• Title/Summary/Keyword: 유색광물

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Heavy Metal Contents of the Surface Water and Stream Sedi-ments from the Talc Mine Area, Western Part of Chungneam (충남 서부 활석광산 주변의 지표수 및 하상 퇴적물의 중금속 함량)

  • 송석환;김명희;민일식
    • Korean Journal of Environment and Ecology
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    • v.15 no.2
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    • pp.139-152
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    • 2001
  • 충남 서부 활석광산 주변의 수계에 대한 원소 함량특성에 대해 알아보고자 대흥 및 광천광산에 대해 수질 및 하상 퇴적물 시료와 함께 광산 주변 토양 및 모암 시료를 채취, 비교하였다. 대흥지역 퇴적물은 대부분 원소에서 SP가 GN에 비해 높았는데 이는 퇴적물 내 유색 및 무색광물 함량 차이로 판단된다. 절대 함량 비교에서 광물 결정구조 내 쉽게 Mg와 치환하는 원소는 낮은비율을, Fe와 치환하는 원소는 높은 비율을 보였는데 이는 퇴적물 내 주 구성광물내 원소 치환특성을 반영하기 때문으로 판단된다. 절대 함량의 감소 순서와 타원소들과 높은 상관관계(>0.85)의 빈도를 보이는 원소들 사이의 차이는 퇴적물 화학조성에 이차광물과 비정질 광물등의 조성도 반영되었음을 암시한다. 대흥지역 지표수는 대부분 원소에서 MSP가 SP와 GN의 중간값을, MSG는 LGN과 MSP의 중간값을 조여 수계의 혼합특성을반영하는 것으로 판단된다. 절대 함량관계에서는 SP는 GW1과 유사했고, GN은 LGN과 유사했으며, 절대함량은(Mg, Fe), (As, Sc), (Mo, V, Se) 순서로 낮아졌다. 광천지역은 갱내수가 천부 지하수에 비해 대부분 원소에서 높은 함량을 보였는데, 이는 갱내수가 더욱더 많은 물-암석반응을 거친 때문으로 판단된다. 절대 함량은 Mg, Br, Fe, (Sc, Cr), (An, Ni, V)순서로 감소하였다. 갱냉수의 지역간 원소 함량 차이는 사문암화가 우세한 광천지역과 활석화가 우세한 대흥지역 모암들 사이의물-암석 상화반응의 차이를 보여주는 것으로 판단된다 두 지역의 상부 토양 및 모암 조성에서 SP가 GN에 비해 높은 Mg 비, Ni, Cr, Co 등 함량을 보였는데, 이는 사문암 지역 내 Mg, Ni, Cr 등이 풍부한 광물들 탓으로 판단된다. 퇴적물과 수질 사이에서는 함량 경향을 뚜렷하지 않았고 원소에 따라 서로 다른 힘량 차이를 보였는데, 이는 퇴적물 원소 함량이 수계 조성을 반영하는 것이 아님을 나타낸다. 상부-토양-암석-수계의 조성관계에서 대흥지역 지표수 중 SP 조성이, 광천지역은 갱냉수가 지하수의 조성에 가까웠다.

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Enriched Geochemical and Sr-Nd isotopic characteristics of Middle Triassic Plutonic Rocks in Hudongri, Chuncheon: Derivation from Enriched Mantle (춘천 후동리 일대에 분포하는 중기 트라이아스기 관입암의 부화된 지화학 및 Sr-Nd 동위원소 특성: 부화된 맨틀로부터 기원)

  • Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.18 no.3
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    • pp.255-267
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    • 2009
  • The intrusive rocks in the Hudongri area, Chuncheon located in central Gyeonggi Massif consist of gabbroic diorite and diorite. K-Ar age of biotite separated from diorite sample records middle Triassic age of 228 Ma. The intrusives are characterized by enrichment of MgO, Ni and Cr as well as large ion lithophile elements such as Sa and Sr, which is indicative of derivation of magma from enriched mantle. The intrusives also have enriched Sr-Nd isotopic compositions, which appear to result from a long-term incompatible element enriched mantle source with an effect of crustal contamination. Occurrence of abundant hydrous minerals such as amphiboles and biotite rather than anhydrous minerals of pyroxene and olivine in mafic intrusive as well as being plotted in volcanic arc field in tectonic environment discrimination diagram indicate the mafic-intermediate intrusives in the Hudongri area, Chuncheon were derived from mantle material enriched by subduction.

