• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.331-337
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• 2006

높은 이온전도도와 충분한 기계적 강도, 전해질 누수가 적은 새로운 형태의 고분자 전해질막(pore-gel SPE)을 연구 개발하였다. 다공성 PVDF-HFP 고분자막의 기공 내에 전해질 용액을 흡수시킨 후 막 내에서 젤화를 진행시켰다. 전해질 용액은 2:2:1의 비를 갖는 PC/EC/DMA에 1M SA(Salicylic acid)를 용해하고 여기에 고분자막을 용해시킬 수 있는 아세톤을 첨가하였다. 초음파를 이용함으로써 고분자막의 용액 흡수율을 증가시키고 또 고분자막에서 젤화를 촉진 시킬 수 있었다. 이렇게 젤화한 막의 이온전도도는 젤화 전 막보다 $1{\sim}2.2$ 배 향상되었고, 인장강도는 gel-type SPE 보다 40 배 증가하였으며, 전해질 누수실험결과 hybrid-type SPE는 13%의 누수를 보였으나 본 연구의 막(pore-gel SPE)은 6%로 감소함을 보였다.

• The Korean Journal of Rheology
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• v.7 no.2
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• pp.158-167
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• 1995

농도 5w%의 초고분자량 폴리에틸렌(분자량:1.5$\times$106)을 상온으로 냉각시켜 벨을 만 들고 이를 방사하여 섬유를 제조하였다. 이때 방사구를 나온 섬유를 $0^{\circ}C$에서 9$0^{\circ}C$까지의 냉 각조를 통과시켜 젤화/결정화 온도를 다르게 하였다. 최대 연신비는 온도가 $0^{\circ}C$에서 7$0^{\circ}C$까 지 증가함에 따라서 증가하고 9$0^{\circ}C$에서 젤화/결정화시킨 섬유의 경우에는 감소한다. 시차주 사열분석, 배향, 인자, 복굴절률, 절단강도와 탄성률을 측정하여 섬유의 물성에 대해 고찰하 였다. 연신비의 증가에 따른 결정화도, 용융 온도, 복굴절률의 증가는 높은 온도에서 젤화/ 결정화시킨 섬유인 경우가 더 뚜렷했다.

• Proceedings of the Korean Nutrition Society Conference
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• 2003.05a
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• pp.217.1-217.1
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• 2003

• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.96.1-96
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• 2002

• Bulletin of Food Technology
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• v.24 no.3
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• pp.377-387
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• 2011

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.337-340
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• 2011

This study investigates the rheological characteristics of $SiO_2$-Kerosene gel propellants with Aerosil(R) R972, Silica 230, Silica 530. Power-law rheological model is used to confirm whether or not gelification is achieved. It was found that the produced gel have shear-thinning effect, and that the viscosity of the gel propellants increases with increasing $SiO_2$ concentration. Among gellants used in this study, gel propellant with Aerosil(R) R972 fits most to the power law model as the shear rate increases. However, gels produced with Silica 230 and Silica 530 gellant deviate from the power law model when the shear rate regime is below 100 [1/s].

• Polymer(Korea)
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• v.39 no.2
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• pp.210-218
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• 2015

The reaction behavior of rigid polyurethane foams were studied on the effects of gelling catalysts of amine type, such as; dimethylcyclohexyl amine (DMCHA) and of potassium type, such as; potassium octoate (PO). Rigid polyurethane foams were provided with polymeric 4,4'-diphenylmethane diisocyanate, polyester polyol, silicone surfactant, blowing agent and a few gelling catalysts. As the contents of catalyst, DMCHA increased from 0 to 2.0 g, the reaction time decreased from ca. 330 to ca. 35 sec and due to the exothermic reaction, the maximum temperature increased from ca. 217 to ca. $234^{\circ}C$, respectively. As the contents of PO increased from 0 to 2.5 g, the reaction time decreased from ca. 79 to ca. 38 sec and the maximum temperature increased from ca. 182 to ca. $271^{\circ}C$, respectively. The kinetic parameters were calculated and the conversions were based on the temperature rising method of adiabatic process. As the content of DMCHA increased, the rate constant $k_0$ increased. But in the case of PO catalyst, $k_0$ did hardly depend upon its amount, and showed us similar reaction rate constants.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.5
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• pp.96-106
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• 2011

There are many advantages in applying gel propellant to a gel propulsion system. These include higher performances, the energy management of liquid propulsion system, reliable storability and low leakage characteristics. Additionally, gel propulsion system are preferable to the high density impulse of propulsion system. Also, when compared to liquid propellants, the gel propellants acquire greater heat energy. Gel propellants achieve a high specific impulse when metal particles with aluminum and boron are added. With respect to atomization, an inactive process occurs due to the variable viscosity of the metal particles and gelling agents. To improve the defect of atomization and combustion characteristics of gel propellant, a variety of issues related to spray and combustion is introduced here.

• Polymer(Korea)
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• v.38 no.1
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• pp.108-112
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• 2014

Novel adhesive polyaspartamides containing catechol and primary amine pendent groups were synthesized through successive ring-opening aminolysis reactions of dopamine (DOP) and ethylenediamine (EDA) with polysuccinimide (PSI). The oxidative gelation of aqueous dopamine-modified polyaspartamide was observed by adding $NaIO_4$ as the oxidizing reagent. FTIR, UV-vis and oscillatory rheometry was used to elucidate the oxidative cross-linking toward gel formation. The prepared gel was characterized by the swelling degree, thermogravimetric analysis (TGA), and by scanning electronic microscopy (SEM).

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.632-637
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• 2014

A microfluidic method for the in situ production of monodispersed alginate hydrogels using biocompatible polymer gelation by crosslinker mass transfer is described. Gelation of the hydrogel was achieved in situ by the dispersed calcium ion in the microfluidic device. The capillary number (Ca) and the flow rate of the disperse phase which are important operating parameters mainly influenced the formation of three distinctive flow regions, such as dripping, jetting, and unstable dripping. Under the formation of dripping region, monodispersed alginate hydrogels having a narrow size distribution (C.V=2.71%) were produced in the microfluidic device and the size of the hydrogels, ranging from 30 to $60{\mu}m$, could be easily controlled by varying the flow rate, viscosity, and interfacial tension. This simple microfluidic method for the production of monodisperse alginate hydrogels shows strong potential for use in delivery systems of foods, cosmetics, inks, and drugs, and spherical alginate hydrogels which have biocompatibility will be applied to cell transplantation.