• Polymer(Korea)
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• v.38 no.6
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• pp.767-773
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• 2014

Rheological and electrical properties of polystyrene (PS)/carbon nanotube (CNT) nanocomposites via coagulated precipitation were investigated. Chemical modification and surfactant wrapping of CNT to improve the dispersion of CNTs may reduce the intrinsic properties of pristine CNT. To avoid this problem, PS and CNTs were dissolved and dispersed in dimethylformamide and then PS/CNT nanocomposites were prepared by the coagulated precipitation of CNT-dispersed PS solution in water. The coagulated precipitation method was highly effective enhancing the electrical conductivity of nanocomposites. Furthermore, the effect of adding poly(styrene-co-divinylbenzene) crosslinked particles to PS matrix on the rheological and electrical properties was investigated. With the addition of the crosslinked particles, the electrical percolation threshold of CNT reduced to 0.25 wt% and electrical conductivity increased further. It is speculated that CNTs in the volume occupied by crosslinked particles helped electrical pathway formation.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.11
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• pp.927-936
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• 2014

This paper presents development and verification of the progressive failure analysis upon the composite laminates. Strength and stiffness of the fiber-reinforced composite are analyzed by property degradation approach with emphasis on the material nonlinearity and continuum damage mechanics (CDM). Longitudinal and transverse tensile modes derived from Hashin's failure criterion are used to predict the thresholds for damage initiation and growth. The modified Newton-Raphson iterative procedure is implemented for determining nonlinear elastic and viscoelastic constitutive relations. Laminar properties of the composite are obtained by experiments. Prediction on the un-notched tensile (UNT) specimen is performed under the laminate level. Stress-strain curves and strength results are compared with the experimental measurement. It is concluded that the present nonlinear CDM approach is capable of predicting the strength and stiffness more accurately than the corresponding linear CDM one does.

• Composites Research
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• v.20 no.5
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• pp.64-69
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• 2007

Matrix dominant properties of composites are largely degraded under harmful environments such as temperature and humidity. Therefore we should consider the harmful environmental factors in the design of an UAV integral fuel tank subjected to high temperature and high humidity. The harmful environment experiment was performed for carbon/epoxy composites made of a unidirectional prepreg USN175B, and a plain woven fabric prepreg WSN3. The immersion experiment was performed under $90^{\circ}C$. The specimens were tested when the weight gam of specimen was saturated. The specimens were tested under $74^{\circ}C$ to obtain tensile and inplane shear properties. The results showed that the matrix dominant properties were extremely degraded by hygrothermal environment. To consider the variability of load, the anti-optimization method was applied. By using this method, the worst load case was found by comparing the load convex model and stability boundary. The stability boundary was obtained by analysis of the integral wing fuel tank of UAV using degraded properties. To do this, it was known that the worst load case of the integral wing fuel tank was the hovering mode load case.

• Proceedings of the KAIS Fall Conference
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• 2011.05b
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• pp.989-992
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• 2011

삼원 촉매는 주로 코제라이트 세라믹으로 제작되는 다공성 부품이다. 그러나 코제라이트 세라믹은 열적충격온도가 낮아 엔진의 혼합기가 농후한 경우 삼원촉매의 열적 내구성이 급격히 떨어져 내구 수명을 제대로 만족시키지 못하는 차량이 급격히 증가하고 있다. 따라서 본 논문은 유한요소법으로 구한 SiC 세라믹 재료의 등가 물성치를 기초로 SiC 세라믹 촉매 담체의 기계적 물성치를 유한요소해석용시험편으로 구한 뒤 SiC 세라믹 촉매담체가 실차에 설치될 경우의 열피로 성능에 대하여 평가하였다.

• Korean Journal of Materials Research
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• v.3 no.5
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• pp.529-537
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• 1993

The mecllanical properties of AI/TiCp composite fabrication by liquid mixing was investigat ed. The composites, containing 10 wt% Tic. were producwi using induction furnace with mechanical stirring. The amounts of' 1.5wt% Mg were, added to wetting agents. Thr presence of aluminum in TiC composites showed rnhanced strengrh without loss of ductility at room and clrvated temperatures. Espe cially, wear resistance was found to dramatically irnprovc. I3ul excess stirring d~terrninrd the mect~ani~ cal properties. Approximate values at present work were 500 rpm. There was no inrerfacial reaction of any kind and the interface remains clearly deineated.

