• 한국균학회지
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• 제39권3호
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• pp.175-179
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• 2011

LED광원에 대한 큰느타리버섯의 생육특성, 에르고스테롤 및 항산화활성에 미치는 영향을 조사하였다. 원기형성기에 LED광원을 조사한 결과 청색광 및 적색광에서 원기가 형성되지 않았다. 초발이 이후 LED광원을 조사시 형광등과 청색광에서 다른 처리구 보다 갓의 크기는 커지며, 갓의 굵기가 굵어지는 경향이었다. 그러나 대의 길이는 형광등과 청색광에서 다른 처리구 보다 짧았다. 생육특성 중 상품수량은 청색광 및 녹색광에서 형광등과 대등하였다. DPPH는 청색광, 녹색광 및 주황색광에서 가장 높았고, 총폴리페놀함량은 LED 처리구 모두 형광등 처리구보다 높았으며, 에르고스테롤은 녹색광에서 가장 높았다. 이상의 결과 큰 느타리버섯의 고품질 버섯 생산을 위해서는 녹색광이 적합하였다.

• 한국결정성장학회지
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• 제19권1호
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• pp.15-18
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• 2009

본 연구에서는 근 자외선 및 가시광 영역에서 우수한 발광 강도를 가지는 적색 형광체를 얻기 위하여 고상 반응법으로 합성하여 $EU^{3+}$와 $Bi^{3+}$가 도핑 된 ${Y_2}{SiO_5}$의 발광 특성을 관찰하였다. 근자외선 영역인 ${\lambda}_{ex}=395nm$ 기준으로 측정하였고, $^5D_0-^7F_2$의 에너지 천이에 의해 612 nm 영역에서 강한 peak가 발생하였다. CST가 $Eu^{3+}-O^{2-}$에 의해 258 nm 영역 대에서 생성되었고, $Bi^{3+}$가 함께 도핑 된 것은 $Eu^{3+}-Bi^{3+}-O^{2-}$에 상호작용에 의해 282 nm 영역대의 장파장 쪽으로 이동하였다. $350\;nm{\sim}480\;nm$ 영역 대에 '$^7F_0{\to}^5L_9$ (364 nm), $^7F_0{\to}^5G_3$(381 nm), $^7F_0{\to}^5L_6$(395nm), $^7F_0{\to}^5D_3$(415 mn) and $^7F_0{\to}^5D_2$(466 nm)는 $Bi^{3+}$와 $EU^{3+}$ f-f 천이에 의해 발생하였다. $Bi^{3+}$의 도핑농도가 증가할수록 발광 강도가 증가함을 보이다가 0.125 mol 일 때 발광강도가 가장 우수하였고, $Bi^{3+}$의 도핑 농도가 0.125 mol 이상 되면 발광강도가 현저히 감소하는 것을 확인하였다.

• 한국재료학회지
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• 제26권9호
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• pp.504-511
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• 2016

To prepare $Mn^{4+}$-activated $K_2TiF_6$ phosphor, a precipitation method without using hydrofluoric acid (HF) was designed. In the synthetic reaction, to prevent the decomposition of $K_2MnF_6$, which is used as a source of $Mn^{4+}$ activator, $NH_5F_2$ solution was adopted in place of the HF solution. Single phase $K_2TiF_6$:$Mn^{4+}$ phosphors were successfully synthesized through the designed reaction at room temperature. To acquire high luminance of the phosphor, the reaction conditions such as the type and concentration of the reactants were optimized. Also, the optimum content of $Mn^{4+}$ activator was evaluator based on the emission intensity. Photoluminescence properties such as excitation and emission spectrum, decay curve, and temperature dependence of PL intensity were investigated. In order to examine the applicability of this material to a white LED, the electroluminescence property of a pc-WLED fabricated by combining the $K_2TiF_6$:$Mn^{4+}$ phosphor with a 450 nm blue-LED chip was measured.

• 한국세라믹학회지
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• 제47권2호
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• pp.122-126
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• 2010

In this article photoluminescence of the $Al_2O_3:xCr_2O_3$ solid solutions prepared by solid state reaction method are represented. The effect of $Cr_2O_3$-activator concentration and heat treatment time on the PL characteristics have been discussed in conjunction with microstructure of phosphor samples. The $Al_2O_3:xCr_2O_3$ phosphors show the highest PL intensity at x=0.003 mole when the samples are reacted at $1600^{\circ}C$ for 5 h. The PL emission and absorption spectra show the maximum peaks at 698 nm and at 398 nm respectively. The CIE color coordinate is (x=0.646, y=0.316) at 0.003 mole $Cr_2O_3$, which value is very close to the NTSC coordinate of red color. This characteristic feature of $Al_2O_3:xCr_2O_3$ has been applied for an additive to improve the color characteristic of other red phosphor $LiEuW_2O_8$ which has a relatively poor color purity with an emission peak centered at 615 nm and with a CIE coordinate (x=0.530, y=0.280). The $Al_2O_3:0.003Cr_2O_3$ phosphor has been mixed with the $LiEuW_2O_8$ phosphor powder and the PL characteristics and CIE color coordinates are characterized. The $Al_2O_3:xCr_2O_3$ phosphor was found effective for improving the CRI (color rendering index) of $LiEuW_2O_8$ phosphor.

