• Title/Summary/Keyword: 자원회수

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A Study on the Recovery of Shape-controlled Copper Oxide from the Waste etchant of PCB Industry (PCB 産業에서 배출되는 산성 염화동 폐액으로부터 입자형상이 제어된 산화동 회수에 관한 연구)

  • 김영희;류도형;김수룡;어용선
    • Resources Recycling
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    • v.10 no.6
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    • pp.15-21
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    • 2001
  • Shape-controlled copper oxides have been recovered from copper-containing waste etchant by neutralization with alkalihydroxide. Large amount of copper-containing waste etchant is generated from Printed Circuit Board industry. In an environmental and economic point of view, retrieve of the valuable natural resource from the waste is important. In recycling process of copper oxide from the waste etchant, reaction temperature controls shapes and sizes of the products. Copper oxide recovered below reaction temperature $40^{\circ}C$ was of a needle shape, while copper oxide comes in a platy shape above $40 ^{\circ}C$ . Physical properties of samples have been characterized using SEM, XRD, TGA and Atomic absorption spectroscopy.

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고온환원 및 전해법을 조합한 전기로제강분진 처리기술에 관한 연구

  • 윤기병
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2002.05a
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    • pp.66-73
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    • 2002
  • 전기로제강분진을 적절한 공정을 통하여 처리하여 유가금속을 회수하고 처리잔사를 철원으로 재활용한다면 환경오염방지 및 폐자원의 재자원화 효과가 기대된다. 본 연구에서는 고온환원과 전해공정을 조합한 새로운 전기로제강분진 처리공정을 제안하고, 각 공정에 대한 기초실험을 수행하여 그 가능성을 조사, 검토 하였다. 전기로제강분진의 고온환원실험과 환원과정에서 분위기와 증기압의 차이를 이용한 Zn및 Pb 성분의 분리, 휘발실험의 결과들이 분석되었으며, 아울러 환원처리잔사 중의 Fe성분함량을 증가시켜 철원으로 재활용할 수 있는 가능성을 확인하기 위하여 전기로제강분진과 millscale을 혼합, 환원하는 실험을 수행하였다. 또한 환원과정의 휘발산물인 조산화아연의 침출 및 전해에 관한 기초실험을 수행하여 고순도금속아연회수의 가능성도 조사, 검토하였다.

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Separation and Recovery of Silicon and Silicon Carbide from Slicing Sludge of Silicon Ingot (실리콘 잉고트 절단 슬러지로부터 실리콘 및 실리콘카바이드 분리 회수)

  • Kim, Byoung-Gyu;Jang, Hee-Dong;Chang, Won-Chul
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.186-190
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    • 2004
  • 실리콘 잉곳의 절단공정에서 발생하는 폐슬러지는 실리콘과 실리콘카바이드 등의 유가자원이 함유되어 있으며, 이를 효과적으로 분리, 회수하는 방법에 대해 검토하였다. 폐슬러지에 함유된 오일은 유기 용매에 의해 용해되어 효과적으로 분리되었고, 불순물인 철분은 자력선별에 의해 제거할 수가 있었다. 또한 실리콘과 실리콘카바이드의 혼합 분말은 중액선별을 통하여 고순도의 실리콘과 실리콘카바이드로 분리할 수가 있었다.

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포장과 법률 - 자원의 절약과 재활용촉진에 관한 법률 시행령 ③

  • (사)한국포장협회
    • The monthly packaging world
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    • s.354
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    • pp.106-117
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    • 2022
  • 환경부는 지난 5월 3일 '자원의 절약과 재활용촉진에 관한 법률 시행령(약칭 : 자원재활용법 시행령)'을 일부 개정했다. 합성수지재질 제품의 회수와 재활용을 촉진하기 위해 제품·포장재의 제조업자나 수입업자가 제품·포장재의 제조 또는 수입으로 발생한 폐기물을 회수해 재활용해야 하는 재활용의무 대상 제품·포장재에 합성수지재질의 제품 중 산업용 필름, 교체용 정수기 필터, 어망, 폴리프로필렌 재질의 생활용품 등 15개 품목을 추가한 것이다. 다만 사업자의 급격한 부담 증가를 방지하기 위해 전년도 연간 매출액이 10억 원 미만인 제조업자 등은 2025년까지 재활용의무를 면제받을 수 있다. 다음에 그 상세한 내용을 지난호에 이어서 살펴보도록 한다. 재활용의무를 면제받을 수 있다. 다음에 그 상세한 내용을 지난호에 이어서 살펴보도록 한다.

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Treatment of Metal Wastes with Manganese Nodules (망간단괴 제연 시 금속계 폐자원의 처리)

  • Park Kyung-Ho;Nam Chul-Woo;Kim Hong-In;Park Jin-Tae
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.17-21
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    • 2005
  • Deep-sea Manganese nodules was treated with reduction-smelting process with adding the spent Ni-Cd battery or the cobalt contained spent catalyst for recovery of nickel and cobalt metals. The nickel in the spent Ni-Cd battery could be recovered by adding $5\%$ coke as a reducing agent regardless of the amount of battery added. However, to recover cobalt from the spent catalyst, it is require to add more coke for reduction of cobalt oxide in the catalyst. The treatment of metal wastes with manganese nodules can contribute to lower the cost for the processing of nodules and to facilitate the recycling of metal wastes.

