• Title/Summary/Keyword: 임계 크기의 결함

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Effect of Amine Oxide Zwitterionic Surfactant on Characteristics of Liposome (아민 옥사이드 양쪽성 계면활성제 첨가가 리포좀 특성에 미치는 영향에 관한 연구)

  • Mo, DaHee;Lee, SuMin;Lee, JuYeon;Han, DongSung;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.291-298
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    • 2016
  • In this study, zwitterionic surfactants were added to liposome systems at different pH conditions to understand the effect of surfactants on liposome characteristics. For this purpose, amine oxide surfactants having different hydrocarbon chain lengths were synthesized and the structure of the resulting product was elucidated by using $^1H$ NMR, $^{13}C$ NMR, and FT-IR. In addition, the physical properties of newly synthesized surfactants such as critical micelle concentration (CMC), surface tension and isoelectric point were measured. The stability characteristics of liposome systems including average particle sizes and zeta potentials were measured by varying pH and hydrocarbon chain lengths of an amine oxide surfactant. Effects of the pH and hydrocarbon chain length of an amine oxide surfactant on fluidity of a liposome membrane were also examined by measuring the deformability and the binding degree between the surfactant and liposome.

Evaluation of Adhesive Strength for Nano-Structured Thin Film by Scanning Acoustic Microscope (초음파 현미경을 이용한 나노 박막의 접합 강도 평가)

  • Park, Tae-Sung;Kwak, Dong-Ryul;Park, Ik-Keun;Miyasaka, Chiaki
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.4
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    • pp.393-400
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    • 2012
  • In recent years, nano-structured thin film systems are often applied in industries such as MEMS/NEMS device, optical coating, semiconductor or like this. Thin films are used for many and varied purpose to provide resistance to abrasion, erosion, corrosion, or high temperature oxidation and also to provide special magnetic or dielectric properties. Quite a number of articles to evaluate the characterization of thin film structure such as film density, film grain size, film elastic properties, and film/substrate interface condition were reported. Among them, the evaluation of film adhesive to substrate has been of great interest. In this study, we fabricated the polymeric thin film system with different adhesive conditions to evaluate the adhesive condition of the thin film. The nano-structured thin film system was fabricated by spin coating method. And then V(z) curve technique was applied to evaluate adhesive condition of the interface by measuring the surface acoustic wave(SAW) velocity by scanning acoustic microscope(SAM). Furthermore, a nano-scratch technique was applied to the systems to obtain correlations between the velocity of the SAW propagating within the system including the interface and the shear adhesive force. The results show a good correlation between the SAW velocities measured by acoustic spectroscope and the critical load measured by the nano-scratch test. Consequently, V(z) curve method showed potentials for characterizing the adhesive conditions at the interface by acoustic microscope.

Stability Analysis for a Dyke Subjected to Tidal Fluctuations (조위변동(潮位變動)을 받는 호안제(護岸堤)의 사면안정해석(斜面安定解析))

  • Kim, Sang Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.3
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    • pp.91-100
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    • 1988
  • Assuming that tidal level is constantly changed with an amplitude of 10 meters and a cycle of 12 hours, the slope stability for a typical dyke is analysed. The variation of pore water pressure within the dyke during the tidal change is obtained using a computer program, FLUMP, which is incorporated with saturated-unsaturated and transient flow. The results show that the variation of free water surface and distribution of pore water pressure within the dyke during the tidal fluctuations can be clearly predicted with the computer program. When a tide is lowered to the minimum level, the predicted pressure head is higher than the level of the free water surface in some parts of the dyke; that is, excess pore water pressure is generated in a zone affected by the tidal change. Also an unsaturated zone which shows negative pore water pressure is temporally created when a tide is lowered. The shear strength of the zone can be predicted based on the proposal suggested by Fredlund et al. It is emphasized that the excess pore water pressure generated during tidal fluctuations and strength parameters for the unsaturated zone should be considered in analyzing the slope stability of dykes. When those are considered, the critical slip surface seems to be located below the free water surface obtained when a tide is at the lowest.

