demolition Agent(SCDA) is getting the spotlight. The SCDA is a powder which has expansive strength when it is mixed with water. In these Characteristics, SCDA can destroy the concrete or rock as it is poured into boreholes of the concrete or rock structures. However, there is no industrial standard for the use of SCDA effectively yet. In this study, experimental study to measure the expansive pressure was conducted depending on various boundary conditions such as waterproof, length of the steel pipe, submerged of steel pipe. Furthermore, computational analysis using damage plasticity model to predict the minimum required pressure of the SCDA for the concrete demolition depending on spacing between holes(k-factor) and compressive strength of the concrete was conducted. Obtained results indicates that water heat dissipation with submerged steel pipe shows the stable pressure for measuring the SCDA and hole distance(k-factor) is the most important factor for crack initiation of concrete.

• Journal of Digital Convergence
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• v.13 no.9
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• pp.149-159
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• 2015

This paper aims to examine the relationships between Leader Supervisory Style, Creativity and Job Involvement in the age of convergence. In addition, this study examined the moderating effects of Leader-Member Exchange. To accomplish these purposes, the main factors of the Leader Supervisory Style were found from the previous studies. The following are the summary of hypothesis test : First, Leader Supervisory Style have differential influence on Creativity. Second, Leader Supervisory Style have differential influence on Job Involvement. Third, the moderating effects of Leader-Member Exchange have partially moderated effect on the relationship between Leader Supervisory Style and Creativity. Forth, the moderating effects of LMX Leader-Member Exchange have partially moderated effect on the relationship between Leader Supervisory Style and Job Involvement. Therefore, the results of this study have many theoretical and practical implications.

• Journal of Digital Convergence
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• v.11 no.11
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• pp.177-190
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• 2013

Recently, our society is seeing cultural value in a new light, perceiving it as an element that creates new values added. Reflecting this trend, the local governments in various levels focus on reviving the regional economies by enhancing cultural competencies and developing the culture and tourism industries. This research is conducted to perform the policy project 'administrative support plans to make Seongnam a hub of international culture and tourism,' which was proposed as part of the urban renewal strategy of the city. This study proposes the establishment of 'policy communities' to build the infrastructure for 'creative cultural content tourism' as a plan to accomplish the policy goal pursued by Seongnam. The focuses include what the policy communities are, how they work, and what the local government has to do with them for a successful implementation of proposed policies, by theoretically examining the composition variables of policy communities. In particular, the study concentrates on how to reconstruct the infrastructure for the culture content technology (CT) in the IT-based city and to transform itself into a city of "creative cultural content tourism". If the policy communities are formed under the proposed model in this paper, it is expected that they will become the viable alternatives in the field.

• Journal of Digital Convergence
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• v.18 no.10
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• pp.325-334
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• 2020

This study was done to examine parents, peer, teacher attachment, depression, and self-conception in adolescents. A survey using a structured questionnaire was conducted with 2,3 grade students of middle school located in 137 subjects. Data were analyzed using an independent t-test, one-way ANOVA, Pearson's correlation, and multiple stepwise regression analysis with the SPSS WIN 22.0 program. There was a significant difference in parents attachment(F=13.878, p<.001), peer attachment(F=7.431, p<.001), teacher attachment(F=7.425, p<.001), depression(F=13.241, p<.001), and self-conception(F=13.136, p<.001) according to participants' school grades. In the correlations of study variables, self-conception showed statistically significant correlations with parents, peer and teacher attachment in aspects of positive, and depression in aspect of negative. Participants' depression explained 61% of variance in self-conception. Findings from this study should be useful in the development of programs to promote participants' self-concept through their depression as a major problem in adolescent mental health.