• Composites Research
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• v.32 no.1
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• pp.65-70
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• 2019

The aircraft composites wing parts are usually integrated with adhesive or fastener. These laminated composites have weak interlaminar strength, which can lead to delamination. In order to compensate the disadvantages of laminated composites, it is possible to improve the strength, durability, shock and fatigue resistance by reinforcing the fiber in the thickness direction. In addition, using a single structure near-net-shape saves the manufacturing time and the number of fasteners, thus can reduce the overall cost of the composite parts. In this study, compression test, tensile test and open-hole tensile test are carried out for three structural architecture of 3D (three-dimensional) textile preforms: orthogonal(ORT), layer-to-layer(LTL) and through-the-thickness(TTT) patterns. Among these, the orthogonal textile composite shows the highest Young's modulus and strength in tensile and compression. The notch sensitivity of the orthogonal textile composite was the smallest as compared with UD (unidirectional) and 2D (two-dimensional) fabric laminates.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.21 no.1
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• pp.27-34
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• 2015

Heating patterns depending on the packaging materials were examined in order to investigate the causes of thermal deformation of packages used for ready-to-eat foods for microwave heating due to the non-uniformity of microwaves. Physical properties including tensile strength, heat-resistance and elongation of four different CPP grades were compared. High retortable CPP had higher sealing strength and heat resistance compared to the conventional CPPs. All CPP samples tested were proved to have melting temperatures around $160^{\circ}C$. However, they were all thermally deformed by microwave heating due to a limited penetration of microwave and non-uniform heating within the spicy sauce of high viscosity contained high salt, especially on the above the filling line and sealing edge of pouches. When the laminated stand-up pouches composed of G-PET/PET/PET/CPP and G-PET/PET/NY/CPP were retorted and microwaved, significant deformations were noticed in both samples after retorting. Besides, pouches contained titanium dioxide showed more intense thermal deformation than the control. When the $10{\mu}m$ aluminium foil was affixed on the pouch, small thermal deformation was observed only in the bottom layer. More studies are required to prevent the thermal deformation of packaging materials used for RTE foods during microwave heating by developing the technologies to increase the thermal stability of CPP layer and the modification of packaging design to modify the microwave access into the package.

• Restorative Dentistry and Endodontics
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• v.30 no.1
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• pp.49-57
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• 2005

The purpose of this study was to evaluate the effect of multiple application of all-in-one dentin adhesive system on microtensile bond strength to caries-affected dentin. Twenty one extracted human molars with occlusal caries extending into mid-dentin were prepared by grinding the occlusal surface flat. The carious lesions were excavated with the aid of caries detector dye. The following adhesives were applied to caries-affected dentin according to manufacturer's directions; $Scotchbond^{TM}$ Multi-Purpose in SM group, Adper Prompt $L-Pop^{TM}$ 1 coat in LP1 group, 2 coats in LP2 group, 3 coats in LP3 group, $Xeno^{(R)}$ III 1 coat in XN1 group, 2 coats in XN2 group. and 3 coats in XN3 group. After application of the adhesives, a cylinder of resin-based composite was built up on the occlusal surface. Each tooth was sectioned vertically to obtain the $1{\times}1\;mm^2$ sticks. The microtensile bond strength was determined. Each specimen was observed under SEM to examine the failure mode. Data were analyzed with one-way ANOVA. The results of this study were as follows; 1. The microtensile bond strength values were; SM ($14.38{\pm}2.01$ MPa), LP1 ($9.15{\pm}1.81$ MPa), LP2(14.08{\pm}1.75$ MPa), LP3 ($14.06{\pm}1.45$ MPa). XN1 (13.65{\pm}1.95$ MPa). XN2 ($13.98{\pm}1.60$) MPa, XN3 ($13.88{\pm}1.66$) MPa, LP1 was significantly lower than the other groups in bond strength (p < 0.05). All groups except LP1 were not significantly different in bond strength (p > 0.05). 2. In LP1, there were a higher number of specimens showing adhesive failure. Most specimens of all groups except LP1 showed mixed failure.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.171-176
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• 2013

The need of volatile organic compound (VOC) free coating material has been increased to solve environmental problems such as the global warming. Nowadays, about 70~80% of coating materials used in the worldwide are a liquid type. Therefore, the development of non-solvent coating material that can minimize VOCs emissions is necessary to solve the global warming problem. In this study, acrylic monomers were added to develop non-solvent paints in order to improve disadvantages of the poor adhesion of a conventional phenolic resin caused by acidification. As a result, the blend resins of 2.818 Mpa phenol- formaldehyde resin/poly methyl methacrylate (PE/PMMA) has the best properties and performances for the adhesives.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.65-65
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• 2012

