• Title/Summary/Keyword: 재활용성평가

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The Study on the Composting by Using Dam Suspended Particle Sawdust and Sewage Sludge (댐부유물 톱밥과 하수슬러지를 이용한 퇴비화 연구)

  • Ryu, Ji-Hune;Lee, Jong-Jin;Hong, Joo-Hwa;Chang, Ki-Woon;Lee, Gyu-Seung;Park, Gwan-Soo;Han, Ki-Pil
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.98-103
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    • 2010
  • This study was carried out on the composting of the most part of the plant waste materials inflowed-drifting into the dam during the localized heavy rain and the rainy season, due to the abnormal climate change, and for the sewage sludge banned to dispose legally into the ocean from the year of 2012. It was analysed the distinctive physicochemical qualities of the compost with treatment S-1(dam suspended particle sawdust : oak tree bark : sewage sludge : chicken manure = 30 : 20 : 40 : 10) and treatment S-2(dam suspended particle sawdust : oak tree bark : sewage sludge : chicken manure = 30 : 30 : 30 : 10). Both S-1 and S-2 maintained for 10 days at above $65^{\circ}C$ of the compost pile temperature, and the most of its pathogen were destroyed. In case of pH, until the 90th day into composting, S-1 with the pH value of 7.78 was slightly higher than S-2. The C/N value of S-1 was 15.3 and that of S-2 was 16.9. The quality of its final product was satisfied to the manufacture-standards. The GI value of S-1 was 91 higher than that of S-2, which was 84. In conclusion, it is highly recommendable to manufacture S-1 for its frequent usage of dam suspended particle sawdust and sewage sludge, and for its excellent quality and safety.

Electrochemical Decontamination of Metallic Wastes Contaminated with Uranium Compounds (우라늄화합물로 오염된 금속폐기물의 전해제염)

  • 양영미;최왕규;오원진;유승곤
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.11-23
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    • 2003
  • A study on the electrolytic dissolution of SUS-304 and Inconel-600 specimen was carried out in neutral salt electrolyte to evaluate the applicability of electrochemical decontamination process for recycle or self disposal with authorization of large amount of metallic wastes contaminated with uranium compounds generated by dismantling a retired uranium conversion plant in Korea. Although the best electrolytic dissolution performance for the specimens was observed in a Na2s04 electrolyte, a NaNO$_3$ neutral salt electrolyte, in which about 30% for SUS-304 and the same for Inconel-600 in the weight loss was shown in comparison with that in a Na$_2$SO$_4$ solution, was selected as an electrolyte for the electrochemical decontamination of metallic wastes with the consideration on the surface of system components contacted with nitric acid and the compatibility with lagoon wastes generated during the facility operation. The effects of current density, electrolytic dissolution time, and concentration of NaNO$_3$ on the electrolytic dissolution of the specimens were investigated. On the basis of the results obtained through the basic inactive experiments, electrochemical decontamination tests using the specimens contaminated with uranium compounds such as UO$_2$, AUC (ammonium uranyl carbonate) and ADU (ammonium diuranate) taken from an uranium conversion facility were performed in 1M NaNO$_3$ solution with the current density or In mA/$\textrm{cm}^2$. it was verified that the electrochemical decontamination of the metallic wastes contaminated uranium compounds was quite successful in a NaNO$_3$ neutral salt electrolyte by reducing $\alpha$ and $\beta$ radioactivities below the level of self disposal within 10 minutes regardless of the type of contaminants and the degree of contamination.

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Requirement and Perception of Parents on the Subject of Home Economics in Middle School (중학교 가정교과에 대한 학부모의 인식 및 요구도)

