• Journal of Powder Materials
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• v.21 no.3
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• pp.222-228
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• 2014

Much research into fuel cells operating at a temperature below $800^{\circ}C$. is being performed. There are significant efforts to replace the yttria-stabilized zirconia electrolyte with a doped ceria electrolyte that has high ionic conductivity even at a lower temperature. Even if the doped ceria electrolyte has high ionic conductivity, it also shows high electronic conductivity in a reducing environment, therefore, when used as a solid electrolyte of a fuel cell, the powergeneration efficiency and mechanical properties of the fuel cell may be degraded. In this study, gadolinium-doped ceria nanopowder with $Al_2O_3$ and $Mn_2O_3$ as a reinforcing and electron trapping agents were synthesized by ultrasonic pyrolysis process. After firing, their microstructure and mechanical and electrical properties were investigated and compared with those of pure gadolinium-doped ceria specimen.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.358-362
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• 2003

An electrochemical reduction technology which can reduce the decay heat, volume, and radioactivity of spent fuel by a factor of quarter by converting oxide type spent fuel to a metallic form in a molten salt was developed and mock-up test in a 5kg $U_3O_8$/batch scale was carried out. The electrochemical reaction was analyzed regarding the operational factors. The research efforts was also concentrated on the apparatus development for a hot test. Fresh $U_3O_8$ powder was metallized with a more than 99% yield via this electrochemical technology and design data for the 20kg $U_3O_8$/batch scale apparatus were also obtained.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.421-425
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• 2003

The reductive extraction process is an important step to refine the TRU product from the electrorefining process for the preparation of transmutation reactor fuel. In this study, it was studied on the reductive extraction between the eutectic salt and Bi metal phases. The solutes were zirconium and the rare earth elements, where zirconium was used as a surrogate for the transuranic(TRU) elements. All the experiments were performed in a glove box filled with a argon gas. Li-Bi alloy was used as a reducing agent to reduce the high chemical activity of Li. The reductive extraction characteristics were examined using ICP, XRD and EPMA analysis. The reduction reaction was equilibrated within 3 hours after the Li addition. Three eutectic salt systems were compared and Zr was successfully separated from the rare earth elements in all the three salt systems.

• Journal of Hydrogen and New Energy
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• v.15 no.4
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• pp.324-332
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• 2004

According to the rapid depletion of the fossil fuels, the electricity and hydrogen will gradually take charge of the future energy supply. Especially, in order to control the supply and demand of electricity, energy storage medium is necessary and this could be solved by the combination of water electrolysis and fuel cell. Although electricity can be generated from such alternative energies as hydropower, nuclear, solar, and wind-power resources, alternative energy storage medium is also required since regenerative energies, solar and wind-powers, are intermittent energy resources. In this regard, hydrogen production from water electrolysis was recognized as a superb method for electricity storage. In this work, the current development and economic status of alkaline, solid polymer, and high temperature electrolysis were reviewed, and then the practical use of water electrolysis technology were discussed.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.694-700
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• 2008

Proton conducting oxides based on the $BaCe_{0.9}M_{0.1}O_{3-{\delta}}$ (M = La, AL) were tested for the alternative electrolyte materials of fuel cell. The power density for single cell of Air |Pt| $BaCe_{0.9}M_{0.1}O_{3-{\delta}}$ |Pt| $H_2(3%H_2O)$ system was maximum $0.04W/cm^2$ at $1000^{\circ}C$. In this system, proton transport number was proved to depend on the lattice parameters and the distortion of $CeO_6$ octahedral as a function of the ionic radii of acceptor ions. This proton conducting oxide system requires developing the new electrode materials for application.

