• Title/Summary/Keyword: 이온 비율

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Analysis of Changes in Ion Concentration with Time and Drainage Ratio under EC-based Nutrient Control in Closed-loop Soilless Culture for Sweet Pepper Plants (Capsicum annum L. 'Boogie') (EC 기준 순환식 파프리카 수경재배에서 시간 경과 및 배액율에 따른 이온농도 변화 분석)

  • Ahn, Tae-In;Shin, Jong-Wha;Son, Jung-Eek
    • Journal of Bio-Environment Control
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    • v.19 no.4
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    • pp.298-304
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    • 2010
  • Nutrient uptake by plants and drainage ratio in culture beds can affect ion balance and concentrations of nutrient solutions in electrical conductivity (EC)-based closed-loop soilless culture. This study was conducted to analyze ion concentration changes with time and drainage ratio under EC-based nutrient control in closed-loop soilless culture for sweet pepper plants (Capsicum annum L. 'Boogie'). At first experiment, ion concentrations of the nutrient solution were periodically analysed while collected drainage was being reused by mixing with fresh nutrient solution at a dilution rate of EC $2.2\;dSm^{-1}$. Changes in ion concentrations of $K^+$, $Ca^{2+}$, $Mg^{2+}$, $NO_3^-$, $SO_4^{2-}$, and $PO_4^{3-}$ were 1.13, 5.35, 0.92, 0.9, 1.10, $0.19\;meq{\cdot}L^{-1}$, respectively. Ion balance such as $K^+$ : $Ca^{2+}$ and $SO_4^{2-}$ : $NO_3^-$ were mainly affected during the recirculation of nutrient solution. At second experiment, ion concentrations and EC of drainage were compared before and after replenishment under different four drainage ratios of 7%, 16%, 39%, and 51%. Ion ratios of the recirculated nutrient solutions such as $K^+$ : $Ca^{2+}$ for cation and $SO_4^{2-}$ : $NO_3^-$ for anion were investigated. ECs of drainage decreased with increase of drainage ratio and each ion concentration showed the same trends as EC did. Ion balances in drainage with drainage ratio were a little different from each other, but each ratio could be corrected by replenishment process. The ion balance at 7% drainage ratio was closest to initial ratio and followed by 16%, 51%, and 39% in the order. Ion balance such as $K^+$ : $Ca^{2+}$ and $NO_3^-$ : $PO_4^{3-}$ were mainly affected the correction process.

Ion Exchange Modeling in ETA and NH$_3$ Aqueous Solutions (ETA 및 암모니아 수용액에서 이온교환 모델링)

  • 안현경;김상대;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.307-311
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    • 2003
  • The test did for the determine the optimized ratio of cation to anion in mixed ion exchange demineralizers. Binary, ternary, quaternary, and quinary cation and anion adsorption was performed to develop a comprehensive experimental data set from small-volume batch tests to obtain the selectivity coefficients of many cations and anions. The quantitative run time might be estimated by such ion exchange models as semi-empirical mass action and surface complexation models. The demineralizer can be used longer by increasing the ratios of cation to anion exchange resins in the bed.

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Comparision of Cation-Anion Balance in Leaves on the Stalk Positions of Young Tobacco Plant (담배식물(植物)의 엽서별(葉序別) 이온균형(均衡) 비교(比較))

  • Lee, Yun-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.3
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    • pp.223-229
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    • 1986
  • These studies were investigated ionic balance of leaves from different stalk positions of tobacco plant (cv. NC82) grown on pots supplied with nitrate salts solution in the phytotrone. The results of studies are summerized as follows: 1. In comparision with the leaves along the stalk positions, lower position contained higher proportion of total cation and total anion including organic acid, but their concentration lessened gradually at the upper stalk. The ratio in amounts of inorganic cations and anions in leaf laminae depended on their stalk positon, being more than three times in the fifth, but becoming about 1.3 in the tenth. 2. Inorganic cations in the laminae were mostly $K^+$, $Ca^{{+}{+}}$, and $Mg^{{+}{+}}$, comprising about 80% of total with the first two regardless of their stalk positions. Among these two ions $Ca^{{+}{+}}$ tended to become higher at lower stalks, while $K^+$ was higher in younger and became lower when leaves got older and/or more number of leaves were emerged. 3. Total cations were balanced with inorganic and organic acid anions. Composition of inorganic and organic anions were different along stalk positions, ionic balance was governed by organic acid anions dominantly in older leaves, but by inorganic anions in the younger leaves. 4. The discrepancy in the balance between total cations and anions was more pronounced in the older leaves containing higher amount of cations and organic acids. It was suggested that discrepancy was due to precipitation of oxalate as Ca-salt which was not dissolved in the methylation solution of measurement employed.

