• Title/Summary/Keyword: 응결촉진제

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The Fundamental Properties of High Fluidity Mortar with Activated Ternary Blended Slag Cement (활성화된 삼성분계 고유동 모르타르의 기초특성)

  • Bae, Ju-Ryong;Kim, Tae-Wan;Kim, In-Tae;Kim, Hyoung-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.74-82
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    • 2017
  • This research presents the results of the strength and drying shrinkage properties to study the effect of ground granulated blast furnace slag(GGBFS), fly ash(FA) and calcium sulfoaluminate(CSA) for activated ternary blended slag cement. The activated ternary blended cement(ATBC) mortar were prepared having a constant water-cementitious materials ratios of 0.4. The GGBFS contents ratios of 100%, 80%, 70% and 60%, FA replacement ratios of 10%, 20%, 30% and 40%, CSA ratios of 0%, 10%, 20% and 30% were designed. The superplasticizer of polycarboxylate type were used. The activator was used of 10% sodium hydroxide(NaOH) + 10% sodium silicate($Na_2SiO_3$) by weight of binder. Test were conducted for mini slump, setting time, V-funnel, water absorption, compressive strength and drying shrinkage. According to the experimental results, the contents of superplasticizer, V-funnel and compressive strength increases with an increase in CSA contents for all mixtures. Moreover, the setting time, water absorption ratios and drying shrinkage ratio decrease with and increase in CSA. One of the major reason for the increase of strength and decrease of drying shrinkage is the accelerated reactivity of GGBFS with alkali activator and CSA. The CSA contents is the main parameter to explain the strength development and decreased drying shrinkage in the ATBC.

Isothermal Conduction Calorimetry Analysis of Alkali Activated Slag Binder (알칼리 활성 슬래그 결합재의 미소수화열 분석)

  • Choi, Young-Cheol;Cho, Hyun-Woo;Oh, Sung-Woo;Moon, Gyu-Don
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.237-243
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    • 2015
  • In this research, isothermal conduction calorimetry analysis has been conducted to investigate the reactivity of alkali activated slag binders. In order to secure the reactivity and workability of alkali activated slag binders, experiences with various types and concentrations of alkali activators were performed. Isothermal conduction calorimetry were measured with different alkali activators and mass ratio of $SO_3$ to binders as variables, and sodium tripolyphosphate ($Na_2P_3O_{10}$) and hydrated sodium borate ($Na_2B_4O_710H_2O$) were used to control setting time. As a results, alkali activated slag binders required alkali activators with 4 to 5 percent of concentration to accelerate the formation of calcium silicate hydrate(C-S-H) by alkali-activation, and overall heat generation rate delayed as accumulated heat decreased due to the high $SO_3$ contents. Moreover, the use of hydrated sodium borate as setting retarder causes elongated setting time due to delaying heat generation, so it can be considered that setting retarder played an important role in delaying total heat generation rate.

Properties of Portland Cement Clinker Using Polysilicon Sludge (폴리실리콘 슬러지를 원료로 사용한 포틀랜드 시멘트 클링커의 특성)

  • Lee, Seung-Heun;Lee, Se-Jin;Woo, Yang-Yee;Park, Jeoung-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.328-334
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    • 2014
  • This study reviewed the usability of sludge, a material that is additionally created when polysilicon (a solar light material) is produced, as the raw material for cement clinker. It was evaluated that when cement clinker is produced, the chloric component of polysilicon acted as a mineralizer in the firing process. In addition, the physical features of the produced cement were measured. The setting time of the produced cement was reduced as the amount of content of polysilicon sludge increased. Such results were drawn because the chloric component acted as hydration accelerator and enhanced the dissolution of calcium hydroxide that was formed by hydration of $C_3S$. Furthermore, for such reason, on the day 1, the compression strength of mortar increased as the content of polysilicon sludge increased. In day 3, 7, and 28, the tendency in which the compression strength increasing up to 5% of the amount of added polysilicon sludge was shown. It is because when clinker was produced, the chloric component increased the amount of $C_3S$ mineral created, thus enhancing the compression strength after day 3.

