• Title/Summary/Keyword: 유동 혼합 특성

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Characterization of Bio-oils Produced by Fluidized Bed Type Fast Pyrolysis of Woody Biomass (목질바이오매스의 급속열분해에 의해 생성된 바이오오일의 특성 분석)

  • Choi, Joon-Weon;Choi, Don-Ha;Cho, Tae-Su;Meier, Dietrich
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.6
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    • pp.36-43
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    • 2006
  • Using fluidized bed type fast pyrolysis system (capacity 400 g/h) bio-oils were produced from beech (Fagus sylvatica) and softwood mixture (spruce and larch, 50:50). The pyrolysis was performed for 1~2 s at the temperature of $470{\pm}5^{\circ}C$. Pyrolysis products consisted of liquid form of bio-oil, char and gases. In beech wood bio-oil was formed to ca. 60% based on dry biomass weight and the yield of bio-oil was 49% in soft wood mixture. The moisture contents in both bio-oils were ranged between 17% and 22% and the bio-oil's density was measured to $1.2kg/{\ell}$. Bio-oils were composed of 45% carbon, 47% oxygen, 7% hydrogen and lower than 1% nitrogen,which was very similar to those of original biomass. In comparison with oils from fossil resources, oxygen content was very high in bio-oils, while no sulfur was found. More than 90 low molecular weight components, classified to aromatic and non aromatic compounds, were identified in bio-oils by gas chromatographic analysis, which amounted to 31~33% based on the dry weight of bio-oils.

A development of new dielectric tracer test method for groundwater logging: laboratory soil column test (지하수 검층을 위한 새로운 유전율 추적자 시험법의 개발)

  • Kim Man-Il;Kim Hyoung-Soo;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.14 no.3 s.40
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    • pp.301-311
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    • 2004
  • This study is suggested a new dielectric tracer test method to understand geological structure of porous media and groundwater flow to use the dielectric constant which is one of electrical special quality of various geological materials. To measure their parameters, tracer material is made an ethanol mixing liquid(EML) having a same specific gravity of water. Also, soil materials are prepared a dielectric tracer test using the FDR system that could measure dielectric constant for saturated standard sand and river sand layers which have different initial porosity. To compare with their results, we discussed with the concentration variation of saline water having a saline concentration $3\%$ which is general tracer material by using the electro multi-meter system in the laboratory or field test. In two tracer experiment results, EML tracer test could confirm definitely EML concentration variation from each saturated soil layer as standard and river sands. However, tracer test of saline water $3\%$ concentration could not confirm permeating movement of water by degree of salinity change because these are settled at lower part column in a whole column area continuously. These causes are that specific gravity of saline water is heavier than water. That is, it could know that deposition of saline water is composed of lower part of soil column continuously independently of the direction of water into saturated soil material.

Improvement of Low-temperature Fluidity of Biodiesel from Vegetable Oils and Animal Fats Using Urea for Reduction of Total Saturated FAME (요소 이용 포화도 저감을 통한 동.식물성 바이오디젤의 저온유동성 개선)

  • Lee, Yong-Hwa;Kim, Kwang-Soo;Jang, Young-Seok;Shin, Jung-Ah;Lee, Ki-Teak;Choi, In-Hu
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.113-119
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    • 2014
  • The compositions of saturated and unsaturated fatty acids in biodiesel feedstocks are important factors for biodiesel properties including low-temperature fluidity and oxidative stability. This study was conducted to improve low-temperature fluidity of biodiesel by reducing total saturated FAME (fatty acid methyl ester) in animal fat biodiesel fuels via urea-based fractionation and by mixing plant biodiesel fuels (rapeseed-FAME, waste cooking oil-FAME, soybean-FAME, and camellia-FAME) with enriched-polyunsaturated FAME derived from animal fat biodiesel. Our results showed that the reduction of total saturated FAME in animal fat biodiesel lowered CFPP (Cold Filter Plugging Point) to $-15^{\circ}C$. Mixing plant biodiesel fuels with the enriched-polyunsaturated FAME derived from animal fat biodiesel lowered CFPP of blended biodiesel fuels to $-10{\sim}-18^{\circ}C$.

