• Title/Summary/Keyword: 유량과 농도변화의 관계

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Mineral extraction from by-products of brown rice using electrodialysis and production of mineral salt containing lower sodium (전기투석을 이용한 현미부산물로부터의 미네랄성분 추출 및 나트륨감량형 미네랄 소금 제조)

  • No, Nam-Doo;Park, Eun-Jung;Kim, Mi-Lim
    • Food Science and Preservation
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    • v.22 no.6
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    • pp.859-866
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    • 2015
  • The purpose of this study was to develop a supplemental healthy food that can help prevent high blood pressure-related diseases caused due to the excessive consumption of sodium in salt. This was achieved by using ion-displacement techniques to produce mineral salt with lower sodium content by using fermented brown rice by-products rich in minerals. Mineral salt containing 2019.2 mg/100 g of potassium, 678.5 mg/100 g of magnesium, 48.7 mg/100 g of calcium, and 19.5 mg/100 g of sodium was obtained by fermenting brown rice by-products to create a culture medium for the mineral salt. Mineral salt containing 1769.7 mg/100 g of potassium, 573.6 mg/100 g of magnesium, 35.3 mg/100 g of calcium, and 19.5 mg/100 g of sodium was obtained by filtering and refining the by-product extract of fermented brown rice. The results showed that when the stream velocity of the instrument used for electrolysis was 200 mL/min and the current and the concentration of the reactive liquid in the purified water chamber were higher, the effect of electrolysis was greater. Ion hot water extraction of the fermented brown rice by-products improved by up to 95% and was collected as purified water within 90 min of the reaction time. Chloride ions with pH 7.4 were produced by mixing sodium hydroxide in a purified saline water chamber with electro-analyzed water. The salt produced in this study contained low sodium, 5.7~30%, as compared to 40% sodium content of the normal salt.

Experimental Study on the Characteristics of CO2 Capture with Spray Towers Using Ammonia Solution (암모니아수 흡수제를 사용하는 분무탑의 이산화탄소 포집 기본특성에 관한 실험적 연구)

  • Lim, Youngbok;Choi, Munkyoung;Lee, Jinwon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.2
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    • pp.165-172
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    • 2014
  • Experiments were conducted to identify basic characteristics of $CO_2$ capture using a spray tower with a single nozzle. Results were evaluated in terms of $CO_2$ saturation which is the main determining factor of regeneration energy, and capture efficiency under various operating conditions. Changes in the capture efficiency under various conditions are well expressed as a monotone increasing function of the relative solvent $(NH_3):CO_2$ flow rate. Although changes in $CO_2$ saturation are also well described as a function of the $NH_3/CO_2$ flow rate ratio, these are expressed as a monotone decreasing function, in contrast with the increasing function of $CO_2$ efficiency. In recent research on the relationship between $CO_2$ saturation and capture efficiency, $CO_2$ saturation was found to decrease when capture efficiency increased. In conclusion, the results show that the amount of solvent used for achieving high capture efficiencies is excessive, as is the amount of regeneration energy needed.

Seasonal Variations of Nitrifying Bacteria in Agricultural Reservoir (농업용 저수지에서의 질화세균의 계절적인 변화)

