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Effects of Carbon, Tungsten, and Vanadium on the Microstructure, High-Temperature Wear Properties, and Surface Roughness of High Speed Steel Rolls (고속도강롤의 미세조직, 고온마모특성, 표면조도에 미치는 탄소, 텅스텐, 바나듐의 영향)

  • Ha, Dae Jin;Sung, Hyo Kyung;Park, Joon Wook;Lee, Sunghak
    • Korean Journal of Metals and Materials
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    • v.47 no.7
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    • pp.406-415
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    • 2009
  • A study was conducted on the effects of carbon, tungsten, and vanadium on the wear properties and surface roughness of four High Speed Steel (HSS) rolls manufactured by the centrifugal casting method. Hot-rolling simulation tests were carried out using a high-temperature wear tester capable of controlling speed, load, and temperature. HSS rolls contained a large amount (up to 25 vol.%) of carbides such as MC, $M_{2}C$, $M_{7}C_{3}$, and $M_{6}C$ carbides formed in the tempered martensite matrix. The matrix consisted mainly of lath tempered martensite when the carbon content in the matrix was small, and contained a considerable amount of plate tempered martensite when the carbon content increased. The high-temperature wear test results indicated that the wear properties and surface roughness of the rolls improved when the amount of hard MC carbides formed inside solidification cells increased. The rolls distribution was also homogeneous. The best wear properties and surface roughness were obtained from a roll where a large amount of MC carbides was homogeneously distributed in the lath tempered martensite matrix. The proper contents of carbon equivalent, tungsten equivalent, and vanadium were 2.0~2.3%, 9~10%, and 5~6%, respectively.

A Study on High performance Electrical Precipitation Technology for PM Removal in Exhaust Gas (배가스 내 미세먼지 제거를 위한 고성능 집진 기술에 대한 연구)

  • Kim, Soyeon;Kim, Minsung;Choi, Sangmi;Jung, Minkyu;Lee, Jinwook
    • Plant Journal
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    • v.18 no.1
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    • pp.50-54
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    • 2022
  • The demand for high-efficiency dust collectors is rapidly increasing to remove PM from exhaust gas emission facilities, such as thermal power plants, steel mills, and industrial cogeneration plants, as the Pmemission standards have been strengthened. In this study, the electrospray is adapted for existing electrosratic precipitator(EP) to remedy its shortcomings and to improve the performance. Electrospray has been mainly used for the purpose of generating very fine droplets, but fir the purpose of EP, the flow rate over 10 mL/min per nozzleis required, and a high flow rate condition of 65 to 200 times is required. The electrospray of high flow rate has a completely different spray shape from the low flow rate condition, and was visualized through various figures such as corona discharge photographs and shadow images.

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Fabrication of surface-enhanced Raman scattering substrate using black silicon layer manufactured through reactive ion etching (RIE 공정으로 제조된 블랙 실리콘(Black Silicon) 층을 사용한 표면 증강 라만 산란 기판 제작)

  • Kim, Hyeong Ju;Kim, Bonghwan;Lee, Dongin;Lee, Bong-Hee;Cho, Chanseob
    • Journal of Sensor Science and Technology
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    • v.30 no.4
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    • pp.267-272
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    • 2021
  • In this study, Ag was deposited to investigate its applicability as a surface-enhanced Raman scattering substrate after forming a grass-type black silicon structure through maskless reactive ion etching. Grass-structured black silicon with heights of 2 - 7 ㎛ was formed at radio-frequency (RF) power of 150 - 170 W. The process pressure was 250 mTorr, the O2/SF6 gas ratio was 15/37.5, and the processing time was 10 - 20 min. When the processing time was increased by more than 20 min, the self-masking of SixOyFz did not occur, and the black silicon structure was therefore not formed. Raman response characteristics were measured based on the Ag thickness deposited on a black silicon substrate. As the Ag thickness increased, the characteristic peak intensity increased. When the Ag thickness deposited on the black silicon substrate increased from 40 to 80 nm, the Raman response intensity at a Raman wavelength of 1507 / cm increased from 8.2 × 103 to 25 × 103 cps. When the Ag thickness was 150 nm, the increase declined to 30 × 103 cps and showed a saturation tendency. When the RF power increased from 150 to 170 W, the response intensity at a 1507/cm Raman wavelength slightly increased from 30 × 103 to 33 × 103 cps. However, when the RF power was 200 W, the Raman response intensity decreased significantly to 6.2 × 103 cps.

