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Rotations between Erythroblasts and Kupffer Cells in Human Fetal Hepatic Erythropoiesis - Trasmission and Scanning Electron Microscopic Observation (태아 간 적혈구형성에서 별큰포식세포의 적혈구모세포섬형성 - 투과 및 주사전자현미경적 관찰)

  • Lee, Won-Bok;Shin, Do-Shik;Kim, Kyung-Yong
    • Applied Microscopy
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    • v.29 no.1
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    • pp.43-56
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    • 1999
  • The relationship between intravascular erythroblasts and Kupffer cells in the human fetal liver from 11 to 20 week gestation was studied ultrastructurally. The walls of the developing sinusoids consisted of two cell types devoid of basal lamina, the nonfenestrasted endothelial cells and Kupffer cells. Kupffer cells examined were easily identified by their content of phagosmes and their morphological features, and partially proliferated by mitotic division which was different way of proliferation from adult. Some extruded nuclei of acidophilic erythroblasts were trapped within Kupffer cells which exhibited various stages of intracellular digestion of the nuclei. During high activity of human fetal hepatic erythropoiesis, Kupffer cells were found in association with developing erythrob-lasts, which was similar with erythroblastic islands. The developing erythroblasts were partially surrounded by multilaminated membrane system of the Kupffer cell consisting erythroblastic island, or in contact with Kupffer cell via cytoptasmic processes in the sinu-soidal lumen. The presence of these islands was confirmed by transmission and scanning electron microscopic study. The results demonstrate that Kupffer cells in fetal heaptic erythropoiesis phagocytized expelled nuclei and contributed to erythropoiesis mechanically and physiologically by the hypertrophy and the formation of erythroblastic islands.

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Removal of Volatile Organic Contaminant(toluene) from Specific Depth in Aquifer Using Selective Surfactant-Enhanced Air Sparging (계면활성제와 폭기를 이용한 대수층의 특정깊이에 존재히는 휘발성 유기오염물질 (톨루엔)의 휘발제거)

  • Song, Young-Su;Kwon, Han-Joon;Yang, Su-Kyeong;Kim, Heon-Ki
    • Economic and Environmental Geology
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    • v.43 no.6
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    • pp.565-571
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    • 2010
  • An innovative application of surfactant-enhanced air sparging(SEAS) technique was developed in this study. Using a laboratory-scale physical model packed with water-saturated sand, air sparging was implemented to remove water-dissolved toluene that was introduced into a specific depth of the system with finite vertical width prior to sparging. An anionic surfactant(Sodium dodecylbenzene sulfonate) was introduced into the contaminated layer as in dissolved form in the toluene-contaminated solution for SEAS, whereas no surfactant was applied in the control experiment. Due to the suppressed surface tension of water in the surfactant(and toluene)-containing region, the toluene removal rate increased significantly compared to those without surfactant. More than 70% of the dissolved toluene was removed from the contaminated layer for SEAS application while less than 20% of toluene was removed for the experiment without surfactant. Air intrusion into the contaminated layer during sparging was found to be more effective than that without surfactant, enhancing air contact with toluene-contaminated water, which resulted in improved volatilization of contaminant. This new method is expected to open a new option for remediation of VOC(volatile organic compound)-contaminated aquifer.

Leaching Behavior of Gold from CPU chip Grinding Products in Iodide/Iodine Solution (Iodide/Iodine용액에서 CPU chip 분쇄물의 금 침출특성)

  • Jung, Insang;Joe, Aram;Choi, Joonchul;Song, Youjin;Park, Poongwon;Park, Kyungho;Lee, Sujeong;Park, Jaikoo
    • Resources Recycling
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    • v.25 no.1
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    • pp.3-9
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    • 2016
  • The leaching behavior of gold from waste CPU chip using Iodide/Iodine solution was studied. The direct leaching of gold with Iodide/Iodine solution for CPU chip under the size of 150 mesh showed leaching ratio of 20%. It was assumed that the copper film was produced on the gold particle during grinding process and the copper film prevents lodine/Iodide solution from contacting with leachable gold. Meanwhile, the extraction of gold was improved to 90% by pretreatment process with $HNO_3$ solution. In order to explain the result, EDS and ICP analysis for the leaching residue were conducted. It was found that the copper coated on the surface of the gold particle was removed about 80% by $HNO_3$, resulting in the increment of gold leaching rate.