  • Lee, Hee-Soon;Lee, Young-Ok
    • Korean Journal of Ecology and Environment
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    • v.35 no.3 s.99
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    • pp.152-159
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    • 2002
  • The seasonal variations of nitrifying bacterial population sampled from 3 sites in Moon-Chon reservoir were analyzed by in situ hybridization with fluorescently labeled rRNA-targeted oligonucleotide probes from August 2000 until July 2001. In addition, physico-chemical parameters such as temperature, pH, chi-a and DOC were measured to determine correlations between those factors and the size of nitrifying bacterial populations. Total bacterial numbers varied in the range of $0.8{\sim}1.5{\times}10^6\;cells/ml$ independent of sites and had the maximal values in March at all 3 stations. The ratio of eubacteria to total bacteria ranged from 44.9% to 79.5%, and the ratio of each nitrifying bacteria to eubacterial numbers reached only $1.0{\sim}7.4%$. The variations of ammonia-oxidizing bacteria ranged from $1.1{\times}10^4$ to $3.0{\times}10^4\;cells/ml$ without noticeable peak values whereas those of nitrite-oxidizing bacteria varied in $1.3{\sim}5.7{\times}10^4\;cells/ml$ with the increasing tendency in winter regardless of the sites. Moreover it was observed that the numbers of nitrite-oxidizing bacteria were higher than those of ammonia-oxidizing bacteria. Total bacterial numbers correlated with water temperature (r = 0.355, p<0.05) and DOC (r = 0.58G, p<0.01) positively whereas nitrite-oxidizing bacteria correlated with temperature (r = -0.416, p<0.05) and pH (r = -0.568, p = 0.001) negatively. In addition, DOC represented good correlations with eubacterial numbers (r = 0.448, p<0.01). These results indicate that temperature, DOC and pH might be one of the main factors affecting variations of bacterial populations in the aquatic ecosystem. It was also suggested that FISH method is a useful tool for detection of slow growing nitrifying bacteria.

Adsorption Analysis of Benzene Vapor in a Fixed-Bed of Granular Activated Carbon (활성탄 충전층에서 벤젠 증기의 흡착특성)

  • Kim, Seong-Soo;Kim, Jong-Hyun;Park, Sang-Wook
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.495-500
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    • 2009
  • Activated carbon was used as an adsorbent to capture benzene vapor from gaseous stream of nitrogen in a fixed-bed to obtain the breakthrough data. The deactivation model is used to analyze the adsorption kinetics of benzene vapor using the experimental breakthrough data. The experimental breakthrough data are fitted very well to the deactivation model than the adsorption isotherm models in the literature.

Algal Bioassay for the Treated and Raw Wastewater in the Kyongan Stream (경안천에서 하수처리수와 생하수에 대한 algal bioassay)

  • Lee, Ok-Hee;Hwang, Soon-Jin;Cho, Kyung-Je;Shin, Jae-Ki
    • Korean Journal of Ecology and Environment
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    • v.34 no.3 s.95
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    • pp.192-198
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    • 2001
  • The Kyongan Stream and the inlet part of Paltang Reservoir are under significant influence of the effluent of sewage wastewater treatment plant (SWTP) and untreated domestic wastewater (DOW). The fertility of wastewater was evaluated through bioassay using natural phytoplankton population diluted in five levels. The concentrations of $NH_4$, SRP and SRSi were positively correlated with the biomass of phytoplankton. P concentration showed stronger correlation (r = 0.959, p<0.001)than other nutrients. Compared with the initial concentrations, $NH_4$ concentrations in samples from SWTP and DOW decreased 96% and 7%, respectively during the cultivation, and those of SRSi decreased 97% and 60%. However, $NO_3$ concentrations in samples neither showed any particular change nor any increase. Chl-a concentration ranged between $20\;{\mu}g/l$ and $125\;{\mu}g/l$, which maximum value increased up to 83 times. Estimated from the relationship between chl-a and SRP, the P concentration that can maintain the biomass of algae under mesotrophic state (<25\;{mu}g$\;chl-a/l$) was $83\;{mu}g\; P/l$. The volume of flow to maintain this level solely by natural dilution was about $16{\sim}25$ times of in flowing volume in the stream. However, it is not feasible to tap water of such quantity. Therefore, it is imperative to build an advanced sewage wastewater treatment facility that can reduce $NH_4$ and SRP concentrations that promote the growth of phytoplankton in discharged water.

