• Journal of the Korean Chemical Society
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• v.48 no.5
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• pp.473-482
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• 2004

The homobimetallic anion, $M^+({\eta}^5-MeCp)Mn(CO)_2Mn(CO)_5^-(M^+=Na^+,\;PPN^+)$was disrupted by CH2CHCH2Cl in THF at various temperatures ($20^{\circ}C~50^{\circ}C$) under the pseudo 1st order reaction conditions where excess of allyl chloride was employed under a nitrogen atmosphere. This homobimetallic anion seems to be involved in a concerted reaction mechanism in which a four-centered transition state is proposed. After undergoing the transition state, this reaction eventually leads to (MeCp)Mn$(CO)_3$ on addition of CO and $({\eta}^1-allyl)Mn(CO)_5$, respectively. However, in case of $Na^+$ analog, $Na^+$ may play a novel counter ion effect on the disruption reaction either by transferring one terminal CO from the $Mn(CO)_5$ moiety on to the $({\eta}^5-MeCp)Mn(CO)_2$of the corresponding homobimetallic complex, eventually resulting in $({\eta}^5-MeCp)Mn(CO)_3$ or through the interaction between $Na^+$ and the leaving group (Cl) of allyl chloride. This reaction is of overall second order with respect to homobimetallic complex with the activation parameters (${\Delta}H^{\neq}=17.15{\pm}0.17kcal/mol,\;{\Delta}S^{\neq}=-9.63{\pm}0.10$ e.u. for $Na^+$ analog; ${\Delta}H^{\neq}=22.13{\pm}0.21 kcal/mol,\;{\Delta}S^{\neq}=9.74{\pm}0.19$ e.u. for $PPN^+$ analog reaction).

• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.85-92
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• 2011

Evaluation of the removal efficiencies of Fe(II) by reactive sand media coated with manganese (MCS), iron (ICS) and both of iron and manganese (IMCS) was investigated as functions of solution pH ranging from 2 to 9, reaction time and concentration of Fe(II) in a batch reactor using each reactive medium and additional oxidants such as $KMnO_4$ and NaOCl. When only Fe(II) was present in solution without any reactive medium, removal of Fe(II) was quite low below pH 5 due to a slow oxidation of Fe(II) and/or negligible precipitation but greatly increased above pH 5 due to a rapid oxidation of Fe(II) and subsequent precipitation of oxidized Fe species. ICS showed negligible efficiency on the removal of Fe(II) through adsorption. However, an efficient removal of Fe(II) was observed at low solution pH in the presence of IMCS or MCS through rapid oxidation and subsequent precipitation. Removal efficiency of Fe(II) by IMCS in the presence or absence of NaOCl was quite similar. Removal rate of Fe(II) by IMCS and additional oxidants gradually increased as the solution pH increased. From the kinetic experiments, removal pattern of Fe(II) was better described by pseudo-second-order equation than pseudo-first-order equation. A rapid removal of Fe(II) using IMCS in the presence of $KMnO_4$ was observed in the first 10 min. The initial removal rate of Fe(II) using $KMnO_4$ was 14,286 mg/kg hr. In case of using NaOCl, the removal of Fe(II) occurred rapidly in the first 6 hrs and then reached the near-equilibrium state. Removal of Fe(II) on IMCS was well expressed by Langmuir isotherm and the maximum removal capacity of Fe(II) was calculated as 1,088 mg/kg.

• Journal of Environmental Impact Assessment
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• v.32 no.6
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• pp.431-436
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• 2023

As the industry develops, the amount of heavy metals flowing into the ecosystem is increasing. Heavy metals are difficult to decompose and remain in the ecosystem for a long time and cause toxicity, which is removed by physicochemical methods such as adsorption, filtration, and chemical precipitation during water treatment. In this study, Alginate bead was selected as a chelating resin for adsorbing and removing heavy metals, and the Jellyfish Extract at Immunity reaction (JEI) were mixed to evaluate the adsorption efficiency of heavy metals accordingly. beads mixed with JEI showed high adsorption efficiency in lead (79-99%) and copper (64-70%) according to the characteristics of Alginate, and low adsorption efficiency in cadmium (25-37%) and zinc (5-6%). Although heavy metal adsorption did not increase in proportion to the content of JEI, 50% and 100% JEI beads showed significant increases. As a result of applying the reaction rate equation, it was found that it was more suitable for the pseudo-secondary reaction equation than the pseudo-first reaction equation.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.292-295
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• 2005

