• Title/Summary/Keyword: 전기변색

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New Evaluation Method for the Lightfastness of Colored Papers by Radiant Energy (광방사에 의한 채색지의 새로운 내광성 평가 방법)

  • Kim, Hoon;Kim, Hong-Bum;Kwon, Sae-Hyuk
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.6
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    • pp.37-43
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    • 1997
  • Density of a dye or pigment teduces by radiant energym and dinsity change induces color change. In this paper, we habe worked out an equation to predict the color change by the radiant energy under the assumption of colorant density changing pattern by radiant energy and the color changing pattern by colorant density chane. And the damaging factors in the equation was established by experiments. To evaluate the efectiveness of the equation and the method, several samples were irradiated by common light source and color change was measured. Good coincidence between the ceasured and the calculated color change was found. And it was also found that there is a close relationhaip between the spectral damaging factor and the spectral absorptance in visible wavelength range.

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PULP CANAL OBLITERATION CAUSED BY TRAUMA (외상에 의한 근관내 석회화 변성 치아의 처치)

  • Lee, Sung-Ryong;Lee, Chang-Seop;Lee, Sang-Ho;Lee, Nan-Young
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.2
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    • pp.256-261
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    • 2004
  • Pulp canal obliteration(PCO) is seen commonly in dental pulp after traumatic tooth injuries and is recognized clinically as early as 3 monthly after injury. Pulp canal obliteration is characterized by deposition of hard tissue within the root canal space and yellow discoloration of the clinical crown. Opinion differs among practitioners as to whether to treat these cases upon early detection of PCO or to observe them until symptoms or radiographic signs of pulpal necrosis are detected. PCO may make root canal treatment necessary because of the development of apical periodotitis or for cosmetic reasons. If carefully executed, root canal treatment in teeth with an PCO is hightly successful and may act as a basis for internal bleaching. During a game, a 12-year-old girl was hit in the face. At that time, she was diagnosis a subluxation of the maxillary right central incisor. At the 24-month recall examination, a root canal of the tooth had been calcified and discolored gradually. We performed endodontic treatment to prevent perfect pulp canal obliteration and internal bleaching.

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Synthesis and Electrochromism of Fluorane Dyes for Direct Thermal Printing and Pressure-Sensitive Printing (감압 감열 기록용 Fluorane계 색소의 합성과 전기변색성)

  • Kim, Sung Hoon;Bae, Jin Seok;Hwang, Seok Hwan;Song, Han Chul;Gwon, Tae Sun;Doh, Myung Ki
    • Journal of the Korean Chemical Society
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    • v.40 no.3
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    • pp.209-215
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    • 1996
  • Fluorane dyes has been widely used for pressure and heat sensitive recording system as color forming materials. A new method of synthesizing fluorane dye by the Bamberger reaction has been developed. Electorchromic properties of fluorane dyes was discussed. The fading reaction kinetics follow a first-order relationship and resolved in two kinetics of first-order reaction with rate constant $k_1$ and $k_2$.

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Chemical Stimuli-Responsible Characteristics of Polymer Films Using PMMA Containing Styryl Dye (Styryl계 PMMA를 이용한 고분자 필름의 화학적 자극-응답 특성)

  • 이선화;이범훈;정재윤;윤기종;조재환
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.60-63
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    • 2003
  • Smart 재료는 외부의 환경으로부터 자극을 받을 경우 형상, 색, 전기적 또는 광학적 특성 등이 변할 수 있는 소재를 말한다. 기존의 재료들은 단지 주어진 환경변화를 수동적으로 받아들이는 데 대하여 smart 재료는 이런 한계를 넘어 생물체처럼 환경에 반응한다는 점에서 앞으로 새로운 소재로 각광받을 수 있을 것이다. 변색성 재료도 이와 같은 중요한 smart 소재에 해당하는데, 물질에 따라 광, 온도, 화학물질, 전기장 등의 외부 환경조건에 응답할 수 있다. (중략)

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Optical Patterning and Applications of Photo-chromic Polymers (광변색 고분자의 광학적 패터닝과 응용)

  • Kim, Jun-Young;Fukuda, Takashi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.76-76
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    • 2007
  • Several kinds of photo-chromic polymers containing push-pull structure were synthesized and investigated on optical patterning by photo-induced surface relief gratings (SRG) technique. The azobenzene segment was introduced as a functional group for a photo-triggered tran-cis isomerization. Consequently, we have fabricated micro-size regular pattern by one-step process without photo-mask.

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RF Sputtered Lithium Nickel Oxide Films and Their Electrochromism (RF 스퍼터링에 의해 제조된 Li-Ni-O 박막의 전기변색 특성)

  • Kim, Young-Il;Kim, Bae-Whan;Choy, Jin-Ho;Campet, Guy;Park, Nam-Gyu;Portier, Josik;Morel, Bertrand
    • Journal of the Korean Chemical Society
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    • v.41 no.11
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    • pp.594-599
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    • 1997
  • Lithium nickel oxide ($Li_{2x}Ni_{1-x}O$) thin films have been prepared by the RF sputtering of lithiated nickel oxide target, where the film microstructure was controlled by the sputtering atmosphere $(Ar/O_2)$ and the substrate temperature ($T_s=50/230^{\circ}C$). From the transmission electron microscopic analysis, it is found that the most porous film with the grain size of $∼80\AA$ could be fabricated under the sputtering atmosphere of $P(O_2)=8{\times}10^2$ mbar with the $$T_s$=50^{\circ}C.$ In the optical and electrochemical studies, the$Li_{2x}Ni_{1-x}O$ films exhibit a significant electrochromic property in association with the lithium insertion/deinsertion process. The amount of charge insertion ($Q_i$) and the optical density (OD) variation depend on the crystallinity of the film as well as its thickness, and for the $Li_{2x}Ni_{1-x}O$ film (170 nm thickness) prepared under $O_2$ atmosphere and $T_s=50^{\circ}C$, the OD could be increased up to ∼1.3 by the charge insertion with $Q_i=30\;mC/cm^2.$

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The Development of Electrochromic Materials for Energy Saving Smart Windows. (에너지 절약 스마트윈도우용 전기변색 재료의 개발)

  • Cho, Bong-Hee;Kim, Young-Ho
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1308-1310
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    • 1994
  • The electrochromism of $WO_3$ and $V_2O_5$ thin films have been studied. The $WO_3$ thin film is found to be cathodic coloration material and the coloration efficiency of this film is close to $60 [cm^2/C]$ in the near infrared region. The $V_2O_5$ thin film exhibits cathodic coloration in tile near infrared and anodic coloration in the blue and near UV region. The cathodic coloration in the $450{\sim}1100 nm$ wavelength range is relatively weak with a maximum coloration efficiency of $6 [cm^2/C]$).

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Response-Improved Electrochromic Display Device Based on Organic Materials (고응답성 유기계 전기변색성 소자의 제작과 특성)

  • 권태선
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.81.1-91
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    • 1994
  • Irradiation of aromatic diazonium salts resulted in an effcient elimination of nitrogen, yielding substitution products. This paper was not only studies about photolysis of aromatic diazonium with double salts but also coexistence of ion and radical when they was photolysis. Photolysis of aromatic diazonium was depend on excite wave length therefore photolysis products out put different absorption intensity such other. We also confirmed coexistence of ion and radical when they was accomplished photolysis. In case of BD, there are ion decomposition process about 90 percentage, decreased ion decomposition process the other side radical`s it was becomeing increased according to excite of short-wave length.

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