• Title/Summary/Keyword: 유기물 분석

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Experimental Study of the mechanism of methane generation under various organic conditions on Lake or Reservoir (호소 환경 조건에 따른 메탄 발생 기작 정량화 실험 연구)

  • Bang, Young Jun;Lee, Sung Woo;Kim, Dong Hyun;Lee, Seong Oh
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.173-173
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    • 2022
  • 유기 퇴적 오염물은 다양한 형태로 호소 바닥에 축적되어 호소 환경 및 생태계에 악영향을 미치고 있으며 메탄가스와 같은 온실가스의 발생을 유발한다. 또한, 수력 산업, 관개, 이·치수 등 다양한 목적에 의해 수체의 형성이 활발하게 이루어지면서 하천 및 호소에 의한 탄소유출을 전지구적 탄소순환에 적극적으로 포함시켜야 한다는 필요성이 증가하고 있다. 따라서 하천 및 호소에서 발생하는 다양한 생지화학적 반응에 의한 메탄 발생 메커니즘 파악은 유역의 중요한 환경평가 지표를 나타내며 탄소 순환을 이해하는데 매우 중요하다. 수온, 수심, 유기물 조건에 따른 하천 및 호소의 메탄 발생을 분석한 연구들이 선행되었으나 생지화학적 특성을 정리하고 이에 따른메탄 발생을 정량화한 연구들은 거의 없는 상황이다. 본 연구는 호소 내 메탄을 발생시키는 기작을 판별하기 위해 수온과 호소 환경과 유사한 TOC(총유기탄소)와 TP(총인) 조건과 같은 유기물 조건을 설정하여 BMP Test를 수행하였다. 반응수조에서 발생한 가스를 포집한 후 GC(Gas Chromatograpghy) 분석을 통해 메탄 생성량을 산출하였고, 유기물 조건에 따라 이론적인 메탄 생성량 대비 실제 발생한 메탄 생성량을 나타내는 생분해도를 산출하여 호소 환경별 주요 기작에 따른 가스 발생을 정량화 하였다. 실험 결과 수온에 가장 큰 영향을 받았으며, 수온에 따라 TP, TOC 순으로 메탄 발생의 영향성을 확인하였다. 향후에는 호소 환경에서의 유기물 조건을 반영하기 위해 입도비, 점착성/ 비점착성 조건, 수체의 높이 조건을 포함한 추가 실험을 수행하고 메탄수율을 정량화하여 호소 내 유기퇴적물에 대한 생지화학적 및 수환경 영향 평가 기법 개발이 가능할 것으로 기대한다.

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Properties of Organically Practiced Paddy Soils (유기농 실천 논토양의 이화학적 특성)

  • Hong, Seung-Gil;Park, Kwang-Lai;Kim, Jinho;Ahn, Minsil;Lee, Chorong;Kim, Min-Gi;Kim, Seok-Cheol
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.69-76
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    • 2016
  • To produce the primary data for best management of soil nutrient in organically practiced soils, 75 leading organic farms whose paddy fields were certified as organic were selected. Soil samples were collected from the paddy fields before plowing, and then analyzed for the determination of physico-chemical properties. Soil pH, organic matter and available phosphate were analyzed and averaged 6.2, $25.6mg\;kg^{-1}$ and $88.4mg\;kg^{-1}$, respectively. Contrary to the national-scale-surveyed paddy soils including organic and conventional farming, pH was higher, available phosphate was lower in the organically practiced soils, but organic matter was similar. With the increasing cultivation period in organic, soil pH and porosity were also increased, EC, available phosphate, bulk density and soil hardness were lower than those from the national survey. Organic matter, however, was not significantly changed. The bulk density was negatively correlated with the organic matter content for both surface topsoil ($R^2=-0.5424$) and subsoil ($R^2=-0.6429$) (p<0.05). Soil quality is improved in most of soil chemical and physical composition factors excluding organic matter and available phosphate. However, it is necessary to establish the counter measure plan for organic matter management and to develop phosphate-containing materials which can be used as organic agricultural material in the future.

Determination of the Origin of Particulate Organic Matter at the Lake Paldang using Stable Isotope Ratios (${\delta}^{13}C$, ${\delta}^{15}N$) (입자성 유기물의 안정동위원소비를 이용한 팔당호 수계내의 유기물 기원 연구)

  • Kim, Min-Seob;Kim, Jong-Min;Hwang, Jong-Yeon;Kim, Bo-Kyong;Cho, Hang-Soo;Youn, Seok Jea;Hong, Suk-Young;Kwon, Oh-Sang;Lee, Won-Seok
    • Korean Journal of Ecology and Environment
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    • v.47 no.2
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    • pp.127-134
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    • 2014
  • Organic carbon and nitrogen stable isotope ratios of particulate organic matter (POM) were determined at 7 stations (6 stations in Han river and Paldang dam outflow station) from May to October 2013, in order to understand the origin of POM at the Han river. ${\delta}^{13}C$ values of POM in four stations showed significant seasonal changes season, but ${\delta}^{15}N$ values were enriched in around Kyeongan stream (K). POC, PN and Chl-a concentration showed a similar seasonal pattern in Kyeongan stream, with an apparent decrease from July to August. POC and PN concentration has a higher correlation with Chl-a concentration in Kyeongan stream (K). ${\delta}^{13}C$ and ${\delta}^{15}N$ values of POM has a lighter value during lower Chl-a concentration peroid, compared to other seasons. Our results revealed that Kyeongan stream (K) seemed to be influenced by substantial amount of organic manure or fertilizer input in 2013, compared to the previous year (2012). These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the identification of organic matter origin in aquatic environments.