  • Shin Hyo-Shick;Park Mi-Soog
    • Journal of Korean Home Economics Education Association
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    • v.18 no.3 s.41
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    • pp.1-22
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    • 2006
  • The purpose of this study is that I should look for a desirous directions about home economics by studying the requirements and perception of the high school parents who have finished the course of home economics. It was about 600 parents whom I have searched Seoul-Pusan, Ganwon. Ghynggi province, Choongcheong-Gyungsang province, Cheonla and Jeju province of 600, I chose only 560 as apparently suitable research. The questions include 61 requirements about home economics and one which we never fail to keep among the contents, whenever possible and one about the perception of home economics aims 11 about the perception of home economics courses and management. The collections were analyzed frequency, percent, mean. standard deviation t-test by using SAS program. The followings is the summary result of studying of it. 1. All the boys and girls learning together about the Idea of healthy lives and desirous human formulation and knowledge together are higher. 2. Among the teaching purposes of home economics, the item of the scientific principle and knowledge for improvements of home life shows 15.7% below average value. 3. The recognition degree about the quality of home economics is highly related with the real life, and about the system. we recognize lacking in periods and contents of home economics field and about guiding content, accomplishment and application qualities are higher regardless of sex. 4. The important term which we should emphasize in the subject of home economics is family part. 5. Among the needs of home economic requirement in freshman, in the middle unit, their growth and development are higher than anything else, representing 4.11, and by contrast the basic principle and actuality is 3.70, which is lowest among them. 6. In the case of second grade requirement of home economics content for parents in the middle unit young man and consuming life is 4.09 highest. 7. In the case of 3rd grade requirement of economics contents in the middle unit the choice of coming direction and job ethics is highest 4.16, and preparing meals and evaluation is lowest 3.50.

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Evaluation of Lead, Copper, Cadmium, and Mercury Species in the Leachate of Steel Making Slag by Seawater (해수에 의한 제강 슬래그의 납, 구리, 카드뮴 및 수은 화합물의 용출특성 평가)

  • Lee, Han-Kook;Lee, Dong-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.75-84
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    • 2005
  • The aim of this study is to evaluate the leaching characteristics of lead, copper, cadmium, and mercury from steel making slag by seawater. To demonstrate the leaching characteristics of heavy metals from steel making slag by seawater, it was carried to various leaching tests such as regular leaching tests, liquid/sold(LS) leaching test and pH static test. From the leachability of $Pb^{+2},\;Cu^{+2},\;and\;Cd^{+2}$ from steel making slag in pH static test, it is distinguished between distilled water and seawater. With distilled water, it is very low between pH 7-8 and pH 11-12. On the other hands, with the seawater, its leaching is higher than that of distilled water. In particular, concentration of $Hg^{+2}$ leached from slag by seawater is lower than that of distilled water. Meanwhile, we found that the heavy metals from steel making slag would be dissolved and precipitated using geochemcial equilibrium program such as visual minteq. Lead and copper leached from steel making slag with seawater were dissolved nearly in the range of pH 11-12, but in the range of pH 7-10 those were precipitated about 90%. And cadmium leached from steel making slag with seawater were dissolved completely. On pH static test with distilled water, lead leached from steel making slag seemed to be similar to pH static test with seawater. However, copper and cadmium leached from steel making slag were dissolved. In general, the species of lead leached from steel making slag were formed mainly of $PbCl^+,\;PbSO_4$, the species of copper were formed mainly of $CuSO_4,\;CuCO_3$, the species of cadmium were formed mainly of $CdCl^+,\;CdSO_4$ due to being sorbed with the anions($Cl^-,\;CO_3^{-2},\;SO_4^{-2}$) of the seawater. Both pH static test with seawater and distilled water, it is not in the case of the mercury. Most of mercury leached from steel making slag was precipitated(SI=0). Because the decreasing of $Hg^{+2}$ concentrations depends ferociously on the variation of chloride($Cl^-$) existed in the seawater. $Hg^{+2}$ leached from steel making slag could be sorbed strongly with chloride($Cl^-$) compared of carbonate($CO_3^{-2}$) and sulfate($SO_4^{-2}$) in the seawater. On the basis of that result, we found that the species of mercury was formed of calomel($Hg_2Cl_2$) as one of finite solid. Due to forming a calomel($Hg_2Cl_2$) in the seawater, the stability of mercury species by steel making slag should be higher than those of lead, copper, and cadmium species. Regarding the results stated above, we postulated that the steel making slag could be recycled to sea aggregates due to being distinguishing leachability of heavy metals($Pb^{+2},\;Cu^{+2},\;Cd^{+2},\;and\;Hg^{+2}$) between leaching tests by distilled water and seawater.

