• Title/Summary/Keyword: 이산화탄소법

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Effect of Essential Oil from San-Jo-In (Zizyphus jujuba Mill. seeds) on Human Electroencephalographic Activity (산조인(Zizyphus jujuba Mill.) 에센셜오일 흡입이 인간의 뇌파에 미치는 영향)

  • Cho, Haeme;Yu, Byoungsun;Sowndhararajan, Kandhasamy;Jung, Ji-Wook;Jhoo, Jin-Woo;Kim, Songmun
    • Journal of Life Science
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    • v.23 no.9
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    • pp.1170-1176
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    • 2013
  • Essential oils have been used to treat psychophysiological disorders, but their effects on human electroencephalographic (EEG) activity have not been thoroughly investigated. We evaluated the effects of essential oil of Zizyphus jujuba seeds, a Korean folk medicine known as San-Jo-In, on human EEG activity. For this purpose, essential oil was extracted from San-Jo-In by the supercritical carbon dioxide extraction method. The effect of its inhalation on EEG activity was evaluated by measuring the EEG power spectrum (25 indices) in 20 healthy participants. The results of the EEG power spectrum indicated that the values of the theta wave decreased significantly (p<0.05) in the left (from 17.277 to $13.854{\mu}V$) and right parietal (from 15.324 to $13.020{\mu}V$) regions compared to the other regions. During the inhalation of San-Jo-In oil, the EEG spectrum values of fast alpha, relative gamma, and spectral edge frequency increased 50% compared to those before inhalation. The values of the fast alpha wave increased significantly (p<0.05) in the left prefrontal (from 0.063 to $0.085{\mu}V$), right prefrontal (from 0.064 to $0.085{\mu}V$), and left frontal (from 0.073 to $0.100{\mu}V$) regions following inhalation of the San-Jo-In essential oil. The changes in the EEG activities following inhalation of San-Jo-In suggest that the oil can improve psychological well-being by increasing attention and relaxation.

Convergence Evaluation of Indoor Air Measurement in Medical Institution (의료기관 실내공기 측정의 융합적 평가)

  • Lee, Yu-Hee;Choi, Yu-Jin;Choi, Jung-OK
    • Journal of the Korea Convergence Society
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    • v.8 no.1
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    • pp.71-76
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    • 2017
  • The purpose of this study was to investigate the indoor air quality of medical institutions and to present the detailed management plan by analyzing the actual situation of management and analyzing the difference according to the place in a convergent. ($PM_{10}$), carbon dioxide ($CO_2$), formaldehyde (HCHO), total aerobic bacteria (TAB) and carbon monoxide (CO) were investigated in 153 hospitals in Busan. As a result, The overall output average did not exceed the maintenance criteria, but the maximum values for each item were 91% for $PM_{10}$, 97% for $CO_2$, 96% for HCHO, and 99% for bioaesol. And It is confirmed that this is very close to the standard. In addition, the results of each place showed different values according to each feature, but there was no significant difference in the results of five measurements. In conclusion, Indoor air in medical institution considering the characteristics should be performed systematic and detailed management of ventilation facilities and energy problems.

Effect of the Physical Parameters and Alkalinity in the Ammonia Stripping (반응조의 물리적 인자와 알칼리도가 암모니아 탈기에 미치는 영향에 관한 연구)

  • An, Ju-Suk;Lim, Ji-Hye;Back, Ye-Ji;Chung, Tae-Young;Chung, Hyung-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.8
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    • pp.583-590
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    • 2011
  • The effect of the physical parameters in the reactor (aeration depth, bubble size, and surface area) and the alkalinity of the solution on the ammonia stripping by bubbling were evaluated. When an airflow of 30 L/min was bubbled below the solution surface in the range 6-53 cm, the ammonia removal rate were observed to be the same regardless of the bubbling depths. At pH 10.0 and a temperature of $30^{\circ}C$, the average rate constant and the standard deviation were $0.178h^{-1}$ and 0.004. No appreciable changes in the ammonia removal rate were also observed with varying the bubble size and the air-contacting surface area. Alkalinity of the solution was found to affect the ammonia removal rate indirectly. This is expected because the pH of the solution would vary with dissolution of gaseous $CO_2$ by air bubbling. The real wastewaters from landfill site and domestic wastewater treatment plant were tested. In the case of domestic wastewater (pH = 7.1, alkalinity = 75 mg/L), the ammonia removal rate was poor even with the control of pH to 9.3. The raw landfill leachate (pH = 8.0, alkalinity = 6,525 mg/L), however, showed the appreciable removal rate with increasing pH during aeration. When the initial pH of the leachate was adjusted 9.4, the removal rate was significantly increased without changing the pH during aeration.