The air texturing공정은 노즐에서 전달되는 초음속 에어기류에 의해 overfeed를 수반하여 yarn속 fiber가 뒤얽혀 loop와 crimp를 발달시키는데, 고강력 고탄성율 고내열성 내절단성 등의 특성을 가지는 아라미드섬유를 에어 가공사로 가공 할 경우 가공 전 필라멘트 상태일 때 보다 표면에 생기는 loop로 인하여 촉감이 좋아지고 또한 타 소재와 접착 시 접착제 담지 성능이 향상 되어 접착력이 상승되고, 이를 통해 보강재로서의 기능이 강화되는 반면 역학물성이 기존의 아라미드 보다 저하되는 약점을 가지고 있어 최근 ATY 공정조건이 ATY 사의 구조와 물성변화에 미치는 영향에 대한 많은 연구결과가 발표되고 있다. 본 연구에서는 Aiki air jet texturing machine에서 $Heracron^{(R)}$ para-aramid(840, 1000d, 1500d)를 사용하여 ATY nozzle의 직경을 0.6, 0.75, 1, 1.2mm로 변화를 주어 12개의 para-aramid ATY 시료를 제조하여 이들의 섬도, 강신도, 초기탄성률, 열수축률 그리고 형태불안정성(instability)등의 물성변화를 분석하여 다음과 같은 결과를 얻었다. 노즐의 직경이 증가함에 따라 사 내의 filament간의 움직임이 자유로워 교락이 증가하고 루프가 형성되어 단위길이 당 mass가 커지므로 섬도가 미세하게 증가하는 것을 볼 수 있다. 또한 직경이 증가할수록 절단강도와 초기탄성률은 감소하고 절단신도가 증가하는 경향을 볼 수 있는데 이는 축 방향으로의 배열이 적어져 하중을 분담하는 portion이 감소하고 사의 loop형성이 많아짐으로서 상대적으로 인장력에 대응하는 fiber의 수가 적어지기 때문으로 사료된다. 이는 현미경 관찰로 확인할 수 있는데 직경이 증가함에 따라 사의 loop의 엉킴이 증가하고 filament가 조밀한 것을 확인할 수 있다. 직경 변화에 따른 건 습열 수축률은 1% 미만의 매우 낮은 값으로 영향을 받지 않는 것을 확인 할 수 있는데 para-aramid의 열적특성의 안정성에 기인하는 것으로 사료되며 ATY의 불안정성은 노즐 직경 증가에 따른 어떤 경향성을 찾아볼 수 없었지만 840d, 1000d, 1500d로 섬도가 증가함에 따라 사의 불안정성이 증가하였다.

• Journal of the Korean Applied Science and Technology
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• v.33 no.4
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• pp.771-776
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• 2016

The acrylate copolymer having good thermal stability, coating and adhesion properties was designed and prepared. We prepared copolymers in >95% high yield using methyl methacrylate, isobornyl methacrylate and 2-hydroxyethyl methacrylate monomers by the bulk and emulsion polymerization techniques. The $^1H$-NMR spectrum was used to identify chemical structure and glass transition temperatures increased from $123^{\circ}C$ to $140^{\circ}C$ confirmed by DSC, DMA and TGA analysis. In addition, as the content of IBMA increased, storage modulus and thermal decomposition temperature increased. As the content of IBMA increased from 10% to 30% in the composition for the entire monomer, tensile strength increased from 22 to 30 MPa in both polymers prepared by bulk and emulsion techniques. The contact angle increased from 70 to up to 88 degrees due to hydrophobic property of IBMA.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.29-29
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• 2011