The Effect of Application of Cattle Slurry and Chemical Fertilizer on Productivity of Rye and Hairy Vetch by Single or Mixed Sowing (답리작으로 호밀과 헤어리베치의 단, 혼파 재배 시 우분뇨 및 화학비료의 시용에 따른 생산성 평가)

  • Jo, Ik-Hwan;Yun, Young-Bum;Park, Wung-Ryeol;HwangBo, Soon;Lee, Sung-Hoon;Lee, Ju-Sam
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.28 no.4
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    • pp.323-330
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    • 2008
  • This study was carried out to evaluate the effect of application of cattle manure and chemical fertilizer on dry matter productivity and nutritive values of rye and hairy vetch according to two different sowing methods such as single or mixed-sowed cultivation. Dry matter and TDN yields for rye single culture, and rye and hairy vetch mixed culture were 7.2 and 4.0 ton/ha, and 8.0 and 4.4 ton/ha, respectively. They were significantly (p<0.05) higher than that (4.5 and 2.7 ton/ha) of hairy vetch single culture. Moreover, plots produced by mixed-sowing cultivation had a higher crude protein (CP) as 7.7% than that of only rye plot, and higher TDN and RFV as 55.8 and 79.4%, respectively. Within rye alone plots, completely cattle slurry application produced significantly higher annual DM and TDN yields (7.4 and 4.1 ton/ha) than those of P+K fertilization (7.2 and 3.9 ton/ha) as a chemical fertilizer and non-fertilizer (5.5 and 3.1 ton/ha). Cattle slurry application plot revealed 75.52 and 78.97% of N+P+K fertilization plot for annual DM and TDN, respectively. Within mixed-sowing cultivation with rye and hairy vetch, completely cattle slurry application produced 7.6 ton/ha DM and 4.5 ton/ha TDN, showing 79.50 and 86.77% of N+P+K fertilization plot, respectively. Furthermore, the CP content for cattle slurry plots was 8.5%, which was significantly (p<0.05) higher than those of other plots, and it was also highest in TDN (58.3%) and RFV (86). Overall, rye mixed-sowing with hairy vetch rather than rye alone sowing reduced DM yields, but leaded to enhancement of feed value and nutritive yields. And also, it would be expected that cattle slurry application in comparison with chemical fertilizers might result in reutilization of resources, improved forage quality and, extended harvest period by preventing feed value from rapidly deteriorating.

Development of B4C Thin Films for Neutron Detection (스퍼터링 코팅기법을 이용한 중성자 검출용 B4C 박막 개발)

  • Lim, Chang Hwy;Kim, Jongyul;Lee, Suhyun;Cho, Sang-Jin;Choi, Young-Hyun;Park, Jong-Won;Moon, Myung Kook
    • Journal of Radiation Protection and Research
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    • v.40 no.2
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    • pp.79-86
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    • 2015
  • $^3He$ gas has been used for neutron monitors as the neutron converter owing to its advantages such as high sensitivity, good ${\gamma}$-discrimination capability, and long-term stability. However, $^3He$ is becoming more difficult to obtain in last few years due to a global shortage of $^3He$ gas. Accordingly, the cost of a neutron monitor using $^3He$ gas as a neutron converter is becoming more expensive. Demand on a neutron monitor using an alternative neutron conversion material is widely increased. $^{10}B$ has many advantages among various $^3He$ alternative materials, as a neutron converter. In order to develop a neutron converter using $^{10}B$ (actually $B_4C$), we calculated the optimal thickness of a neutron converter with a Monte Carlo simulation using MCNP6. In addition, a neutron converter was fabricated by the Ar sputtering method and the neutron signal detection efficiencies were measured with respect to various thicknesses of fabricated a neutron converter. Also, we developed a 2-dimensional multi-wire proportional chamber (MWPC) for neutron beam profile monitoring using the fabricated a neutron converter, and performed experiments for neutron response of the neutron monitor at the 30 MW research reactor HANARO at the Korea Atomic Energy Research Institute. The 2-dimensional MWPC with boron ($B_4C$) neutron converter was proved to be useful for neutron beam monitoring, and can be applied to other types of neutron imaging.

