• Journal of Food Hygiene and Safety
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• v.21 no.2
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• pp.52-59
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• 2006

This survey was conducted to monitor the current status of pesticide residues in imported agricultural products circulated in Gwangju, 2005. A total of 108 samples was analyzed by multiresidue method. Of these samples, 32 were citrus fruits, 60 were tropical fruits and grapes, and 16 were vagetables. The origin was Philippine for 39 samples, U.S.A. for 36, China for 12, New Zealand for 11, Chile for 6, etc. The overall rate of detections was 30.6% and no samples had violative residues. Of citrus fruits,20 samples (62.5%) had residues and the residues were thiabendazole, imazalil, chlorpyrifos, etc. Of tropical fruits and grapes, 13 samples (12.0%) had residues and the residues were azoxystrobin, chlorpyrifos, carbendazim, captan, etc. 16 of vagetables had no detectable pesticide residues. Thiabendazole (71% in oranges and 56% in grapefruits) and imazalil (50% in oranges) were found in citrus fruits, which were frequently used as post-harvest pesticides. And azoxystrobin which is one of strobilurin fungicides, was often detected in mango, tropical fruit(27%).

• Korean Journal of Environmental Agriculture
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• v.31 no.1
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• pp.45-51
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• 2012

BACKGROUND: This study was carried out to establish pre-harvest residue limit of fungicides pyrimethanil and trifloxystrobin in persimmon, based on dissipation and biological half-lives of two fungicides residue. METHODS AND RESULTS: Both pyrimethanil and trifloxystrobin were extracted with acetonitrile, clean-up with $NH_2$ SPE cartridge and residue were analyzed by HPLC/DAD. Limit of Detection was 0.01 mg/kg. Average recovery were $81{\pm}1.62%$, $98{\pm}1.58%$ of pyrimethanil, and $91{\pm}2.94%$, $98{\pm}1.25%$ of trifloxystrobin at fortification levels at 0.1 and 0.5 mg/kg, respectively. CONCLUSION: The biological half-lives of pyrimethanil were 15.6 and 11.6 days at sprayed with recommended and double dosage, respectively. The biological half-lives of trifloxystrobin were 10.4 and 10.3 days at sprayed with recommended and double dosage, respectively. The pre-harvest residue limit of pyrimethanil and trifloxystrobin were recommended as 2.69 and 0.83 mg/kg for 10 days before harvest, respectively.

• Korean Journal of Environmental Agriculture
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• v.6 no.1
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• pp.61-66
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• 1987

1. In the vegetable crops, only MEP and Malathion showed a litte higher positive rate than other pesticides in general. On the other hand, parathion and captan were not detectable at all. 2. In the fruits, pesticides, MEP, PAP and Parathion had a little high positive rate, and Diazinon, and captan were not detectable at all. 3. However, the detected values of the pesticides in the vegetables and fruits were far below from korean tolerances and internationally recommended limits and tolerances, showing only $\frac{1}{3}{\sim}\frac{1}{66}$ and $\frac{1}{8}{\sim}\frac{1}{500}$ of Korean tolerance in vegetables and fruits, respectively.

• Life and Agrochemicals
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• s.273
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• pp.23-23
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• 2011

• Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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• 2003.10a
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• pp.150.1-150
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• 2003

열무의 안전한 생산을 위한 생산단계에서의 각 농약 잔류량 변화 추이와 최종 소비단계에서의 농산물 안전성 평가자료로 활용하기 위하여 실제 시험포장에 열무를 파종한 후 수확 10일 전에 4 종(diazinon, endosulfan, cypermethrin, cyhalothrin)의 살충제를 각 성분별로 안전사용 기준에 따라 기준량 및 배량의 처리구에 직접 살포하여 열무의 포장상태에서의 잔류량 감소(생물학적 반감기) 변화를 조사하였다. 각 농약별로 2 수준 농도의 표준물질을 첨가하여 실험한 결과 평균회수율은 diazinon 98.7∼99.9%, endosulfan 97.6∼98.5%, cypermethrin 98.3∼99.6%, cyhalothrin 98.4∼99.1%이였고, 검출한계는 diazinon 및 cypermethrin은 0.04 mg/kg, endosulfan은 0.012 mg/kg, cyhalothrin은 0.01 mg/kg 이었다. 약제 살포 후 분해속도가 빠른 성분은 diazinon ＞ endosulfan ＞ cypermethrin ＞cyhalothrin 순이었다. 작물체(열무)내에서 시간의 경과에 따른 잔류량의 변화를 1차 반응으로 표현하여 농약 4종의 살포농도별 생물학적 반감기를 산출한 결과, 기준량 살포의 경우 diazinon 0.9일, endosulfan 2.0일, cypermethrin 2.2일, cyhalothrin 2.5일 그리고 배량 살포의 경우에는 diazinon 1.1일, endosulfan 2.0일, cypermethrin 2.1일, cyhalothrin 2.2일로 나타났다. 안전한 농산물 생산을 위한 열무 중 약제 살포 후 수확일은 잔류허용기준(MRL)을 적용시킬 경우 기준량으로 볼 때 diazinon은 6일 후, endosulfan은 10일 후에 수확하는 것이 바람직한 것으로 나타났으며 합성 피레스로이드계인 cypermethrin과 cyhalothrin은 농약살포 후 2 시간 후에 농약 잔류량이 잔류허용기준 미만으로 나타났다.

