• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.138-147
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• 1992

Chemically-modified electrodes were fabricated and their electrocatalytic behaviors have been investigated. As a modifying layer, poly-[1-methyl-3-(pyrrol-1-ylmethyl) pyridinium] was electropolymerized onto Pt electrodes under constant current. The thickness of the polymer film was controlled by means of total charge consumed during the electropolymerization. SEM was used to measure the thickness. There was a linear relationship between the passed charge and the film thickness. Ferro/ferricyanide, used as an electron mediator in this study, was rapidly ion-exchanged into the polymer layer with its concentration of 1.2~1.3M. It was found that electrooxidation of ascorbic acid is catalyzed by incorporated ferri/ferrocyanide couple. Kinetic parameters for electrooxidation were determined by RDE experiments. The results indicate that the present system corresponds to ER+S case based on the Saveant theory. Improving methods have been proposed to be R+S case which is ideal for electrocatalysis.

• Journal of the Korean Electrochemical Society
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• v.14 no.3
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• pp.138-144
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• 2011

The transport phenomena of electron and ion around the electrode have been analyzed, herein the computational program to simulate the electrochemical signal of cyclic voltammetry has been implemented. For the dominant mass-transfer system, the governing equation and its boundary conditions are confined to the semi-infinite diffusion model and the reversible reaction at the electrode. In order to obtain the numerical solutions of cyclic voltammetry, MATLAB was used for the explicit finite difference method. Experimental results from the cyclic voltammetry of electrochemical system(10 mM $K_3Fe(CN)_6$ and 0.1M KCl) upon the ITO glass substrate were compared with the numerical solutions. Present program explains the experimental results fairly well, where they approached the simulated ones closely with deceasing the scan rate. Furthermore, the effects of electrode area, electrochemical reaction constants and transfering coefficients in the cyclic voltammetry were discussed quantitatively.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.6
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• pp.1-9
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• 2015

This paper introduces a zero-dimensional modeling on the plasma generation in electrothermal gun operation. The plasma generator consists of alumina bore and aluminum electrodes which is electrically powered by outer pulse forming network and, traditionally, its numerical simulations have employed time-dependent one-dimensional governing equations. However, by assuming isothermal approximation along the bore and choked bore exit condition, present analysis simplifies the mass and energy equations into zero-dimensional approximation of plasma conditions coupled with mass ablation model and plasma property evaluation. The numerical results show good agreement with the corresponding one-dimensional computations and thus verify the present modeling approach.

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.107-109
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• 2002

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.71.2-71.2
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• 2010

고체산화물연료전지는 청정에너지원으로써 기존의 발전방식을 대신할 차세대 에너지원으로 각광 받고 있다. 고체산화물 연료전지는 고온에서 작동하는 특성상 실험을 통하여 전극미세구조 및 구동조건을 최적화하는 것은 매우 어렵다. 본 연구는 전기화학식을 이용한 전산모사를 통해서 고체산화물 연료전지의 구동조건에 따른 성능 평가 및 전극의 미세구조 최적화 과정을 수행하였다. 전극 내 전달현상을 무시하고 오직 전기화학반응만을 고려한 전산모사는 단전지의 전극미세구조 및 구동조건에 따른 전지성능을 빠르게 예측할 수 있으며, 이를 기반으로 다양한 조건에서 얻은 전지 성능 데이터를 통해 전극미세구조를 최적화하였다. 개회로전압, 활성화분극, 저항분극, 물질수송손실을 표현하기 위하여 Nernst 식, Butler-Voler 식, 옴의 법칙, dusty-gas 모델을 각각 사용하였으며, 전극미세구조 및 구동조건의 변화는 물질확산계수 및 교환전류밀도를 통하여 그 영향이 전지성능에 반영된다. 온도, 압력, 주입 연료의 조성에 대한 성능평가가 수행되었으며, 1023K, 1 bar의 조건하에서 최적의 단전지 성능을 위한 기공도와 기공크기를 조사하였다. 더 향상된 단전지 성능 확보를 위해서 실험에서 쓰이는 기능층(functional layer)과 유사하게 넓은 반응 면적과 원활한 반응물 및 생성물의 이동을 보장하도록 기공도 및 기공크기를 그레이딩한 전극구조(graded-electrode)를 디자인하고 성능을 평가하였다. 그 결과 기존의 전지구조 대신에 그레이딩된 전극을 사용할 경우 50%이상 향상된 전지성능을 예측할 수 있었다.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.6
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• pp.83-88
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• 2010

In this paper, to propose a valid method solving a problem relevant to grounding from actual field data, the experimental results relevant to touch and step voltages and surface potential profiles measured around the real-sized and small-sized grounding electrode models were described. The ground surface potential profiles and dangerous voltages around the concrete pedestals employed in street facilities such as street lamps, traffic signal lamp and controllers as a case study were measured and discussed. The hemispherical cell with a diameter of 1,160[mm] was employed to simulate uniform soil. As a result, the results measured with the small-sized model were in reasonably agreement with the data obtained from the real-sized installation. It was found that the small-sized model test could be employed as a useful means evaluating the dangerous voltages around grounding electrodes installed at the inaccessible areas such as mountains, underground, underwater, and so on.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.5
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• pp.401-412
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• 2013

The paper is to study on the simulation of the micro/macroscale thermo-electrochemical model of a single cell of anode-supported SOFC with direct internal reforming. The coupled heat and mass transport, electrochemical and reforming reactions, and fluid flow were simultaneously simulated based on mass, energy, charge conservation. The micro/macroscale model first calculates the detailed electrochemical and direct internal reforming processes in porous electrodes based on the comprehensive microscale model and then solve the macroscale processes such as heat and mass transport, and fluid flow in SOFCs with assumption of fully-developed flow in gas channel. The simulation results evaluate the overall performance by analyzing distributions of mole fraction, current density, temperature and microstructural design in co/counter flow configurations.

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.1475_1476
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• 2009

본 논문에서는 스트리머 방전에 대한 연구의 일환으로 전자사태의 발생과정 및 절연파괴현상을 2차원 유한요소법을 이용하여 해석하였다. 평행 평판 전극을 모델로 도입하고 전자밀도에 대한 경계조건을 변화시켜 각각 시뮬레이션을 통하여 신뢰성 있는 결과를 도출하였다.

• Proceedings of the KIEE Conference
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• 1997.07e
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• pp.1859-1860
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• 1997

다전극 DFB(distributed feedback) 레이저서, 레이징모드간 비팅을 통하여 초고속으로 자려펄스열을 발생시킬 수 있음을 제안한다. 이러한 자려펄스생성을 수정된 시영역 동적 모델(large signal time-domain dynamic model)을 이용하여 조사하였다.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.39 no.10
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• pp.16-24
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• 2002

In this paper, we fabricated heterojunction phototransistors(HPT's) with optically transparent ITO emitter contacts. Heterojunction transistors(HBT's) having the same device layout were fabricated to compare with HPT's. The model parameters of the devices were extracted and compared. Emitter contact resistance(RE) of the HPT was about 6.4$\Omega$, which was very similar to that of HBT and the other DC model parameters of the Inp/InGaAs HPT showed the similarities to those of the HIBT.