• Journal of the Korean Applied Science and Technology
• /
• v.35 no.3
• /
• pp.579-586
• /
• 2018

In this study, surfactants were synthesized using fatty alcohols of 8, 10, 12 and 14 carbon chains length. The structures of the synthesized surfactants was confirmed by FT-IR and $^1H$-NMR analysis. The surface tension of the diluted surfactant was measured as 26~32 mN/m depending on the carbon length and the critical micelle concentration was measured as $10^{-3}{\sim}10^{-5}mol/L$.The minimum value per molecule of the synthesized sulfonic acid surfactant is 1.68 to $1.30nm^2$. The physical properties of the synthesized surfactants were determined by measuring the critical micelle concentration, foaming power, emulsifying stability, and contact angle.

• Journal of the Korean Applied Science and Technology
• /
• v.31 no.1
• /
• pp.7-13
• /
• 2014

A cationic ester type surfactant, namely N-2-hydroxy-3-(2-hydroxyacetoxy) proply-N,N-dimethyldodecylaminium chloride(HPDA) was synthesized and confirmed by FT-IR and $^1H$-NMR spectroscopy. Surface tensions on the diluted aqueous solutions of the synthetic compounds were measured and evaluated critical micelle concentration. Surface tension was 33~34 dyne/cm in the range of $10^{-3}{\sim}10^{-2}mol/L$ and critical micelle concentration(c.m.c) value was $8.5{\times}10^{-3}mol/L$ by surface tension method. Emulsifying properties of the synthetic surfactant(HPDA) and Sodium lauryl sulfate (SLS), tetradecyl trimethyl ammonium bromide (TTAB) was tested. As a results, synthetic glycolic acid ester type compounds(HPDA) has been confirmed as a good emulsifier. The foaming power and stability of synthesized ester type surfactant was measured by Ross-Miles method.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.37 no.4
• /
• pp.343-352
• /
• 2013

In this study, a smooth flat surface, low fin, Turbo-B, and Thermoexcel-E surfaces are used to examine the effect of the flow velocity on the pool boiling heat transfer coefficients (HTCs) and critical heat fluxes (CHFs). HTCs and CHFs are measured on a smooth square heater of $9.53{\times}9.53mm^2$ at $60^{\circ}C$ in a pool of pure water at various fluid velocities of 0, 0.1, 0.15, and 0.2 m/s. Test results show that for all surfaces, CHFs obtained with flow are higher than those obtained without flow. CHFs of the low fin surface are higher than those of the Turbo-B and Thermoexcel-E surfaces due largely to the increase in surface area and sufficient fin spaces for the easy removal of bubbles. CHFs of the low fin surface show even 5 times higher CHFs as compared to the plain surface. On the other hand, both Turbo-B and Thermoexcel-E surfaces do not show satisfactory results because their pore sizes are too small and water bubbles easily cover them. At low heat fluxes of less than $50kW/m^2$, HTCs increase as the flow velocity increases for all surfaces. In conclusion, a low fin geometry is good for application to steam generators in nuclear power plants.

• Applied Chemistry for Engineering
• /
• v.2 no.3
• /
• pp.216-221
• /
• 1991

Surface activities of four potassium N-acyl-N-methyl-${\beta}$-alaninate including surface tension, foaming power, foam stability, emulsifying power and dispersion power were measured respectively, and critical micelle concentration(cmc) was evaluated. Consequently these anionic surfactants with long chain acyl amide showed good emusifying power of O/W type, foaming, foam stability and dispersion effect.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2007.11a
• /
• pp.28-28
• /
• 2007

해수 임펠러(impeller) 재료로 사용되고 있는 스테인리스강을 이용하여 케비테이션 발생 시 고체입자 충격에 의한 충격하중 및 침식손상을 조사하였다. 충격하중은 압전센서를 이용하여 측정되었으며, 고체입자충격의 경우 기포붕괴에 비해 전체적으로 높은 충격하중을 가한 것으로 나타났다. 또한 충격하중과 침식손상과의 관계를 고찰하기 위해 침식표면에 형성된 침식핏(pit)을 측정하였으며, 고체입자충격 및 기포붕괴 조건에서의 임계충격하중을 구하였다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2008.04a
• /
• pp.69-75
• /
• 2008

