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Determination of Trace-Level Perchlorate by IC-MS/MS and Distribution in the Han River (IC-MS/MS를 이용한 수중의 과염소산이온 분석방법 최적화 및 한강수계내 분포조사)

  • Kim, Hyun-Hee;Han, Ihn-Sup;Jeong, Gwan-Jo;Park, Hyeon;Han, Sun-Hee;Cho, Wan-Seon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.4
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    • pp.349-356
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    • 2010
  • Ion chromatography (IC) coupled with conductivity detector (CD) is a common system for the determination of perchlorate in water samples. Although the IC method with CD has been widely used for the determination of trace level perchlorate ion in water, sensitivity decreases dramatically as the complexity of the matrices increases. Here we proposed the application of ion chromatography coupled with mass spectrometry (IC-MS/MS) to significantly improve selectivity of perchlorate. The mean recovery of the method was 104.4 ${\pm}$ 5.7% and the relative standard deviation (RSD%) was 1.9 ${\pm}$ 1.3%. The alculated method detection limit (MDL) was 0.0207 ${\pm}$ 0.0099 ${\mu}g/L$. The concentrations of perchlorate were minimum <0.1 ${\mu}g/L$ and maximum 18.3 ${\mu}g/L$ in source water (Namhan, Bukhan and Han River). Hongreung showed higher concentrations ($1^{st}$-14.3 ${\mu}g/L$, $2^{st}$-18.3 ${\mu}g/L$) than the other places. And the concentrations of perchlorate were 0.18~0.34 ${\mu}g/L$ in the samples taken from the six water treatment plants and six intake stations in Seoul.

Length of Estrous Cycle and Duration of Estrus following Natural and Induced Estrus in Korean Native Goats (山羊의 自然 및 誘起發情時 發情週期 및 發情持續時間에 관한 硏究)

  • Lee, Ji-Sam;Song, U-Jun;Choe, Gyeong-Mun;Park, Chung-Saeng
    • Korean Journal of Animal Reproduction
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    • v.15 no.1
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    • pp.59-66
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    • 1991
  • This study was carried out to investigate the length of the estrous cycle and duration of estrus in Korean native goats. The effects of the type of last estrus : induced or natural, and the length of preceeding estrous cycle on the subsequent cycle and duration of estrus in goats were also examined. From 481 observations, the mean length of estrous cycles was 18.1${\pm}$0.5days. The cycle length was significantly(P<0.05) shorter following induced estrus (15.2${\pm}$0.8 d) than natural estrus(19.0${\pm}$0.6 d). Significantly higher(P<0.05) incidence of short estrous cycle was observed following induced estrus(40%) than natural estrus(27%). The frequency distribution in the estrous cycle was 30%, 3%, 56% and 11% for short(3-11 d), medium(12-16 d), normal(17-24 d) and long(${\geqq}$25 d), respectively. The most frequent type of short estrous cycle was 6 days in length. Mean duration of estrus was 34.0${\pm}$0.5 h with a range of 18 to 84 h. Duration of estrus was not significantly different the preceeding natural (33.8${\pm}$0.6 h) and induced estrus (34.4${\pm}$1.1 h), and was not significantly affected by the last cycle length. These results suggest that the short estrus cycles are more frequent following induced estrus than natural one, and the duration of estrus are affected greatly by the various intrinsic and extrinsic factors.

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Two-dimensional Numerical Simulation of Rainfall-induced Slope Failure (강우에 의한 사면붕괴에 관한 2차원 수치모의)

  • Regmi, Ram Krishna;Jung, Kwan-Sue;Lee, Gi-Ha
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.34-34
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    • 2012
  • Heavy storms rainfall has caused many landslides and slope failures especially in the mountainous area of the world. Landslides and slope failures are common geologic hazards and posed serious threats and globally cause billions in monetary losses and thousands of casualies each year so that studies on slope stability and its failure mechanism under rainfall are being increasing attention of these days. Rainfall-induced slope failures are generally caused by the rise in ground water level, and increase in pore water pressures and seepage forces during periods of intense rainfall. The effective stress in the soil will be decreased due to the increased pore pressure, which thus reduces the soil shear strength, eventually resulting in slope failure. During the rainfall, a wetting front goes downward into the slope, resulting in a gradual increase of the water content and a decrease of the negative pore-water pressure. This negative pore-water pressure is referred to as matric suction when referenced to the pore air pressure that contributes to the stability of unsaturated soil slopes. Therefore, the importance is the study of saturated unsaturated soil behaviors in evaluation of slope stability under heavy rainfall condition. In an actual field, a series of failures may occur in a slope due to a rainfall event. So, this study attempts to develop a numerical model to investigate this failure mechanism. A two-dimensional seepage flow model coupled with a one-dimensional surface flow and erosion/deposition model is used for seepage analysis. It is necessary to identify either there is surface runoff produced or not in a soil slope during a rainfall event, while analyzing the seepage and stability of such slopes. Runoff produced by rainfall may result erosion/deposition process on the surface of the slope. The depth of runoff has vital role in the seepage process within the soil domain so that surface flow and erosion/deposition model computes the surface water head of the runoff produced by the rainfall, and erosion/deposition on the surface of the model slope. Pore water pressure and moisture content data obtained by the seepage flow model are then used to analyze the stability of the slope. Spencer method of slope stability analysis is incorporated into dynamic programming to locate the critical slip surface of a general slope.