Petrology of host granites and enclaves from the Bohyeonsan area, Euiseong Basin (의성분지 보현산 일대 화강암류와 포획암에 대한 암석학적 연구)

  • 좌용주;김건기
    • The Journal of the Petrological Society of Korea
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    • v.9 no.3
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    • pp.187-203
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    • 2000
  • Mafic microgranular enclaves (MME) occur in the granites from the Bohyunsan area. The host granites are generally of granodioritic and granitic compositions. The MME can be divided into magic mineral clusters, quartz diorite and diorite according to their occurrence. Halter variation diagrams show linear trends between the MME and the host granites. Though the rim compositions of plagioclase in the host granites and the MME are similar the core compositions of plagioclase in some host granites show abnormally high An content. The Mg/(Mg+Fe) ratio of hornblende in the host granites gradually increase from the core to the rim. The chemical composition of minerals in the host granites had been affected by more marc magma composition. The modelling of major elements of the MME and hybrid host granites also indicate that they result from simple mingling/mixing between a dioritic magma and the host granite magma. The MME are thus interpreted to be globules of a more mafic magma which intruded the granite magma. Partial equilibration has been achieved between the MME and the host granites after they were commingled with each other.

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Chemical Weathering Characteristics of Red Saprolites at Granitic Hills in Yeongam, Southwestern Korea (한반도 남서부 영암의 화강암 구릉대 적색토의 화학적 풍화 특색)

  • Kim, Young-Rae
    • Journal of the Korean Geographical Society
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    • v.47 no.3
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    • pp.315-327
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    • 2012
  • Red saprolites are appeared in granitic hills in Yeongam, Southern Korean Peninsula. These red saprolites were analyzed for their geochemistry, including CIA, A-CN-K and A-CNK-FM ternary plots, to understand the chemical weathering trend and rubefaction of the saprolites. These saprolites were compared with laterite profiles in Cameroon formed under humid tropical conditions. The red saprolites in Yeongam show commonly massive loss of CaO, $Na_2O$, but $K_2O$ is being slow. The red saprolites in Yeongam relative to laterite and kaolinite profiles of Cameroon and Spain show weak chemical alteration owing to slow removal of $K_2O$, but high mafic constituents, $Fe_2O_3$ and MgO, for most of the samples. In the saprolites of Yeongam, mafic oxides become enriched because of the fast and massive removal of alkali constituents, such as CaO, $Na_2O$ and $K_2O$, relative to other elements, resulting in rubefaction of the saprolites. It is found that the rubefaction of the saprolites is not necessarily proportional to chemical weathering intensity.

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Geochemical characteristics of Ogcheon granite in Ogcheon area (옥천화강암의 지구화학적 특성)

  • 윤현수;김대업;박석환
    • The Journal of the Petrological Society of Korea
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    • v.8 no.2
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    • pp.81-91
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    • 1999
  • The area of the study is located in Ogcheon district, middle part of Ogcheon Fold Belt. The area is covered by metasedimentary rocks of Ogcheon Supergroup at northern, eastern and southern part. Jurassic Ogcheon granite which intruded into Ogcheon Supergroup at central part, was intruded by Cretaceous quartz porphyry at western part. The granite consists of quartz, plagioclase, alkali feldspar, biotite, sphene, apatite, epidote, opaque and so on. It is generally characterized by grey to light grey, medium-grained, mafic enclave and partly weak foliation. In terms of geochmical compositions, the granite is felsic, peraluminous, subalkaline and calc-alkaline, and it was differentiated from single granitic magma. It shows parallel LREE enrichment and HREE depletion patterns with 0.84 Eu negative anomaly, which has REE variation trend and anomaly value similar to Jurassic granites in Korea. From charactristics of petrology, mineralogy and geochmistry, it may be interpreted that the Ogcheon granite body was derived from melting of I-type crustal material related to syn-collisional tectonic setting and emplaced more or less rapidly into the Ogcheon Supergroup.