• The Korean Journal of Pesticide Science
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• v.17 no.4
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• pp.307-313
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• 2013

This study was carried out to investigate the residual characteristics of fungicide azoxystrobin and difenoconazole in Prunus mume fruits, and establish pre-harvest residue limits (PHRL) based on dissipation and biological half-lives of fungicide residues. The fungicides were sprayed onto the crop at recommended dosage once and 3 times in 7 days interval, respectively. The samples were harvested at 0, 1, 2, 4, 6, 8, 10, 12 and 14 days after treatment. These residual pesticides were extracted with QuEChERS method, clean-up with $NH_2$ SPE cartridge, and residues were analyzed by HPLC/DAD and GLC/ECD, respectively. Method quantitative limits (MQL) of azoxystrobin were 0.03 mg $kg^{-1}$ and of difenoconazole were 0.006 mg $kg^{-1}$. Average recovery were $93.2{\pm}2.49%$, $85.5{\pm}1.97%$ for azoxystrobin at fortification levels at 0.3 and 1.5 mg $kg^{-1}$, and $100.8{\pm}6.74%$, $87.6{\pm}9.92%$ for difenoconazole at fortification levels at 0.06 and 0.3 mg $kg^{-1}$, respectively. The biological half-lives of azoxystrobin were 5.9 and 5.2 days at recommended dosage once and 3 times in 7 days interval, respectively. The biological half-lives of difenoconazole were 9.3 and 8.0 days at recommended dosage once and 3 times in 7 days interval, respectively. The PHRL of azoxystrobin and difenoconazole were recommended as 5.32 and 1.64 mg $kg^{-1}$ for 10 days before harvest, respectively.

• Korean Journal of Food Science and Technology
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• v.42 no.6
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• pp.664-675
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• 2010

This survey was carried out to estimate pesticide residue levels in commercial agricultural products in the year 2009. Residues were examined in 16 commodities (rice, foxtail millet, buckwheat, kidney beans, peanuts, sesame, oranges, grapefruit, kiwifruit, spinach, perilla leaves, leeks, garlic stem, garlic, ginger, and oak mushroom) collected from 22 provinces in Korea. Analyses were performed by multi-methods capable of detecting up to 60 pesticides by LC/MS/MS. A total of 510 samples were collected and analyzed. Of the samples, 96.1% contained no detectable pesticide residues. Detectable residues at or below the MRLs were found in 3.5% of the samples. However, in 0.4% of the samples (spinach and leeks), residue (ethaboxam and fluquinconazole) levels exceeded the MRLs. Furthermore, intake assessments of 7 kinds of pesticide residues were carried out, excluding those exceeding the MRLs. The results showed that the ratios of EDI (estimated daily intake) to ADI (acceptable daily intake) were 0.0001-0.0006%, which indicates that the detected pesticide residues were in a safe range. It is concluded that residual pesticides in agricultural products are properly controlled in Korea.

• Life and Agrochemicals
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• s.263
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• pp.18-21
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• 2010

여러 연구기관에서 행한 각종 연구결과들을 종합해보면 우리 농산물은 국민건강에 위해를 끼치지 않는 농약잔류 수준이다. 일부 농산물에 아주 미량이나마 검출되고 있는 잔류농약들은 국내외에서 이미 위해성평가가 철저히 이루어져서 안전성이 입증된 것들이며 또 잔류허용기준 이내에서 농약이 검출되어 안전하다고 할 수 있다.

• Agrochemical news magazine
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• v.17 no.4 s.133
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• pp.68-71
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• 1996

• 사료
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• s.46
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• pp.54-59
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• 2010