Development of Eco-friendly Combustion Process for Waste 2,4,6-trinitrotoluene (폐 2,4,6-trinitrotoluene의 환경 친화적 연소처리공정 개발)

  • Kim, Tae Ho;An, Il Ho;Kim, Jong Min
    • Clean Technology
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    • v.27 no.3
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    • pp.247-254
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    • 2021
  • In this study, an eco-friendly combustion process of waste 2,4,6-trinitrotoluene (TNT: 2,4,6-trinitrotoluene) was developed, and fundamental data for the quantity of the organic matter in the final combustion residues is presented. Because complete combustion of TNT is not possible theoretically, the combustion process was optimized to reduce organic matter content in the combustion residue by performing measures such as heating time changes, addition of propellant material, and after treatment using a high-temp electrical furnace. From the results, it was confirmed that the organic matter content in the residue could be decreased to 7 ~ 10% with each method. The quantity of the organic matter could be minimized by optimizing the combustion conditions of the process. With only a combustion time increase, the amount of organic matter in the combustion residues was measured at about 9 wt%. The environmental friendliness of the final exhaust gas was also confirmed by real time gas component analyses. In addition, the organic contents could be reduced by a further 2 wt% by applying an additional heat treatment using an external electric furnace after the first incineration treatment. In the combustion process of propellant added waste TNT, it was found that various TNT wastes could be treated using the same eco-friendly protocols because the organic content in the residue decreased in accordance with the amount of propellant. The amount of the organic matter content produced by all these methods fulfilled the requirements under the Waste Management Act.

Geochemical Results and Implication of the Organic Matter in the Holocene Sediments from the Hupo Basin (후포분지 홀로세 퇴적물의 유기물에 대한 지화학 분석 결과 및 의미)

  • Kim, Ji-Hoon;Park, Myong-Ho;Kong, Gee-Soo;Han, Hyun-Chul;Cheong, Tae-Jin;Choi, Ji-Young;Kim, Jin-Ho;Kang, Moo-Hee;Lee, Chi-Won;Oh, Jae-Ho
    • Economic and Environmental Geology
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    • v.43 no.1
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    • pp.1-12
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    • 2010
  • Geochemical approaches on the two recovered piston cores were performed to understand the characteristics of organic matters and the influence of the sea level variation of the East Sea in the Hupo Basin since the Holocene. The analyzing results on organic components (TOC and TN), and isotopic compositions of organic matters showed the variation to core locations and sampling depths. In core 08HZP-01, their values were gradually changed with depth from 4 mbsf to seafloor. However, rapid variation was observed at the boundary of 4.71 mbsf (meter below seafloor) in core 08HZP-03. Based on TOC/TN, $\delta^{13}C_{org}$ and $\delta^{15}N_{org}$, the origin of organic matters in the Hupo Basin can be divided into three groups; 1) predominant marine algae, 2) $C_3$ land plant, and 3) mixture of $C_3$ land plant and marine/freshwater algae. It is likely that the vertical and spatial variations of organic and isotopic compositions reflect the shifts in sedimentary environment (including sediment transportation) by ocean currents and sea-level changes and others during the Holocene period.

Inhibiting Floral Induction of Angelica gigas NAKAI in the Hilly Altitude Area (중.산간지대에서 참당귀의 화성억제 연구)

  • 이승필;조지형;민기군;권태용;최장수;박노권;최부술
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.1
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    • pp.1-8
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    • 1995
  • This study was carried out to investigate the effects of floral inhibition of An-gelica gigas NAKAI in the hilly altitude located in the Northern Gyeongbuk Province from Feb. 1992 to Nov. 1994. The results obtained were as follows : As the cultivated areas are high, rate of bolting was significantly decreased, having high yield, good growth, and medicinal quality. It is considered that the optimal cultivating area was at least above 600m altitude. In the hilly altitude, the more shorten nursery period was, the more decreased rate of bolting was, it results in decreased yield, having no significant differences in contents such as extracts and decursin. In bolting response from temperature treatment of the seedlings, treatment of high temperature was significantly decreased floral induction, but rate of establishment was decreased by decayed root. Bolting rate at different organic resources has more reduced in single fertilization than that of in organic application, but among organic resources, compost of rice straw has the lowest bolting rate. As a result, yield and medicinal qualities at various organic resources were increased in application of organic resources which was no con-siderable tendency among organic resources.