• Polymer(Korea)
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• v.37 no.4
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• pp.526-532
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• 2013

The effect of CNT dispersion method on rheological and electrical properties of polystyrene/carbon nanotube (PS/CNT) nanocomposites via latex technology was compared. The nanocomposites were prepared through freeze-drying the dispersed suspension comprised of CNTs and PS particles. In this study, physical dispersion method, either sodium dodecylsulfate (SDS) addition or polyvinyl pyrrolidone (PVP) wrapping, was employed to prevent the deterioration of intrinsic properties of CNT caused by chemical modification. The physical method applied to latex technology was very effective in CNT dispersion. With SDS addition, the enhancement of rheological properties was low compared to PVP wrapping because the properties of matrix were deteriorated due to the incorporation of low molecular weight SDS. The electrical percolation threshold of PS/SDS-stabilized CNT and PS/PVP-wrapped CNT nanocomposites was 0.23 and 0.90 wt%, respectively. The enhancement of electrical conductivity was low in the case of PVP wrapping because the non-conducting PVPs wrapped around CNT restricted the electrical connection between CNTs.

• Journal of the Korean Society for Nondestructive Testing
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• v.22 no.4
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• pp.333-346
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• 2002

The continuous indentation techniques are one of the most effective methods to nondestructively estimate mechanical properties. There are many applications in various dimensions of materials from macro-scale, through micro-scale, even to nano-scale range. The macro-range technology of kgf-load level is now focused on the evaluation of tensile properties and residual stress of bulk materials, for example, used in conventional load-bearing structures and in-use pipelines. The technology and the apparatus were successfully developed by a domestic research group. The micro-range technology of gf-load level can be applied to investigate some property-gradient materials such as weldment. Because it has better spatial resolution than the macro-range technology. The nano-range technology (called nanoindentation technique) of mgf-load level is basically used to evaluate hardness and modulus of micro- and nano-materials. Moreover, many researches are going on to measure tensile properties and residual stress. The nanoindentation technology is easy to be applied to the various fields, such as semiconductor devices, multiphase materials, and biomaterials, though other methods are too difficult to be applied due to dimensional or environmental limitations. On the basis of these accomplishments, the international and the domestic standards are being established.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.313-319
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• 2012

In this work, the electroplating of copper was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and contact angle measurements. Its mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). From the results, it was found that the mechanical interfacial properties of Cu-plated carbon fibers-reinforced composites (Cu-CFRPs) enhanced with increasing the Cu plating time, Cu content and COOH group up to Cu-CFRP-30. However, the mechanical interfacial properties of the Cu-CFRPs decreased dramatically in the excessively Cu-plated CFRPs sample. In conclusion, the presence of Cu particles on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the Cu-CFRPs, but the excessive Cu content can lead the failure due to the interfacial separation between fibers and matrices in this system.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.327-327
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• 2008

Lead-free $(K_{0.5}Na_{0.5})NbO_3$ 압전 세라믹스는 다양한 광소자로의 응용과 압전 특성, 초전 특성을 이용한 압전 소자로의 응용이 가능한 재료로 보고되고 있다. 그러나 KNN계 압전소재 특성상 판상 형태의 결정립으로 인해 낮은 소결 밀도를 갖게 되고, 그로인해 압전물성의 저하를 초래하는 문제점을 가지고 있다. 따라서, 본연구에서는 다양한 밀링 방법을 적용하여 입자 사이즈를 작게 하고 소성체의 결정립을 구형화 함으로써 저온소결에서의 압전물성을 개선시키고자 한다. $(K_{0.5}Na_{0.5})NbO_3$를 기계적 분쇄법에 의해 입자사이즈에 따라 변화되는 상의 분석과 압전체로서의 특성을 관찰하였다. 결정학적 상분석 및 미세 조직은 XRD, SEM을 이용하여 관찰하였고, Capacitance는 Impedance analyzer(HP4192A)로 측정하였으며, Impedance 주파수 특성은 Network Analyzer로 측정하여 Kp, Kt와 Qm을 측정하였다.

• Polymer(Korea)
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• v.27 no.5
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• pp.493-501
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• 2003

Poly(methyl methacrylate) (PMMA) particles, denture base resin, were synthesized by suspension polymerization through control of polymerization conditions (stabilizer concentration, co-monomer concentration, and the agitation speed) and evaluated changes in molecular weight and particle size. We also investigated their mechanical properties of compression-molded samples which were from synthesized polymer powder mixed with methyl methacrylate (MMA) solution. under the condition of volumetric ratio as 2:1(PMMA powder and MMA solution). The results shows that the mechanical properties were mainly affected by particle size over 100 ${\mu}$m (in particle size) and by molecular weight under 100 ${\mu}$m (in particle size). From these results, we concluded that the most appropriate particle size of PMMA powder for heat-cured denture base resins is around 100 ${\mu}$m. and its molecular weight is around 300000 (M$\sub$n/).