Current Status of Lime Bordeaux Mixture Research using Properties of Lime based Minerals (석회계 광물 특성을 활용한 석회보르도액 연구 현황)

  • Kim, Young-Jin;Seo, Jun-Hyung;Kim, Yang-Soo;Cho, Kye-Hong;Cho, Jin-Sang
    • Resources Recycling
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    • v.31 no.3
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    • pp.16-26
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    • 2022
  • Limestone is the largest mineral resource in South Korea and is used in various industries, particularly as a primary raw material in the cement and iron industries. However, research on the utilization of limestone in fields such as agriculture, powder, and green chemistry is severely lacking. In this review, studies concerning the crop antibacterial industry using unslaked or slaked lime produced from limestone were analyzed. Reports regarding lime bordeaux mixture were also considered. By compiling research results, processing technologies for improving the antibacterial efficiency of lime bordeaux mixture are discussed. In addition, plans for the revitalization of research on crop antibacterial agents through the limestone processing industry were summarized.

Design and Implementation of a CMS-based Education System (CMS 기반 교육시스템의 설계 및 구현)

  • Kim, Soon-Cheol;Jeong, Hyeok
    • Journal of Korea Society of Industrial Information Systems
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    • v.14 no.5
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    • pp.103-111
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    • 2009
  • In this paper, we implement the web-based education system on CMS(Contents Management System). The goal of this paper is that Everyone who uses this system will use and maintain the web site easily. All procedures can be performed on the web and all content by the manager can be applied to users. This allows both user and administrator to use the web-based education system in a better environment. This system also will try to cover all user levels by providing web standards. So more user can use the standard web service without worrying about time and space. For this reason, this system will be developed with web standard guide so that all users won't experience any problems with the browsers of primary platforms complying with W3C. This paper can provide the possibility to overcome the limitations of current web-based education system.

Life Cycle Analysis of Greenhouse Gas Emissions of By-Product Hydrogen Produced from Coke Oven Gas in Steel Mill (제철소 코크스 오븐 가스 부생수소 전과정 온실가스 배출량 분석)

  • YEIM LEE;WOOJAE SHIN;YEJIN YU;HANHO SONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.636-642
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    • 2022
  • The "Hydrogen Economic Activation Road map" was announced in 2019, and hydrogen demand is expected to exceed 470,000 tons per year in 2022 and keep increasing. Under this circumstance, it has become important to understand the greenhouse gas (GHG) emissions associated with various hydrogen production pathways. In this study, the evaluation of life cycle GHG emissions regarding the hydrogen produced as by-product from coke oven gas (COG) in steel mill is conducted. To cover the possible range of operations, three literatures were reviewed and their data of inputs and outputs for the process were adopted for calculation. Life cycle inventories and emission factors were mostly referred to GaBi and Intergovernmental Panel on Climate Change (IPCC) guidelines, respectively. When there are multiple products from a single process, the energy allocation method was applied. Based on these sources and the assumptions, the life cycle emission values of COG-based hydrogen were found to be 3.8 to 4.7 kg/CO2-eq./kg-H2.

Tidal current and river plume distribution characteristics before and after the development of the Kwangyang Bay (광양만 개발 전·후 조류 및 하천유출류 변동 특성)

  • Kim, Cha Kyum
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.102-102
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    • 2021
  • 광양만의 해수교환은 주로 여수해만을 통해 이루어지고, 만의 동측에는 노량수로를 통해 진주만으로의 해수교환이 일어나고 있으며, 만의 북측에는 섬진강을 끼고 있다. 광양항 건설 전 만내의 수심은 약 10 m 이내로 얕았으며, 만의 입구인 여수해만과 노량수로에서의 수심은 약 20 m 이상이었다. 광양만은 1982년 광양제철소의 건설을 시점으로 하여 광양항의 확장 개발, 폐기물처리장 건설 등으로 인한 매립이 진행되었다. 특히, 섬진강 하구는 광양만 개발 전에는 넓은 조간대 퇴적층의 발달로 다양한 생태계환경을 유지하고 있었으나, 광양항 건설 및 하구에서 모래 준설 등으로 인해 근래에 와서는 해수의 역류가 심각한 상태이다. 1982년 광양제철소 건설이후 계속적으로 광양만을 개발함으로써 해양환경에 큰 변화가 발생하였다. 따라서, 본 연구에서는 광양만 개발 전·후의 조석 및 해수유동의 변화특성을 해석하기 위해 조석 및 조류에 대한 현장관측과 3차원 해수유동 수치모형실험을 수행한 후 남해도를 둘러싸고 있는 광양만, 진주만 등의 조석 및 조류의 변동특성을 해석하였다. 광양만 개발 전·후의 해수유동의 변동특성을 해석하기 위해 김 등(1999)에 의해 개발된 3차원 layer·level 혼성 해수유동 모델을 광양만, 진주만을 포함하는 남해도 주변해역에 적용하여 30일간의 수치계산결과를 이용하여 해수유동의 변동특성을 해석하였다. 모델에서 격자간격은 동서-남북방향 동일하게 200 m, 시간간격은 20 sec, 계산영역은 동서방향으로 52 km, 남북방향으로 65 km인 260×325 격자체계로 구성 운영하였다. 외해 개방경계에서 조위는 수로국에서 관측한 조위와 본 연구에서 관측한 조위를 보간하여 사용하였다. 광양만 개발전·후의 조류의 변동특성을 수치해석한 결과 여수해만에서는 광만만 개발전이 개발 후보다 유속이 강하게 나타났으나, 노량수로에서는 개발 후가 개발전보다 유속이 훨씬 강하게 나타났다. 이와 같은 현상은 광양만 개발로 광양만으로 유입되는 조량이 감소함으로 인해 여수해만에서는 유속이 감소한 것으로 생각된다. 노량수로에서 개발 후가 개발전보다 유속이 증가한 것은 여수해만을 통해 유입한 해수가 개발 후에는 광양만의 해수면적 감소로 광양만의 서측으로 유입하는 조량이 감소한 반면에 광양만의 북측(섬진강 하구) 또는 동측(노량수로)으로 유입하는 조량이 많기 때문인 것으로 사료된다.