본 연구는 지하유류저장공동 굴착 시 비교적 정밀하게 해석된 단열체계 및 수리인자를 토대로 투수성구조영역과 수리암반영역으로 세분화하여 연구지역의 불규칙하고 복잡한 지하수유동체계를 해석해 보고자 하였다. FZ-2 구조대와 인접한 수리암반영역 Domain-A와 B는 Domain-C와 D에 비해 수평수벽공의 초기압이 최대 약 $15kg/cm^2$정도 높으며, 상 하부의 수리적 연결성이 양호하여 지하공동굴착 시 상 하부의 수위차가 크지 않고 지하수 함양량은 약 $35{\sim}50mm/year$의 범위를 보인다. 또한 공동굴착 시 투수성 단열과의 교차에 의한 수위강하에 민감한 반응을 보이며 상 하부의 수위강하양상이 유사한 특성을 나타낸다. 반면, FZ-1 구조대와 인접한 Domain-C와 D는 지하공동 부근의 수리전도도가 각각 $7{\times}10^{-10},\;2{\times}10^{-9}m/sec$로 Domain-A와 B에 비해 최대 약 6배정도 낮고, 상 하부의 수리적 연결성이 양호하지 않기 때문에 공동굴착 전 이중수위측정시설 설치 시 계측된 상 하부의 수위차는 최대 약 120 m로 매우 크다. 그리고 상부의 지하수는 하부의 낮은 수리전도도로 인하여 수직방향보다 수평방향으로의 유동이 우세하며 공동굴착 시 수위변화는 크지 않고 함양량은 $10{\sim}15mm/year$의 범위를 나타낸다.

• Resources Recycling
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• v.20 no.6
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• pp.28-36
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• 2011

The adsorption of nickel(Ni) from sulfuric acid solution was carried out by ion exchange method. A series of batch tests in synthetic solutions were carried out using Lewatit Monoplus TP 220 resin. The following experimental parameters, such as temperature, shaking rate, reaction time, pH, resin dosage and concentration of nickel ions etc. were investigated to establish the effective optimum conditions of nickel adsorption. The solution pH(2.0~5.0) and shaking rate had little effects on the adsorption of nickel and adsorption time of 72hours was required to reach equilibrium. The experimental results show a good agreement with Feundlich isotherm and pseudo-second order reaction. The adsorption behavior of Ni obtained from synthetic solution was compared with that of waste electroplating solution. Elution of nickel from loaded resin increased with increase in $H_2SO_4$ concentration.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.2
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• pp.66-73
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• 2017

This study was to evaluate the influential parameters such as intial Cs concentration, reaction temperature, contact time and pH variation of solution on Cs adsorption. Using the experimental data, adsorption kinetics, isotherms and thermodynamic properties were analyzed. The Cs ion adsorption of the zeolite X was effective in the range from pH 5 to 10 and reached equilibrium after 60 minutes. The adsorption kinetics and isotherms of Cs ion with the zeolite X was described well by the pseudo-second-order kinetic and Langmuir isotherm model. The maximum adsorption capacities of Cs ion calculated from Langmuir isotherm model at 293~333 K were from 303.03 mg/g to 333.33 mg/g. It was found that thermodynamic property of Cs ion absorption on the zeolite X was spontaneous and endothermic reaction. The experimental data were fitted a second-order polynomial equation by the multiple regression analysis. The values of the dependent variable calculated by this best fitted model equation were in very good agreement with the experimentally obtained values.

• Korean Journal of Environmental Agriculture
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• v.8 no.2
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• pp.119-127
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• 1989

The minimum concentrations of nonionic and anionic surfactants inducing phytotoxicity were investigated after spraying or flooding surfactant solutions to annual plants. Of the sufactants tested, LE, NP, SPSS, LN, PAAS and DBC induced phytotoxicity at the lowest concentrations through all treatments and Tween, Span, SP, SC, STPP and CLIS induced the least phytotoxicity even at high concentration. At flooded paddy field tests, anionic surfactants induced phytotoxicity at the lower concentration than nonionic, but showed similar tendencies with other treatments. In pre-emergence treatments of upland and dry paddy field tests, there was little phytotoxicity induced at over 10 percent, while phytotoxicity was induced at the lowest concentration among 6 treatments in flooded paddy field tests.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.168-168
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• 2011

