• Korean Journal of Materials Research
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• v.7 no.12
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• pp.1089-1096
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• 1997

본 연구에서는 에폭시/산무수물계에 화학양론비(r=산무수물/에폭시)를 0.5, 0.7,0.9,1.1로 변화시켜 서로 다른 두종류의 경화촉진제 1-cyanoethy1-2-ethy1-4-methy1 imidazole(2E4MZ-CN)과 N,N-dimethy1 benzy1 amine(BDMZ)을 첨가한 시료에 대한 경화거동과 경화 후 물성을 관찰하였다. 이 시료의 등온 경화거동은 동역학 측정기(dynamic mechanical analyzer, DMA)와 시차주사 열량분석기(differential scanning calorimeter, DSC)를 이용하여 조사하였다. DMA로부터 구해진 결과를 보면 경화시 상대저장강성을 (relative storage rigidity, RSR)과 상대손실강성율(relative loss rigidity, RSR)과 상대손실강성율(relative loss rigidity, RLR)의 변화가 r값과 경화촉진제의 종류에 영향을 받았다. 그리고 DSC결과는 r값이 감소함에 따라 경화가 촉진되는 것으로 나타났다. 경화물의 성질을 조사하기 위하여 사용된 DMA로부터 얻어진 유리전이온도(glass transition temperature, T$_{g}$)와 가교결합간의 평균분자량(average molecular weigh between crosslinks, M$_{c}$은 사용한 두 경화촉진제에 대하여 r값의 영향이 다르게 나타났다. BDMA의 경우는 T$_{g}$가 1:1화학양론비인 r=0.9에서 최고치를 보였으나, 2E4MZ-CN은 r이 감소함에 따라 계속 증가하는 양상을 보였다. 이와 같은 경향은 2E4MZ-CN을 경화촉진제로 사용하였을 때 에폭시가 과량으로 될수록 잔류 에폭시기들간의 에케르반응이 추가적으로 일어나 M$_{c}$가 감소하기 때문이다.

• Korean Journal of Environmental Agriculture
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• v.40 no.2
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• pp.108-117
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• 2021

BACKGROUND: Dichlobentiazox is a newly registered pesticide in Korea as a triazole fungicide and requires establishment of an official analysis method for the safety management. Therefore, the aim of this study was to determine the residual analysis method of dichlobentiazox for the five representative agricultural products. METHODS AND RESULTS: Three QuEChERS methods were applied to establish the extraction method, and the EN method was finally selected through the recovery test. In addition, various adsorbent agents were applied to establish the clean-up method. As a result, it was found that the recovery of the tested pesticide was reduced when using the d-SPE method with PSA and GCB, but C₁₈ showed an excellent recovery. Therefore this method was established as the final analysis method. For the analysis, LC-MS/MS was used with consideration of the selectivity and sensitivity of the target pesticide and was operated in MRM mode. The results of the recovery test using the established analysis method and inter laboratory validation showed a valid range of 70-120%, with standard deviation and coefficient of variation of less than 3.0% and 11.6%, respectively. CONCLUSION: Dichlobentiazox could be analyzed with a modified QuEChERS method, and the method determined would be widely available to ensure the safety of residual pesticides in Korea.

• Bulletin of the Society of Naval Architects of Korea
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• v.20 no.4
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• pp.17-24
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• 1983

In this study, it was investigated the distribution of residual stress in the direction of loading between the root and toe the load fillet welds for thick steel plate. Residual stress distributions are measured by sectioning method which is one of stress-relaxation technique in welded joint, and analyzed by two dimensional finite element method on thermo-elasto-plastic theory under plane stress condition. These are compared the results of F.E.M analysis with the experimental result by stress-relaxation techniques. As a results, the following conclusion were obtained. (1) In the no penetration fillet welded joint specimen using mild steel plate with 25mm in thickness, the residual stress of loading direction near the root was about $10kg/mm^2$ tensile. (2) The tensile residual stress has been observed in fillet region of the fillet joint by F.E.M. analysis method. (3) The range of compressive residual stress distribution from the root was largest in the case of 5mm root penetration.

• Journal of Welding and Joining
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• v.15 no.2
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• pp.64-71
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• 1997

In order to define the effects on shapes of welding joint, during Post Welding Heat Treatment (PWHT), we have carried out numerical analysis on the several test pieces by using computer program which was based on thermal-elasto-plastic-creep theories for the study. And then, welding residual stresses after PWHT were measured same test-pieces to compare with the results of numerical analysis. The main results obtained from this study is as follows: 1) The distribution modes of welding residual stresses are same on the all test pieces after and during PWHT by the both sides (measurement and numerical analysis). 2) The mechanical difference for change the thickness of plate and bevel angle are not appeared. 3) In a mechanical point of view (like material quality test, welding deformation etc.), manimum bevel angle (40$^{\circ}$.) is more suitable than maximum bevel angle (70$^{\circ}$).