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Study on Organic Material Used in Bioreactor for the Treatment of Acid Mine Drainage (산성 광산 폐수 처리용 생물반응기에 사용되는 유기물의 연구)

  • 김경호;나현준;이성택
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.45-50
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    • 1997
  • The change of industrial structure has brought the sharp declination of mine products, and has made many mines closed, which results in environmental pollution by untreated acid mine drainage(AMD). AMD with low pH and high concentration of heavy metals could severely destroy the ecosystem. Many researches have been carried out for the treatment of AMD. In this study, we have treated AMD with oak compost, mushroom compost, sludge cake and cow manure which usually used in AMD treatment systems, and compared the capability of each organic matter. Cow manure and oak compost have been most effective among 4 organic materials. Oak compost removed the heavy metals by ion exchange between Ca-rich particles and soluble heavy metal ions. It also captured the heavy metals using bound functional groups like -OH and -COO-. Sulfate reducing bacteria existing in the cow manure removed effectively heavy metals by producing metal sulfide compound. Therefore, it is effective to use both organic materials in mixture on the treatment of AMD.

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Modeling Fate and Transport of Organic and Nitrogen Species in Soil Aquifer Treatment-(I) Model Development and Verification (토양/대수층 처리(soil aquifer treatment)에서 유기물과 질소화합물 제거와 이송 모델링-(I) 모델 개발 및 검증)

  • Kim Jung-Woo;Kim Jeong-Kon;Cha Woo-Suk;Choi Hee-Chul
    • Journal of Soil and Groundwater Environment
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    • v.10 no.3
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    • pp.9-15
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    • 2005
  • Soil aquifer treatment is a water reuse technology that secondary or tertiary treated wastewater is infiltrated into the aquifer in which physical and biochemical reactions occur. Major consideration in SAT is the removal and transport of DOC and nitrogen species. In this study, reaction mechanism in SAT was examined considering nitrification, denitrification and organic oxidation. In addition, SAT modeling system was developed as the reaction mechanism was applied to groundwater flow and transport model. In verification of the reaction module by 1-dimensional unsaturated soil column test, the experimental data of all of the species, ammonium, nitrate, DOC and DO, were well matched with the simulation results. In sensitivity analysis, ammonium partition coefficient, dissolved oxygen inhibition constant and biomass decay rate affect ammonium, DOC and DO concentration of effluent, respectively.

Pollution of Agricultural Environment I. Adsorption of Several Herbicide on Soils and Theoretical Evaluation (농업환경(農業環境)의 오염(汚染)과 그 대책(對策) 제(第) 1 보(報) 몇가지 제초제(除草劑)에 의한 토양(土壤) 흡착(吸着)의 이론적분석(理論的分析))

  • Han, Dae-Sung;Kim, Jeong-Je;Shin, Young-Oh
    • Korean Journal of Environmental Agriculture
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    • v.3 no.1
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    • pp.22-29
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    • 1984
  • The Freundlich-type adsorption isotherms were obtained in this study on the adsorption of linuron, bentazon, trifluralin and butachlor by soils. A strong correlation was shown between soil organic matter content and the adsorption of linuron. Soils with high organic matter content adsorbed more linuron. There was no significant correlation between the adsorption of bentazon and clay content. There was a tendency that increase in organic matter content acts against the adsorption of bentazon. Repulsive forces seemed to exist between negatively charged soil particle surfaces and betazon molecules which become weakly charged negative ions in soil solution. Organic matter content and cation exchange capacity appeared to be enhancing the adsorption of trifluralin and butachlor. Clay content was not significantly correlated with the adsorption of these herbicides. Trifluralin was adsorptive to the greatest extent, followed by linuron and butachlor, bentazon being the least.

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Correlation between Leakage Current of Organic Treated Insulators and Grain Size of Pentacene Deposited film (유기물 처리 절연막의 누설전류 및 펜타센 증착 표면에 생긴 그레인 크기 사이의 상관관계)

  • Oh Teresa;Kim Hong-Bae;Son Jae-Gu
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.6 s.348
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    • pp.18-22
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    • 2006
  • The inspection of surface properties under n-octadecyltrichlorosilane treated $SiO_2$ film was carried out by current-voltage characteristic and the scanning electron microscope. The voltage at zero current in low electric field is the lowest at 0.3 % OTS treated $SiO_2$ film with hybrid type. $SiO_2$ films changed from inorganic to hybrid or organic properties according to the increase of OTS content. OTS treated $SiO_2$ films with hybrid properties decreased the leakage currents, and the grain size of pentacene deposited sample was also the most small at the hybrid properties. The perpendicular generation of pentacene molecular was related with the surface of insulators. The surface with hybrid properties decreased the grain size, but that with inorganic or organic properties increased the grain size.