Equilibrium, Kinetics and Thermodynamic Parameters Studies on Metanil Yellow Dye Adsorption by Granular Activated Carbon (입상활성탄에 의한 메타닐 옐로우 염료의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.96-102
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    • 2014
  • Adsorption of metanil yellow onto granular activated carbon were studied in a batch system. Various operation parameters such as adsorbent dosage, pH, initial concentration, contact time and temperature were optimized. Experimental equilibrium adsorption data were analyzed by Langmuir and Freundlich adsorption isotherm. The equilibrium process was described well by Freundlich isotherm model. From determined separation factor (1/n), adsorption of metanil yellow by granular activated carbon could be employed as effective treatment method. By analysis of kinetic experimental data, the adsorption process were found to confirm to the pseudo second order model with good correlation and the adsorption rate constant ($k^2$) decreased with increasing initial concentration. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The activation energy was determined as 23.90 kJ/mol. It was found that the adsortpion of metanil yellow on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G=-2.16{\sim}-6.55kJ/mol$) and the positive enthalpy change (${\Delta}H=+23.29kJ/mol$) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

Effects of Ozone Treatment to Pig Liquid Manure on Reduction of Odorous Gases (돈분뇨 액비의 악취저감을 위한 오존처리 효과)

  • Jeong, J.W.;Yoo, Y.H.;Park, K.H.;Kam, D.H.;Choi, H.J.;Kim, T.I.;Cho, Y.S.
    • Journal of Animal Environmental Science
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    • v.13 no.3
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    • pp.161-170
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    • 2007
  • Ozone from a pilot-scale ozone generator was treated on fermented pig liquid manure stored in a storage tank in order to reduce odor substances during the process of fermented liquid manure production. The group of ozone treatment showed one less than the organic matter compared that of the control. The preferable condition for characteristic changes was when the ratio of BOD to COD was less than 1.5. Ozone treatment showed better oxidizing power than control as it removed more suspended solids and had less methyl isobutyl ketone(P<0.05). Odor reduction measured by olfactory method was higher in ozone treatment than in control.

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Antimicrobial Chitosan-silver Nanocomposite Film Prepared by Green Synthesis for Food Packaging (녹색합성법에 기인한 식품포장용 키토산-은나노 항균 복합필름의 개발)

  • Kyung, Gyusun;Ko, Seonghyuk
    • Korean Journal of Food Science and Technology
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    • v.46 no.3
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    • pp.347-351
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    • 2014
  • We studied the green synthesis and antibacterial activity of chitosan-silver (Ag) nanocomposite films for application in food packaging. Green synthesis of Ag nanoparticles (AgNPs) was achieved by a chemical reaction involving a mixture of chitosan-silver nitrate ($AgNO_3$) in an autoclave at 0.1 MPa, $121^{\circ}C$, for 15-120 s. The formation of AgNPs in chitosan was confirmed by both UV-Visible spectrophotometry and transmission electron microscopy (TEM) and the effects of chitosan-$AgNO_3$ concentration and reaction time on the synthesis of AgNPs in chitosan were examined. The resulting chitosan-Ag composite films were characterized by various analytical techniques and their antibacterial activity was evaluated based on the formation of halo zones around films, indicating inhibition of the growth of Escherichia coli. A fourier-transform infrared (FTIR) spectroscopy analysis showed that free amino groups in chitosan acted as effective reductants and AgNP stabilizers. The composite films exhibited enhanced antibacterial activity with increasing Ag content on the surface of as-prepared composite films.

Property Change of Heat-reservoir Refractory Brick With Varying Compositions and Sintering Conditions Utilizing Mill-scale and Red-firing Clay As Raw Materials (밀스케일과 적점토를 원료로한 축열재에서 원료성분과 소성조선에 따른 특성 변화)

  • Kim, Jeong-Seog;Kim, Hong
    • Resources Recycling
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    • v.8 no.1
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    • pp.23-28
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    • 1999
  • Firing characteristics, transverse rupture strength, and heat capacity were studied of the heat-reservoir refractory materials made of red-firing clay, mill scale, and water glass. The firing shrinkage increased with increase of the clay proportion in samples. The volume of fired bodies showed shrinkage by drying up to $300^{\circ}C$, steady expansion in the 300-$700^{\circ}C$ range due to phase transition of iron oxides. and drastic expansion above $1200^{\circ}C$. Flexural strength decreased from 5.6 Mpa to 2.35 Mpa with the decrease of the ratio of clay to mill scale from 1:1 to 1:3 Heat capacities changed from 1.1 Joul/g$^{\circ}$C to 1.35 Joul/g$^{\circ}$C with the ratio of millscale to clay ratio from 1:1 to 1:3. Mill scale in the specimen appears to exist as liquid phase during firing. Firing the specimens in air leads to the eruption of the molten mill scale to the sample surfaces. Contrarily, firing samples in a refractory sagger with a cover suppressed the eruption of the molten mill scale to the surfaces. The addition of mill scale gave rise to porous sintered bodies which would delay cooling rates of heat-reservoir brick.

