• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.24 no.4
• /
• pp.164-168
• /
• 2014

The sodium-sulfur batteries which operate at $350^{\circ}C$ have been mainly used in the field of energy storage system. This batteries consist of liquid sodium anode, sulfur cathode and ${\beta}^{{\prime}{\prime}}$-alumina solid electrolyte. The conditioning process for stabilization of the batteries is essential since the cells show considerable fluctuation of discharge voltage at the beginning of discharge/charge cycles. It is found that one of the reasons of the fluctuation is the gradual change of contact area between molten sodium and solid electrolyte.

• Clean Technology
• /
• v.20 no.1
• /
• pp.88-94
• /
• 2014

During the past decades much attention has been paid to the desulfurization of diesel oil which is important as a source for the fuel cells to prevent the sulfur poisoning of both diesel steam reforming catalyst and electrode of fuel cell. Although alternative desulfurization techniques have been investigated, desulfurization for ultra-low sulfur diesel (ULSD) is still challenged. Therefore, this research focuses on the desulfurization of commercial ULSD for the application to molten carbonate fuel cell (MCFC). Herein, the performances of several kinds of commercial adsorbents based on activated carbons, zeolites, and metal oxides for desulfurization of ULSD were screened. The results showed that metal oxides based materials can feasibly reduce sulfur concentration in ULSD to a level of 0.1 ppmw while activated carbons and zeolites did not reach this level at current conditions.

• Transactions of the Korean hydrogen and new energy society
• /
• v.27 no.6
• /
• pp.753-763
• /
• 2016

High temperature sodium/sulfur battery(Na/S battery) has good electrochemical properties, but, the battery has some problems such as explosion and corrosion at al. because of using the liquid electrodes at high temperature and production of high corrosion. Room temperature sodium/sulfur batteries (NAS batteries) is developed to resolve of the battery problem. To recently, room temperature sodium/sulfur batteries has higher discharge capacity than its of lithium ion battery, however, cycle life of the battery is shorter. Because, the sulfur electrode and electrolyte have some problem such as polysulfide resolution in electrolyte and reaction of anode material and polysulfide. Cycle life of the battery is improved by decrease of polysulfide resolution in electrolyte and block of reaction between anode material and polysulfide. If room temperature sodium/sulfur batteries (NAS batteries) with low cost and high capacity improves cycle life, the batteries will be commercialized batteries for electric storage, electric vehicle, and mobile electric items.

• Journal of the Korean Electrochemical Society
• /
• v.16 no.3
• /
• pp.111-122
• /
• 2013

Sodium sulfur (NAS) battery is a high energy storage system (ESS). These days, as the use of renewable green energy like wind energy, solar energy and ocean energy is rapidly increasing, the demand of ESS is increasing and NAS battery is considered to be one of the most promising ESS. Since NAS battery has a high energy density(3 times of lead acid battery), long cycle life and no self-charge and discharge, it is a good candidate for ESS. A NAS battery consists of sulfur as the positive electrode, sodium as the negative electrode and ${\beta}$"-alumina as the electrolyte and a separator simultaneously. Since sulfur is an insulator, carbon felt should be used as conductor with sulfur and so the composition and property of the cathode could largely influence the cell performance and life cycle. Therefore, in this paper, the composition of NAS battery, the property of carbon felt and sodium polysulfides ($Na_2S_x$, intermediates of discharge), and the effects of these factors on cycle performance of cells are described in detail.

• Transactions of the Korean hydrogen and new energy society
• /
• v.17 no.3
• /
• pp.317-323
• /
• 2006

Electric conductive material should be homogeneously mixed with sulfur in sulfur electrode fabrication of lithium/sulfur battery, because sulfur is electric insulator. In this paper electrochemical properties of Li/S battery was studied with various compositions of sulfur electrodes. When content of sulfur changed from 40 wt.% to 80 wt.%, the 60 wt.% sulfur electrode showed the maximum capacity of 1489 mAh/g-sulfur. Electrochemical properties of Li/S battery using 60 wt.% sulfur was also investigated with various carbon contents. The discharge capacity changed as a function of carbon contents. The optimum composition was 25 wt.% carbon for 60 wt.% sulfur electrode.

• 한국전기화학회:학술대회논문집
• /
• 2002.10a
• /
• pp.63-63
• /
• 2002

• 한국전기화학회:학술대회논문집
• /
• 1999.10a
• /
• pp.67-67
• /
• 1999

• Korean Journal of Metals and Materials
• /
• v.49 no.2
• /
• pp.174-179
• /
• 2011

We investigated the surface morphology changes of a lithium/sulfur battery using multi-walled canbon nanotube added sulfur electrode during charge-discharge cycling. The Li/S cell showed the first discharge capacity of 1286 mAh/g-S, which utilized is 71% of the theoretical value. It decreased to 328 mAh/g-S at the 100th cycle, which corresponds to about 19% utilization of the total sulfur in the cathode. The spherical lumps of the reaction product were observed on the surface of the sulfur electrode. This material was verified as lithium sulfide by X-ray diffraction measurement. The pores in the separator were filled with reaction product. Thus the diffusion of the $Li^+$ ion decreased, which resulted in the decreased capacity of the Li/S cell.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.1
• /
• pp.83-91
• /
• 2011

We investigated the effect of composition of a sulfur electrode with MWNT on the discharge behavior and cycling property of a Li/S cell. The MWNT content of a 60wt.% sulfur electrode varied from 10 wt.% to 30 wt.%. The optimum content of MWNT is 20wt.%, which shows the best cycling property. The first discharge capacity is 1166 mAh/g and decrease to the 542 mAh/g after 30th cycle. The homogeneous distribution of MWNT is an important factor for cycling properties.

• 한국신재생에너지학회:학술대회논문집
• /
• 2005.11a
• /
• pp.130-139
• /
• 2005

메탄올을 직접 연료로 하는 직접 메탄올 연료전지 (DMFC)는 연료의 높은 에너지 밀도로 인하여 휴대용 전자 기기의 차세대 에너지원으로 주목 받고 있다. 전자기기에 적용하기 위해서는 고성능 소재 부품의 개발, 시스템 통합 등의 고난도 기술이 필요하다. 본고에서는 귀금속 담지량이 절대적으로 감소한 신규 cathode 촉매, 하이브리드 신규 막, 고성능 스텍, 시스템 통합의 개발 경과대해 기술하고 있다.