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Analysis of Water Penetration through Pores in Spray-applied Waterproofing Membrane Using X-ray CT Images (X-ray CT를 이용한 분무식 방수 멤브레인의 공극 내 물 침투 분석)

  • Choi, Soon-Wook;Kang, Tae-Ho;Chang, Soo-Ho;Lee, Chulho;Choi, Myung-Sik;Kim, Kwang Yeom
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.4
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    • pp.211-219
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    • 2017
  • The spray-applied waterproofing membrane is installed on shotcrete or concrete surface to make impermeable layer with 3-5 mm thick for the purpose of waterproofing. This study aims to determine the internal structure of a spray-applied waterproofing membrane including pores by using X-ray CT technique. Before obtaining X-ray images of the membrane specimens, a waterproof performance test was performed on the membrane specimens with a water pressure of 500 kPa for 28 days. Results show that the movement of moisture is made through micropores. This is based on the fact that the large pores inside the membrane are not saturated and the degrees of saturation of the micropores are high. X-ray image is effective for determining the pore size distribution and whether the membrane with pores contains the water However, it is necessary to pay attention to the determination of water content, since water content may vary depending on the threshold value of X-ray image analysis applied to calculate the water content.

Superconductivity of High $T_c$ Superconductor $(Y_{1-x}Eu_x)Ba_2Cu_3O_{7-{\delta}}$ (고온초전도체 $(Y_{1-x}Eu_x)Ba_2Cu_3O_{7-{\delta}}$의 초전도성)

  • Chung Won Yang;Kweon Jung Ohk;Cho Eun Kyung;Kim Keyung Nam;Han, Sang Mok
    • Journal of the Korean Chemical Society
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    • v.36 no.1
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    • pp.16-23
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    • 1992
  • High $T_c$, superconductor $(Y_{1-x}Eu_x)Ba_2Cu_3O_{7-{\delta}}$ (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared and the physical properties were observed. XRD analysis showed that the structures of all the specimen were orthorhombic and the lattice parameters a, b and c increased with the increasing x value. Electrical resistivity and magnetization measurements revealed that pure high $T_c$, superconducting phases were formed at above 90 K. The critical temperatures increased with increasing the amount of Eu. From the measurement of magnetization and the size of the grains using SEM micrographs, volume diamagnetic susceptibilities for each specimen were calculated. These values decreased with the increasing x value. The composition of Ba in the lattice site decreased as the concentration of Eu increased, and this was confirmed by EPMA. It was found out that the volume diamagnetic susceptibility of each specimen was directly influenced by the composition of Ba in the lattice site.

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Usefulness and Limitations of Extreme Value Theory VAR model : The Korean Stock Market (극한치이론을 이용한 VAR 추정치의 유용성과 한계 - 우리나라 주식시장을 중심으로 -)

  • Kim, Kyu-Hyong;Lee, Joon-Haeng
    • The Korean Journal of Financial Management
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    • v.22 no.1
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    • pp.119-146
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    • 2005
  • This study applies extreme value theory to get extreme value-VAR for Korean Stock market and showed the usefulness of the approach. Block maxima model and POT model were used as extreme value models and tested which model was more appropriate through back testing. It was shown that the block maxima model was unstable as the variation of the estimate was very large depending on the confidence level and the magnitude of the estimates depended largely on the block size. This shows that block maxima model was not appropriate for Korean Stock market. On the other hand POT model was relatively stable even though extreme value VAR depended on the selection of the critical value. Back test also showed VAR showed a better result than delta VAR above 97.5% confidence level. POT model performs better the higher the confidence level, which suggests that POT model is useful as a risk management tool especially for VAR estimates with a confidence level higher than 99%. This study picks up the right tail and left tail of the return distribution and estimates the EVT-VAR for each, which reflects the asymmetry of the return distribution of the Korean Stock market.