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Petrography and mineral chemistry of Fe-Ti oxides for the Mesozoic granitoids in South Korea : a reconsideration on the classification of magnetite- and ilmenite-series (남한의 중생대 화강암의 Fe-Ti 산화광물에 대한 암석기재와 광물화학: 계열분류에 대한 재고찰)

  • 조등룡;권성택
    • The Journal of the Petrological Society of Korea
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    • v.3 no.1
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    • pp.1-19
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    • 1994
  • We present petrography, mode and chemistry data for Fe-Ti oxide minerals from the Mesozoic granitoids in South Korea. Magnetites from the Daebo Uurassic) granites are nearly pure $Fe_3O_4$, while those from the Bulgugsa (Cretaceous) granites contain considerable amounts of Mn and Ti. This is probably related to rapid cooling of the Bulgugsa granites compared with slow cooling of Daebo granites, which is supported by geologic relations and hornblende geobarometry results of Cho and Kwon (1994) on the emplacement depth for these granites. The composition of ilmenite does not shew appreciable difference between the Daebo and Bulgugsa granites. However, $Fe_2O_3$ contents are higher for the ilmenites coexisting with magnetite than for those without magnetite. In the temperature vs. oxygen fugacity diagram, the Bulgugsa granites plot near Ni-NiO and QFM buffer curves, although only two samples show greater than the granite solidus temperature. The mode data suggest that both magnetite- and ilmenite-series exist in Daebo and Bulgusa granites from the Kyonggi massif, Ogcheon belt and Youngnam massif, while only magnetite-series exists in Bulgugsa granites from the Kyongsang basin. Many ilmenite-series granites occur in the Ogcheon belt, which might be related to assimilation of carboniferous sediments in the belt. The proportion (44 : 56) between ilmenite- and magnetite-series for the Daebo granites is significantly different from that of Ishihara et al. (1981) who showed, using magnetic susceptibility data, predominance of ilmenite-series (more than 70%) for the Daebo granites, which can be mainly attributed to preference in sampling and to wrong assignment of age for some plutons. We also found magnetite in weakly-magnetized Kanghwa granite which was formerly classified as ilmenite-series by Ishihara et al. (1981). The proportion of ilmenite-series increases in the order of hornblende biotite granite, biotite granite and two mica granite. We conclude from these observations that the ilmeniteseries granites might have originated from contamination of carboniferous crustal material and/or such source material.

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Presence of Leucocratic Granites of the Taebaegsan Region and Its Vicinities (태백산지역과 인근에 분포하는 우백질 화강암체의 존재)

  • Yoo, Jang Han;Koh, Sang Mo;Moon, Dong Hyeok
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.263-272
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    • 2013
  • The Taebaegsan region and its vicinities mainly consist of Precambrian granitic gneisses and Cambrian meta-sedimentary rocks. And lots of leucocratic(alkali) granites smaller than the stocks are found here and there. Therefore the presence of leuco-granites is not properly described yet in the former studies. For the effective distinction of several granitic rocks, outcrop characteristics, mineral identification, and petro-chemical properties were studied. Some part of granitc gneisses could be classified into typical metamorphic rocks such as migmatites and banded gneisses. And some shows rather dark appearance with gray quartz and feldspars, and others two mica granites, leucocratic ones etc. But all of leucocratic granites of the region usually show bright milky white to beige color. Since they mainly consist of quartz, feldspars, muscovite, and small amounts of sericites, amphiboles, tourmaline and lepidolite. And all of alkali granites belong to the calc-alkalic, peraluminous and S-type in character. During magmatic differentiation of leucocratic granites, CaO and total Fe contents are clearly decreased than those of the older granitic rocks. On the other hand, magmatic evolution also had induced the greisenization and albitization which enriched the relative amounts of alkali elements such as $K_2O$ and $Na_2O$.

The Overview of Layered structures in Mafic - Ultramafic Macheon Intrusion (고철질-초고철질 마천관입암의 층상구조 개관)

