• Journal of the Korean Electrochemical Society
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• v.5 no.2
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• pp.79-85
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• 2002

The present article is concerned with the application of the Monte Carlo simulation to electrochemistry of lithium intercalation from the thermodynamic view point. This article first introduced the fundamental concepts of the ensembles, and Ising and lattice gas models in statistical thermodynamics for the Monte Carlo simulation in brief. Finally the Monte Carlo method based upon the lattice gas model was employed to analyse thermodynamics of the lithium intercalation into the transition metal oxides. Especially we dealt with the thermodynamic properties as the electrode potential curve and the partial molar internal energy and entropy of lithium ion in the case of the $LiMn_2O_4$ electrode, and consequently confirmed the utility of the Monte Carlo method in the field of electrochemistry of the lithium intercalation.

• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.568-574
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• 2020

Gas diffusion layer (GDL) is one of the main components of PEMFC as a pathway of reactants from a flow field to an electrode, water transport in reverse direction, heat management and structural support of MEA. In this study, the effect of GDL on fuel cell performance was investigated for commercial products such as 39BC and JNT30-A3. Polarization curve measurements were performed at different flow rates and relative humidity conditions using 25 ㎠ unit cell. The parameters on operating conditions were calculated using an empirical equation. The electrical resistance increased as the GDL PTFE content increased. The crack of microporous layer had influence on the concentration loss as water pathway. In addition, the ohmic resistance increased as the relative humidity decreased, but decreased as the current density increased due to water formation. Curve fitting analysis using the empirical equation model was applied to identify the tendency of performance parameters on operating conditions for the gas diffusion layer.

• Korean Journal of Optics and Photonics
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• v.16 no.6
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• pp.527-534
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• 2005

We investigate the pulsation characteristics in a multi-section DFB laser which is composed of one DFB section, phase tuning section, and gain section. Multi-section DFB lasers with anti-phase (AP) complex-coupled (CC) DFB structure show wide current ranges of gain and phase tuning sections fer stable pulsations compared to those with in-phase CC DFB structure or index-coupled DFB structure. For multi-section DFB lasers with AP CC DFB structure, the current range of a gain section for stable pulsations increases and the tuning range of the pulsation frequency increases as a coupling strength or a gain coupling coefficient increases Also, the tuning range using the phase variation in a phase tuning section increases. For a fixed coupling strength, the current ranges of gain and phase tuning sections for stable pulsations increase and the tuning range of the pulsation frequency increases as the length of a DFB section increases.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.3
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• pp.45-54
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• 2004

Microwave characteristics of ridge type CPW traveling-wave(TW) electroabsorption modulator and photodetector are affected by the thickness of intrinsic layer, width of guiding layer, and the separation of signal and ground electrodes. These factors are determined effective index of microwave and characteristic impedance due to changing of capacitance(C) and inductance(L) of device. However, conventional equivalent circuit of TW-structure is approximated to microstrip and CPW transmission line by distribution of electric and magnetic fields, respectively. In this paper, we analyzed microwave characteristics of TW-structure and found more accurate value of C and L by using finite difference time domain (FDTD) method. These values are adopted circuit element of equivalent circuit. Microwave characteristics obtained by the FDTD and equivalent circuit model show good agreement.

• Korean Journal of Materials Research
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• v.11 no.3
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• pp.207-214
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• 2001

Silica glass is a core material for optical fiber in optical telecommunications, but its centrosymmetry eliminates the second order nonlinearity. But it is experimentally well known that the space charge polarization induces the Second Harmonic Generation (SHG) when a strong DC voltage is applied to silica glass for a long period of time with metal blocking electrodes. In this report, the results of a theoretical calculation of the nonlinear optical property caused by the space charge polarization, and a model of a numerical analysis to predict the small chance in nonlinear optical property as functions of time and space are provided. Assuming that amorphous silica is a solid state electrolyte and sodium ion is the only mobile charge carrier, 'Finite Difference Method' was employed for modeling of numerical analysis. The distributions of the concentration of sodium ion and electric field as functions of a normalized length of the specimen and a normalized applied voltage were simulated.