정보화 사회가 도래함으로 개인별 정보 이용량이 급격히 증가하였고 스마트폰과 같은 모바일 기기의 개발로 정보 이용량이 최고치를 갱신 중이다. 이러한 흐름 속에 사람들은 빠른 처리 속도와 고도의 저장 능력을 요구하게 되고 이에 따라 새로운 Random Access Memory에 대한 연구가 활발히 진행되고 있다. 현재 Dynamic Random Access Memory (DRAM)가 눈부신 발전과 성과를 이룩하고 있지만 전원 공급이 중단 될 경우 저장된 내용들이 지워진다는 단점을 가지고 있다. DRAM의 장점에 이러한 단점을 보완할 수 있는 차세대 반도체 소자로 주목 받고 있는 것이 Magnetic Random Access Memory (MRAM)이다. DRAM에서 Capacitor와 유사한 기능을 하는 MTJ stack은 tunneling magnetoresistance (TMR) 현상을 나타내는 자기저항 박막을 이용하여 MRAM 소자에 집적된다. 본 연구에서는 MRAM의 자성 재료로 구성된 MTJ stack을 효과적으로 식각하고 우수한 식각 profile을 얻는 동시에 재증착의 문제를 해결하는데 목적을 둔다. 본 IrMn 자성 박막의 식각 연구는 유도결합 플라즈마 반응성 이온 식각 (Inductively Coupled Plasma Reactive Ion Etching: ICPRIE)법을 이용하여 진행되었다. 특히 본 연구에서는 종래의 $Cl_2$, $BCl_3$ 그리고 HBr과 같은 부식성 가스가 아닌 부식성이 없는 $CH_4$가스를 선택하여 그 농도를 변화시키면서 식각하였고 더 나아가 $O_2$를 첨가하면서 그 효과를 극대화하려고 시도하였다. IrMn 자성 박막의 식각 속도, TiN 하드 마스크에 대한 식각 선택도 그리고 profile 등이 조사되었고 최종적으로 X-ray photoelectron spectroscopy (XPS)를 이용하여 식각 메카니즘을 이해하려고 하였다.

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.302-308
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• 2022

The PdO nanoparticle with large surface area was selected to solve the environmental pollution problem at fire range caused by high energy explosives research department explosive (RDX) and high melting explosive (HMX). By simulating water pollution, RDX and HMX nitramine explosives were dissolved in water, followed by the degradation reaction at 313 K by adding PdO. In order to measure the degradation reaction rate of explosives, ¹H NMR was used, which can monitor the reaction rate without losing sample during reaction, and observe the progress of the reaction through the spectrum. The results showed that the degradation of RDX and HMX by PdO nanoparticles are pseudo-first order reaction. The degradation of explosives compounds were observed via the chemical shift and peak intensity analysis of NMR peaks. The measured rate constants for these reactions of RDX and HMX were 2.10 × 10^-2 and 6.35 × 10^-4 h^-1, respectively. This study showed that the application of PdO nanoparticles for explosives degradation is a feasible option.

• Analytical Science and Technology
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• v.26 no.4
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• pp.228-234
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• 2013

Methamphetamine is an amine-containing illegal drug and is distributed unlawfully in South Korea. Finding a rapid, convenient and semi-quantitative determination method for methamphetamine is a very important issue in the area of forensic drug testing. As an effort to develop new screening method, the reactions between three organic compounds which are structurally similar to methamphetamine and N-(9-fluorenylmethoxycarbonyloxy) succinimide (FMOC-NHS) were performed on silica gel ($SiO_2$) TLC plates. Three reference compounds were synthesized and used for the identification, comparison and study of the limit of detection (LOD) of the products obtained from a direct reaction on a TLC plate. As a result, FMOC-NHS as a derivatization reagent generated compounds containing highly UV-active functional groups on the TLC plate after reacting with primary- and secondary amines. In the experiment 2D the LOD of amines was in the range of 0.045 and 0.01 mg/mL ($2{\mu}L/spot$), and in 1D the LOD was in the range of 0.002 and 0.007 mg/mL ($2{\mu}L/spot$). The LODs of the compounds tested were dependent on the concentration of the derivatizing reagent.