• Title/Summary/Keyword: 입자 직경

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Preparation of Alkyl Acrylate and Functional Monomer Multi Core-Shell Composite Particles (알킬 아크릴레이트와 관능성 단량체계 다중 Core-Shell 복합입자의 제조)

  • Choi, Sung-Il;Cho, Dae-Hoon;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.1-12
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    • 2013
  • Multi core-shell composite particles were prepared by the water-born emulsion polymerization of various core monomers such as methyl methacrylate (MMA), ethyl methacrylate (EMA) and shell monomers such as MMA, EMA, 2-hydroxyl ethyl methacrylate (2-HEMA), glycidyl methacrylate (GMA) and methacrylic acid (MAA) in the presence of different concentrations of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the conversion, particle size and distribution, average molecular weight, molecular structure, glass transition temperature with DSC, contact angle after plasma treatment, tensile strength and isothermal decomposition kinetics. In the case of the concentration of 0.02 wt% SDBS, the conversion of MMA core-(EMA/GMA) shell composite particles was excellent as 98.5%. In the case of the concentration of 0.03 wt% SDBS, the particle size of EMA core-(MMA/GMA) shell composite particles was high as $0.48{\mu}m$. We confirmed that 3 points of glass transition temperatures appear for multi core-shell composite particles compared to 1~2 points of glass transition temperatures appear for general copolymer particles. Overall, the adhesion strength of shell composite particles was in the order of EMA/MAA > EMA/2-HEMA > EMA/GMA.

Spray Drying of Lignocellulose Nanofibril (LCNF) and Characterization of Spray-dried LCNF (리그노셀룰로오스 나노피브릴의 분무건조 및 건조물의 특성)

  • Park, Chan-Woo;Han, Song-Yi;Lee, Seung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.3
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    • pp.288-296
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    • 2017
  • In this study, the effect of spray-drying conditions and surfactant addition on the spray-drying yield, morphological characterization, size distribution and re-dispersity in water of spray-dried lignocellulose nanofibril (LCNF) were investigated. The freeze-dried LCNF after solvent exchange had linear fiber morphology with a diameter of 70-300 nm, and the spray-dried LCNF showed rod-like particle morphology. The spray-drying yield and particle size of spary-dried LCNF at $140^{\circ}C$ was highest and smallest, respectively. As LCNF concentration and blowing rate decreased and increased, respectively, the spray-drying yield and particle size were increased. The highest spray-drying yield was found at distearyl dimethyl ammonium chloride (DDAC) addition of 10 phr at $140^{\circ}C$. As the particle size decreased and the DDAC content increased, filtration time of spray-dried LCNF in water was decreased and increased, respectively.

An experimental study on heat transfer augmentation in fluidized bed heat exchanger (유동층형(流動層形) 열교환기(熱交換器)에서 전열증진(傳熱增進)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Yoo, Ji-Oh;Seo, Jeong-Yun
    • Solar Energy
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    • v.13 no.2_3
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    • pp.91-106
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    • 1993
  • The purpose of this study was to investigate the enhancement of heat transfer coefficient in double pipe fluidized bed heat exchangers. The inner tube used a smooth tube and a finned tube equipped with longitudinal fins. The heat transfer coefficients between the heated tube and fluidized bed of alumina beads were calculated as a function of fluidized velocity in various particle sizes($d_p$=0.41, 0.54, 0.65, 0.77mm) and static bed heights($H_o$=50, 100, 150, 200, 250mm). The coefficient for finned tube is higher than for smooth tube. And the maximum increasing rate is 7.8 times in smooth tube and 12.9 times in finned tube.

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Size-segregated mass and ion concentrations of atmospheric aerosols in Cheonan City between 2006 and 2007 (2006~2007년 천안시 대기 에어로졸의 입경별 농도 및 이온성분 특성)

  • Lee, Hyung-Bae;Oh, Se-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1349-1353
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    • 2008
  • Size-segregated mass and ion concentrations of atmospheric aerosols in Cheonan City were measured using a high volume air sampler equipped with a 5-stage cascade impactor and a ion chromatography between March 2006 and April 2007. The mean values of 24-hr average concentrations of TSP, PM10, PM2.5, and PM1 were 61.7, 55.2, 43.7, $33.2{\mu}g/m^3$, respectively. Mass size distributions of atmospheric aerosols were bimodal distributions with a saddle point in $1.5\;{\sim}\;3.0{\mu}m$ range in diameter separating coarse and fine particle modes. Fine particles, PM2.5 were 70.8% of the total mass of aerosols. Major ion components in aerosols were ${NH_{4}}^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$ for cations, and ${SO_{4}}^{2-}$, ${NO_{3}}^-$, $Cl^-$ for anions. ion components occupied 37.4% of coarse particles and 46.2% of fine particles in mass.

Synthesis of Alumina Nano Particles by PAA Gel Method from Kaolin (카올린으로부터 PAA Gel법에 의한 알루미나 나노 입자의 합성)

  • 김지경;이상근;신준식;홍성수;박성수;박희찬
    • Journal of the Korean Ceramic Society
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    • v.41 no.3
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    • pp.253-258
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    • 2004
  • Non-aggregated nanoscale $\alpha$-Al$_2$O$_3$ powders were prepared successfully by polyacrylamine (PAA) gel method. The method was very simple and polymer network inhibited the aggregate of $\alpha$-Al$_2$O$_3$ powders. In this investigation, nanoparticles of $\alpha$-Al$_2$O$_3$ with a diameter of about 8-15 nm were fabricated by calcining the gel precusors with various concentrations of aluminum sulfate, acrylamide and N,N'-methylene-bis-acrylamide (BIS) in air at 110$0^{\circ}C$ for 2 h. The molar ratio of aluminum sulfate to acrylamide did not have any influence on the size of particles. On the other hand, as the molar ratio of BIS to acrylamide increased, the size of nanoparticles decreased.

