• Title/Summary/Keyword: 전극 전위

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Studies on the Electrochemical Properties of $TiO_{2-x}$ Thin Films Prepared by Air Oxidation and Water Vapor Oxidation (공기 산화와 수증기 산화에 의해 제조된 $TiO_{2-x}$ 박막의 전기화학적 성질에 관한 연구)

  • Yong-Kook Choi;Ki-Hyung Chjo;Q-Won Choi;Jeong-Sup Seong;Jeong-Geun Oh
    • Journal of the Korean Chemical Society
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    • v.37 no.4
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    • pp.401-407
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    • 1993
  • The titanium oxide thin films were prepared by air oxidation and water vapor oxidation. The electrochemical properties of the electrodes were studied in 1M NaOH solution. The peak potentials of oxygen reduction from cyclic voltammogram techniques were observed at aroung -0.9 ∼ -1.0 V vs. SCE and the reaction was totally irreversible process. The electrochemical properties of titanium dioxide electrodes prepared by water vapor oxidation exhibited different from the air oxidized electrodes, but it was similar to single crystal $TiO_2$. The peak potentials of oxygen reduction were observed at slightly more positive than flat band potentials and depended on pH.

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The characteristics of AlW thin film for TFT-LCD bus line (TFT-LCD bus line을 위한 Al-W 박막 특성에 관한 연구)

  • Dong-Sik Kim;Chong Ho Yi;Kwan Soo Chung
    • Journal of the Korean Vacuum Society
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    • v.9 no.3
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    • pp.233-236
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    • 2000
  • The structural, electrical and chemical characteristics of Al alloy thin film with low impurity concentrations AlW deposited by using dc magnetron sputtering deposition are investigated for the applications as data bus line in the TFT-LCD panel. The deposited thin films show the decrease of resistivity and the increase of grain size after the RTA at $300^{\circ}C$ for 20 min.. Moreover, the resistivity of AlW does not show appreciable grain size dependence after RTA. It is concluded that the decrease of resistivity after RTA is due to the increase of grain size. The annealed AlW is found to be hillock free. And for investigating chemical attack in TFT-LCD etching processing the electric potential of AlW alloy for Ag/AgCl were investigated by cyclic voltammetry. When W wt.% of AlW alloy was higher than about 3%, the electric potential of AlW was more positive than ITO's. Therefore AlW alloy thin film can be propose to use for data bus line.

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Potential-dependent Complex Capacitance Analysis for Porous Carbon Electrodes (다공성 탄소전극의 전위에 따른 복소캐패시턴스 분석)

  • Jang, Jong H.;Yoon, Song-Hun;Ka, Bok H.;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.255-260
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    • 2003
  • The complex capacitance analysis was performed in order to examine the potential-dependent EDLC characteristics of porous carbon electrodes. The imaginary capacitance profiles $(C_{im}\;vs.\;log\lf)$ were theoretically derived for a cylindrical pore and further extended to multiple pore systems. Two important electrochemical parameters in EDLC can be estimated from the peak-shaped imaginary capacitance plots: total capacitance from the peak area and $\alpha_0$ from the peak position. Using this method, the variation of capacitance and ion conductivity in pores can be traced as a function of electric potential. The electrochemical impedance spectroscopy was recorded on the mesoporous carbon electrode as a function of electric potential and analyzed by complex capacitance method. The capacitance values obtained from the peak area showed a maximum at 0.3V (vs. SCE), which was in accordance with cyclic voltammetry result. The ionic conductivity in pores calculated from the peak position showed a maximum at 0.2 V (vs. SCE), then decreased with an increase in potential. This behavior seems due to the enhanced electrostatic interaction between ion and surface charge that becomes enriched at more positive potentials.

Analysis of Transient Potential Rises of Horizontal Ground Electrodes Considering the Frequency-Dependent of Soil (토양의 주파수의존성을 고려한 정보통신설비용 수평접지전극의 과도전위상승 분석)

  • Ahn, Chang Hwan
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.2
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    • pp.147-153
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    • 2016
  • The lightning protection of information and communication facilities is very important factor to improve a reliability of the action of these equipment. Especially the transient potential rise of ground electrode being injected with the lightning current is to be a basic data of the dielectric strength for both power and communication facilities so that more accurate analysis should be required. The transient potential rise can be calculated from the ground impedance and the ground impedance is strongly dependent upon the shape of the ground electrode and the frequency-dependence of soil. The Debye's equation which is able to calculate the characteristics of dielectrics is used to analyze the frequency-dependent of soil. Also, the method to calculate the transient potential rise from the ground impedance is specified in this paper. In order to analyze the transient potential rise resulting from calculations with Debye's equation, TLM(transmission line method) and case of ${\rho}$(resistivity)-constant are simulated, respectively. The length of a horizontal ground electrode is 30 m and simulations were performed at 10, 100, $1000{\Omega}{\cdot}m$ with the standard lightning current waveform. In result, the transient potential rise of horizontal ground electrode calculating with Debye's equation is lower than it of other models.

Potentiometric Response of Chitin - based Membrane Electrode to various Metal cations (키틴 막 전극의 양이온에 대한 감응 연구)

  • Choi, Bun-Hong;Yun, Young-Ja
    • Analytical Science and Technology
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    • v.11 no.4
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    • pp.235-242
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    • 1998
  • Membrane electrode based on chitin(po1y-[$1{\rightarrow}4$]-${\beta}$-N-acetyl-D-glucosamine) was prepared by mixing uniformly grounded of chitin (100 mesh) with PVC and DOS. We investigated the potential response of chitin membrane electrode to metal ions. It was observed that the response slopes for $Cd^{2+}$(34.9 mV/decade) and $Cu^{2+}$(34.0 mV/decade) were larger than those for other ions in pH 4 acetate buffer. The potentiometric response of chitin electrode to varying pH was nearly constant in the pH range of 2~12.