• Journal of the Korean Chemical Society
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• v.39 no.1
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• pp.57-65
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• 1995

The electrochemical reduction of methylene blue (MB) in 1.0${\times}$10-2 M KNO3 aqueous solution was investigated by direct current (DC), differential pulse (DP) polarography, cyclic voltammetry (CV) and controlled potential coulometry (CPC). The electrode reduction of melthylene blue was processed CE reaction mechanism by two electrons transfer at the first reversible wave (- 0.18 volts vs. Ag/AgCl). MB was strongly adsorbed on the stationary mercury electrode and the reduction product of conptrolled potential electrolysis was rapidly auto-oxidized in air to the original methylene blue. Upon the basis of interpretation of cyclic voltammogram with pH change, possible CE electrode reaction mechanism was suggested.

• Korean Journal of Veterinary Service
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• v.34 no.2
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• pp.179-185
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• 2011

Neospora caninum is now recognized as one of the important causes of abortion in cattle worldwide, but there was no report on seroprevalence of antibodies to N. caninum in cattle at Seoul slaughtering center. Serum samples from 610 Korean indigenous cattle (Hanwoo) and 246 Holstein cattle from 452 farms located all over the country, Korea, were tested for N. caninum antibodies using a commercial enzyme-linked immunosorbent assay (ELISA) kit. Seven of 610 (1.1%) Hanwoo and 54 of 246 (22.0%) Holstein cattle were seropositive.

• Journal of Institute of Control, Robotics and Systems
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• v.17 no.10
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• pp.989-994
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• 2011

This study aims to demonstrate the feasibility of a visual servoing-based paired structured light (SL) robot for estimating structural displacement under various external loads. The former paired SL robot, which was proposed in the previous study, was composed of two screens facing with each other, each with one or two lasers and a camera. It was found that the paired SL robot could estimate the translational and rotational displacement each in 3-DOF with high accuracy and low cost. However, the measurable range is fairly limited due to the limited screen size. In this paper, therefore, a visual servoing-based 2-DOF manipulator which controls the pose of lasers is introduced. By controlling the positions of the projected laser points to be on the screen, the proposed robot can estimate the displacement regardless of the screen size. We performed various simulations and experimental tests to verify the performance of the newly proposed robot. The results show that the proposed system overcomes the range limitation of the former system and it can be utilized to accurately estimate the structural displacement.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.805-811
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• 2006

The microstructural changes in Ni/YSZ anode substrate and crack formation during Ni oxidation were investigated. The composition of as-sintered anodes was 56 wt% NiO+44 wt% YSZ and that of electrolyte was 8 mol% yttria. After complete reduction, specimens were oxidized in $N_2$ + air at $600\sim800^{\circ}C$. Oxygen partial pressure was controlled in between 0.05 atm and 0.2 atm $O_2$. When the anode was oxidized, at higher than $690^{\circ}C$, three layers were formed in the specimens. The first was fully oxidized layer(NiO/YSZ), the second was a mixed layer and the third, near-intact layer. Under $640^{\circ}C$ such distinctive layers were not observed. Cracks formed at electrolyte layer when weight gain attained at $65\sim75%$ of the total gain due to complete oxidation despite of different oxidation temperature and oxygen partial pressure.

• Journal of Hydrogen and New Energy
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• v.22 no.5
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• pp.641-648
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• 2011

KEPRI (KEPCO Research Institute) designed and operated the lab-scale high temperature electrolysis (HTE) system for hydrogen production with $10{\times}10cm^2$ 5-cell stack at $750^{\circ}C$. The electrolysis cell consists of Ni-YSZ steam/hydrogen electrode, YSZ electrolyte and LSCF based perovskite as air side electrode. The active area of one cell is 92.16 $cm^2$. The hydrogen production system was operated for 2664 hours and the performance of electrolysis stack was measured by means of current variation with from 6 A to 28 A. The maximum hydrogen production rate and current efficiency was 47.33 NL/hr and 80.90% at 28 A, respectively. As the applied current increased, hydrogen production rate, current efficiency and the degradation rate of stack were increased respectively. From the result of stack performance, optimum operation current of this system was 24 A, considering current efficiencies and cell degradations.