Radial uniformity problem in RFI ionized magnetron sputtering (RFI ionized magnetron sputtering에서 radial uniformity 문제)

  • 주정훈
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.85-90
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    • 1997
  • A new ionized sputtering process was developed to fill small trench or via using additional ionizing mechanism of sputtered particles from 32cm $AlCu_x$(x=0.5%) cathode target with rotating magnet, then drawn toward substrate by small negative DC potential. The radial uniformity in RFI magnetron sputtering was studied by plasma diagnosis and appropriate RFI coil design to improve it. Optical emission intensities of excited species. $Ar^{\circ}, \;Ar^+;Al^+, \;Al^{\circ}$ are measured across the radial direction and showed close correlation with deposit's bottom to top thickness ratios in trenches and vias of submicron opening and 1.5 aspect ratio. After increase of the diameter of RF coil from 29 cm to 32 cm and improved the power leading feedthrough symmetry by removal of asymmetric single turn region, there was an increase of uniformity from 7.5% to 1.5% in bottom to top thickness ratio in 0.6 $\mu\textrm{m}$ vias.

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Physico-chemical Properties of Bracken(Pteridium aquilinum) Root Starch -1. Morphology and Chemical Properties- 중복기사검색 (고사리(Pteridium aquilinum) 뿌리 전분의 이화학적 특성에 관한 연구 -1. 전분의 일반 성상 및 화학적 특성-)

  • Jo, Jae-Sun
    • Korean Journal of Food Science and Technology
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    • v.10 no.1
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    • pp.57-62
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    • 1978
  • The morphology and chemical properties of bracken (Pteridium aquilinum) root starch were investigated. The starch granules were mainly sphere and cocoon with the diameter of $5-12\mu$. Polarized micrograph indicated that the starch granule had a hilum at the center of granule, showing a crossed-birefringence. X-ray diffraction pattern demonstrated that the granules showed B-type. The density of the starch was 1.49 and the amylose content was 22%. The ferricyanide number and alkali number were 0.292 and 11.03, respectively. Proximate analysis showed that the starch contained 0.52% lipid, 0.63% ash and 150ppm phosphorus of which over 80% were found in the amylopectin fraction. The iodine affinity and molecular weight of amylose were 16.1 and 83,000 respectively. The degree of branching and glucose units per segment of amylopectin were 3.7% and 27, respectively.

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Identification of Virus from Azuki Bean Plant (팥에 발생하는 바이러스 분리 동정)

  • 허남기;강문석;하건수;김혜자;최장경
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.2
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    • pp.160-165
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    • 1997
  • Three types of virus disease symptoms were observed in azuki bean plants: yellow mosaic; mosaic; severe mosaic with dwarf. The symptoms developed in the indicator plant inoculated with a virus- infected leaf of azuki bean showed similar host range with those of AMV, CMV and AzMV. In antiserum response, yellow mosaic symptom formed sediments with AMV antiserum, mosaic type with CMV antiserum, respectively, From the electron microscope observation, eclliptic particle (18~58$\times$18nm), isometric particle (30nm), and filamentous(730$\times$12nm) combined with inclusion body were observed in yellow mosaic, mosaic, and severe mosaic with leaf curling symptoms, respectively, The results demonstrate that yellow mosaic, mosaic, and severe mosaic with dwarf are caused by AMV, CMV and AzMV.

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Synthesis of Hollow Mesoporous Carbon Nitride Spheres Using Polystyrene Spheres as Template (폴리스티렌 구형입자를 주형으로 이용한 할로우 메조포러스 질화탄소 구형입자의 합성)

  • Park, Sung Soo;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.15 no.2
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    • pp.63-68
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    • 2014
  • Hollow mesoporous carbon nitride material with sphere shape was synthesized using polystyrene sphere as template and cyanamide as nitrogen and carbon atom sources via thermal treatment process. The process of the silica removal is not necessary because silica as template is not in use for the synthesis of hollow mesoporous carbon nitride material and any solvents are also not in use. The size of polystyrene spheres was about 170 nm. Hollow diameter and wall thickness were 82 nm and 13 nm, respectively, in hollow mesoporous carbon nitride sphere. Surface area, mesopore size and pore volume of hollow mesoporous carbon nitride material was $188m^2g^{-1}$, 3.8 nm and $0.35cm^3g^{-1}$, respectively. The wall in hollow sphere has graphitic structure. Hollow mesoporous carbon nitride material has potential applications in the area of fuel cell, catalysis, photocatalysis, electroemmision device, etc.

Spray Image of Gelled Kerosene with Nanoparticles at Multi-hole Pintle Injector (미세입자를 첨가한 케로신 젤 추진제의 멀티 홀 핀틀 인젝터에서의 분무 이미지)

  • Hwang, Juhyun;Choi, Myeunghwan;Koo, Jaye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.5
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    • pp.73-79
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    • 2021
  • This study was carried out to analyze the properties of the gel propellant and spray characteristics according to the addition of fine particles. The multi-hole diameter was 0.4 mm to induce a high shear rate, and a kerosene gel propellant was prepared using 5 wt% of the Thixatrol ST and SUS304 of 100 nm. The experiment was conducted by fixing the supply pressure in the axial direction to 0.7 MPa and adjusting the supply pressure in the radial direction from 0.7 MPa to 2.1 MPa. Due to the addition of fine particles, pressure vibration during spraying, a small TMR(Total Momentum Ratio) of up to 0.19, and a phenomenon that the spraying angle rapidly increased to more than 70 degrees occurred.