기포반응도는 월성발전소를 비롯한 CANDU형 원자로의 주된 안전성 쟁점사안으로 끊임없이 논의되어 왔다. 이는 설계기준사고가 노심에서 열에너지 불균형이 원인이 되어 기준이상의 핵연료 파손과 방사성물질 누출로 발전할 위험이 있는 사건들로 정의될 때, 사건 진행 과정에 기포반응도 증가는 조기에 운전중단을 실패할 경우 출력폭주로 이어지므로 사건의 결말이 중대사고로 전환될 위험이 크기 때문이다. 본 연구는 공개된 최신 핵자료인 ENDF/B-VII.0를 NJOY.99로 처리한 연속에너지 반응단면적 라이브러리를 구축하고 MCNP-4C에 접속하여 37봉 천연우라늄 핵연료다발의 표준노심격자에 대한 기포반응도를 시뮬레이션하여, 지금까지 각종문헌에 제시된 값들과 비교, 종합하므로 내제된 불확실성을 추정하는 내용이다. ENDF/B-VII.0 기반 MCNP-4C의 CANDU 노심격자 모델은 동일한 핵자료와 핵종농도를 사용한 WIMS-IAEA 모델과 비교할 때, 초기 노심의 임계도 오차 약 3.51mk가 연소 진행에 따라 $7.5\times10^{-4}mk$/MWD/teU의 비율로 감소하는 것으로 나타났다. 또한 MCNP-4C 예측기포반응도는 초기노심에서 기포율 50% 및 100%에 대해 각각 8.38 및 15.96mk, 평형노심에서 7.68 및 14.72mk로 계산된다. 이는 월성 2, 3, 4 FSAR의 초기노심 및 평형노심에서 100% 기포상태에 대한 값, 약15.0 및 10.6mk와 비교할 때, 초기노심은 약 1.0mk 평형노심은 약4, 1mk 보수적이지만, 다른 연구결과들과는 최대오차 ${\pm}1{\sim}2mk$ 이내에서 잘 일치하는 것으로 평가되었다. 본 연구는 CANDU 노심의 기포반응도 불확실성 요인의 규명 및 영향평가를 위한 노력의 일부로서 앞으로 감속재의 붕산농도 변화, 감속재 및 냉각재의 중수 순도 변화, 기기노화에 의한 격자 구조 및 물성 변화, 중성자속 및 출력 분포 불균형, 반응도조절장치의 위치, 등 주요 설계변수의 변화에 대한 반응도영향 분석연구를 계속할 계획이다.

• Proceedings of the KSME Conference
• /
• 2003.04a
• /
• pp.1512-1517
• /
• 2003

Augmentation of CHF by ultrasonic is experimentally studied under subcooling pool boiling condition. Experiment is carried out for downward-facing plate with and without the ultrasonic. The working fluid is distilled water. Experimental apparatus is composed of a bath, power supply, test section, ultrasonic generator, DAQ system. Experiment is performed with the subcooling temperature of $5^{\circ}C$, $20^{\circ}C$, $40^{\circ}C$ and the inclined angle of $0^{\circ}$, $10^{\circ}$, $20^{\circ}$, $45^{\circ}$, 90. From the experimental results, it is found that ultrasonic effect enhances CHF of the downward-facing plate. As increasing the degree of subcooling, the rate of CHF increase is enhanced. As increasing the inclined angle, the rate of CHF increase decreases. Also, we can see that the heat transfer mechanism of CHF augmentation is closely connected with the dynamic behavior of bubble generation and departure.

• Nuclear Engineering and Technology
• /
• v.26 no.4
• /
• pp.493-501
• /
• 1994

An experimental study has been peformed on the pool-boiling critical heat flux (CHF) phenomenon on downward -facing plates. The CHF for inclinations of -90$^{\circ}$(horizontally downward position), -88$^{\circ}$, -86$^{\circ}$, -84$^{\circ}$, -60$^{\circ}$ and -40$^{\circ}$ were measured using plate-type test sections of 20mm 200mm and 25mm 200mm in a pool of saturated water under atmospheric pressure. The measured CHF was lower for the wider test section and decreased as its orientation approached to the horizontally downward position. The lower CHF can be attributable to the increased difficulty for the bubbles in escaping from the heater surface. When compared with the previous works, the overall trends were similar; however, a transition angle, at which the decrease rate in the CHF was changed, was observed in the vicinity of -80$^{\circ}$.

• Korean Journal of Food Science and Technology
• /
• v.19 no.3
• /
• pp.220-224
• /
• 1987

The concentration ranges forming surface excess of bovine serum albumin(BSA) and ovalbumin solutions were determined, and the factors affecting the foam separation of BSA were investigated. The surface tension of BSA solution decreased from 72 to 61 dynelcm, when the concentration changed from $5{\times}10^{-3}$ to $3{\times}10^{-2}%$, and the critical micelle concentration was appeared to be at 0.03% of BSA. At the isoelectric point (pH 4.9) of BSA, the foamate volume was maximum, but enrichment ratio was minimum, resulting in the maximum recovery rate. When the pH deviated from the isoelectric point, the foamate volume decreased and the enrichment ratio increased. The enrichment ratio increased, while the foamate volume decreased drastically as the temperature was elevated above $20^{\circ}C$, resulting in the decrease in recovery rate. As the gas flow rate increased, the enrichment ratio decreased and the foamate volume increased. When $(NH_4)_2SO_4$ was added, the enrichment ratio decreased, but the maximum foamate was obtained at ionic strength 7. The concentration to form the surface excess of ovlbumin, which has lower surface hydrophobicity than BSA, was 200 times higher than that of BSA. This fact indicates the possibility of selective foam separation by hydrophobicity difference of proteins.

• Applied Chemistry for Engineering
• /
• v.30 no.2
• /
• pp.241-246
• /
• 2019

In this paper, reactive surfactants were synthesized by using acrylic acid or 3-butenoic acid as nonionic surfactants, polyoxyethylene(23) lauryl ether (Brij 35) and polyoxyethylene(20) stearyl ether (Brij S20). The synthesis of surfactants was confirmed by FT-IR and $^1H$-NMR. The surface tension, emulsifying property, and foam power and stability were also measured. The surface tension value was 35~41 dyne/cm at an critical micelle concentration (cmc) which was measured as $1.0{\times}10^{-4}{\sim}9.7{\times}10^{-5}mol/L$ using a surface tension method. The emulsifying power of synthesized surfactant was measured with benzene, soybean oil and monomer. Also, the initial height of the bubbles and the height after 5 minutes were measured and the values were compared with each other.