Fire Hazard of PP and LLDPE dust in Chemical Plant Process (석유화학플랜트에서 발생하는 PP(Poly Propylene) 및 LLDPE(Linear Low Density Poly Ethylene) 분진의 연소 위험성에 관한 연구)

  • 김정환;이창우;현성호;권경옥
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.16-22
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    • 2001
  • Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

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A Study on the Low Concentration Carbon Dioxide Adsorbent and Optimal Conditions (저농도 이산화탄소 포집용 흡착제 개발 및 최적조건에 관한 연구)

  • Lee, Ju-Yeol;Park, Duck-Shin;Cho, Young-Min;Kwon, Soon-Park;Hwang, Yoon-Ho;Song, Hyung-Jin;Lee, Sang-Bong
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.1-12
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    • 2012
  • In this study, $CO_2$ adsorbent was developed for removing low concentration of $CO_2$ in multiple-use facilities. The efficiency of the adsorbent which was improved selective $CO_2$ adsorption capabilities was evaluated. The pellet type adsorbent was modified from a commercial zeolite with mixing LiOH, binder, additives, and $H_2O$. Column tests showed over 90 % of $CO_2$ was adsorbed within 400min. Chamber tests including batch and continuous types were performed for evaluating the adsorbent module. By batch tests, it was evaluated that about 92% of $CO_2$ was removed within 30 min. By continuous tests, 70% of $CO_2$ was removed within 30 min. It was analyzed that over 2,500 ppm of $CO_2$ was continuously removed as shown chamber tests. The reproducibility tests repeatedly performed for 15 days shows that over 1,000 ppm of $CO_2$ was continuously removed. Adsorption capacity of the developed adsorbent was 5.0mmol $CO_2/g$ adsorbent which was analyzed by TGA. It was estimated that the modified adsorbent was applicable to low $CO_2$ concentration and low temperature of indoor environment.

