• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.173-177
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• 2011

In this study, the formation of $AlPO_4$-type porous materials from alum sludge was investigated. The materials were synthesized by the reaction of aluminum hydroxide and phosphoric acid with an organic template. Cationic surfactant, natural humic acid, and amino acids were used for the organic template. The residual organic templates were removed by calcination at $600^{\circ}C$ in the air. Powder X-ray diffraction patterns showed the charicteristic patterns of the $AlPO_4$-type porous materials. The morphology of the material was examined using a scanning electron microscopy. The coordination environment of $Al^{3+}$ ion was investigated by $^{27}Al$ MAS NMR technique. Both tetrahedrally and octahedrally coordinated$Al^{3+}$ ions were found in the as-synthesized samples while all $Al^{3+}$ ions were tetrahedrally coordinated in the calcined products. The development of mesopore in the solid material was confirmed by the measurement of BET specific surface area. Finally, they were used for removal of toxic formaldehyde from the air and the formaldehyde molecules were adsorbed on the surface of pores. In conclusion, $AlPO_4$-type porous materials from alum sludge might be applicable in the removal of toxic volatile organic compounds from the air.

• Explosives and Blasting
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• v.34 no.4
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• pp.10-18
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• 2016

Explosive blasting utilizes the energy produced from the explosion of explosive materials. Since the black powder, the first type of explosive, was invented, various types of explosives have been developed until a recent emulsion explosive which is powerful as well as safe in use. The detonators continue to be developed from safety fuse to the recent electronic detonators which allow extremely accurate and flexible control of delay time. However, the good explosives and detonators do not always lead to the good blast results. It entirely depends on the blast engineer. It is necessary to develop the empirical or theoretical models based on the field experience and sound theoretical algorithm. Such models would be very useful for blast design and, furthermore, provide the idea of further technical development. This paper introduces some models used in explosive blasting and attention to be paid for field application.

• Clean Technology
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• v.24 no.3
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• pp.255-266
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• 2018

In this paper, the effects of large national industrial complexes on the generation of local hazardous substances were analyzed based on their size, industrial characteristics. In Seoul, the proportion of hazardous substances, which adversely affect the atmosphere of the entire city, was much less than that of other regional industrial complexes, centered on knowledge-based industries. On the other hand, other national industrial complexes based on manufacturing industries, such as machinery, metal, electricity, and electronics, were found to have a combination of industry characteristics and logistics and regional characteristics. Overall, it was found that the increase in productivity in large national industrial complexes was not proportional to the increase in hazardous substances throughout the region. In addition, it was also found that in North Gyeongsang Province, which is based on the heavy chemical industry, the percentage of hazardous substances is different from other regions due to the characteristics of the industry.

• The Journal of the Convergence on Culture Technology
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• v.9 no.3
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• pp.593-599
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• 2023

Nickel oxide (NiO) nanoparticles were successfully synthesized by a simple liquid phase process for producing ceramics powder using a precursor impregnated with a nickel(II) nitrate hexahydrate aqueous solution in an industrial pulp. The microfibrile structure of the precursor impregnated with nickel nitrate hexahydrate aqueous solution was confirmed by scanning electron microscope (SEM), and the crystal structure and particle size of nickel oxide (NiO) particles produced as the heat treatment temperature of the precursor were analyzed by X-ray diffraction (XRD) and SEM. As a result, it was confirmed through XRD and SEM analysis that the temperature at which the organic material of the precursor is completely thermally decomposed was 495-500℃, and the size and crystallinity of the nickel oxide particles produced increased as the heat treatment temperature increased. The size of the nickel oxide particles obtained by heat treatment at 500-800℃ for 1 hour was 50-200 nm. It was confirmed by XRD and SEM analysis that a NiO crystal phase was formed at a heat treatment temperature of 380℃, only a single NiO phase existed until 800℃.

• Journal of Industrial Convergence
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• v.20 no.10
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• pp.33-38
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• 2022

In this paper, a simple method of forming a solution-based carbon nanotube (CNT) for use as a conductive material for electronic devices was studied. The CNT thin film coating was performed on the glass by applying the spin coating method and the argon atmospheric pressure plasma process. In order to observe changes in electrical and physical properties according to the number of coatings, samples formed in the same manner from times 1 to 5 were prepared, and surface shape, reflectance, transmittance, absorbance, and sheet resistance were measured for each sample. As the number of coatings increased, the transmittance decreased, and the reflectance and absorptivity increased in the entire measurement wavelength range. Also, as the wavelength decreases, the transmittance decreases, and the reflectance and absorption increase. In the case of electrical properties, it was confirmed that the conductivity was significantly improved when the second coating was applied. In conclusion, in order to replace CNT with a transparent electrode, it is necessary to consider the number of coatings in consideration of reflectivity and electrical conductivity together, and it can be seen that 2 times is optimal.