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Application of MPI Technique for Distributed Rainfall-Runoff Model (분포형 강우유출모형 병렬화 처리기법 적용)

  • Chung, Sung-Young;Park, Jin-Hyeog;Hur, Young-Teck;Jung, Kwan-Sue
    • Journal of Korea Water Resources Association
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    • v.43 no.8
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    • pp.747-755
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    • 2010
  • Distributed Models have relative weak points due to the amount of computer memory and calculation time required for calculating water flow using a numerical analysis based on kinematic wave theory when compared to the conceptual models used so far. Typically, the distributed models have been mainly applied to small basins. It was necessary to decrease the resolution of the grid to make it applicable for large scale watersheds, and because it would take up too much time to calculate using a higher resolution. That has been one of the more difficult factors in applying the model for actual work. In this paper, MPI (Message Passing Interface) technique was applied to solve the problem of calculation time as it is one of the demerits of the distributed model for performing physical and complicated numerical calculations for large scale watersheds. The comparison studies were performed a single domain and a divided small domain in Yongdam Dam watershed in case of typoon 'Ewiniar' at 2006. They were compared to analyze the application effects of parallelization technique. As a result, a maximum of 10 times the amount of calculation time was saved but keeping the level of quality for discharge by using parallelization code rather than a single processor.

Water Supply Change Outlook for Geum River Basin Considering RCP Climate Change Scenario (RCP 기후변화 시나리오를 고려한 금강유역의 미래 용수공급 변화전망)

  • No, Sun-Hee;Jung, Kwan Sue;Park, Jin Hyeog;Ryoo, Kyong Sik
    • Journal of Korea Water Resources Association
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    • v.46 no.5
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    • pp.505-517
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    • 2013
  • In this study, water supply for Geum River Basin was calculated by regulating the future water supply of Dam with the future expected discharges. HadGEM2-AO, which is the climate change prediction model that KMA (Korea Meteorological Administration) recently introduced was used for this study. The data of weather stations within the Geum River basin was extracted with the new Greenhouse Gas RCP scenario. The runoff of Geum river basin was simulated using the ArcSWAT for the 1988~2010 period. After validating the model, the similarity of results between simulation and observation at the Yongdam Dam and Daecheong Dam was 92.25% and 95.40%, respectively, which shows a good agreement with observed data. As the result of analysis for the discharges, the discharges would increase 47.76% under the RCP4.5 scenario and 36.52% under the RCP8.5 scenario. Water balance analysis was conducted by the KModSim for predicting the water supply under the runoff variation. We analyzed the volume of water intake with national standard of water supply 95% by Dam Operation Manual. By the analysis under RCP4.5 scenario, $9.41m^3/s$, $24.82m^3/s$ of additional water supply is available on Yongdam Dam and Daecheong Dam. By the analysis under the RCP8.5 scenario, $6.48m^3/s$, $21.08m^3/s$ of additional water supply is available on Yongdam Dam and Daecheong Dam.

Analysis of runoff aggregation structure and energy expenditure pattern for Choyang creek basin on the basis of power law distribution (멱함수 법칙분포를 기반으로 한 조양하 유역의 유출응집구조와 에너지소비 양상에 대한 해석)

  • Kim, Joo-Cheol;Cui, Feng Xue;Jung, Kwan Sue
    • Journal of Korea Water Resources Association
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    • v.50 no.11
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    • pp.725-734
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    • 2017
  • The main purpose of this study is to analyze runoff aggregation structure and energy expenditure pattern of Choyang creek basin within the framework of power law distribution. To this end geomorphologic factors of every point in the basin of interest, which define tractive force and stream power as well as drainage area, are extracted based on GIS, and their complementary cumulative distributions are graphically analyzed through fitting them to power law distribution. The results indicate that three distinct behavioral regimes are observed from the complementary cumulative distributions of three geomorphogic factors. Based on the parameter estimation of power law distribution by maximum likelihood drainage area and stream power can be judged as scale invariance factor without finite scale while tractive force as scale dependence factor with finite scale. Furthermore, it is judged that tractive force would not follow power law distribution because it shows limited complex system behaviors only within the small extent of scale. The exponent of power law distribution for drainage area obtained in this study by maximum likelihood is larger than the previous researches due to the difference of parameter estimation methodologies. And the exponent for stream power is smaller than the previous researches due to the scaling property of channel slope for the basin of interest.