• Journal of Welding and Joining
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• v.9 no.3
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• pp.10-17
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• 1991

용접구조물에서 용접이음부가 차지하는 비율은 매우 작은 경우가 많지만 용접이음부에는 각종 초기결함(이들 결함으로부터 진전하는 피로 균열, 환경에 의한 균열등을 포함) 및 용접 초기의 부정형을 비롯해서 형상적 불연속 등에서 유기되는 국부적인 응력, 변형률의 집중, 잔류응력, 구속응력, 용접금속이 갖는 숙명적인 야금적 특성의 불균일, bond부 및 HAZ부에서의 용접열 싸이클에 의한 재질의 국부적 강도저하등 용접부의 강도를 저하시키는 인자들이 복합되기 쉽고, 용접구조물 전체의 내파괴 건전성평가에서 용접부가 파괴 강도는 매우 중요하다. 용접구조물의 설계, 시공의 목적은 소요성능의 확보에 있고 구조물이 사용중에 성능손실이나 불안정 파괴가 발생하지 않도록 하는 것이 주요요건이 될 것이다. 현재의 제강기술수준에서 볼 때 모재의 강 도보다 오히려 용접부의 강도 특히 피로강도 및 파괴 인성을 적절하고 합리적으로 평가하는 것이 매우 중요하다고 해도 과언이 아닐 것이다. 용접부의 강도를 평가하는데 있어서 용접부에 발 생하는 용접결함에 대한 평가는 매우 중요하며 이들 결함에 대한 허용결함한계를 평가하여 보수 여부 및 용접구조물의 신뢰성을 평가 할 필요가 있다.

• Journal of Ocean Engineering and Technology
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• v.16 no.4
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• pp.32-36
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• 2002

In this paper, a numerical methodology for health monitoring of weldment was proposed using finite element method coupled with continuum damage mechanics. The welding-induced residual stress distribution of T-joint weldment was calculated using a commercial finite element package SYSWELD+. The distribution of latent damage was evaluated from the stress and strain components taken as the output of a finite element calculation. Numerical examples were given to demonstrate the usefulness of this so-called "post-processing approach" in the case of welding-induced damage assessment.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.05a
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• pp.889-898
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• 2002

This part of ISO 1940 gives recommendations for determining unbalance and for specifying related quality requirements of rigid rotors; it specifies a) a representation of unbalance in one or two planes; b) methods for determining permissible residual unbalance; c) methods for allocating it to the correction planes; d) methods for identifying he residual unbalance state of a rotor by measurement; e) a summary of errors associated with the residual unbalance identification. This part of ISO 1940 is also intended to facilitate the relations between manufacturer and user of machines. Detailed consideration of errors associated with the determination of residual unbalance is covered in the 2nd part of ISO 1940 (ISO 1940-2 will deal with these errors).

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.05a
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• pp.74-74
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• 2004

탄소섬유강화 적층재(Carbon Fiber Reinforced Plastic, 이하 CFRP)는 강성도는 뛰어나지만 충격특성에는 취약한 단점이 있다. 따라서 충격저항과 충격에너지 흡수율이 상대적으로 우수한 유리섬유강화 적층재(Glass Fiber Reinforced Plastic, GFRP) 및 아라미드섬유강화 적층재(Aramid Fbier Reinforced Plastic, 이하 AFRP)를 CFRP 적용분야에 대체하고 점차적으로 피로특성을 개선시켜 나간다면 특성이 더욱 개선된 제품을 사용할 수 있을 것으로 판단된다.(중략)

• Proceedings of the KWS Conference
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• 2003.05a
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• pp.263-265
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• 2003

The transverse crack, a type of cold crack, occurs perpendicular to the axis of the weld interface, longitudinal residual stresses ($\sigma$k direction) are more important in transverse crack occurrence from my own experience. Specimens were fabricated and welded under actual construction conditions, and then residual stresses of longitudinal stresses were measured for different welding conditions with SAW and FCAW process. The residual stress values for the specimen welded Interpass temperature below 30$^{\circ}C$ was higher than the specimen welded interpass temperature of 100～120$^{\circ}C$. And also the residual stress values for a specimen measured at weld surface, as welded condition, was higher than that of longitudinal residual stresses that was measured from a small test piece, due to the residual stress was relieved in the process of the cutting and machining. Transverse weld cracks were detected in the area of the maximum residual stresses both SAW and FCAW process.

• Journal of the Korean Vacuum Society
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• v.1 no.1
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• pp.145-152
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• 1992

Si surfaces exposed to CHF3/C2F6 gas plasmas ih reactive ion etching (RIE) have been characterized by X-ray photoelectron spectroscopy (XPS). CHF3/C2F6 gas plasma exposure of Si surface leads to the deposition of residual film containing carbon and fluorine. The narrow scan spectra of C 1s show various bonding states of carbon as C-Si, C-F/H, C-CFx(x $\leq$ 3), C-F, C-F2, and C-F3. The chemical bonding states of fluorine are described with F-Si, F-C and F-O. And the oxygen and silicon are also detected. The effects of parameters for reactive ion etching as CHF3/C2F6 gas ratio, RF power, and pressure are investigated.