Effect of Fine Particle Cement and Recycled Aggregates as Alkali Activator on the Engineering Properties and Micro-Structure of High Volume Blast Furnace Slag Concrete (알칼리 자극제로서 미분시멘트와 순환골재가 고로슬래그 다량치환 콘크리트의 공학적 특성 및 미세구조에 미치는 영향)

  • Han, Min-Cheol;Lee, Hyang-Jae;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.6
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    • pp.602-608
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    • 2013
  • The aim of this study is to investigate experimentally the effect of the combination of fine particle cement with high Blaine fineness (FC) and recycled aggregates on the engineering properties and micro structure of high volume blast furnace slag (BS) concrete with 75% BS and 21 MPa. FC manufactured by particle classification at the plant with Blaine fineness of more than $7000cm^2/g$ was used as additional alkali activator for high volume blast furnace slag concrete made with recycled fine and coarse aggregates. FC was replaced by 15, 20 and 25% OPC. Test results showed that the incorporation of FC resulted in an increase in the compressive strength compared to BS concrete without FC by as much as 30% due to accelerated hydration and associated latent hydraulic reaction. It was found that the use of FC and recycled aggregates played an important role in activating BS for high volume BS concrete by offering sufficient alkali.

An Experimental Study on Engineering Characteristics of Wet Dredged Soil and Dry Dredged Soil after Chemical Treatment (습윤준설토와 노건조준설토의 약품처리 후 공학적 특성에 관한 실험적 연구)

  • Chang, Yongchai;Park, Kiyoun;Park, Jongcheol;Lee, Ingyu
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.3
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    • pp.71-76
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    • 2012
  • Since sediment in a stable state is disturbed during the process from sediment in a natural state to dredged soil, the turbidity of water is not good. When the dredged soil settles again, the volume change in the sediment occurs. Coagulant and flocculant are added for turbidity mitigation of the water and faster settling process of suspended solid, and the amount of the substances affects the characteristics of the dredged soil. This study is to investigate the characteristics of the dredged soil depending on the amount of three chemical products added to the wet dredged soil and the dry dredged soil through measuring the suspended solids (SS), volume change and sedimentation velocity. The experimental measurements show that the SS decreased, the volume change rate increased, and the sedimentation velocity increased, as the chemical amount increased. In addition, it was found that the dry dredged soil reacted even with little quantity of the chemicals because derelict and microorganism are removed due to the drying process at $100{\pm}5^{\circ}C$.

Quality Improvement of High Volume Fly Ash Concrete due to Early Strength Gain Admixture (조강형 혼화제에 의한 플라이애시 다량 치환 콘크리트의 품질 향상)

  • Han, Cheon-Goo;Park, Jong-Ho;Lee, Joung-Ah
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.117-124
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    • 2009
  • The purpose of the study was to improve quality of high volume fly ash concrete. The study evaluated on the possibility of early quality improvement of high volume fly ash concrete with early strength gain admixture ('GA' below) developed by the preceding research. The study regarded applying naphthalene admixture ('NA' below) to mix proportion substituting FA 15 % to be plain. In the event of substituting FA 20, 25 and 30 %, the study compared engineering properties of concrete with plain by applying GA. Because of features of fresh concrete, fluidity falls down when GA is applied. Therefore, its use amount shall be increased. Only, in W/B 60 %, it was beneficial since slump loss was reduced about 35~70 mm than plain. The study could see that AE use should be increased proportionally since air content was reduced by coming from AE absorption operation of unburned coal content included in FA according to an increase in the amount of FA use. Reduction effect of bleeding could be anticipated since the amount of bleeding appeared at least in FA 20 %. Because of hardened concrete, time of setting appeared in the same level as plain when GA was applied. Therefore, it is judged that delay of setting can be reduced. In compressive strength, the study could check the same strength development as plain when GA was applied, having nothing to do with W/B and curing temperature. However, it is thought that we shall pay attention to GA use in the event of FA 30 % substitution. Freezing and melting resistance had less early value than plain. However, it is judged that there will be no problem of frost resistance since there is no a large difference between freezing and melting resistance and plain in overall. In accelerated neutralization, it was analyzed that a problem of weakening in neutralization appointed as a demerit when FA was applied in mass in proportion with GA use could be settled to some extent.

