• Title/Summary/Keyword: 전극 전위

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A Study on the Preparation of the Silver Selenide Electrode and Its Properties (Silver Selenide 전극의 제조 및 그 특성에 관한 연구)

  • Gwon-Shik Ihn;Tae-Won Min;Soo-Hyung Lee
    • Journal of the Korean Chemical Society
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    • v.20 no.4
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    • pp.280-289
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    • 1976
  • The silver selenide electrode has been prepared and its properties as an indicating electrode for silver ion have been investigated. Epoxy resin was used as a filler of silver selenide electrode. Silver metal plate was directly connected with the membrane of the electrode and the silver paste was used as its binder. The sintered electrode was more sensitive and stable than the pressed electrode, and the silver selenide electrode more sensitive than the silver sulfide electrode to silver ion. The linear relationship between the electrode potential and logarithmic concentration of silver ion has been observed down to 10-6 M for the electrode. Several heavy metal ions except mercuric ion did not interfere this linearity, but halide, cyanide, and thiocyanate ions did intensively interfere owing to the formation of silver compounds and complexes. This electrode has been applied to the potentiometric titration for determining halide ion. It is concluded that interferences from ,$CN^-, SCN^-, S^-, I^-, Br^-, Cl^- and Hg^{2+}$ ions are detrimental to the practical use of the electrodes for measuring pAg.

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Electrochemical Characteristics of Assembled-Graphite/DSA Electrode for Redox Flow Battery (Redox Flow Battery용 일체화된 흑연/DSA 전극의 전기화학적 특성)

  • Kim, Hyung-Sun
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.123-127
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    • 2010
  • An assembled-graphite/DSA(Dimensionally Stable Anode) was prepared using graphite powder to increase durability and energy efficiency of redox flow battery and investigated its electrochemical properties in vanadium-based electrolyte. The cyclic voltammetry (CV) was carried out in the voltage range of -0.7V and 1.6V vs. SCE at 5 mV/sec scan rate to analyze vanadium redox reaction. From the CV results, the assembled-graphite/DSA electrode showed a fast couple reaction and good reversibility in 2M $VOSO_4$ + 2.5 M $H_2SO_4$ electrolyte. Therefore, it has been expected that this electrode increases power density as well as energy density of redox flow battery.

A Mathematical Model for the Discharge Mechanism of a Metal Hydride Electrode (금속수소 전극의 방전기구에 대한 수학적 모델)

  • Shin, Chee Burm;Hong, Jung Ho;Yun, Kyung Suk;Cho, Byung Won;Cho, Won Il;Jeon, Gui
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.768-773
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    • 1998
  • A mathematical model of discharge mechanism of metal-hydride (MH) electrode was presented. A computer simulation program was developed in order to predict the variation of electrode potential and the distribution of hydrogen concentration within MH particles during discharge. By investigating the effects of the discharge current density, the size of MH particle, the diffusivity of hydrogen in MH particle, and the porosity of the electrode, it was found that these factors exerted a collective effect on the discharge characteristic of the electrode and the utilization of hydrogen in the MH particle. It was confirmed that and optimization of design factors of an MH electrode is necessary in order to execute a high-rate discharge and to improve the utilization of hydrogen in MH particle.

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Characteristics of Redox Flow Battery Using the Soluble Lead Electrolyte (납이 용해된 전해액을 사용하는 레독스 플로우 전지의 특성)

  • An, Sang-Yong;Kim, Eung-Jin
    • Journal of the Korean Electrochemical Society
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    • v.14 no.4
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    • pp.214-218
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    • 2011
  • The electrochemical characteristics and performance of redox flow battery using the soluble lead has been evaluated. Cyclic voltammetry was performed on the materials to evaluate deposition and dissolution of lead and lead dioxide. In the negative region, a reduction peak is not observed, and on the reverse scan, on-set voltage is observed at -0.47 V(vs SCE). In the positive region, the distinct peak is observed on the forward and reverse scan. The charge/discharge experiments were carried out graphite electrode in the beaker cell. The charging(deposition) of lead occurs at around 0.5 V(vs SCE) and discharging(dissolution) of lead occur at around 0.25 V(vs SCE). The potential difference is about 0.25 V. The charging(deposition) of dioxide lead is at 1.77 V(vs SCE) and discharging(dissolution) is at around 0.95 V(vs SCE) during first cycle. On subsequent cycles, the charging of dioxide lead starts at below 1.5 V(vs SCE), after a period the voltage increase to 1.7 V(vs SCE). The voltage of discharging is stable at around 1.0 V(vs SCE).

Surface Potential Properties of CuPc/Au Device with Different Substrate Temperature (CuPe/Au 소자의 기판 온도 변화에 따른 표면전위 특성)

  • Lee, Ho-Shik;Park, Yong-Pil;Kim, Young-Pyo;Cheon, Min-Woo;Yu, Seong-Mi
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.10a
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    • pp.758-760
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    • 2007
  • Organic field-effect transistors (OFETs) are of interest for use in widely area electronic applications. We fabricated a copper phthalocyanine (CuPc) based field-effect transistor with different metal electrode. So we need the effect of the substituent group attached to the phthalocyanine on the surface potential was investigated by Kelvin probe method with varying temperature of the substrate. We were obtained the positive shift of the surface potential for CuPc thin film. We observed the electron displacement at the interface between Au electrode and CuPc layer and we were confirmed by the surface potential measurement.

