• Resources Recycling
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• v.28 no.2
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• pp.46-53
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• 2019

In this study, the extraction and reduction behavior of platinum group metals in a non-aqueous solvent based on ionic liquids was investigated in order to confirm a new extraction technology of platinum group metals. Platinum was selectively extracted using an ionic liquid $[C_4mim]PF_6$ from a mixed solution of $PdCl_2$, $PtCl_4$ and $RhCl_3$ dissolved with concentration ratio of 10:1:0.5 M. After stripping of the metals by 1 M $HNO_3$ solution, the platinum was preferentially reduced by aqueous electrolysis on gold electrode at -0.8 V (vs. Pt-QRE). The residual palladium and rhodium were transferred to ionic liquid of $[C_4mim]Cl$. The metallic palladium and rhodium could be sequentially reduced on gold and STS304 as working electrodes by non-aqueous electrolysis, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.6
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• pp.619-624
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• 2012

In this study, we demonstrated the operation of an electroosmotic pump with cylindrical porous glass frits and evaluated its long-term operation. The performance of this electroosmotic pump was characterized in terms of maximum flow rate, current, and pressure using deionized water and 1 mM borate buffer. The maximum flow rate, current, and pressure linearly increase with voltage. The maximum flow rate is normalized by the pumping area and voltage for comparison of the performance between the electroosmotic pumps with cylindrical and planar frits. The normalized maximum flow rate of the cylindrical-type pump is higher than that of the planar-type pump because of their different geometries. The cylindrical-type electroosmotic pump has five times better performance than the planartype electroosmotic pump for a given pump package volume. It can operate stably for over 3 hours.

• Journal of Life Science
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• v.17 no.2 s.82
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• pp.293-297
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• 2007

Green fluorescent protein (GFP) is an attractive reporter for bioprocess monitoring. A fluorescence-based method was developed to quantify GFP levels in transgenic plants and protein extracts. In this study, GFP was produced and secreted from suspension cells derived from transgenic rice. The RAmy3E promoter placed before the GFP gene controlled by sugars such as sucrose. The effects of sucrose concentration on the secretion of GFP and total protein into the medium were investigated in batch suspension culture. It was possible, therefore, to induce the expression of the GFP by removing sucrose from the cultured media or by allowing the rice suspension cells to deplete sucrose catabolically. The dry cell weight (7.06 g/L) and GFP level were detected as highest at 12%, 3% sucrose after 20 day culture, respectively. However secreted GFP fluorescence at the other sucrose concentrations (6%, 12%, 18% and 24%) were a little amount in media.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.149-154
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• 2011

In order to explore properties of various rubber compounds after thermal aging under the condition similar to the operating environment of a fuel cell-stack, heat resistance and compression set of those compounds were investigated for a long term operation in $H_2SO_4$, $H_2O$, and LLC (ethylene glycol : $H_2O=50:50$) solution. It was assumed that aging Acrylonitrile butadiene rubber (NBR) and Elthylene Propylene diene rubber (EDPM) compound in the solution resulted in discoloration as time passed. It was also found that hydrolysis was developed on the Silicone rubber (VMQ) compound intentionally aged under acidic condition by means of TGA, SEM, and EDS analysis.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.45 no.6
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• pp.60-66
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• 2008

The operating voltage of Li/SOCl2 battery decrease immediately when we give a load battery stored for long time. It is called voltage delay. We cannot rapidly operate equipment at emergence situation because the voltage delays. So we have to overcome voltage delay. We reported the results improved voltage delay in this paper through the control of the carbon cathode forming density. It is the classic method in order to control of voltage delay that is coating polymer in the lithium surface or put in the additive to electrolyte. If the carbon cathode forming density decreases, the operating voltage of battery becomes to increasing because solution resistance of battery reduce.

• Journal of Power System Engineering
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• v.18 no.6
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• pp.120-125
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• 2014

In this paper, suitable working fluid of 1MW Organic Rankine Cycle(ORC) with liquid-vapor ejector using effluent from power plant is selected. The results of comparison performance of 5 refrigerants are as follows; R600a, R134a, R1270, R236fa, R235fa. The operating parameters considered in this study include the condensation capacity evaporation capacity and efficiency. As a result of comparison of basic ORC system and with liquid-vapor ejector, with ORC system presents the higher system efficiency since the ejector makes the turbine outlet pressure lower than condensation pressure through its pressure recovery. Also, this ejector ORC system is advantageous in miniaturizing the size of components owing to decrease of evaporation capacity and condensation capacity.

• Journal of the Microelectronics and Packaging Society
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• v.28 no.4
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• pp.51-55
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• 2021

The nurses manually carry out the intravenous therapy for the patients. Using an Arduino, the fine flow controlling device was invented to provide an ongoing patient care. The medication is injected through a peristaltic pump, and the amount of the solution is controlled with a RGB color sensor. The power of the device is supplied through the batteries. An amount of the injection is measured with LIG strain sensor fabricated by 355nm UV pulsed laser. This system will provide a better medical service.