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The Purification of Decontamination Liquid Waste by Electrosorption (전기적 흡 . 탕착에 의한 제염폐액의 정화처리기술)

  • 정종헌;문제권;김규남;이성호;이상문
    • Resources Recycling
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    • v.8 no.3
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    • pp.18-25
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    • 1999
  • The study on the electrosorption of cobalt ions onto a porous activated carbon fiber (ACF) was performed to treat radioactive liquid wastes resulting from chemical or electrochemical decontamination and to regenerate the spent carbon electrode, Cyclic voltammetry was investigated on a rotating-disk electrode (RDE) to determine the region of potentials within which only double-layer charging should occur. The application of an electric potential increased the sorption of the cobalt ions. The adsorbed cobalt Ions could be released into the solution by reversing the appling potential, showing the reversibility of the process.

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Cesium Ion-Selective Electrode Based on Upper-rim Calix[4]crown Ionophore (캘릭스 [4]크라운 유도체를 이온선택성 물질로 사용한 세슘이온 선택성 막전극)

  • Namgung, Miok;Ihm, Hyejae;Paek, Kyungsoo;Yun, Youngja
    • Analytical Science and Technology
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    • v.13 no.4
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    • pp.428-432
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    • 2000
  • A PVC membrane electrode based on upper-rim calix[4]crown as ionophore was prepared using dioctyl sebacate (DOS) as a plasticizer. The potential response of this membrane electrode to alkali, alkaline earth metal cations were examined. This membrane electrode exhibited a Nemstian response to $10^{-5}-10^{-1}M$ of CsCI with a slope of 52.3 mV/decade in Tris-buffer(pH 7.20). Its response time ($t_{90%}$) was 10s and it could be used for at least 2 months.

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자연전위의 효율적 측정을 위한 전극의 잡음요소 분석

  • Song, Seong-Ho;Gwon, Byeong-Du
    • Journal of the Korean Geophysical Society
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    • v.5 no.1
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    • pp.9-18
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    • 2002
  • We performed a long-term monitoring of self-potential(SP) using the Cu-CuSO₄non-polarizable electrode and copper-clad electrodes(CCE) in a test site in order to analyze the effects of surrounding environmental noises such as temperature, rainfall and soil moisture content on the electrodes. Analysis of the temperature dependence of the non-polarizable electrodes showed that is temperature coefficient was about +0.5 mV/°Fwhen its end was exposed to atmosphere while it was less than +0.5 mV/℃ when submerged into the subsurface, which reflects that there exists an 8 to 11 hour lag between temperatures at the depth of 15 cm and atmosphere. CCE was independent of atmospheric temperature in subsurface but showed temperature coefficient of 1.0 mV/℃ when exposed to atmosphere. Drifts of 1 to 2 mV recorded with the non-polarizable electrode directly related to the soil moisture content when it was buried in subsurface. Drift with CCE also showed similar trend to the soil moisture content, and 5 mV drift was recorded according to 5% of daily variation. The soil moisture content had strong effects on the measurement with CCE in rainfall since the flow potential is generated on the surface of the electrode.

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Resistivity Survey Using Long Electrodes (긴 전극을 사용하는 전기비저항 탐사)

  • Cho, In-Ky;Lee, Keun-Soo;Kim, Yeon-Jung;Kim, Rae-Young
    • Geophysics and Geophysical Exploration
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    • v.19 no.1
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    • pp.45-50
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    • 2016
  • Generally, a point source has been routinely used in the electrical resistivity measurements because of easy installation. If steel-cased wells are used as long electrodes, we can expect the better depth of investigation. However, the resistivity data with long electrodes can not be processed with a conventional inversion algorithm because a long electrode produces the different primary potential distribution compared with the point source. In this study, we proposed a new technique to process the electrical resistivity data with long electrodes by replacing the long electrode with a sequence of point electrodes. Comparing the potentials obtained from the technique with the analytic/numerical solution, we ensure that the proposed technique can be used for the numerical resistivity modeling based on the finite difference or finite element method.

의용생체공학(2)

  • Hong, Seung-Hong
    • Journal of the Korean Society for Precision Engineering
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    • v.2 no.1
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    • pp.33-40
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    • 1985
  • 의료의 고도화를 위해서는 각종 생체현상의 계측기술이 중요시된다. 그림1과 같은 생체현상의 계측과 감시를 위한 계통도에서와 같이 생체에서 얻어지는 정보를 바르게 계측하여 평가하기 위해서는 앞에서 기술한 생체의 물성에 관한 지식이 필요하다. 다음에 전극, 변환기등의 각종 새로운 센서의 개발이 중요하며, 그리고서 얻어지는 데이터를 증폭하여 전송하는 기술과 데이터를 처리하여 표시하거나 기록하는 방법도 중요하다. 지금까지는 측정이 불가능하다고 생각되어진 것들을 가능하게 하기 위한 새로운 센서의 개발과 정성적으로만 측정되었던 것들까지도 정량적으로 측정되는 새로운 계측시스템이 고안되어 비관혈계측의 경향으로 연구되고 있다. 이들 센서들 중에는 생체의 활동전위를 검출하는 전극과, 활동전위 이외의 일반생체현상을 변환기(transducer)를 이용하여 전기신호로 변환하여 검출하는 센서가 있다.

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