• Title/Summary/Keyword: 이종질량

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Electrochemical Characteristics of Silicon/Carbon Anode Materials using Petroleum Pitch (석유계 피치를 사용한 실리콘/탄소 음극소재의 전기화학적 특성)

  • Lee, Su Hyeon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.561-567
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    • 2018
  • In this study, the electrochemical characteristics of Silicon/Carbon anode materials were analyzed to improve the cycle stability of silicon as an anode materials of lithium ion battery. Porous silicon was prepared from TEOS by the $st{\ddot{o}}ber$ method and the magnesiothermic reduction method. Silicon/Carbon anode materials were synthesized by varying the mass ratio between porous silicon and pitch. Physical properties of the prepared Silicon/Carbon anode materials were analyzed by XRD and TGA. Also the electrochemical performances of Silicon/Carbon anode materials were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance tests in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC : DEC = 1 : 1 vol%). The Silicon/Carbon anode composite (silicon : carbon = 5 : 95 in weight) has better capacity (453 mAh/g) than those of other composition cells. The cycle performance has an excellent capacity retention from 2nd cycle to 30th cycle.

Isolation and Some Properties of Bitter Taste Compounds from Cultured Oyster, Crassostrea gigas (양식산 굴로부터 쓴맛 성분의 분리 및 성질)

  • LEE Jong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.1
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    • pp.98-104
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    • 1995
  • Five bitter taste compounds (OY-22, OY-23, OY-24, OY-25 and OY-26) were firstly isolated from cultured oyster (Crassostrea gigas) at Gamak Bay, Sourthern coast of Korea, between November, 1989 and January, 1990, and smoked-canned oyster, which were produced by the same oysters. They were presumed as cyclic peptides composed with 6 or 7 amino acids, including sulfur on the basis of NMR and MS spectra. Val and Leu in OY-24, leu and lie in OY-25 and tow leucines in OY-26 were detected from those each compounds, seperately, by the amino acid analysis. Another amino acids were thought as non-constitutional amino acids. They showed non-toxic to mice $(100{\mu}g/20g\;mice i.p.)$ and non actibacterial artivities to Asp. niger and B. subtilis $(10{\mu}g/disk)$. The chemical structures and other biological activities of them are now in studying.

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Numerical Simulation for Detonation Characteristics of Heavily Aluminized High Explosives (알루미늄 입자가 다량 함유된 고폭약의 데토네이션 특성에 대한 수치적 연구)

  • Kim, Wuhyun;Gwak, Min-cheol;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.5
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    • pp.10-18
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    • 2017
  • The problem of non-ideal detonation propagation velocities in heterogeneous hybrid mixtures is studied in the case of a high explosive with suspended fine aluminum (Al) particles. Since there exist difference in the time scales of the characteristic induction and combustion of High Explosives and solid particles, the process of energy release behind the leading shock front occurs over an extended period of time. The problem is analyzed by the theory of the mechanics of multiphase media with mass, momentum and heat exchanges between particles and gases. The numerical results match the available experimental results of heavily aluminized (5~25% Al weight) HMX explosive obtained previously.

In-Site Application of Heavyweight Concrete for Radiation Shielding (방사선 차폐용 중량콘크리트의 현장 적용성)

  • Yang, Seung-Kyu;Um, Tae-Sun;Lee, Jong-Ryul;Kim, Yong-Ho;Wu, Sang-Ik;Kim, Tae-Bong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.577-580
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    • 2008
  • This paper was discussed about in-site application of heavyweight(or high density) concrete. Heavyweight concrete was placed with the method of conventional. Placement of conventionally mixed heavyweight concrete is subject to the same considerations of quality control as normal density concrete, except that it is far more susceptible to variations in quality due to improper handling. It is particularly subject to segregation during placement. Segregation of heavyweight concrete results not only in variation of strength but, far more importantly, in variation in density that are intolerable for work this type, since this adversely affects shielding properties. Heavyweight concrete materials and heavyweight concrete should be sampled and tested prior to and during construction to insure conformance with applicable standards and specifications.