• Applied Biological Chemistry
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• v.28 no.4
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• pp.271-277
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• 1985

A polarograph with specially designed cell compartment usable in kinetic study of the mitochondrial respiration of a small sized sample was made, and its performance and experimental conditions were examined. An applied potential (ca-1.2V vs. SCE) which gives rise to the second step reduction of oxygen caused a considerable level of a residual current independent of oxygen, which is temporarily interpreted as the reduction current of the membrane-bound redox material(s) of mitochondria. A potential corresponding to the first slop reduction of oxygen (ca-0.4V vs SCE) did not produce the residual current. Thus, it is suggested that a measurement of oxygen concentration in a sample of mitochondria and submitochondrial particles by using dropping mercury electrode should be done with an applied potential of about -0.4V vs SCE. Consumption of oxygen by mitochondria was observed to follow practically zero order kinetics. Its rate constant exhibited the proportional relationship with the respiratory activity of mitochondria. Usefulness of tile instrument was properly demonstrated in the work on the temperature effect on the respiration of mitochondria isolated from several plant 4issues which were selected on the basis of chilling susceptivity.

• Journal of the Korean GEO-environmental Society
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• v.14 no.4
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• pp.5-13
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• 2013

The water leakage of reservoir embankment usually occurs around channelling pipes, which gives little influence on the embankment in a normal state. However, the embankment can be destroyed when the water level of reservoir increases with heavy rain and the rainy season in summer. Investigating the water vein and its path is therefore very important from the viewpoint of disaster prevention and embankment maintenance. The water leakage in dams and levees where the channelling pipes are working as weak zone was analyzed by using both numerical simulation and experimental method in this study. To detect the water leakage, an electrical resistivity survey was used and investigated for its' usability. The numerical results show the size and location of weak zone increases the importance of selection of electrode spacing. The leakage experiments of model embankment present the best result is obtained under the conditions of electrode spacing of 0.3m and dipole-dipole array. By studying the water leakage in dams and levees, the electrical resistivity survey is observed it is a very useful method to predict the leakage.

• Nuclear Engineering and Technology
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• v.14 no.2
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• pp.78-85
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• 1982

The steady-state rotation of plasma centrifuge is theoretically analyzed to understand the physics of rotating plasmas and its feasibility for isotope separation. The centrifuge system under consideration consists of an annular gap between coaxial cylindrical anode and cathode in the presence of an externally-applied axial magnetic field. A problem for coupled partial differential equations describing centrifuge fields is formulated on the basis of the magnetohydrodynamic equations. Two-dimensional solutions are found analytically in the form of Fourier-Bessel series. The current density and velocity distributions are discussed in terms of the Hartmann number and the geometrical parameter of the system. At typical conditions, rotational speeds of the plasma up to the order of 10$^4$m/sec are achievable, and increase either with increasing Hartmann number, or with increasing ratio of the axial length to the inner radius of the cylinder. In view of much higher speeds of rotation which can be achieved in plasma centrifuge, it is expected that its efficiency is superior to mechanically driven gas centrifuges.

• Journal of Korean Tunnelling and Underground Space Association
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• v.6 no.4
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• pp.327-343
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• 2004

During tunnel construction, ground failures often occur due to existence of weak zones, such as faults, joints, and cavities, ahead of tunnel face. It is hard to detect effectively weak zones, which can lead underground structure to fail after excavation and before supporting, by using conventional characterization methods. In this study, an enhanced analytical method of predicting weak zones ahead of tunnel face is developed to overcome some problems in the conventional geophysical exploration methods. The analytical method is based on Coulomb's and Gauss' laws with considering the characteristics of electric fields subjected to rock mass. Using the developed method, closed form solutions are obtained to detect a spherical shaped zone and an oriented fault ahead of tunnel face respectively. The analytical results suggest that the presence of weak zones and their sizes, location, and states can be accurately predicted by combining a proper inversion process with resistance measured from several electrodes on the tunnel face. It appears that the skin depth or resistivity in rock mass is affected by the diameter of tunnel face, natural electric potential and noises induced by experimental measurement and spatial distribution of uncertain properties. The developed analytical solution is verified through experimental tests. About 1800 concrete blocks of 5cm by 5cm by 5cm in size are prepared and used to model a joint rock mass around tunnel face. Weak zones are simulated ahead of tunnel face with a material which has relatively higher conductivity than concrete blocks. Experimental results on the model test show a good agreement with analytical results.

• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.71-76
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• 2007

We have demonstrated the resonant resistance pattern changes of the polymer film in the quartz crystal analysis by the function of the molecular polarity phase transition phenomena. PVA and PMMA/PVAc blend films were used as hydrophilic and/or hydrophbic film, respectively. In the comparison between the hydrophilic shows the pattern changes near by the phase transition temperature. For more detailed explanation, the static capacity in the oscillation parameter was measured and the morphology of Au quartz crystal electrode was studied by AFM. It is suggested that the different resonant resistance pattern change is reliable in the condition of different polarity, and the conclusion is important to analysis of the real mechanism a normal quartz crystal experiments.