  • Song, Yong-Sun;Kim, Dong-Yeon;Park, Kye-Hun
    • The Journal of the Petrological Society of Korea
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    • v.16 no.3
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    • pp.162-179
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    • 2007
  • Macheon Layered Intrusion (MLI) which intruded into Precambrian gneiss complex of the northern Jirisan area, southeastern part of Youngnam (or Sobaeksan) Massif, is a layered mafic-ultramafic complex of Triassic age (ca. 223 Ma). The MLI is divided into Layered Series and Laminated Series. Layered Series is subdivided into Central Zone (Lower Zone) consisting of olivine gabbros and Peripheral Zone (Middle or Upper Zone) consisting of hornblende gabbros based on the type of cumulus texture and the main mafic phase. The Central Zone of Layered Series comprises thinly laminated olivine gabbros and uniform or thickly laminated coarse olivine gabbros which consist of mela-gabbro, troctolite, leuco-troctolite, and anorthositic rocks. Laminated Series is also subdivided into quartz-bearing biotite-pyroxene gabbros and homblende diorite and both have variable amount of interstitial quartz and microcline. Laminated series display moderately to slightly developed igneous lamination which is defined by the planar alignment of lath-shape plagioclases. Chilled margin of quartz-bearing biotite-pyroxene gabbro with surrounding Precambrian gneisses insists shallower intrusion of more felsic cognate magma evolved in the deep a little later. Rocks of Layered Series have orthocumulus to adcumulus olivine, adcumulus to intercumulus plagioclase, and intercumulus to heteradcumulus pyroxene and hornblende. Magmatic modally grading, folding, and cross-lamination are not rarely occurred in thinly layered rocks. These textural characteristics define main mechanisms of the formation of layered and laminated structure in mafic-ultramafic rocks of Macheon Layered Intrusion are gravity settling and in-situ crystallization associated with slumping and density current.

Petrological Study on Small-scale Granites in the Central Part of Yeongnam Massif (영남육괴 중부지방에 존재하는 소규모 화강암체들의 암석학적 연구)

  • Kim, Hyeong-Gyu;Jwa, Yong-Joo;Kim, Jae-Hwan;Park, Sung-Chul
    • The Journal of the Petrological Society of Korea
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    • v.28 no.4
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    • pp.279-298
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    • 2019
  • Mupung granite, which is located adjacent to Gimcheon granites to the north and Geochang granites to the south, has been known to consist of biotite-hornblende granite (Gbh), porphyritic granite (Gp), and hornblende-biotite granite (Ghb). In this study, we subdivided the Gbh of Mupung granite into biotite granite (Gb) and biotite hornblende granite (Gbh), based on petrological observations. The grayish Gb with medium to coarse grain and porphyritic texture contains a small amount of muscovite, but the hornblende and mafic microgranular enclave (MME) is not observed in Gb. On the other hand, MME can be commonly found in pinkish Gbh. The mafic minerals in Gbh are mostly hornblende and biotite. In the Gb in Mupung granites, the hornblende and sphene (which is the characteristic minerals in Gimcheon granite) are not observed. In addition, the trend of the changes in major elements of Gb in Mupung granites is similar to that of Geochang granites. These petrological characteristics suggest that the Gb in Mupung granite has a similarity with Geochang granite (than Gimchen granite). We also observed that the texture and composition of minerals of Gbh, as well as those of surrounding Gp and Ghb, are consistent with the characteristics of Cretaceous granites in Gyeongsang basin, rather than those of Jurassic granites in Yeongnam massif.

Use of Discriminant Analysis to Identify Soil Quality Variation by Land Use (판별분석을 이용한 토지이용별 토양 특성 변화 연구)

  • Ko Kyung-Seok;Kim Jae Gon;Lee Jin-Soo;Kim Tack Hyun;Lee Gyoo Ho;Cho Choon Hee;Oh In Suk;Cheong Young Wook
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.207-219
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    • 2005
  • The physical and chemical characteristics of soils in a small watershed were investigated and the effect of geology and land use on soil quality were examined by using multivariate statistical methods, principal components analysis and discriminant analysis. The soil developed from andesite had finer texture and higher contents of water extractable inorganic components, clay, and mafic minerals than the soil developed from granite. It is considered that the accumulation of salts in the farmland soils indicated by electrical conductivity, contents of cations and anions and pH was caused by fertilizer input during cultivation. The low contents of organic matter in the farmland soils was due to the enhanced oxidation of organic matter by tillage and by the harvest of crops. The contents of inorganic components are increased as following order: upland > orchard > paddy field > forest. The high contents of water soluble $SO_4\;^{2-}$ of paddy soils is due to the oxidation of sulfides mineral formed during the flooding period during the air-dry and extraction. The results of principal components analysis show the difference of soil quality was controlled by geology and land use. PCI indicate the input of fertilizer, mineral weathering and ion exchange reaction by application of nitrogenous fertilizers. The results of two discriminant analyses using water extractable inorganic components and their ratios by land use were also clearly classified by discriminant function 1 and 2. In discriminant analysis by components, discriminant function 1 indicated the effect of fertilizer application and increased as following order: upland > orchard > paddy field > forest soil. The investigated and predicted data for land use from discriminant analysis showed similar results. The discriminant analysis can be used as a useful method certifying the change of land use.