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A Study on the Volatility Transition of Steel Raw Material Transport Market (제철원료 운송시장의 변동성 전이 분석에 대한 연구)

  • Yo-Pyung Hwang;Ye-Eun Oh;Keun-Sik Park
    • Korea Trade Review
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    • v.47 no.4
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    • pp.215-231
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    • 2022
  • Analysis and forecasting of the Baltic Capsize Index (BCI) is important for managing an entity's losses and risks from the uncertainty and volatility of the fast-changing maritime transport market in the future. This study conducted volatility transition analysis through the GARCH model, using BCI which is highly related to steel raw materials. As for the data, 2,385 monthly data were used from March 1999 to March 2021. In this study, after basic statistical analysis, unit root and cointegration test, the GARCH, EGARCH, and DCC-GARCH models were used for volatility transition analysis. As the results of GARCH and EGARCH model, we confirmed that all variables had no autocorrelation between the standardized residuals for error terms and the square of residuals, that the variability of all variables at this time was likely to persist in the future, and that the variability of the time-series error term impact according to Iron ore trade (IoT). In addition, through the EGARCH model, the magnitude convenience of all variables except the Iron ore price (IOP) and Capesize bulk fleet (BCF) variables was greater than the positive value (+). As a result of analyzing the DCC-GARCH (1,1) model, partial linear combinations were confirmed over the entire period. Estimating the effect of variability transition on BCF and C5 with statistically significant linear combinations with BCI confirmed that the impact of BCF on BCI was greater than the impact of BCI itself.

An Investigation into Ultrasonic Flotation Separation of Spent MgO-C Refractories Using Acetic Acid (아세트산을 활용한 폐 마그카본(MgO-C) 내화물의 초음파 부상 분리에 관한 연구)

  • Yunki Byeun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.40-46
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    • 2024
  • A novel approach is presented to address issues associated with the use of strong acidic solutions for the leaching of magnesium oxide (MgO) from spent magnesia-carbon refractories. An ultrasonic flotation and separation process is employed, with a mildly acidic solvent, acetic acid, used to selectively chelate MgO from the spent refractories. When using 2 M acetic acid as a solvent, the recovery of the graphite exhibited 99.7 % with high purity of 72.7 %, showing a significant improvement compared to using water as the solvent. Furthermore, the technology presented in this study offers a method for producing magnesium acetate through the reaction of MgO in spent refractory with acetic acid, providing a means for the purification and separation of graphite.

A Semi-analytical Approach for Numerical Analysis of Residual Stress in Oxide Scale Grown on Hot-rolled Steels (열간압연강에서 형성된 산화물 스케일의 잔류 응력 수치 분석을 위한 준해석적 방법 개발)

  • Y.-J. Jun;J.-G. Yoon;J.-M. Lee;S.-H. Kim;Y.-C. Kim;S. Nam;W. Noh
    • Transactions of Materials Processing
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    • v.33 no.3
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    • pp.200-207
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    • 2024
  • In this study, we developed a semi-analytical approach for the numerical analysis of residual stress in oxide scales formed on hot-rolled steels. The oxide scale, formed during the hot rolling process, experiences complex interactions due to thermal and mechanical influences, significantly affecting the material's integrity and performance. Our research focuses on integrating various stress components such as thermal stress, growth stress, and creep behavior to predict the residual stress within the oxide layer. The semi-analytical method combines analytical expressions for each stress component with numerical integration to account for their cumulative effects. Validation through instrumented indentation tests confirms the reliability of our model, which considers thermal expansion coefficient (CTE) differences, scale growth, and creep-induced stress relaxation. Our findings indicate that thermal stress resulting from CTE differences significantly impacts the overall residual stress, with growth stress contributing a compressive component during cooling, and creep behavior playing a minor role in stress relaxation. This comprehensive approach enhances the accuracy of residual stress prediction, facilitating the optimization of material design and processing conditions for hot-rolled steel products.