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Effect of Major Tributaries Water Quality Improvement in the Geum River Area, Korea using EFDC Model (EFDC 모델을 이용한 금강 주요 지류의 수질개선 효과)

  • Kim, Jin soo;Kim, Ja young;Seo, Dong il
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.266-266
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    • 2019
  • 금강의 주요 지류인 미호천과 갑천은 대전광역시와 청주시가 위치하고 있으며, 두 도시지역에서 유입되는 오염물질로 인하여 금강 본류에 높은 오염부하를 제공하고 있다. 따라서 본 연구에서는 3차원 수리동역학 모델인 EFDC 모델을 사용하여 미호천과 갑천의 수질개선이 금강의 수질에 미치는 효과를 분석하였다. 대상유역은 대청댐부터 백제보 까지 70km 구간이며, 모델의 격자는 Curvilinear-Orthogonal Coordinate를 사용하였으며 횡단방향 8개로 분할하여 총 6,698개의 격자로 구성하였다. 경계조건구성 및 모델의 보정은 국가정보 포털인 수자원관리종합정보시스템(WAMIS), 물환경정보시스템(WEIS), 국가기후데이터센터(data,kma,go,kr) 등에서 제공하는 유량, 수질, 기상 등 데이터를 활용하였으며, 모의 기간은 2017년이다. 수질의 보정은 대상유역 내 6곳의 수질 측정 지점에서 수행되었으며, 적합성 평가를 위해 R-square와 NSE(Nash-Sutcliffe Efficiency) 두 가지의 통계 지표를 활용하였다. 수질의 경우 TN, TP, TOC, Chl-a 순으로 평균 R-square값은 0.75, 0.51, 0.36, 0.57이고 평균 NSE (Nash-Sutcliffe Efficiency)값은 0.59, -0.18, -1.10, 0.27으로 모의 값과 실측값 사이의 상관관계는 TN에서 가장 높았으며 반대로 TOC는 가장 낮았다. 모의결과가 실측값을 정확히 반영하지는 못했지만, 수질의 평균적인 현상은 반영한 것으로 판단된다. 두 주요 지류의 수질이 동시에 15% 또는 30% 개선되었을 경우를 모의하여 금강 본류의 수질변화를 6곳의 수질 측정 지점에서의 실측값과 비교하여 분석하였다. 두 지류가 동시에 15%의 수질 개선 시에는 금강 본류 수질은 TN, TP, TOC, Chl-a 순으로 평균 11.80%, 7.90%, 8.63%, 7.04%의 개선되었으며, 30% 수질 개선 시에는 평균 23.66%, 15.92%, 17.36%, 14.26%의 개선되었다. 각 지점에서 고른 개선이 확인되었으며, 개선 효과는 TN이 가장 컸고, 반대로 Chl-a가 가장 적었다. 갑천과 미호천의 수질이 별개로 개선되었을 경우를 모의한 결과, 미호천의 개선이 갑천에 비해 금강의 수질 개선에 영향이 컸다. 이는 두 지류의 수질 농도는 비슷하나 갑천에 비해 유량이 많은 미호천의 오염 부하량이 높은 것으로 분석된다. 연구 결과 금강의 수질을 개선하기 위해서는 두 지류의 수질 개선이 필수적인 것으로 판단된다. 금강의 TN 농도는 두 지류의 영향이 가장 컸으며, 개선 효과는 Chl-a에서 가장 적었다. 또한 갑천에 비해 미호천이 금강 수질에 영향이 큼을 확인하였다.

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Water Ouantity/Quality Analysis and Pollutants Load Estimation in Sillicheon River, Jumunjin, Gangneung (강릉 신리천의 수량 수질 분석 및 오염부하량 추정)