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Characteristics of TiN Films by ion Beam Assisted Deposition (이온빔 보조 증착에 의한 TiN 박막의 특성)

  • Kim, Sang Hyun;Kim, Dae Hyeon
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.1
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    • pp.161-166
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    • 2004
  • In this research, TiN films has been grown to the stainless steel substrate by ion beam assisted deposition. TiN film was grown to the nitrogen atmosphere of around $10^{-15}$ Torr with Arion bombardment. The chemical composition, color and adhesion of TiN films were examined as a variation of En(ion energy per atom). The N/Ti ratio increased linearly as the increase of En and saturated around 1.2 at high En. As a results, the bright golden color was obtained when En reached a certain value of Ecn. As a results, the N/Ti ratio is about 0.9.

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Patterns of Leaching and Distribution of Cations in Reclaimed Soil according to Gypsum Incorporation Rate (석고 혼합량에 따른 간척지토양의 양이온 용탈 및 분포)

  • Ryu, Jin-Hee;Chung, Doug-Young;Hwang, Seon-Woong;Lee, Kyeng-Do;Lee, Sang-Bok;Choi, Weon-Young;Ha, Sang-Keun;Kim, Si-Ju
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.596-601
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    • 2010
  • Serious problems in reclaimed land for agriculture are high soil salinity and very poor vertical drainage. However, desalinization in these soils is very difficult. To identify the change of soil permeability by the gypsum incorporation in soils we observed elution patterns and salt distribution of the soil using soil columns packed with reclaimed saline soil with various rates of gypsum amendment. Saturated hydraulic conductivity ($K_{sat}$) of the top soil of reclaimed saline soils without gypsum incorporation was close 0 cm $hr^{-1}$ while $K_{sat}$ increased up to 0.3 cm $hr^{-1}$ with increasing amount of gypsum for 0.4% or more gypsum. Also $K_{sat}$ of the reclaimed saline soils for top soil was drastically increased to 1.0 cm $hr^{-1}$ or slightly greater after 141 hour's elution experiment. The cumulative amount of cation recovered in the effluent also increased in the order of gypsum incorporation rate 0.8% > 0.6% > 0.4 > 0.2%. Soil EC in soil columns decreased from initial 33.9 dS $m^{-1}$ to less than 0.4 dS $m^{-1}$ and exchangeable Ca 2+ increased by 32~140% according to gypsum incorporation rate.

Fabrication of ionic liquid and polymer based solid-state electrolyte for secondary battery (이온성 액체와 고분자 기반의 이차전지용 고체 전해질의 제조)

  • Kang, Hye Ju;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.6
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    • pp.1591-1596
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    • 2020
  • The solid-state electrolyte based on polymer has great attention to develop its ionic conductivity from conventional polymer electrolyte by using wide range of ionic liquids with remarkable processability, flexibility and is applicable to various electrochemical devices including batteries, supercapacitor. Polymer electrolyte based on Ionic liquid with high conductivity, wide electrochemical stability, thermal stability is used in various electronic devices. In this work, we have investigated and developed solid-state electrolyte based on ionic liquid and polymer with enhanced ionic conductivity and electrochemical performances to conduct to various electronic devices including secondary battery. The ionic conductivity of polymer based solid state electrolyte with optimized ratio of the ionic liquid was 1.46-2 S/cm. The ionic liquid and polymer based electrolyte with enhanced ionic conductivity is promising candidates to utilize in wide range of secondary batteries.

Chloride Binding Properties of Portland Cement Binder Incorporating CaAl2O4-CaAl4O7 (CaAl2O4-CaAl4O7 혼입 포틀랜드 시멘트 결합재의 염소이온 고정 특성)