Thermogravimetric Analysis of Black Mass Components from Li-ion Battery (폐이차전지 블랙 매스(Black Mass) 구성 성분의 열중량 특성 분석)

  • Kwanho Kim;Kwangsuk You;Minkyu Kim;Hoon Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.25-33
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    • 2023
  • With the growth of the battery industry, a rapid increase in the production and usage of lithium-ion batteries is expected, and in line with this, much interest and effort is being paid to recycle waste batteries, including production scrap. Although much effort has been made to recycle cathode material, much attention has begun to recycle anode material to secure the supply chain of critical minerals and improve recycling rates. The proximate analysis that measures the content of coal can be used to analyze graphite in anode material, but it cannot accurately analyze due to the interaction between the components of the black mass. Therefore, in this study, thermogravimetric analysis of each component of black mass was measured as the temperature increased up to 950℃ in an oxygen atmosphere. As a result, in the case of cathode material, no change in mass was measured other than a mass reduction of about 5% due to oxidation of the binder and conductive material. In the case of anode material, except for a mass reduction of about 2% due to the binder, all mass reduction were due to the graphite(fixed carbon). In addition, metal conductors (Al, Cu) were oxidized and their mass increased as the temperature increased. Thermal analysis results of mixed samples of cathode/anode show similar results to the predictive values that can be calculated through each cathode and anode analysis results.

A Study on the Reduction of Iron Oxide from Slag in the EAF Process (전기로 공정에서 슬래그 중 산화철의 환원 회수에 관한 연구)

  • Kim, Young-Hwan;Yoo, Jung-Min
    • Resources Recycling
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    • v.25 no.4
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    • pp.54-59
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    • 2016
  • EAF processed slag which contains about 20 ~ 35 weight percent FetO is poured to slag pot and cooled. If we recover Fe from molten slag by the reduction, we will improve steel yield rate and reduce slag quantity poured from the furnace. Usually, carbon is used as a reductant and slag foaming agent in the EAF process. In this experiment, after melt the metal in induction furnace and then add slag with carbon and Al dross powder as a reductant, we investigated the reduction of FetO from slag and change of Phophorus content. As the result, when we use Al dross as a reductant, recovery rate is two times more than carbon. Phosphorus pick up is less than 50ppm with reduction of EAF slag.

Review of EOR Market and Technical Development Trends (석유회수증진기술의 시장 및 개발기술 동향)

  • Kim, Hyun-Tae;Lee, Kun-Sang;Son, Han-Am;Yoo, In-Hang
    • Economic and Environmental Geology
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    • v.45 no.1
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    • pp.59-68
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    • 2012
  • With the decline in discoveries of new oil fields and increasing demand from developing countries it is believed that enhanced oil recovery (EOR) technologies will play a key role to meet the energy demand in years to come. Based on the recently-published data, this paper discusses current status of global EOR market and technical development trends. The EOR market includes oil produced through various EOR recovery methods, such as thermal recovery, gas injection, chemical injection. Also, EOR methods are addressed screening criteria by reservoir and fluid characteristics including lithology, depth, thickness, and oil properties such as composition and gravity. Finally, the examples of field applied by various EOR methods are discussed with respect to reservoir characteristics and performance.

Recovery of Tin from Waste Tin Plating Solution by Ion Exchange Resin (주석도금폐액으로부터 이온교환수지를 이용한 주석 회수)

  • Shin, Gi-Wung;Kang, Yong-Ho;Ahn, Jae-Woo;Hyeon, Seung-Gyun
    • Resources Recycling
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    • v.24 no.3
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    • pp.51-58
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    • 2015
  • In order to recover tin from the waste tin plating solution, we used the ion exchange method using three types of ion exchange resins. The ion exchange resin with tertiary functional group(Lewatit TP 272) has not adsorption ratio of tin. The ion exchange resin with iminodiacetic functional group(Lewatit TP 207) has high adsorption ratio of tin, but impurity content in the recovered tin solution was relatively high. Whereas, in case of the ion exchange resin with functional group of ethylhexyl-phosphate(Lewatit VP OC 1026), adsorption ratio of tin was less than that of Lewatit TP 207. However, it was possible to remove impurities in the recovered tin solution by controlling the pH of the solution. High purity tin solution can be recovered by removing the organic materials with water washing process.

A Study on Particle-Size Distribution and Collect Rate of the Oyster Shells as Breaking and Crushing (파쇄 및 분쇄를 통한 굴 패각의 입도분포와 회수율에 관한 연구)

  • Jung, Ui-In;Kim, Bong-Joo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.458-465
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    • 2017
  • The purpose of the present study was to examine the method of physically processing oyster shells for use as raw material(aggregate) through experimentation. The results of the experiment found that the adequate particle size of the pulverized oyster shells should be smaller than 10mm due to their shape. Also, after considering various particle size distributions and residual rates by particle size, the study found the cutter mill to be the most suitable tool for pulverizing oyster shells. The use of a cutter mill resulted in recovery rates of 97.3%, 98.2%, and 98.9% for inner screens of 8mm, 12mm, and 20mm respectively, revealing how the increase of screen size results in slightly higher recovery rates. The experiment involving the difference between the inner screen of the cutter mill and the speed of the inverter shows that a smaller screen size and a faster inverter speed result in a lower fineness modulus, while a rise in inverter speed for an identical screen made possible the material recovery of a much lower range of particle sizes.