Preparation of Birnessite (δ-MnO2) from Acid Leaching Solution of Spent Alkaline Manganese Batteries and Removals of 1-naphthol (폐 알칼리망간전지의 산 침출액으로부터 버네사이트(δ-MnO2)의 제조 및 1-naphthol 제거)

  • Eom, Won-Suk;Lee, Han-Saem;Rhee, Dong-Seok;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.11
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    • pp.603-610
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    • 2016
  • This work studies the synthesis of birnessite (${\delta}-MnO_2$), a catalyst of oxidative-coupling reactions, from the powder of spent alkaline manganese batteries (SABP, <8 mesh) and evaluate its reactivity for 1-naphthol (1-NP) removals. Manganese oxides using commercial reagents ($MnSO_4$, $MnCl_2$) and the acid birnessite (A-Bir) by McKenzie method were also synthesized, and their crystallinity and reactivity for 1-NP were compared with one another. 96% Mn and 98% Zn were extracted from SABP by acid leaching at the condition of solid/liquid (S/L) ratio 1:10 in $1.0M\;H_2SO_4+10.5%\;H_2O_2$ at $60^{\circ}C$. From the acid leaching solution, 69% (at pH 8) and 94.3% (pH>13) of Mn were separated by hydroxide precipitation. Optimal OH/Mn mixing ratio (mol/mol) for the manganese oxide (MO) synthesis by alkaline (NaOH) hydrothermal techniques was 6.0. Under this condition, the best 1-NP removal efficiency was observed and XRD analysis confirmed that the MOs are corresponding to birnessite. Kinetic constants (k, at pH 6) for the 1-NP removals of the birnessites obtained from Mn recovered at pH 8 (${Mn^{2+}}_{(aq)}$) and pH>13 ($Mn(OH)_{2(s)}$) are 0.112 and $0.106min^{-1}$, respectively, which are similar to that from $MnSO_4$ reagent ($0.117min^{-1}$). The results indicated that the birnessite prepared from the SABP as a raw material could be used as an oxidative-coupling catalyst for removals of trace phenolic compounds in soil and water, and propose the recycle scheme of SAB for the birnessite synthesis.

Evaluation of Possibility of Water Plant Wastes in Composting for Agricultural Recycling (수생식물 고사체의 농업적 재활용을 위한 퇴비화 가능성 평가)

  • Choi, Ik-Won;Seo, Dong-Cheol;Kang, Se-Won;Seo, Young-Jin;Lee, Sang-Gyu;Kang, Seog-Jin;Lim, Byung-Jin;Lee, Jun-Bae;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.248-252
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    • 2012
  • To evaluate the possibility of water plant wastes in composting for agricultural recycling, Phragmites communis (PHRCO), Typha orientalis (TYHOR) and Zizania latifolia (ZIZLA) were used as a compost materials. In composting basin, cumulative oxygen consumptions of the compost used by water plant wastes were rapidly increased at the early stage and slightly decreased in around 15 days. Cumulative oxygen consumptions under different water plant wastes were higher in the order of TYHOR > ZIZLA > PHRCO. Temperature changes during composting process were rapidly increased at the early stage and then slowly decreased to $30{\sim}40^{\circ}C$. The maximum temperatures were higher in the order of ZIZLA ($72.2^{\circ}C$ at 11 days after starting composting) > TYHOR ($70.2^{\circ}C$ at 10 days after starting composting) > PHRCO ($66.5^{\circ}C$ at 7 days after starting composting). Oxygen consumptions at maximum temperature were higher in the order of TYHOR ($12,485mg\;O_2\;kg^{-1}$) > ZIZLA ($12,400mg\;O_2\;kg^{-1}$) > PHRCO ($9,340mg\;O_2\;kg^{-1}$). Organic matter contents, moisture contents and OM/N rates in the compost ranged 39.5~44.8%, 29.6~35.6% and 27.9~32.9, respectively. Considering that water plant waste can supply some of the nutrient requirements of crops and is a valuable fertilizer.