InSb 적외선 감지 소자용 $Si_3N_4$, $SiO_2$ 절연막 계면 특성 연구

  • Park, Se-Hun;Lee, Jae-Yeol;Kim, Jeong-Seop;Kim, Su-Jin;Seok, Cheol-Gyun;Yang, Chang-Jae;Park, Jin-Seop;Yun, Ui-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.163-163
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    • 2010
  • 중적외선 영역 ($3{\sim}5\;{\mu}m$)은 공기 중에 존재하는 이산화탄소나 수증기에 의해 흡수가 일어나지 않기 때문에 군사적으로 중요한 파장 영역이며, 야간에 적을 탐지하는데 응용되고 있다. InSb는 77 K에서 중적외선 파장 흡수에 적합한 밴드갭 에너지 (0.228 eV)를 갖고 있으며, 다른 화합물 반도체와 달리 전하 수송자 이동도 (전자: $10^6\;cm^2/Vs$, 정공: $10^4\;cm^2/Vs$)가 매우 빠르기 때문에 적외선 화상 감지기 재료로 매우 적합하다. 또한 현재 중적외선 영역대에서 널리 사용되는 HgCdTe (MCT)와 대등한 소자 성능을 나타냄과 동시에 낮은 기판 가격, 소자의 제작 용이성 때문에 MCT를 대체할 물질로 주목 받고 있다. 하지만, 기판과 절연막의 계면에 존재하는 결함 때문에 에너지 밴드갭 내에 에너지 준위를 형성하여 높은 누설 전류 특성을 보인다. 따라서 InSb 적외선 소자의 구현을 위하여 고품질의 절연막의 연구가 필수적이라고 할 수 있겠다. 절연막의 특성을 알아보기 위해, n형 InSb 기판에 플라즈마 화학 기상 증착법 (PECVD)을 이용하여 $SiO_2$, $Si_3N_4$를 증착하였으며, 증착 온도를 $120^{\circ}C$에서 $240^{\circ}C$까지 $40^{\circ}C$ 간격으로 변화하여 증착온도가 미치는 영향에 대하여 알아보았다. 절연막과 기판의 계면 특성을 분석하기 위하여 77 K에서 커패시턴스-전압 (C-V) 분석을 하였으며, 계면 트랩 밀도는 Terman method를 이용하여 계산하였다 [1]. $Si_3N_4$를 증착하였을 경우, $120{\sim}240^{\circ}C$의 증착 온도에서 $2.4{\sim}4.9{\times}10^{12}\;cm^{-2}eV^{-1}$의 계면 트랩 밀도를 가졌으며, 증착 온도가 증가할수록 계면 트랩 밀도가 증가하는 경향을 보였다. 또한 모든 증착 온도에서 flat band voltage가 음의 전압으로 이동하였다. $SiO_2$의 경우 $120{\sim}200^{\circ}C$의 증착온도에서 $7.1{\sim}7.3{\times}10^{11}\;cm^{-2}eV^{-1}$의 계면 트랩 밀도 값을 보였으나, $240^{\circ}C$ 이상에서 계면 트랩밀도가 $12{\times}10^{11}\;cm^{-2}eV^{-1}$로 크게 증가하였다. $SiO_2$ 절연막을 사용함으로써, $Si_3N_4$ 대비 약 25% 정도 낮은 계면 트랩 밀도를 얻을 수 있었으며, 모든 증착 온도에서 양의 전압으로 flat band voltage가 이동하였다. 두 절연막에 대한 계면 트랩의 원인을 분석하기 위하여 XPS 측정을 진행하였으며, 깊이에 따른 조성 분석을 하였다. 본 실험에서 최적화된 $SiO_2$ 절연막을 이용하여 InSb 소자의 pn 접합 연구를 진행하였다. Be+ 이온 주입을 진행하고, 급속열처리(RTA) 공정을 통하여 p층을 형성하였다. -0.1 V에서 16 nA의 누설 전류 값을 보였으며, $2.6{\times}10^3\;{\Omega}\;cm^2$의 RoA (zero bias resistance area)를 얻을 수 있었다.

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Synthesis of Soluble Copolyimides Using an Alicyclic Dianhydride and Their $CO_2/CH_4$ Separation Properties (지환족 다이안하이드라이드를 이용한 용해성 폴리이미드 공중합체 합성 및 메탄/이산화탄소 분리특성)

  • Park, Chae Young;Lee, Yongtaek;Kim, Jeong Hoon
    • Membrane Journal
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    • v.24 no.1
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    • pp.1-9
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    • 2014
  • In this study, four soluble homo- and co-polyimides using 5-(2,5-dioxotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride (DOCDA) and 4,4'-diaminodiphenyl ether (ODA) monomers were synthesized to develop the gas separation membrane with good $CO_2/CH_4$ separation properties. To prepare the copolyimides, 20 mol% of three dianhydrides - (4,4'-(hexafluoroisoproplidene)diphthalic anhydride (6FDA), 4,4'-biphthalic anhydride (BPDA), 3,3',4,4'-benzophenone tetracarboxylic dianhydride (BTDA) - were added in DOCDA-ODA monomer mixture, respectively. All the synthesized homo- and co-polyimides were characterized by FT-IR. Their thermal properties were analyzed with differential scanning calorimeter (DSC). Dense membranes were prepared from these copolyimides to check their gas permeation properties for $CO_2$ and $CH_4$ gases using a time-lag method. The permeation testing results are as follows; DOCDA/ODA homopolymer showed 1.71 barrer of $CO_2$ permeability and 74.35 of $CO_2/CH_4$ selectivity. The three polyimide copolymers (DOCDA/6FDA-ODA, DOCDA/BPDA-ODA, DOCDA/BTDA-ODA) showed lower $CO_2/CH_4$ selectivities and higher $CO_2$ permeabilities than the homopolymer (DOCDA-ODA). DOCDA/6FDA-ODA showed twice times higher $CO_2$ permeabilities without severe $CO_2/CH_4$ selectivity loss than the DOCDA-ODA.