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Luminescence Properties of $BaNb2O6:RE^{3+}$(RE=Eu, Dy) Phosphor Powders

  • Gang, Dae-Min;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.172-172
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    • 2013
  • 최근에 디스프로슘 이온이 도핑된 형광체의 백색 발광 현상 때문에 백색 발광 소재의 제조에 관한 연구가 상당한 관심을 끌고 있다. 본 연구에서는 $Eu^{3+}$$Dy^{3+}$ 이온의 몰 비를 변화시키면서 $BaNb_2O_6:RE^{3+}$ (RE=Eu, Dy) 형광체 분말을 합성한 결과를 보고한다. 특히 활성제 이온인 $Eu^{3+}$$Dy^{3+}$ 이온의 몰 비에 따른 $BaNb_2O_6$ 형광체 분말의 결정 구조, 입자의 모양과 크기, 흡광과 발광 스펙트럼의 변화를 관측하였고, 최적의 합성 조건을 제시하고자 한다. 파장 393 nm로 여기 시킨 $Dy^{3+}$ 이온의 몰 비에 따른 $BaNb_2O_6$ 형광체 분말의 발광 스펙트럼은 580 nm에 주 피크를 갖는 황색 스펙트럼이 관측되었다. 이 발광 신호는 $^4F_{9/2}-^6H_{13/2}$ 전이 신호이다. $Dy^{3+}$ 이온의 몰 비가 0 mol인 경우에는 발광 신호가 검출되지 않았다. $Dy^{3+}$ 이온의 몰 비가 0.10 mol일 때 발광 피크의 세기는 최대이었으며, $Dy^{3+}$ 이온의 몰 비가 더욱 증가함에 따라 발광 스펙트럼의 세기는 계속 증가하지 않고 갑자기 감소하기 시작하였다. 이것은 $Dy^{3+}$ 이온의 몰 비가 임계값을 초과하여 더욱 증가하면 모체 격자들 사이에 치환 고용되어 있는 $Dy^{3+}$ 이온들 사이의 거리가 더욱 가까워져서 $Dy^{3+}$ 이온들이 서로 용이하게 결합함으로써 내부 산란에 의하여 발광의 세기가 감소함을 의미한다. 흡광 스펙트럼의 경우에, $Dy^{3+}$ 이온의 몰 비가 0.01 mol일때 형광체 분말은 두 종류의 흡광 스펙트럼을 나타내었다. 첫째는 $Dy^{3+}$ 양이온과 $O^{2-}$ 음이온들 사이에 발생한 전하 전달 밴드에 의해 발생하는 310 nm를 정점으로 하여 280~340 nm 영역에 걸쳐서 광범위하게 분포하는 흡광 신호가 관측되었으며, 둘째는 $Dy^{3+}$ 이온의 $4f^9$ 전자 배열 내에서 발생하는 4f-4f 전이 신호로서, 이것은 350~500 nm 영역에 걸쳐서 비교적 밴드폭이 좁은 다수의 흡광 신호가 나타났다. 본 실험에서는 다섯 개의 피크를 갖는 흡광 신호가 검출되었는데, 이중에서 제일 강한 주 피크인 393 nm의 흡수 파장은 모체 격자 내에 있는 $Dy^{3+}$ 이온의 바닥 상태인 $^6H_{15/2}$ 준위에서 여기 상태인 $^4F_{7/2}$ 인 에너지 준위로 전이하면서 발생한 신호이며, 이에 비하여 상대적으로 흡광 세기가 약한 370, 432, 458, 370 nm의 흡수 파장이 관측되었다.