A Fundamental Study of Ferro Copper Slag for Concrete Aggregate (동슬래그의 콘크리트용 골재 활용에 관한 기본연구)

  • Song, Tae-Hyeob;Lee, Mun-Hwan;Lee, Sea-Hyun
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.35-42
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    • 2003
  • To use ferro copper slag as aggregate in the construction, an evaluation upon the two kinds of ferro copper slag being produced was conducted to determine the basic physical, and mechanical properties, chemical component and environmental noxiousness. As a result of experiment, it was found that two kinds of ferro copper slag satisfies the physical and mechanical properties of aggregate, prescribed in KS F 2526, and that in the result of noxious heavy metal eruption test by single bach extraction, no eruption of noxious heavy metal was detected or the eruption was far below the reference value. And mortar test was conducted by replacing sand of 25, 50, 75, 100% and the performance level was presented upon reviewing the fluidity property and variable aspects of unit weight. The increase of strength in accordance with replacement rate of sand was found to be the below than the equivalent level compared to the testing specimens that did not use ferro copper slag, but those of 25% replacement rate was above than 0%. Thus, two kinds of ferro copper slag, produced in the domestic, were found to be possessing the enough physical properties to use as concrete aggregate assuming that used with sand and in particular, it was reviewed to be advantageous in manufacturing concrete or mortar that requires weight.

Perspective on Rapid and Selective Method for Detecting Microbiology in Dairy Industry: A Review (낙농산업에 필요한 미생물 검사방법과 전망: 총설)

  • Chon, Jung-Whan;Kim, Hyun-Sook;Kim, Hong-Seok;Kim, Dong-Hyeon;Song, Kwang-Young;Yim, Jin-Hyuk;Choi, Dasom;Lim, Jong-Soo;Jeong, Dong-Gwan;Kim, Soo-Ki;Seo, Kun-Ho
    • Journal of Dairy Science and Biotechnology
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    • v.33 no.2
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    • pp.119-127
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    • 2015
  • To date, detection of microbial populations in dairy products has been performed using culture media, which is a time-consuming and laborious method. The recently developed chromogenic media could be more rapid and specific than classical culture media. However, the newly developed molecular-based technology can detect microbial populations with greater rapidity and sensitivity than the classical method involving culture media and chromogenic media. This molecular-based technology could provide various options for monitoring the characterization of different states of bacteria and cells. Thus, it could help upgrade the processing system of the dairy industry so as to maintain the safety and quality of dairy foods. Among the various newly developed molecular-based technologies, flow cytometry can potentially be used for monitoring microbiological populations in the dairy industry if official international standards are available for this purpose. When omics technology would have biomarker identification, it could be regarded as the rapid and sensitive analytical methods. Methods based on PCR, which has become a basic technique in microbiological research, can be developed and validated as alternative methods for quantification of dairy microorganisms. This review discusses methods for monitoring microbiological populations in dairy foods and the limitations of these studies, as well as the need for further research on such methods in the dairy industry.

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Supercritical Water Oxidation of Anionic Exchange Resin (초임계수 산화를 이용한 음이온교환수지 분해)

  • Han, Joo-Hee;Han, Kee-Do;Do, Seung-Hoe;Kim, Kyeong-Sook;Son, Soon-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.549-557
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    • 2006
  • The characteristics of supercritical water oxidation have been studied to decompose the waste anionic exchange resins which were produced from a power plant. The waste resins from a power plant were mixture of anionic and cationic exchange resins. The waste anionic exchange resins had been separated from the waste resins using a solid-liquid fluidized bed. It was confirmed that the cationic exchange resins were not included in the separated anionic exchange resins by the elemental and thermogravimetric analysis. A slurry of anionic exchange resins which could be fed continuously to a supercritical water oxidation apparatus by a high pressure pump was prepared using a wet ball mill. Although the COD of liquid effluent had been reduced more than 99.9% at 25.0 MPa and $500^{\circ}C$ within 2 min, the total nitrogen content was reduced only 41%. The addition of nitric acid to the slurry could reduce the total nitrogen content in treated water. The central composite design as a statistical desist of experiments had been applied to optimize the conditions of decomposing anionic resin slurry by means of the COD and total nitrogen contents in treated waters as the key process output variables. The COD values of treated waters had been reduced sufficiently to $99.9{\sim}100%$ af the reaction conditions of $500{\sim}540^{\circ}C$, 25.0 MPa within 2 min. The effects of temperature and nitric acid concentration on COD were not significant. However, the effect of nitric acid concentration on the total nitrogen was found to be significant. The regression equation for the total nitrogen had been obtained with nitric acid concentration and the coefficient of determination($r^2$) was 95.8%.