Characterization and Feasibility Study of the Soil Washing Process Applying to the Soil Having High Uranium Concentration in Korea (우라늄 함량이 높은 국내 토양에 대한 토양학적 특성 규명 및 토양세척법의 적용성 평가)

  • Chang, See-Un;Lee, Min-Hee
    • Journal of Soil and Groundwater Environment
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    • v.13 no.5
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    • pp.8-19
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    • 2008
  • The physicochemical properties of soils having high uranium content, located around Duckpyungri in Korea, were investigated and the lab scale soil washing experiments to remove uranium from the soil were preformed with several washing solutions and on various washing conditions. SPLP (Synthetic Precipitation Leaching Procedure), TCLP (Toxicity Characteristic Leaching Procedure), and SEP (Sequential Extraction Procedure) for the soil were conducted and the uranium concentration of the extracted solution in SPLP was higher than Drinking Water Limit of USEPA (30 ${\mu}g$/L), suggesting that the continuous dissolution of uranium from soil by the weak acid rain may generate the environmental pollution around the research area. For the soil washing experiments, the uranium removal efficiency of pH 1 solution for S2 soil was about 80 %, but dramatically decreased as pH of solution was > 2, suggesting that strong acidic solutions are available to remove uranium from the soil. For solutions with 0.1M of HCl and 0.05 M of ${H_2}{SO_4}$, their removal efficiencies at 1 : 1 of soil vs. washing solution ratio were higher than 70%, but the removal efficiencies of acetic acid, and EDTA were below 30%. At 1 : 3 of soil vs. solution, the uranium removal efficiencies of 0.1M HCl, 0.05 M ${H_2}{SO_4}$, and 0.5M citric acid solution increased to 88%, 100%, and 61% respectively. On appropriate washing conditions for S2 soil such as 1 : 3 ratio for the soil vs. solution ratio, 30 minute for washing time, and 2 times continuous washing, TOC (Total Organic Contents) and CEC (Cation Exchange Capacity) for S2 soil were measured before/after soil washing and their XRD (X-Ray Diffraction) and XRF (X-Ray Fluorescence) results were also compared to investigate the change of soil properties after soil washing. TOC and CEC decreased by 55% and 66%, compared to those initial values of S2 soil, suggesting that the soil reclaimant may need to improve the washed soils for the cultivated plants. Results of XRF and XRD showed that the structural change of soil after soil washing was insignificant and the washed soil will be partially used for the further purpose.

Dynamic Characteristics of Liquidity Filling Materials Mixed with Reclaimed Ash (매립석탄회를 혼합한 유동성 충진재의 동적거동특성)

  • Chae, Deokho;Kim, Kyoungo;Shin, Hyunyoung;Cho, Wanjei
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.4
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    • pp.5-11
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    • 2014
  • Recently, there have been various lifeline installations constructed in the underground space of urban area due to the effective use of land. For newly installed lifelines or the management of the installed lifelines, many construction activities of excavation and backfilling are observed. Around these area, there are possibilities of collapse or excessive settlement due to the leaking of the pipe or unsatisfactory compaction of backfill material. Besides, construction costs can be saved since the on-site soils are used. The application of this liquidity filling material is not only to the lifeline installation but also to underpin the foundation under the vibrating machinery. On the evaluation of the applicability of this method to this circumstance, the strength should be investigated against the static load from the machine load as well as the vibration load from the activation of the machine. In this study, the applicability of the liquidity fill material on the foundation under the vibrating machinery is assessed via uniaxial compression and resonant column tests. The liquidity filling material consisting of the on-site soils with loess and kaolinite are tested to investigate the static and dynamic characteristics. Furthermore, the applicability of the reclaimed ash categorized as an industrial waste is evaluated for the recycle of the waste to the construction materials. The experimental results show that the shear modulus and 7 day uniaxial strength of the liquidity filling material mixed with reclaimed ash show higher than those with the on-site soils. However, the damping ratio does not show any tendency on the mixed materials.