  • Cho Hong Yeon;Kim Chang Il;Lee Dal Soo
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.16 no.4
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    • pp.196-205
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    • 2004
  • Water qualities (WQ) were measured biweekly from April 2nd to October 29th, 2003 in Sillicheon flowing into the entrance of Jumunjin Harbour and daily water quantities (river discharges) were estimated by the TANK model which has been widely used to compute the runoff discharges in the ungauged watersheds. The spatial and temporal change patterns of the measured WQs were analysed in detail and the correlation between rainfall - WQ and river discharge - WQ were also analysed. From this results, it is found that the correlation coefficient between BOD concentration and rainfall is 0.75 and between the SS concentration and 2-days river discharge is 0.36. The correlation between the COD, TN, TP in the station of Silli Lower Bridge and rainfall runoff quantity was analysed as un-correlated items. As a consequence, the estimated BOD and SS pollutants loads are reliable and show good change patterns even though the accuracy of SS pollutants load is slightly low. The estimated COD, TN and TP pollutants loads, however, can be used only as the reference or averaged values. In order to analyse more accurately the temporal change patterns of these items, more-detailed researches considering the artificial effects and landuse patterns are highly required.

Patterning Zooplankton Dynamics in the Regulated Nakdong River by Means of the Self-Organizing Map (자가조직화 지도 방법을 이용한 조절된 낙동강 내 동물플랑크톤 역동성의 모형화)

  • Kim, Dong-Kyun;Joo, Gea-Jae;Jeong, Kwang-Seuk;Chang, Kwang-Hyson;Kim, Hyun-Woo
    • Korean Journal of Ecology and Environment
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    • v.39 no.1 s.115
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    • pp.52-61
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    • 2006
  • The aim of this study was to analyze the seasonal patterns of zooplankton community dynamics in the lower Nakdong River (Mulgum, RK; river kilometer; 27 km from the estuarine barrage), with a Self-Organizing Map (SOM) based on weekly sampled data collected over ten years(1994 ${\sim}$ 2003). It is well known that zooplankton groups had important role in the food web of freshwater ecosystems, however, less attention has been paid to this group compared with other community constituents. A non-linear patterning algorithm of the SOM was applied to discover the relationship among river environments and zooplankton community dynamics. Limnological variables (water temperature, dissolved oxygen, pH , Secchi transparency, turbidity, chlorophyll a, discharge, etc.) were taken into account to implement patterning seasonal changes of zooplankton community structures (consisting of rotifers, cladocerans and copepods). The trained SOM model allocated zooplankton on the map plane with limnological parameters. Three zooplankton groups had high similarities to one another in their changing seasonal patterns, Among the limnological variables, water temporature was highly related to the zooplankton community dynamics (especially for cladocerans). The SOM model illustrated the suppression of zooplankton due to the increased river discharge, particularly in summer. Chlorophyll a concentrations were separated from zooplankton data set on the map plane, which would intimate the herbivorous activity of dominant grazers. This study introduces the zooplankton dynamics associated with limnological parameters using a nonlinear method, and the information will be useful for managing the river ecosystem, with respect to the food web interactions.

Variation of Liquid to Gas Ratio and Sulfur Oxide Emission Concentrations in Desulfurization Absorber with Coal-fired Thermal Power Plant Outputs (석탄화력 발전설비의 출력에 따른 탈황 흡수탑 액기비와 황산화물 배출농도 변화에 대한 연구)

  • Kim, Kee-Yeong;Moon, Seung-Jae
    • Plant Journal
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    • v.14 no.4
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    • pp.39-47
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    • 2018
  • In this research, when the output of the standard coal-fired thermal power plant operating continuously at the rated output of 500 MW is changed to operate at 300 to 500 MW, the amount of sulfur oxide produced and the amount of sulfur oxide in the absorption tower of desulfurization equipment and proposed an extra liquid to gas ratio improvement inversely proportional to the output. In order to calibrate the combustion efficiency at low power, the ratio of sulfur oxides relative to the amount of combustion gas is increased as the excess air ratio is increased. When the concentration of sulfur oxide at the inlet of the desulfurization absorber was changed from 300 to 500 ppm along with the output fluctuation. The liquid to gas ratio of limestone slurry and combustion gas was changed from 10.99 to 16.27. Therefore, if the concentration of sulfur oxides with output of 300 MW is x, The following correlation equation is recommended for the minimum required flow rate of slurry for the reduction of surplus energy due to the increase of the liquid weight at low load. $y1[m^3/sec]=0.11x+3.74$