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A Study on the Effect of Calcium-Chloride Content on the Strength of Mortar (염화(鹽化)칼슘의 함량(含量)이 Mortar의 강도(强度)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Sung, Chan-Yong;Kang, Sin-Up
    • Korean Journal of Agricultural Science
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    • v.6 no.2
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    • pp.185-191
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    • 1979
  • Compressive and tensile strengths of commonly being used mortar and mortar specially hardened by adding 1%, 2% and 3% of $CaCl_2$ were compared under the different mixing ratio of mortar and ages to investigate the effect of $CaCl_2$ which is being used as a promotor for coagulation and hardness, on the strength of mortar. The results obtained were as follows: 1. The compressive strength of mortar hardened by addition of $CaCl_2$ was higher than that of commonly being used mortar. The highest compressive strength of mortar was obtained when 2% of $CaCl_2$ were added. 2. The tensile strength of mortar, which was made by adding $CaCl_2$ and aged for seven days, was higher than that of commonly being used mortar. The highest tensile strength of mortar was obtained when 1% of $CaCl_2$ was added and aged for 28 days. And the tensile strength of mortar with 2% of $CaCl_2$ was lower than that of commonly being used mortar. 3. When the amount of $CaCl_2$ added was higher than 3%, the mortar was abruptly hardened and thereby occurred crack was considered lowering strength of mortar. 4. The rich mix was effective for the increasing the compressive and tensile strength before seven days of age and less effective after seven days of age. Therefore, the addition of one to two per cent of $CaCl_2$ would be effective for promoting initial strength of mortar during winter season.

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A study on the Effect of Calcium Chloride Admixture on strengths of Concrete (혼화제인 염화칼슘이 콘크리트 강도에 미치는 영향에 관한 연구)

  • Jun, Hyun-Woo;Lim, Chong-Kook
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.13 no.4
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    • pp.2419-2425
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    • 1971
  • In many cold weather concrete constructison jobs calcium chloride $CaCl_2$ can be used safely as an accelerating admixture. For producing satisfactory concrete during cold weather calcium chloride is used to develop the level of strength required in a shorter period by obtaining higher early strength, the resulting in crease in heat of hydration. In this paper, to get adequated data and information of the effect on strength of concrete in using calcium chloride as an accelerating admixture, Portland cement (Type I), High-early-strength cement(Type II) and Pozzolans cement with certain 1.5 percentage of calcium chloride by weight of the cement were tested. As the result of this experiment, followings were founded: 1. At the 1.5 percent of calcium chloride cement ratio, the early strength was accelerated to the highest level, and some 1.5 percent of calcium chloride cement ratio was suitable for the stabilization of the concrete structures. 2. For Some 50 percent of Water Cement ratio was suitable, making good Concrete in the Cold weather by admixture of Calicum Chloide. 3. The concrete of Pozzorans cement in early strength was weak but that in later rised by degree. 4. As abtaining higher early strength the curing period can be reduced, but the finishing work should be done as early as possible.

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Experimental Studies on the Antitumor Effects of Jinryungtang Gagambang Extract (진령탕가감방의 항종양효과(抗腫瘍效果)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Jeong, Jun-Tak;Moon, Goo;Moon, Suk-Jae
    • THE JOURNAL OF KOREAN ORIENTAL ONCOLOGY
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    • v.4 no.1
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    • pp.37-53
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    • 1998
  • The sprig of Jinryungtang Gagambang has been used for curing as a traditional medicine without any experimental evidence to support the rational basis for their clinical use. This experiment was carried out to evaluate the possible therapeutic or antitumoral effects of Jinryungtang Gagambang extract against cancer, and to study some mechanisms responsible for its effect. The cytotoxic and antitumor effects were evaluated on human cell liens (A549, hep3B, Caki-1, Sarcoma 180) after exposure to Jinryungtang Gagambang extract using in ILS, colony forming efficency and SRB assay which were regarded as a valuable method for cytotoxic and antitumor effects of unknown compound on tumor cell lines. The results obtained in this studies were as follows. 1. As a result of exposure to Jinryungtang Gagambang extract, the proliferation of A549, hep3B, Caki-1, good correlations were shown from the results of SRB assay and those of clogenetic assay. 2. The oral administration of Jinryungtang Gagambang extract showed significant effects of increase of MST(mean survival time) and ILS(increased life span) depending on the increasing concentration. 3. Against squamous cell carcinoma induced by MCA, Jinryungtang Gagambang decreased not only the frequency of tumor production but also the number and weight of tumors per tumor bearing mice(TBM). Jinryungtang Gagambang also significantly suppressed the development of 3LL cell-implanted tumors by frequency and their size, and some developed tumors were regressed by the continuous treatment of Jinryungtang Gagambang extract into TBM. 4. Jinryungtang Gagambang extract also increased NK cell activities. According to the above results, it could be suggested that Jinryungtang Gagambang extract has prominent antiutmor effect.

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