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Real-time brain mapping system using EEG and evoke potential (뇌파 및 Evoke potential을 이용한 실시간 Brain mapping system)

  • Cho, Sang-Heum;Kim, Pan-Ki;Park, Sue-Kyoung;Kim, Ji-Eun;Song, Eun;Kang, Mahn-Hee;Ahn, Chang-Beom
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1983-1984
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    • 2008
  • 뇌 활동의 전기적 신호인 뇌파(EEG)와 외부 자극에 대한 유발 전위(EP)를 측정하여 실시간으로 뇌지형도를 생성하는 real-time brain mapping system을 개발하였다. 측정 전극은 32채널을 사용하였고, EEG를 실시간 및 누적 주파수 분석을 통한 뇌파의 활성도 진단, EP를 측정하여 시각적/청각적 자극에 의한 유발 전위 분석을 할 수 있다. 본 시스템은 측정 대상군의 통계적 분석을 위한 Database를 구축하였고, 신뢰성 높은 뇌파 및 유발 전위 신호를 위하여 실시간 측정과정 및 측정 후 Data 검토과정에서 다양한 Artifact 제거 알고리즘이 도입되었다. 또한, 32 채널 Brain map을 구성하여 뇌파를 공간적으로 분석 가능하며, 시간 및 주파수의 증가에 따라 Brain map을 동영상화하여 시간적/주파수적 변화에 따른 분석이 가능하다.

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Effect for Steel Corrosion Protection in Concrete applying Surface Coating Anode and Solar Battery (표면(表面) 코팅 양극(陽極)과 태양전기(太陽電氣)를 이용한 콘크리트 중의 철근(鐵筋) 부식(腐食) 방지(防止)를 위한 효과)

  • Kim, Jong-Pil;Park, Kwang-Pil;Kim, Seong-Soo;Jung, Ho-Seop;Lee, Seung-Tae
    • Resources Recycling
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    • v.18 no.4
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    • pp.44-51
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    • 2009
  • In order to verify the effect of Surface Coating Anode and Solar Battery anode system, accelerated tests in the presence or absence of some chloride content and cracks were carried out. The potential-decay, protection potential and corrosion current density of reinforcing steel in concrete specimen were measured to evaluate the effectiveness of the system. From the test results, the application of the system led to the satisfaction on NACE's criterion in all mixtures of concrete. Additionally it was found that protection potential and corrosion current density were satisfied due to the application of Surface Coating Anode and Solar Battery anode system.

Oxidation of Polymers in Nonaqueous Solutions (비수용액 내에서 중합체의 산화)

  • Choi, Chil Nam;Yang, Hyo Kyung
    • Journal of the Korean Chemical Society
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    • v.45 no.2
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    • pp.138-160
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    • 2001
  • In this study we measured oxidation potentials and current densities for poly(vinylcholride) (PVC) and poly(carbonate)(PC) in nonaqueous solutions, in order to find out how corrosion (oxidation) potentials depend on temperature, pH, enzyme, or added salts. The Tafel's slopes were determined from the Tafel plots of polarization curves. The transfer coefficients (${\alpha}$) wre evaluated from the slope(1-${\alpha}$)nF/2.3 RT, and the electrode reactions appeared irreversible under all conditions.

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Biopotential Signal Measurement, Processing and Analysis (생체전기신호의 측정, 처리 및 해석)

  • 우응제
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.4
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    • pp.12-18
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    • 2004
  • 본 글에서는 인체로부터 생체전기신호를 측정하고 처리 및 해석하는 기술을 소개한다. 일반적인 계측 시스템을 구성하는 필수적인 네 가지 요소는 측정대상, 센서부, 신호처리부, 그리고 출력부이다. 생체전기신호의 측정에서 측정대상은 인체를 포함하는 생명체이다. 경우에 따라서는 생명체로부터 떼어 낸 특정 부위가 측정대상이 될 수도 있으나 본 글에서는 살아 있는 인체를 측정대상으로 설정하기로 한다. 또한 인체로부터 방사되는 에너지를 측정하는 비접촉 방식은 다루지 않고, 측정 부위를 인체의 내부 또는 표면으로 제한한다. 즉, 센서를 측정 부위에 직접 부착하는 접촉형 인체-센서 인터페이스 방법을 사용하는 경우만을 다루기로 한다.(중략)

Measurement of the Ground Resistance using the Fall-of-Potential Method with the Vertically-placed Current and Potential Auxiliary Electrodes (전류 및 전위 보조전극을 수직으로 배치하는 전위강하법을 이용한 접지저항의 측정)

  • Lee, Bok-Hee;Kim, Ki-Bok;Kim, You-Ha
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.3
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    • pp.53-60
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    • 2012
  • The fall-of-potential method is commonly used in measuring the ground resistance of large-scaled grounding system and the current and potential auxiliary electrodes are horizontally arranged. Because the distances between the ground grid to be tested and auxiliary electrodes are limited in downtown areas, it is very difficult to measure accurately the ground resistance of large-scaled grounding system. In this paper, the fall-of-potential method of measuring the ground resistance with the vertically-placed current and potential auxiliary electrodes was examined and discussed. The validity and good accuracy of the proposed method of measuring the ground resistance were confirmed through various simulations and actual tests carried out in uniform and two-layer soil structures.