• 한국광학회지
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• 제32권4호
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• pp.163-171
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• 2021

조명에 사용되는 일반적인 백색 발광 다이오드는 청색 발광 다이오드 위에 황색 형광체를 입힌 구조가 보편적이나 발광 스펙트럼상 짙은 적색 성분이 부족해서 조명의 연색성이 떨어지는 문제가 있다. 본 연구에서는 백색 발광 다이오드의 연색 특성을 개선하기 위해 적색 양자점 조명을 백색 조명의 확산판에 적용한 후 광학 시뮬레이션을 이용해 광구조를 최적화하고자 하였다. 양자점의 평균 자유 행정 및 확산판 내 TiO₂ 입자의 농도를 조절해 연색지수, 휘도 등 광특성을 조사했다. 대부분의 조건에서 연색지수는 90을 넘었고 이는 적색 양자점 필름의 적용이 일반적인 백색 발광 다이오드의 연색 특성을 개선하는 데 효과적인 방법임을 보여준다. 색좌표의 각도 의존성은 확산판과 조명 하단의 반사판 사이에 형성되는 광학적 공동 구조를 활용함으로써 제거할 수 있었는데 이는 공동 내 위치한 양자점 필름을 통한 빛의 다중 투과가 시야각에 따른 광경로의 차이를 줄였기 때문으로 해석된다.

• 한국분말재료학회지
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• 제16권3호
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• pp.203-208
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• 2009

$Y_2O_3$:Eu red phosphor was prepared by microwave synthesis. The crystal phase, particle morphology, and luminescent properties were characterized by XRD, SEM, and spectrofluorometer, respectively. The prepared $Y_2O_3$:Eu particles had good crystallinity and strong red emission under ultravioletet excitation. The crystallite size increased with calcination temperature and satuarated at $1200^{\circ}C$. The primary particle size initially formed was varied from 30 to 450 nm with microwave-irradiation (MI) time. It was found that the emission intensity of $Y_2O_3$:Eu phosphor strongly depends on the MI time. In terms of the emission intensity, it was recommended that the MI time should be less than 15 min. The emission intensity of $Y_2O_3$:Eu phosphor prepared by microwave syntehsis strongly depended on the crystallite size of which an optimal size range was 50-60 nm.

• 한국전기전자재료학회논문지
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• 제15권3호
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• pp.258-263
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• 2002

We present a new toed phosphor, $Gd_{2-x-y}Li_xEu_yO_3$ with superior luminescent Properties compared to the commercially available red phosphor $Y_2O_3:Eu^{3+}$. The phosphor, with a diameter of about $2\mu\textrm{m}$, consists of the psedospherical particles in a regular array. The photoluminescence measurements as a function of the laser power and the Eu mole fraction were performed at zoom temperature The luminescence intensity linearly increases as both the laser power and the Eu mole fraction Increase. As for the dependence on cathodoluminescence, the incorporation of Eu and Li ions into $Gd_2O_3$ lattice brings about an increase in luminescent efficiency. The highest emission intensity for the phosphor occurs at the applied voltage of 500 V, its value is larger than that of $Y_2O_3:Eu^{3+}$ powder by 70%.

• 한국세라믹학회지
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• 제48권1호
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• pp.86-93
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• 2011

Transparent plasma display can be realized by developing the synthetic chemistry of appropriate nanophosphors and generating nanophosphor-based transparent luminescent layers. For this goal, red-emitting $Y(V_{0.5},\;P_{0.5})O_4$:Eu nanophosphors were synthesized by a facile hydrothermal route at $200^{\circ}C$ for 48 h and the resulting nanophosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and emission property of the as-synthesized and annealed nanophosphors were compared. Choosing 2-methoxyethanol as a dispersion medium and applying a standard sonication, well-dispersed nanophosphor solutions could be prepared. Using these dispersions, visible transparent nanophosphor layers were spin-deposited on glass substrates. By combining $Y(V_{0.5},\;P_{0.5})O_4$:Eu nanophosphor layer/glass substrate as a rear plate with a front plate used in a conventional plasma display panels (PDPs), mini-sized transparent red-emitting PDPs were constructed. Transmittance and luminance properties of two transparent test panels using as-synthesized versus $800^{\circ}C$-annealed nanophosphors were characterized and compared.

• 한국재료학회지
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• 제18권3호
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• pp.159-162
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• 2008

$Eu^{3+}$-activated $R_3GaO_6$ (R = Y, Gd) phosphors were prepared in a conventional solid-state reaction and their optical properties were investigated. These compounds exhibit strong red emission under light excitation at 254 nm. The emission spectra are dominated by peaks appearing around 610-630 nm that are induced by the electric dipole transition of $^5D_0\;{\rightarrow}\;^7F_2$ of $Eu^{3+}$. In addition, the appropriate CIE (Commission Internationale de l'clairage) chromaticity coordinates, (x = 0.656, y = 0.336) for $Y_3GaO_6$ and (x = 0.655, y = 0.334) for $Gd_3GaO_6$, become closer to the NTSC (National Television System Committee) standard values. With the optimized activator concentrations, the maximum emission brightness is approximately 80% of $Y_2O_3$:$Eu^{3+}$ typical red-emitting phosphor with improved color purity under an excitation condition of 254 nm.

• 반도체디스플레이기술학회지
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• 제16권4호
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• pp.11-15
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• 2017

Red phosphors, $Sr_2Si_5N_8:Eu^{2+}$, were synthesized as a single-phase crystal structure by optimizing carbon and $Eu^{2+}$ contents in a carbothermal reduction nitridation method. With increasing $Eu^{2+}$ contents, the photoluminescence spectra were red-shifted from 600 nm peak for 1 mol% for to 700 nm for 7 mol%. It was suggested that this red shift is attributed to the energy transfer from one low-energy sited $Eu^{2+}$ (1) to other high-energy sited $Eu^{2+}$ (2). Finally, the best red sample (620 nm emission peak and 80 nm half width for 3 mole% of $Eu^{2+}$) was packaged on a Blue LED together with two additional green and yellow phosphors, the fabricated White LED showed a high color-rendering index of 90 and white color coordinates of x= 0.321 and y = 0.305.