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Heat Transfer in Radiatively Participating Gas-Particle Cavity Flows (輻射가 關與하는 氣體-固體粒子 캐비티 流動에서의 熱傳達)

  • 이종욱;이준식;이택식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.3
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    • pp.551-560
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    • 1988
  • Gas-particle two phase flow and heat transfer in a cavity receiving thermal radiation through selectively transparent walls have been analyzed by a finite difference method. Particles injected from the upper hole of the cavity are accelerated downward by gravity and exit through the lower hole while they absorb, emit and scatter the incident thermal radiation. Gas phase is heated through convection heat transfer from particles, and consequently buoyancy induced flow field is formed. Two-equation model with two-way coupling is adopted and interaction terms are treated as sources by PSI-Cell method. For the particulate phase, Lagrangian method is employed to describe velocities and temperatures of particles. As thermal radiation is incident upon horizontally, radiative heat transfer in the vertical direction is assumed negligible and two-flux model is used for the solution of radiative heat flus. Gas phase velocity and temperature distributions, and particle trajectories, velocities and temperatures are presented. The effects of particle inlet condition, particle size, injection velocity and particle mass rate are mainly investigated.

Visualization of Supersonic Projectile Flow in a Ballistic Range (Ballistic Range를 이용한 초음속 Projectile유동의 가시화)

  • Kang, Hyun-Goo;Shin, Choon-Sik;Choi, Jong-Youn;Lee, Jong-Sung;Kim, Heuy-Dong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.263-266
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    • 2007
  • The ballistic range has long been employed in a variety of engineering fields such as high-velocity impact engineering, projectile aerodynamics, creation of new materials since it can create an extremely high-pressure state in very short time. Two-stage light gas gun is being employed most extensively. The present experimental study has been conducted to develop a new type of ballistic range which can easily perform a projectile simulation. The experiment is conducted to find out the dependence of various parameters on the projectile velocity. The pressure in high-pressure tube, pressure of diaphragm rupture and projectile mass and piston mass are varied to obtain various projectile velocities. The flow field is visualized to see flow around projectile.

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박막태양전지용 투명전도성 ZnO(Al) 박막제조 및 특성 (II)

  • Son, Yeong-Ho;Park, Jung-Jin;Choe, Seung-Hun;Kim, Jin-Ha;Lee, Dong-Min;Choe, Jeong-Gyu;Jeong, Ui-Cheon;Chae, Jin-Gyeong;Lee, Jong-Geun;Jeong, Myeong-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.292-292
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    • 2012
  • 현재 투명전극은 주로 ITO를 사용하고 있으며, ITO는 인듐산화물(In2O3)과 주석산화물(SnO2)이 9대 1의 비율로 혼합된 화합물로 인듐이 주성분이다. 따라서 ITO 사용량의 증가는 인듐의 수요 증가를 이끌어 2003년 이후 인듐 잉곳의 가격이 급등하였다. LCD에 응용되는 금속재료의 가격추이를 비교해보면, 인듐이 가장 큰 변화를 보이고 있으며, 2005년 인듐 가격은 2002년 대비 1,000% 이상 상승하였다가 2007년 이후 500%p 하락하여 2008년 2월 22일 기준으로 톤당 49만 달러에 거래되고 있다. 같은 기간 동안 알루미늄의 가격은 76.6% 상승하였으며 구리는 394%, 주석은 331% 상승하였다. 이러한 인듐의 가격 상승폭은 동일한 기간 동안 다른 금속 재료와 비해 매우 크며, 단위 질량당 가격도 20배 이상 높은 수준이다. ITO의 주성분인 인듐의 이러한 가격의 급등 및 향후 인듐의 Shortage 예상으로 인해 ITO 대체재 확보의 필요성이 증가되고 있다. 태양광 발전산업에서 현재 주류인 결정질 실리콘 태양전지의 변환효율은 꾸준히 향상되고 있으나, 태양전지의 가격이 매년 서서히 하강되고 있는 실정에서 결정질 실리콘 가격의 상승 등으로 고부가 가치 산업유지에 어려움이 있으며, 생산 원가를 낮출 수 있는 태양전지 제조기술로는 2세대 태양전지로 불리는 박막형이 현재의 대안으로 자리매김하고 있으며, 박막태양전지 산업분야가 현재의 정부정책 지원 없이 자생력을 갖추고 또한 시장 경쟁력을 확보하기 위해서는 박막태양전지 개발과 더불어 저가의 재료개발도 시급한 상황이다. 본 연구에서는 In-line magnetron sputtering system을 사용하여 소다라임 유리기판 위에 박막태양전지용 투명전도성 ZnO(Al) 박막을 제작하였고, 특히 이 박막은 n-형 반도체 특성을 가져야하기 때문에 홀이동도와 개리어농도의 상관관계 및 박막의 두께, 광투과율 특성, 온도 의존성을 조사하였고, 이를 논하고자 한다. (본 연구는 중소기업청의 기술혁신개발사업 연구지원금으로 이루어졌음).