• Applied Chemistry for Engineering
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• v.21 no.2
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• pp.217-223
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• 2010

In general, fiber-reinforced plastics (FRP) wastes are simply buried or burned. Landfill brings about a permanent contamination of soil due to the inability of FRP to decompose and incineration causes an issue of generating toxic gases and dusts. There have been several ways to treat the FRP wastes such as landfill, incineration, chemical recycling, material recycling and the utilization of energy from combustion. Most methods excluding material recycling are known to have critical limitations in economic, technical and environmental manners. However it is known that material recycling is most desirable among the methods handling FRP wastes. In this study, to investigate the purpose of feasibility of material recycling, various bulk molding compound (BMC) specimens were prepared with the various contents of unsaturated polyester resin binder (25, 30, 35 wt%) and the various replacement ratios of FRP wastes powder (0, 25, 50, 75, 100 wt%) substituted for filler. To evaluate the physical properties BMC specimens, various tests such as tensile strength, flexural strength, impact strength, hot water resistance and SEM imaging were conducted. As a results, mechanical strengths decreased with an increase of replacement ratio of FRP waste powder and physical properties of BMC specimens were deteriorated in the hot water resistance. The fluidity of BMC with more than 50 wt% of the replacement ratio of FRP wastes powder decreased remarkably, causing a problem in the BMC composite.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.640-647
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• 2015

As the need for next-generation flexible electronics grows, novel materials and technologies that can replace conventional indium tin oxide (ITO) for transparent electrodes have been of great interest. Among them, a conducting polymer, especially poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonate) (PEDOT : PSS) is one of the most promising candidates because it is mechanically flexible, inexpensive, and capable of being processed in solution. Currently, there are a lot of research efforts on enhancing its electrical conductivity to the level of ITO or metal electrodes through chemical and/or physical processing. In this review article, we present various additives and pre-/post-deposition processing methods for improving the electrical conductivity of PEDOT : PSS. Some of representative reports are also introduced, which demonstrated the use of conductivity-enhanced PEDOT : PSS as transparent electrodes in electronics and energy conversion.

• 대한공업교육학회지
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• v.42 no.1
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• pp.140-159
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• 2017

The purpose of this research was to collect and select the theses and articles of the STEAM education in domestic and to analyze a research status by the review, then to suggest a direction of the further research in technology education. The objects of this research were the theses and articles of the STEAM education in domestic published from January 2007 to June 2016. I collected the theses and articles by using the search engine of the Korean Academic Information Service, the Korea Education and Research Information Service, the National Assembly Digital Library, and finally selected 821 theses and articles for the objects. I analyzed the theses and articles by verifying their subjects, abstracts and contents, and applied the analysis framework developed in advance. I used the frequency analysis, the cross analysis to analyze the datas statistically. Also, I used SPSS 18.0 program. Drawing on the finding of this research, major conclusions of this research were as follows. First, the researches of the STEAM education in domestic had been studied numerously from 2012 to 2015, but it has been decreased since 2016. Second, the researches of the STEAM education in domestic have been studied numerously for the development of the educational program and the instructional source. Third, the research objects of the STEAM education in domestic have been studied numerously for elementary school, middle school and high school in a row. Forth, the researches of the STEAM education in domestic have been focused numerously on a science. Fifth, the researches of the STEAM education in domestic have been concerned mainly about the creativity effect among other educational effects.

• Applied Chemistry for Engineering
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• v.27 no.6
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• pp.639-645
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• 2016

We herein report efficient triplet-triplet annihilation upconversion (TTA-UC) achieved in various non-toxic and non-volatile vegetable oils as a UC media using platinum-octaethylporphyrin (PtOEP) and 9,10-diphenylanthracene (DPA) as a sensitizer and acceptor, respectively. Green-to-blue UC was readily achieved from PtOEP/DPA solution in vegetable oils with the quantum yield of 8% without any deoxygenation process. The UC efficiency was found to be significantly dependent on the contents of unsaturated hydrocarbon in vegetable oils and viscosity of the solution, as well. Though the Stern-volmer constant and quantum yield in vegetable oils were measured to be lower than those measured in the deaerated organic solvent, the quenching efficiency was still high enough to be 93%. In the sunflower oil, the UC threshold intensity ($I_{th}$) was approx. $100mW/cm^2$, which is far larger than the sunlight intensity, but we believe that the UC achieved in non-toxic and air-saturated media was still highly applicable to nontraditional visualization techniques such as bioimaging.

• 대한공업교육학회지
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• v.39 no.1
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• pp.247-261
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• 2014

Education about invention in elementary schools has thus far be conducted mostly through special activities and talented activities rather than through normal curricula. However, with the implementation of the 2007 amended curricula, invention education was reflected as a normal subject unit in the practical subject (technology and home economics) curricula, thereby laying groundwork for invention education being able to be provided through normal subject classes. Thus, at the time when invention education has been reflected as a normal subject unit, it is meaningful to research the effects of elementary school students' experience in invention education on their invention attitudes. This study sought to research the effects of elementary school students' experience or non-experience in invention education on their invention attitudes, targeting those in regional talent private schools who did not take invention talent classes, those who received invention education, and those who did not receive invention education at all. The conclusion of this study is outlined as follows. First, students' experience in invention education proved to be positive in boosting their invention attitude, and continued invention education experience like with students in regional talent invention schools significantly boosted their invention attitudes. Second, considering that students' actual experience in invention education had positive effects on their invention attitudes, the reflection of invention education in the amended curricula was found to be very desirable in improving elementary students' attitudes about invention. Third, according to gender, male students' invention attitude level was found to be higher than that of female students, suggesting that male students more worked on computers, electronic (smart) devices and machines in daily life, leading them to further develop invention attitudes.