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ILLUDAS-NPS Model for Water Quality in Urban drainage (도시유역의 수질해석을 위한 ILLUDAS-NPS 모형)

  • Kim Tae-Hwa;Lee Jong-Tae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.482-486
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    • 2005
  • 불투수지역의 증가에 따른 도시지역의 비점오염원 해석 및 예측은 수자원 관리측면에서 중요성이 증가하고 있다. 그러나, 실측자료의 부족, 오염물질 발생경로의 불명확, 간헐성, 강우 및 유역특성에 따라 오염부하량 및 첨두농도 등의 변화가 심하므로 인하여 연구에 어려움이 많은 실정이다. 이를 극복하기 위해서는 장기적인 자료수집과 국내실정에 맞는 모형개발이 이루어져야 할 것이다. 따라서, 본 연구에서는 초기강우에 의한 수질항목별 오염부하량 및 농도계산이 가능한 ILLUDAS-NPS 모형을 개발하였다. 본 모형은 국내의 도시지역 유출해석에 주로 사용되는 ILLUDAS 모형에 건기 및 우기시의 수질해석 과정들을 추가하여 해석되어 진다. 건기시의 경우 유량 및 수질 계산은 계수지정법을 사용하였으며, 우기시의 경우 유량계산은 기존 ILLUDAS 모형의 알고리즘을 이용하였고, 수질 계산은 일일 오염물 축적법과 쓸림방정식을 적용하여 계산시간별 오염물질 부하량 및 농도 등을 계산하였다. 모형의 검정을 위하여 홍제천 시험유역의 총 3가지 강우사상을 대상으로 검토한 결과 총부하량, 첨두농도, 첨두농도 발생시간 등에서 전반적으로 실측치와 유사한 결과를 얻을 수 있었다. 또한, ILLUDAS-NPS 모형과 SWMM, STORM 등의 기존 도시유출$\cdot$수질 모형들에 의한 결과들의 비교에서 SWMM 모형과 다소의 차이는 있으나 대부분 잘 일치함을 확인할 수 있었다. 추후, 합리적이고 보다 정확한 비점오염 해석을 위하여 도시지역의 건거시 오염물질의 축적율 및 초기강우에 의한 오염물질 쓸림량 등에 관한 실험 및 현장자료 축적이 필요하다.월이 긴 것으로 나타났다. 이러한 현상은 유입수가 저수지로 유입되면서 초기수위가 높은 경우에 운동량이 상대적으로 많이 소멸되기 때문으로 판단된다. 또한 탁수층의 두께도 8월 성층의 경우가 상대적으로 큰 것으로 나타났다. 이는 중층의 8월 수온분포 또는 밀도분포가 상대적으로 균일하기 때문에 연직방향 이송$\cdot$확산이 많이 이루어졌기 때문으로 판단된다.이는 토성간의 침투속도 및 투수속도의 경향이 반영된 것이다. 경사에 따라서는 경사도가 증가할수록 지수적으로 감소하였으며 $10\% 경사일 때를 기준으로 $I(mm)=I_{10}{\times}1.17{\times}e^{-0.0164s(\%)}$로 나타났다. 같은 조건에서 강우량과 유거수의 관계는 $Ro_{10}(mm)=5.32e^{0.11R(mm)}(r^2=0.69)$로 나타났다. 이는 토양의 투수특성에 따라 강우량 증가에 비례하여 점증하는 침투수와 구분되는 현상이었다. 경사와 토양이 같은 조건에서 나지의 경우 역시 $Ro_{B10}(mm)=20.3e^{0.08R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는 경사도가 증가할수록 증가하였으며 $10\% 경사일 때를 기준으로 $Ro(mm)=Ro_{10

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