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Observation of Interfacial Adhesion in Silica-NR Compound by Using Bifunctional Silane Coupling Agent (양기능성 커플링제 실란에 의한 실리카-천연고무 복합소재의 계면간 결합 고찰)

  • Lee, Jong-Young;Kim, Sung Min;Kim, Kwang-Jea
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.240-246
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    • 2015
  • Formation of a strong 3-dimensional interfacial network structure via chemical reaction between hydroxyl group on silica surface and NR chain by the addition of bis(triethoxysilylpropyl)tetrasulfide (TESPT) into silica-filled NR compound was observed by using Py-GC/MS and SEM. Addition of TESPT into silica-filled NR compound decreased scorch time ($t_{10}$) due to increased sulfur content, and reduced cure rate index (CRI) via continuous reaction between sulfur atoms in TESPT, which acted as a sulfur donor, and activators and/or accelerators. Addition of TESPT in the compound improved processability and mechanical properties of the compound. Overall, we observed that the addition of TESPT into the silica-filled NR compound formed a silica-TESPT-NR network, and thus the degree of crosslinking was increased resulting in improved mechanical properties.

Characteristics of Lightweight and Thermal Insulation of Bituminous Coal Bottom Ash (유연탄 bottom ash의 경량 및 단열 특성)

  • Lee, Jong Gyu;Yeo, Woon Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.1
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    • pp.39-45
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    • 2018
  • Research on FA(Fly ash) is actively carried out, while the research on BA(Bottom ash) is not so, and research on BA recycling field is urgently required. Therefore, in this study, we investigated the lightweight and thermal insulation characteristics of BA mortar by comparing BA mortar made with porous dry BA(air-cooled) and general mortar. To investigate the lightweight of BA, density test, unit volume mass test and SEM(Scanning Electron Microscope) test were performed. BA mortar and general mortar molds were prepared for the thermal insulation test at room temperature and humidity environment determined by KS A 0006 and they were dried at the temperature of $105{\pm}2^{\circ}C$ until the weight became constant. As a result of the lightweight test, the lightweight of BA mortar is about 30% lighter than the general mortar. Therefore, BA is expected to contribute to reduce the building load when used as building material. As a result of thermal insulation test, the thermal conductivity of BA mortar is about 30% better than that of general mortar.

Vibration Analysis of a Beam-Column with Elastically Restrained Ends and Various Intermediate Constraints (다양한 중간구속조건을 갖는 양단 탄성구속 보-기둥의 진동해석)

  • J.M. Lee;S.H. Lee;K.C. Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.187-194
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    • 1991
  • Vibration analysis methods of a beam-column with elastically restrained ends and various intermediate constraints such as rectilinear springs, rotational springs and concentrated masses are presented. Firstly, an exact method of solutions based on Hamilton's principle and Laplace transform method is shown. This method of solutions is very complicate in cases of having Intermediate constraints more than two. Therefore, Rayleigh-Ritz method using the eigenfunctions of the base system, the system without intermediate constraints, are also investigated. Extensive numerical examples carried out for comparisons with known published works show that the latter method has easy adaptability for wide varieties of boundary conditions and intermediate constraints, and gloves good accuracy for various intermediate constraints with reasonable number of terms in construction of a trial function.

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