The Engineering Properties of High Fluidity mortar with High Volume Slag Cement (고유동 대량치환 슬래그 모르타르의 공학적 특성)

  • Bae, Ju-Ryong;Kim, Tae-Wan;Kim, In-Tae;Kim, Min-Jeong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.12-20
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    • 2017
  • This report presents the results of an investigation on the fundamental properties of mortars high fluidity high volume slag cement(HVSC) activated with sodium silicate($Na_2SiO_3$). The ordinary Portland cement(OPC) was replaced by ground granulated blast furnace slag(GGBFS) from 40% to 80% and calcium sulfoaluminate(CSA) was 2.5% or 5.0% mass. The $Na_2SiO_3$ was added at 2% and 4% by total binder(OPC+GGBFS+CSA) weight. A constant water-to-binder ratio(w/b)=0.35 was used for all mixtures. The research carried out the mini slump, V-funnel, setting time, compressive strength and drying shrinkage. The experimental results showed that the contents of superplasticizer, V-funnel, setting time and drying shrinkage increased as the contents of CSA and $Na_2SiO_3$ increase. The compressive strength increases with and an increase in CSA and $Na_2SiO_3$. One of the major reason for these results is the accelerated reactivity of GGBFS with CSA and $Na_2SiO_3$. The maximum performance was CSA 5.0% + $Na_2SiO_3$ 4% specimens.

Characterization of Cement Waste Form for Final Disposal of Decommissioned Concrete Waste (해체 콘크리트 폐기물 최종처분을 위한 시멘트 고화체 특성 평가)

  • Lee, Yoon Ji;Hwang, Doo Seong;Lee, Ki Won;Jeong, Gyeong Hwan;Moon, Jei Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.271-280
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    • 2013
  • Since the decommissioning of nuclear plants and facilities, large quantities of slightly contaminated concrete waste have been generated. In Korea, the decontamination and decommissioning of the KRR-1, 2 at the KAERI have been under way. And concrete waste was generated about 800 drums of 200 L. The conditioning of concrete waste is needed for final disposal. The concrete waste is conditioned as follows: mortar using coarse and fine aggregates is filled void space after concrete rubble pre-placement into 200 L drum. Thus, this research has developed an optimizing mixing ratio of concrete waste, water, and cement and has evaluated characteristics of a cement waste form to meet the requirements specified in disposal site specific waste acceptance criteria. The results obtained from compressive strength test, leaching test, thermal cycling test of cement waste forms conclude that the concrete waste, water, and cement have been suggested to have 75:15:10wt% as the optimized mixing ratio. Also, the compressive strength of cement waste form was satisfied that including fine powder up to maximum 40wt% in concrete debris wastes about 75%. As a result of scale-up test, the mixture of concrete waste, water, and cement is 75:10:15wt% meet the satisfied compressive strength because the free water increased with and increased in particle size.

Enhancement of the Life of Refractories through the Operational Experience of Plasma Torch Melter (플라즈마토치 용융로 운전경험을 통한 내화물 수명 증진 방안)

  • Moon, Young Pyo;Choi, Jang Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.2
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    • pp.169-178
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    • 2016
  • The properties of wastes for melting need to be considered to minimize the maintenance of refractory and to discharge the molten slags smoothly from a plasma torch melter. When the nonflammable wastes from nuclear facilities such as concrete debris, glass, sand, etc., are melted, they become acid slags with low basicity since the chemical composition has much more acid oxides than basic oxides. A molten slag does not have good characteristics of discharge and is mainly responsible for the refractory erosion due to its low liquidity. In case of a stationary plasma torch melter with a slant tapping port on the wall, a fixed amount of molten slags remains inside of tapping hole as well as the melter inside after tapping out. Nonmetallic slags keep the temperature higher than melting point of metal because metallic slags located on the bottom of melter by specific gravity difference are simultaneously melted when dual mode plasma torch operates in transferred mode. In order to minimize the refractory erosion, the compatible refractories are selected considering the temperature inside the melter and the melting behavior of slags whether to contact or noncontact with molten slags. An acidic refractory shall not be installed in adjacent to a basic refractory for the resistibility against corrosion.

Variations of Complex Permittivity due to Water Content and Heavy Metal Contamination (함수비와 중금속 오염도에 따른 유전상수의 변화)

  • Oh Myoun-Hak;Kim Yong-Sung;Yoo Dong-Ju;Park Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.21 no.5
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    • pp.231-241
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    • 2005
  • Laboratory experiments were performed to examine the effects of water content and to see if permittivity had sufficient sensitivity to identify subsurface contamination. Both real and imaginary permittivities of unsaturated sand were strongly governed by the volumetric water content. Especially, a linear relationship between real permittivity and volumetric water content was derived at high frequencies (MHz ranges). Heavy metals in pore fluid result in significant increases in the effective imaginary permittivity, due to ionic conduction, but decreases in the real permittivity arises due to the decreased orientational polarization of water molecules caused by hydration of ions. Clear increase in the effective imaginary permittivity with heavy metal concentration was found to be valuable in the application of electrical methods for detecting heavy metals in the subsurface. However, because the permittivity is primarily dependent on the volumetric water content of soil, pre-evaluation on the volumetric water content is required.