아라미드 섬유는 열에 강한 튼튼한 방향족 폴리아마이드 섬유이다. 아마이드는 "85%이상의 아미드(CO-NH)기가 두 개의 방향족 고리에 직접 연결된 합성 폴리아미드로부터 제조된 섬유"로 정의된다. 아라미드 섬유는 크게 파라계와 메타계로 대별되는데 본 연구에서 사용한 파라계 아라미드는 인장강도, 강인성, 내열성이 뛰어나며 고강력 고탄성률을 지니고 있다. 일반적인 유기 섬유와는 다른 우수한 성질을 바탕으로 부직포, UD laminatig, staple 등의 형태로 크게 섬유보강 고무 복합재료 등의 각종 복합재료, 로프, 케이블, 방탄방호용과 같은 산업자재의 용도로 자동차, 우주항공, 정보통신, 국방, 등 다양한 관련 산업분야에서 사용이 확대되고 있는 고부가 소재이며 가격대비 성능비가 우수하기 때문에 세계적으로 산업용 섬유 및 초고성능 섬유시장에서 비중이 증가될 것으로 예상되고 있다. 본 연구에서는 Para-Aramid 필라멘트를 이용하여 ATY를 생산할 때 제조공정조건에 따른 ATY 물성을 알아보고 고강도를 요구하는 방화복, 고무 보강용 섬유 등의 소재에 맞는 ATY 사가공 최적공정조건을 도출하여 체계화된 data-base를 구축하여 생산성 향상 및 품질개선과 함께 산업자재용 직물개발에 응용하고자 한다. 아라미드를 ATY로 제조할 경우, 표면에 생기는 loop로 인하여 타소재와 접착시, 접착제 담지 성능이 향상되어 접착력이 상승되는 반면, 아라미드 ATY가 기존의 아라미드의 물성보다 저하되는 약점을 가지고 있으므로 이를 보완하기 위해 본 연구에서는 ATY 제조공정에서 중요 공정인자인 사속, heater 온도, over feed ratio를 변화시켜 시료를 제조하여 이들의 물성을 분석하여 최적의 물성을 갖는 ATY 사가공 공정을 도출함으로써 물성이 저하되는 문제를 보완 가능할 것으로 기대된다. 물성분석은 강신도, 초기탄성률을 각각 측정하여 인장특성을 확인하였으며, 습열수축률과 건열수축률을 측정하여 시료의 열수축률에 대해 측정을 하였다. 표면의 루프 발현 정도를 보기 위하여 Crimp Rigidity(CR%), 형태 불안정성(instability)등을 측정하였으며, 영상 현미경 시스템을 사용하여 ${\times}40$ 배율로 표면특성을 측정하였다.

• Polymer(Korea)
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• v.28 no.2
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• pp.135-142
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• 2004

Poly(vinyl acetate) (PVAc) prepared by emulsion polymerization has broad applications for additives such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly(vinyl acetate-co-butyl acrylate) (VVc-BA) was synthesized using potassium persulfate as catalyst and poly(vinyl alcohol) (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced colloid stability, adhesion, tensile strength and elongation. During VAc-BA emulsion polymerization, no coagulation and complete conversion occur with the reactant mixture of 0.7wt% potassium persulfate, 15wt% poly(vinyl alcohol) (PVA-217), and the balanced monomer that the weight ratio of vinyl acetate to butyl acrylate is 19. As the concentrations of PVA increase, the copolymerization becomes faster and polymer particles are more stable, resulting in enhanced mechanical stability of the VAc-BA copolymer. However, the size of the polymer particles decreases with increasing PVA contents. Properties of the VAc-BA copolymer, such as minimum film formation temperature, glass transition temperature, surface morphology, molecular weight and molecular weight distribution, tensile strength and elongation, were characterized using differential scanning calorimeter, transmission electron microscope and other instruments.

• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.44-52
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• 2022

Epoxy resin has the disadvantage of being easily destroyed by instantaneous impact due to its high crosslinking density despite its high glass transition temperature (T_g) and excellent properties. To compensate for this, in this study, polyol was synthesized by ring opening polymerization of propylene glycol (PPG) diamine, Jeffamine D 2000 and propylene carbonate, and urethane modified epoxy was synthesized using this. The properties of the synthesized urethane modified epoxy were confirmed by FT-IR, H-NMR. To confirm the degree of improvement in impact resistance as an adhesive, a urethane modified epoxy adhesive was prepared by mixing a digylcidyl ether bisphenol A (DGEBA) with curing agent and curing accelerator. Properties test of urethane modified epoxy were shear strength, tensile strength and impact strength. As a result, excellent results were obtained in all test when the ratio of DGEBA : urethane modified epoxy was 8:2.

• Composites Research
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• v.36 no.4
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• pp.246-252
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• 2023

A secondary barrier made of glass fiber reinforced composites has been installed infinitely using automatic bonding machine(ABM) in membrane type LNG cargo containment system (CCS). At the same time, significant thermal stress due to cryogenic heat shrinkage has occurred in the composite on the non-bonding area between the adhesive fixation at both ends. There have been studies from the perspective of structural safety evaluation taking this into account, but none that have analyzed mechanical property taking an prolonged length into account. In this study, 2-parameter Weibull distribution statistical analysis was used to standardize reliable mechanical property for actual length, taking into account the composite's brittle fracture of ceramic material with wide fracture strength dispersion. Related experimental data were obtained by performing uniaxial tensile tests at specific temperatures below cryogenic condition considering LNG environment. As a result, the mechanical strength increased about 1.5 times compared to -20℃ at -70℃ and initial non-linear behavior of fiber stretched was suppressed. As the temperature decreased until the cryogenic, the mechanical strength continued to increase due to cold brittleness. The suggested mechanical property in this study would be employed to secure reliable analysis support material property when assessing the safety of secondary barrier's structures.