Numerical study on flow characteristics at dividing open-channel with changing bifurcation angle using TELEMAC-2D (TELEMAC-2D모형을 이용한 분류각 변화에 따른 개수로 흐름특성변화 수치모의 연구)

  • Jung, Daejin;Jang, Chang-Lae;Jung, Kwansue
    • Journal of Korea Water Resources Association
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    • v.53 no.8
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    • pp.617-626
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    • 2020
  • This study investigates changes of bifurcation discharge ratio, flow velocity distributions and characteristics of separation zone due to variation of bifurcation angle by using TELEMAC-2D model. When the bifurcation angle is reduced from 90° to 45° without changing the boundary conditions, the bifurcation discharge ratio increased by 1.5 times from 0.523 to 0.785 because of increasing the radius of curvatures, the inertia force of the downstream flow, and the pressure gradient by the downstream boundary conditions. The bifurcation discharge ratio increases non-linearly whenever the bifurcation angle decreases by 15° intervals from 90° to 45° in flow with the upstream Froude number of 0.45 to 0.74. In flow with a maximum Froude number of 0.74, the rate of increase for bifurcation discharge ratio is 31.1% and the minimum value. When the Froude number is 0.58, the bifurcation discharge ratio is 0.7 or less, and the maximum rate of increase for that ratio is 53.5%. As the upstream Froude number decreases less than 0.58, the bifurcation discharge ratio exceeds 0.7, and the rate of increase decreases. When the upstream Froude number is 0.4 higher, the dimensionless width and length changing ratio of the separation zone are about 2.56 and 5.5 times higher than in 0.4 or less.

TISSUE LEVELS OF INTERLEUKIN-1α, INTERLEUKIN-1β AND TUMOR NECROSIS FACTOR-α IN PULPAL AND PERIAPICAL PATHOSIS (치수 및 치근단병소에서 interleukin-1α, interleukin-1β, tumor necrosis factor-α의 분포에 관한 연구)

  • Ko, Hyun-Jung;Chung, Kwan-Hee;Lim, Sung-Sam
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.316-327
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    • 1998
  • This study was designed to examine the tissue levels of interleukin-$1{\alpha}$(IL-$1{\alpha}$), interleukin-$1{\beta}$(IL-$1{\beta}$) and tumor necrosis factor-${\alpha}$(TNF-${\alpha}$) in inflamed human dental pulps and periapical lesions, and to determine the relationship between each cytokine and pulpal and periapical pathosis. The pulps used in this experiment, were obtained in routine endodontic treatment and the periapical lesions in periapical surgery after clinical diagnoses were performed. These specimens were divided into four groups as normal pulp group(control group, n=9), acute pulpitis group(n=g), chronic pulpitis group(n= 10) and periapical lesion group(n= 18) and stored in liquid N2. For extract preparation, tissues were finely minced with a scalpel, and the fragments were incubated in $0.5m\ell$ homogenizing buffer (0.1 mol/L potassium chloride, 0.02 mol/L TRIS; pH=7.6) for two hours and grinded with glass homogenizer. Debris was removed by centrifugation and supernatants were immediately tested with enzymelinked immunosorbent assay (ELISA, R&D Co., Minneapolis, USA). Following results were obtained; 1. The concentrations of IL-$1{\alpha}$ in all experimental groups were significantly higher than in control group(p<0.05). And the concentrations of IL-$1{\alpha}$ in periapical lesion group were somewhat higher than in two pulpitis groups, but the differences among those groups were not stastically significant (p>0.05). 2. The concentrations of IL-$1{\beta}$ in all experimental groups were significantly higher than in control group (p<0.05), and all the experimental groups expressed similar concentrations. 3. The concentrations of TNF-${\alpha}$ in all experimental groups were higher than in control group but only the differences between chronic pulpitis group and control group were statistically significant(p<0.05). And the concentrations of TNF-${\alpha}$ in acute and chronic pulpit is groups were higher than in periapical lesion group but only the differences between chronic pulpitis group and periapical lesion group were statistically significant (p<0.05). 4. There was significant correlation only between IL-$1{\alpha}$ and IL-$1{\beta}$ in periapical lesion group (p<0.05).