  • Han, Jae-Doh;Lee, Yun-Su;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.4
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    • pp.1-9
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    • 2020
  • This study conducted to understand effects of CA (CaAl2O4) and CA2 (CaAl4O7) ratio on chloride binding ability and compressive strength and pore structure of cement mortar incorporating mixture of CA and CA2. The Portland cement based specimens were mixed with the clinkers CA and CA2, and these calcium aluminate clinker mixture were replaced 0, 5, 10% by weight of cement. After all the test specimens were cured for 28 days under water curing, they were immersed in the distilled water and NaCl solution. As a result, 28 days compressive strength of all specimens was similar, and As the replacement ratio of calcium aluminate clinker in the specimen increased, Friedel's salt production tended to increase. However, it was dependent on the amount of Al2O3 in the level of 5% replacement and CA ratio in the level of 10% replacement. Through equilibrium isotherm result, it was also indicated that as replacement ratio of calcium aluminate clinker in cement matrix increased, chloride binding capacity was improved, and chloride penetration was suppressed. In this study, the specimen replaced with 10% of the calcium aluminate clinker mixture (CA 39%, CA2 60%) was remarkable to control chloride attack. We figured out necessity to understand optimal CA/CA2 ratio to effectively apply CA2 as a sustainable building material by improving the chloride binding ability in Portland cement based system.

Effects of free metal ions and organo-metal complexes on the absorption of lead and cadmium by plants (식물에 의한 납, 카드뮴 흡수 기작에 미치는 자유이온 및 유기산-중금속 복합체의 영향)

  • Lee, Mina;Seo, Byounghwan;Kim, Kwon-Rae
    • Journal of Applied Biological Chemistry
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    • v.64 no.2
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    • pp.159-164
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    • 2021
  • Heavy metals exist in soils in various chemical forms including free metal ions and organo-metal complexes. The ratio of free metal ions has been known to be highly associated with the plant absorption of heavy metals. This study aims to understand the effect of free ions and organo-metal complexes on the absorption of lead (Pb) and cadmium (Cd) by plants. For this, lettuce grown in a hydroponic system for 28 days was consequently grown another 48 hours using Pb and Cd solutions. The ratios of free ion to organo-metal complexes in the solutions were adjusted at 100:0, 90:10, 70:30, 60:40 by four different organic acids (citric, oxalic, acetic, and humic acid). After that, the concentration of Pb and Cd in lettuce were analyzed. The Pb and Cd absorption by lettuce was more relied on the types of organic acids treated and the type of metals rather than the ratio of free metal ions. For example, citric acid increased the Pb absorption while it decreased the Cd absorption by lettuce. There was no significant relationship between free metal ion ratios and both Pb and Cd uptake by lettuce. It could be explained that citric acid, a relatively higher molecular weight organic acid, has higher ion binding capacity, so it forms organo-Pb complex easily due to the higher affinity of Pb on the binding site in comparison with Cd. Consequently, this complexation would assist Pb uptake by lettuce.

Effect of Ca/K+Mg Ratio in Nutrient Solution on Photosynthesis, Stomatal Resistance, Water Use Efficiency and Transpiration in Butterhead and Leaf Lettuce. (배양액내 Ca/K+Mg 비율이 상추의 광합성, 기공저항, 수분이용효율 및 증산에 미치는 영향)

  • 최기영;차영수;이용범
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 1998.10a
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    • pp.126-128
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    • 1998
  • 토양의 완충능이 없는 양액재배에서 Ca 흡수는 양이온과의 길항작용, 온도, 습도 및 염류농도 등에 의해 변화된다. 배양액내 무기 양이온 중 Ca 과 K, Mg의 복합비율 조성에 따른 상추의 광합성, 기공저항, 수분이용효율 및 증산량을 측정하여 상추 tipburn에 관여하는 Ca 흡수를 알아보고자 본 실험을 수행하였다. (중략)

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Properties of indium tin oxide thin films prepared by ion assisted deposition at room temperature (상온 이온 보조 증착된 ITO 박막의 특성)

  • 이임영;최상대;이기암
    • Korean Journal of Optics and Photonics
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    • v.13 no.3
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    • pp.204-208
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    • 2002
  • We investigate the dependence of indium tin oxide (ITO) thin films on the mixing ratio of Ar:O$_2$ produced by an ion-gun and $O_2$ injected inside the divergence angle of the ion-beam to optimize their sheet resistance and transmittance. The substrate is placed outside the divergence angle, and the films are grown by ion mixing with ITO evaporated at room temperature. From the XRD measurement ITO films are found to be amorphous. ITO thin films show the highest transmittance of 85% at 3$\times$10$^{-5}$ Torr of 0$_2$ and Ae:O$_2$ ratio of 40:60, and the smallest sheet resistance of 132 $\Omega$/$\square$at 1$\times$10$^{-5}$ Torr of $O_2$ and As:O$_2$ ratio of 40:60.