Preparation and Characterization of Anion Exchange Membrane Based on Crosslinked Poly(2,6-dimethyl-1,4-phenylene oxide) with Spacer-type Conducting Group (Spacer-type 전도기가 도입된 가교형 poly(2,6-dimethyl-1,4-phenylene oxide) 음이온 교환막의 제조 및 특성평가)

  • Lim, Haeryang;Kim, Tae-Hyun
    • Membrane Journal
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    • v.27 no.5
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    • pp.425-433
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    • 2017
  • As the problems related to the environmental pollution such as carbon dioxide emission are emerging, the need for the renewable energy and environmentally friendly energy is getting intense. Fuel cells are eco-friendly energy generation devices that generate electrical energy and produce water as a sole by-product. Compared to the traditional proton exchange membrane fuel cell (PEMFC), anion exchange membrane alkaline fuel cell (AEMAFC) has a main advantage of possibility to use low cost metal catalysts due to its faster kinetics. The AEM, which conducts $OH^-$ ions, should possess high ion conductivity as well as high chemical stability at high pH conditions. We hereby introduce a crosslinked poly(2,6-dimethyl-1,4-phenylene oxide) having a spacer-type conducting group as novel AEM, and report a high ion conductivity ($67.9mScm^{-1}$ at $80^{\circ}C$) and mechanical properties (Young's modulus : 0.53 GPa) as well as chemical stability (6.8% IEC loss at $80^{\circ}C$ for 1,000 h,) for the developed membrane.

Biological Co2 Fixation to Antioxidant Carotenoids by Photosynthesis Using the Green Microalga Haematococcus pluvialis (광합성 녹색 미세조류 Haematococcus pluvialis를 이용한 이산화탄소 고정화 및 항산화성 카로티노이드 생산)

  • Kang, Chang Duk;Park, Tai Hyun;Sim, Sang Jun
    • Korean Chemical Engineering Research
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    • v.44 no.1
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    • pp.46-51
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    • 2006
  • As one of the $CO_2$ reduction strategies, a biological method was proposed to convert $CO_2$ to useful biomass with antioxidant carotenoids by photosynthetic microorganisms. One of the photoautotrophs, Haematococcus pluvialis is a freshwater green microalga and accumulates the secondary carotenoid astaxanthin during induction of green vegetative cells to red cyst cells. In this study, $CO_2$ fixation and astaxanthin production using H. pluvialis was conducted by photoautotrophic culture in the $CO_2$ supplemented photo-incubator. Maximum growth rate of H. pluvialis was obtained at a 5% $CO_2$ environment on basic N and P conditions of NIES-C medium. The photoautotrophic induction consisted of 5% $CO_2$ supply and high light illumination promoted astaxanthin synthesis in H. pluvialis, yielding an astaxanthin productivity of $9.6mg/L{\cdot}day$ and a $CO_2$ conversion rate of $27.8mg/L{\cdot}day$ to astaxanthin. From the results the sequential photoautotrophic culture and induction process using H. pluvialis is expecting an alternative $CO_2$ reduction technology with a function of valuable biosubstance production.

CO2 Emission and Productivity of Fossil-fueled Power Plants: A Luenberger Indicator Approach (CO2 배출량을 감안한 화력발전소의 생산성 변화 분석: Luenberger지수 접근법)

  • Kwon, Oh-Sang
    • Environmental and Resource Economics Review
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    • v.19 no.4
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    • pp.733-752
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    • 2010
  • This study applies the Luenberger indicator approach to estimate productivity of the Korean fossil-fueled power plants. A panel data set of 25 power plants was used. The method incorporates $CO_2$ emission as an undesirable output and shows that ignoring $CO_2$ emission overestimates the productivity change. There are two sources of overestimation. First, the usual method estimates productivity change ignoring the increase in $CO_2$ emission that occurred during the study period. Second, the productivity change estimated by the usual method that does not incorporate $CO_2$ emission is very sensitively affected by the change in operation rate. The paper decomposes the productivity change into the efficiency change and the technical change. The results show that the two sources contribute to the productivity change almost equally. It is also shown that the size and the pattern of productivity change are dependent on the plants' fuel types. Non-LNG power plants which saved their energy consumption and thereby reduced their $CO_2$ emission have achieved relatively high rate of productivity improvement.

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