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An Efficient Load-Balancing Algorithm based on Bandwidth Reservation Scheme in Wireless Multimedia Networks (무선 멀티미디어 망에서 대역폭 예약을 이용한 효율적인 부하 균형 알고리즘)

  • 정영석;우매리;김종근
    • Journal of Korea Multimedia Society
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    • v.5 no.4
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    • pp.441-449
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    • 2002
  • For multimedia traffics to be supported successfully in wireless network environment, it is necessary to provide Qualify-of-Service(QoS) guarantees among mobile hosts(clients). In order to guarantee the QoS, we have to keep the call blocking probability below a target value during hand-off session. However, the QoS negotiated between the client and the network may not be guaranteed due to lack of available channels for traffic of a new cell, since on service mobile clients should be able to continue their sessions. In this paper, we propose an efficient load-balancing algorithm based on the adaptive bandwidth reservation scheme for enlarging available channels in a cell. Proposed algorithm predicts the direction of clients in a cell and adjusts the amount of the channel to be reserved according to the load status of the cell. This method is used to reserve a part of bandwidths of a cell for hand-off calls to its adjacent cells and this reserved bandwidth can be used for hand-off call prior to new connection requests. If the number of free channels is also under a low threshold value, our scheme use a load-balancing algorithm with an adaptive bandwidth reservation. In order to evaluate the performance of our algorithm, we measure metrics such as the blocking probability of new calls and dropping probability of hand-off calls, and compare with those of existing schemes.

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The Effect of Weld Line on the Mechanical Strengths and its Elimination Process in the Zr-4 Resistance Upset Welds (지르칼로이-4의 저항업셋용접에서 용접선이 기계적성질에 미치는 영향과 그 소멸과정)

  • Koh, Jin-Hyun;Lee, Jung-Won;Jung, Sung-Hoon
    • Nuclear Engineering and Technology
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    • v.23 no.1
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    • pp.1-11
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    • 1991
  • The objective of this study is to investigate the effect of weld line on the mechanical strengths and the process of weld line elimination in the Zircaloy-4 resistance upset welding for the fabrication of heavy water reactor fuel rods. The weld current and the amount of upset increased linearly with the main heat, in which two relations between them were derived. It was found that the threshold to obtain sound weld was 50% of main heat in terms of weld upset size, mechanical strengths and weld line elimination. The weld microstructure of resistance upset welds of Zircaloy-4 comprsied basketweave, Widmanstatten and martensite respectively by changing the main heats. Dimples on uniaxially fractured surface at weld line in the Zr-4 welds were larger and deeper compared with those on biaxially fractured surface. It was also found that the process of the weld line elimination in the resistance upset weld of Zircaloy-4 could be divided into three stages in terms of the presence of many pores, their shrinkage and elimination, and the shrinkage of the original weld interface with increasing weld currents.

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A Study on the Effect Analysis and Improvement of Cardiopulmonary Resuscitation on Life-rafts (구명뗏목에서의 비상대응 심폐소생술의 효과 분석 및 개선에 관한 연구)

  • Lee, Chang-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.4
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    • pp.433-440
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    • 2019
  • Offshore working environments such as ships, offshore oil and gas plants, and offshore wind turbines are isolated and directly exposed to rough seas, which pose high risks of safety accidents. Therefore, all workers in offshore plants should be able to cope with emergency situations and must be qualified according to relevant laws and regulations such as the International Convention on Standards of Training, Certification and Watchkeeping for Seafarers (STCW Convention) and Offshore Petroleum Industry Training Organization (OPITO) standards. In particular, marine workers should be able to perform cardiopulmonary resuscitation (CPR) in isolated locations or enclosed and confined spaces such as those in life-boats, life-rafts, rescue-boats, etc. Because the floor material is made of rubber, it may be difficult to perform chest compressions in life-rafts used to escape from emergency situations in ships or offshore plants. Chest compressions performed on life-rafts may reduce the accuracy of CPR and increase fatigue for those providing aid. To measure the accuracy and fatigue of those performing CPR in life-rafts, 15 experimenters with more than five years of experience as first aid instructors were exposed to different CPR environments in a marine safety training center equipped with an artificial wave generator. The results showed that the accuracy of CPR in the classroom was 99.6 %, but that in various life-raft environments was only 84 %. T-verification of the two sites confirmed the reduced accuracy of CPR performed on life-rafts. CPR on life-rafts should be performed in groups of two and with the use of automated chest compression devices.