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A Study on the Culture of the French Language (프랑스어 단어 속에 담긴 문화연구)

  • Kwak, No-Kyung
    • Cross-Cultural Studies
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    • v.48
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    • pp.135-191
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    • 2017
  • The purpose of this study was to select words with "shared cultural charge" that are unique in French culture and to study cultural content hidden in these words. It also explores the cultural phenomenon of same French borrowed words used in the Korean language. The study was conducted from two perspectives: perspective of internal French culture defined by Galisson and inter-cultural perspective. The first section of this study introduces the theory "lexiculture" and definition of the words "shared cultural charge." In the following section, among main items of 795 borrowed words in the Korean language, we examined seven words in areas such as clothing, food, and housing. We studied content of the French culture according to the following three categories: (1) dictionary definition, (2) cultural phenomena, (3) special phenomenon in idiomatic expression. Our study illustrated a special connotation beyond the dictionary definition of words. In the next section, we examined the birth of a new cultural phenomenon and process of acquiring a new meaning in the Korean language. Finally, we analyzed differences and similarities between linguistic and cultural elements in both cultures. In this study, we provide basic data for inter-cultural education between France and Korea.

Study on Adsorption Equilibrium, Kinetic and Thermodynamic Parameters of Murexide by Activated Carbon (입상 활성탄에 의한 Murexide의 흡착 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.25 no.1
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    • pp.56-62
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    • 2019
  • The equilibrium, kinetic and thermodynamic parameters of adsorption of murexide by granular activated carbon were investigated. The experiment was carried out by batch experiment with the variables of the amount of the adsorbent, the initial concentration of the dye, the contact time and the temperature. The isothermal adsorption equilibrium was best applied to the Freundlich equation in the range of 293 ~ 313 K. From the separation factor (${\beta}$) of Freundlich equation, it was found that adsorption of murexide by granular activated carbon could be the appropriate treatment method. The adsorption energy (E) obtained from the Dubinin- Radushkevich equation shows that the adsorption process is a physical adsorption process. From the kinetic analysis of the adsorption process, pseudo second order model is more consistent than pseudo first order model. It was found that the adsorption process proceeded to a spontaneous process and an endothermic process through Gibbs free energy change ($-0.1096{\sim}-10.5348kJ\;mol^{-1}$) and enthalpy change ($+151.29kJ\;mol^{-1}$). In addition, since the Gibbs free energy change decreased with increasing temperature, adsorption reaction of murexide by granular activated carbon increased spontaneously with increasing temperature. The entropy change ($147.62J\;mol^{-1}\;K^{-1}$) represented the increasing of randomness at the solid-solution interface during the adsorption reaction of murexide by activated carbon.

Influence of Temperature and Affinity of Disperse Dye on Dyeing of PET(Polyethylene Terephthalate) Microfiber (PET 초극세사 염색에서 분산염료의 친화력과 온도 의존성)

  • Lee, Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.9
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    • pp.532-540
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    • 2019
  • PET microfibers with various diameters (0.5, 0.2, 0.06, and 0.01 dpf) were dyed with a dispersed dye (C.I. Disperse Blue 56) at various temperatures. The dyeing process was conducted under infinite dyebath conditions at constant temperatures. The effects of the dyeing temperature and diameter on the partition coefficient, affinity, and diffusion coefficient of disperse dyes were studied. The curve of isotherms was fitted well to Nernst-type model in a large range of initial dye concentrations. At the same temperature, the partition coefficient and affinity decreased with increasing sample diameter due to the increase in surface area. At all deniers, the partition coefficient and affinity decreased with increasing temperature because the dyeing process is an exothermic reaction. In addition, the decrease in radius of the sample gives rise to a decrease in the heat of dyeing. The fine diameter of the sample resulted in an increased surface area but decreased space between the microfibers. Consequently, decreasing the diameter of the microfibers leads to a decrease in the diffusion coefficient. At the same diameter, the diffusion coefficient increased with increasing temperature because of rapid dye movement and the large free volume of the sample inside. In addition, thermal dependence of the diffusion coefficient increased when the diameter of the sample increased.