• Korean Journal of Food Science and Technology
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• v.29 no.2
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• pp.343-347
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• 1997

Effect of culture conditions on the fermentation of wheat flour solution by mixed lactic acid bacteria of Lactobacillus brevis, L. fermentum and L. plantarum was investigated. The optimum temperature for the fermentation of wheat flour solution was $35^{\circ}C$ because pH decreased the lowest value and TTA (total titrable acidity) increased the highest value at this temperature. In aerobic condition, fermentor was purged with air at 1.0 vvm and was purged with nitrogen gas at 1.0 vvm in anaerobic condition. The decrease of pH and the increase of TTA in aerobic condition were higher than those in anaerobic condition. In aerobic condition, the optimum condition of oxygen supply was found to be oxygen transfer rate coefficient of $60\;hr^{-1}$ which corresponded to agitation speed of 250 rpm in a 5 L fermentor. Repeated fed-batch cultures were performed using pH-stat in order to increase the productivity of fermented wheat flour. With increasing the repeated fraction of culture volume, mean cycle time increased but maximum operation time decreased. However, the volume of produced broth per culture volume per time and total volume of produced broth per culture volume were maximum at the repeated fraction of culture volume of 20%. In a repeated fed-batch fermentation of wheat flour solution using mixed lactic acid bacteria, the culture condition was optimum at temerature of $35^{\circ}C$, aeration rate of 1.0 vvm, oxygen transfer rate coefficient of $60\;hr^{-1}$, and repeated fraction of culture volume of 20%.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.9
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• pp.1027-1031
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• 2014

Free cooling system is used to reduce energy consumption of cooling system. Free cooling system is consisted of cooling group and dry-cooler in which heat exchange of chilled water and out air is conducted. Although this system has an excellent energy saving effect in place having cooling load regularly, data or material of design for free cooling system is lacked. In this study, characteristics analysis of free cooling system is conducted through software HYSYS with changing some facts. The main result is following as : Dry-cooler capacity is influenced by out air temperature, required chilled water temperature and LMTD(Logarithmic Mean Temperature Difference) of heat exchanger. As out air temperature is more low, dry-cooler capacity become increased. in addition, as required chilled water temperature is more high and LMTD is more low, the out air temperature range is widened for using dry-cooler. If out air temperature is below $0^{\circ}C$, antifreeze need to be used because freeze and burst can be occurred. In case of South Korea, antifreeze of 34% of ethylene glycol concentration is proper. When compressor load of R22, R134a and R407C is compared, considering environmental regulation and energy consumption, R134a is best working fluid.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.143.1-143.1
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• 2010

고분자 전해질막 연료전지(Polymer Electrolyte Membrane Fuel Cell; PEMFC)는 수소를 이용하여 전기를 발생시키는 친환경적이고 이상적인 발전장치로 고효율과 높은 전류밀도를 가지며 그 응용분야가 다양하다. 저온에서 작동하는 PEM fuel cell은 전극에서 효과적인 산화환원반응을 위해 그 촉매로 활성이 우수한 Pt(Platinum)을 사용하고 있으나, Pt의 높은 가격은 연료전지의 상용화에 걸림돌이 되고 있다. 본 연구에서는 연료전지의 Pt/C 촉매 층에서 Pt의 분산성을 높여 Pt의 담지량을 줄이고 작동 중 발생하는 Pt의 응집 현상을 방지하여 Pt의 수명을 연장시킬 목적으로, Au(gold) 나노입자를 첨가한 Pt-Au/C 복합나노촉매를 제조하였다. 본 발표에서는 합성된 Pt-Au/C 복합촉매 중 Au 첨가량이 Pt 촉매의 활성에 미치는 영향을 조사하기 위하여, 복합촉매 중에 금속(Pt+Au)의 총 함량이 30 wt.%와 40 wt.% 인 Pt-Au/C 촉매에 대하여 각각 Au 첨가량을 변화시켜, cyclic voltammetry 법에 의해 Au 첨가 효과를 조사한 결과에 대하여 보고하고자 한다. Au 나노입자를 제조하기 위한 출발 물질로는 $HAuCl_4{\cdot}4H_2O$를 이용하였고 trisodium citrate와 $NaBH_4$를 환원제로 하여, 입경이 5~8 nm 인 Au 콜로이드를 제조하였다. Pt-Au/C 복합나노촉매를 제조하기 위하여 먼저 Au/C 복합분체가 제조되었다. 0.03g의 carbon이 첨가된 carbon 현탁액에 합성된 Au 콜로이드 수용액을 첨가한 후 24시간 동안 교반하여 Au/C 복합분체를 제조하였다. 이 Au/C 복합분체에 $H_2PtCl_6{\cdot}6H_2O$ 수용액을 현탁하고 methanol 을 환원제로 사용해 Pt를 환원 석출시켜 Pt-Au/C 복합촉매를 제조하였다. Pt-Au/C 복합 나노촉매에서 Pt와 Au를 다양한 비율(3:1, 2.5:1.5, 2:2)로 합성하였으며 Pt-Au/C 복합촉매 중 금속(Pt+Au) 촉매의 총 함량은 30 wt.%와 40 wt.%로 각각 제조되었다. Au 나노입자 콜로이드의 분산성은 UV-visible spectrum의 흡광도에 의해 관찰되었고, Pt-Au/C 복합 나노촉매의 형상 및 분산성 분석은 transmission electron microscopy(TEM)에 의해 이루어졌다. 또한, 촉매의 전기화학적 특성평가는 cyclic voltammetry(CV)에 의해 조사되었다.