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The Distributions of Liquid Water Content(LWC) and the Potential Enhancement of Precipitation over Andong Area observed from Microwave Radiometer (Microwave radiometer를 이용한 안동지역의 수액량 및 증우가능량 추정)

  • 정관영;김효경;이선기;정영선
    • Korean Journal of Remote Sensing
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    • v.14 no.2
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    • pp.165-174
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    • 1998
  • The observation of liquid water content(LWC) and the estimation of precipitation enhancement by cloud seeding were made over the Andong in Korea from March 1997 through Feb 1998. A dual-channel microwave radiometer was used to measure the liquid water content and water vapor. It was shown that the 90% of observational period had the amount of less than 0.1 mm in LWC, and that the amount of precipitation was proportionally increased to liquid water content. The amount of LWC has maximum in summer and minimum in winter. The content of liquid cloud water was showed higher value from the time of 12 to the time of 17 except for summer season in which it extremely fluctuated with a large precipitation. The majority of liquid water content over the area occurred with westerly and southwesterly wind which were flowed from the Sobaek mountain. The ratio of horizontal LWC flux and vertical precipitation flux, $P_{en}$ is almost ranked in the interval of 0.0~0.5 with maximum of 0.5 in spring, 0.2 in summer and fall, and 0.1 in winter. Accordingly, it is estimated that the potential enhancement of precipitation over Andong area by cloud seeding has high value in spring with westerly wind.

Numerical Analysis of Flow Characteristics for Bifurcation Channel Depending on Channel Planform Change using TELEMAC-2D (TELEMAC-2D를 이용한 분류부 평면형상 변화에 따른 흐름특성 수치모의)

  • Jung, Dae Jin;Jang, Chang-Lae;Jung, Kwan Sue
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.257-257
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    • 2019
  • 최근 기후변화에 따른 대응을 위해 기존 수자원 활용의 고도화 및 배수능력 증대를 위해 다양한 방안이 추진되고 있으며, 그에 따라 기존 개수로에 신규 수로를 연결하여 합류와 분류를 시키는 사례가 증가하고 있다. 특히 신규 개수로 연결을 위한 분류부 형상은 관련 설계기준, 분류유량의 규모, 해당 지점의 하상변동 경향, 지형여건, 흐름 분류시설 및 구조물의 형태(양수펌프장, 스크린이나 수문, 암거설치)와 같은 구조적 요인 등에 의해 달라지지만, 이와 관련된 연구가 매우 부족한 실정이다. 따라서 본 연구에서는 2차원 수치모형을 이용하여 분류부 평면형상 변화에 따른 분류유량비와 흐름분리구역 분포 등에 대한 흐름특성을 분석하고 이수와 치수계획 수립 등에 활용하고자 한다. 본 연구에서는 TELEMAC-2D 모형을 이용하여 주수로 상류 유입흐름의 프루우드 수가 0.74, 0.52인 두 흐름에 대해 형상변화 폭을 주수로 폭(B)의 1B, 주수로 형상변화를 급확대, 점진적 확대 구간길이를 1B~3B로 변화시키며 분류유량비(분류수로 유입유량/상류 유입유량)와 흐름분리구역의 위치와 크기 등에 대한 분석을 수행하였다. 분류부 상류 유입흐름의 프루우드 수가 0.74, 분류유량비는 0.33인 흐름은 주수로 형상변화 구간길이가 1B 일 때 0.44~0.46, 3B일 때 0.54~0.60으로 점차 분류유량비가 증가한다. 반면 상류 유입흐름의 프루우드수가 0.52, 분류유량비가 0.52인 흐름은 주수로 형상변화 구간길이가 1B일 때 0.77~0.82에서 3B일 때 0.70~0.80으로 점차 분류유량비 증가율이 감소하는 경향을 나타내게 된다. 주수로 형상변화 폭을 0.5B, 1B로 달리하여 수로 형상변화를 시킨 경우 분류유량비 증가율은 각각 135~162%, 134~176%로 나타났으며, 이는 수로 형상변화 폭보다 변화구간 길이가 더 큰 분류유량비 변화에 영향을 미치는 것을 확인할 수 있다. 흐름분리구역은 상류 유입흐름의 프루우드 수가 0.74인 경우 수로형상 변화구간과 분류수로 입구에 형성되지만, 상류유입흐름의 프루우드 수가 0.52인 경우 수로형상변화 구간과 주수로 하류에도 형성된다. 수치실험 결과 동일수로 폭 직사각형 $90^{\circ}$ 분류수로에서 분류부 평면형상의 변화에 따라 주수로 하류방향흐름의 관성력은 감소하는 반면 분류수로로 향하는 횡압력경사와 흐름분리구역 발생위치 변화로 인해 분류 수로내 통수능이 증가하여 분류유량비가 급격하게 증가하게 된다. 또한 분류부 상류 유입흐름의 관성력이 작은 경우 분류부 평면형상 변화시 주수로 하류방향에서도 흐름분리구역이 형성되고 주수로 종방향 수위가 상승함에 따라 분류흐름 계획수립 시 세심한 주의가 필요하다.

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