• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.11
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• pp.1345-1352
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• 2012

This paper aims to evaluate the low-velocity impact responses and mechanical properties of balsa-wood and urethane-foam core materials and their sandwich panels, which are applied as the impact limiter of a nuclear spent fuel shipping cask. For the urethane-foam core, which is isotropic, tensile, compressive, and shear mechanical tests were conducted. For the balsa-wood core, which is orthotropic and shows different material properties in different orthogonal directions, nine mechanical properties were determined. The impact test specimens for the core material and their sandwich panel were subjected to low-velocity impact loads using an instrumented testing machine at impact energy levels of 1, 3, and 5 J. The experimental results showed that both the urethane-foam and the balsa-wood core except in the growth direction (z-direction) had a similar impact response for the energy absorbing capacity, contact force, and indentation. Furthermore, it was found that the urethane-foam core was suitable as an impact limiter material owing to its resistance to fire and low cost, and the balsa-wood core could also be strongly considered as an impact limiter material for a lightweight nuclear spent fuel shipping cask.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.5
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• pp.2524-2528
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• 2013

Cell opening characteristics dependent on the cell openers for the conventional formulation of a closed-cell polyurethane foam (PUF) was studied using 1-butanol and lithium salt of 12-hydroxystearic acid (Li-12HSA) as the reactive cell opening agents. While cell openining content of only 10.5 % was obtained for the sample with 4 phr of 1-butanol as the single reactive cell opener, that of 98.0% could be obtained for the sample with 2 phr of Li-12HSA as the reactive co-cell opener. As the results, it showed that a fully open-cell rigid PUF could be obtained by introducing a novel reactive cell opener, having a functional group able to form a bulky side-chain on the urethane networks, without severe loss of mechanical properties of the closed-cell PUF like cell size, bulk density, and thermal conductivity.

• Economic and Environmental Geology
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• v.53 no.3
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• pp.287-296
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• 2020

Mine Reclamation Project is being carried out with the aim of ensuring a sustainable green living and helping to develop eco-friendly mines by analyzing, removing and preventing the harmful factors. Mines developed during the japanese colonial period and mining boom period are still not repaired throughout the country, and from these scattered risks, public safety is worth pursuing as a top priority. The project that is close to public safety in the mine recalmation project is an emergency treatment, and the most widely used method is a filling method similar to the ground subsidence prevention. If dangerous mine cavity or tunnels are located in the mountains, charging with existing materials may not be possible, or unreasonable cases may occur, and new methods of technological development are required. Emergency actions should be carried out safely and efficiently to prevent the loss of precious people's lives on the hiking paths adjacent to dangerous mining sites. In these field conditions, urethane foam materials may be an alternative. In this study, the applicability of urethane foam materials in mining was reviewed through overseas cases. It was also tested on the appropriate depth of top soil for the protection of urethane foam materials through forest fire simulation test. The test result show that approximately 15cm of soil covering (recommended 20cm over) was suitable for maintaining the function of foam materials from forest fires.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.04a
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• pp.176-179
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• 1999

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.388-393
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• 1999

Polyurethane foams are polymeric material with repeating groups of urethane and urea. When these are heated with ethylene glycol and K acetate catalyst at $200^{\circ}C$, the transesterification of them leads to soluble products. The mechanisms of the reaction were investigated from the molecular weight and the component distributions of the products by GPC and IR analysis. The degradation of the urethane groups was faster than that of urea groups in transesterification reaction. K acetate catalyst accelerated the rate of the transesterification because it had a high ionization tendency. Each reaction, using K or Sr acetate as a catalyst, progressed in the same reaction path but yielded different compositions in products because of the difference of the reaction rate.

• Journal of the Korean Society for Railway
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• v.13 no.5
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• pp.476-480
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• 2010

In the corrugated steel panels used for railway vehicles, sound insulation performance is significantly deteriorated by local resonance effect. In this study, as a countermeasure, polyurethane foam is filled in the corrugated steel panel and glass wool layer is inserted in the layered floor panel, and then improvement effect of the sound insulation performance is experimentally estimated. Based on ASTM E2249-02, intensity transmission loss is measured and estimated on the corrugated panel and floor structure. The aim of the study is to identify how the foam filling and inserting glass wool layer improve the sound insulation performance of the train body structure in aspect of the weight increment.

• Fire Science and Engineering
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• v.32 no.2
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• pp.30-37
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• 2018

This study is an analysis of combustion characteristics of synthetic insulation materials such as houses and warehouses. Using combustion cone calorimeter and SEM, the researching has experimented combustion characteristics of four kinds of materials such as flame retardant styrofoam, general styrofoam, urethane and gypsum board. And analyzed. As a result of the test, the ignition time (TTI) for the thermal insulation material was found at 27 s~43 s, and the flame retardant styrofoam was ignited at the lowest TTI at 27 s and disappears at 28 s. In addition, the maximum heat release rate (peak HRR) and average heat release rate (mean HRR) of each material were expressed in the following order: urethane> flame retardant styrofoam> styrofoam> gypsum board. Also, the total smoke release ($m^2/m^2$) was the largest at $30.798m^2/m^2$ in flame-retardant styrofoam. The general CO concentration of styrofoam was 0.275 kg/kg and the emission concentration was 12.807 kg/kg. The residues showed the highest 0.029 g in the gypsum board among the above materials.

• Elastomers and Composites
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• v.46 no.4
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• pp.343-351
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• 2011

We prepared polyurethane foam/cloisite30B/phosphates composites and characterized their rise time, density, cell morphology, and thermal properties. The composites were synthesized with polyadipatediol-cloisite30B composite (f=2.0), polyether-polyol (f=4.6), polymeric 4,4-diphenyl methane diisocyanate (f=2.5), and D-580 (phenyl polyoxyalkenyl phosphate). As a blowing agent, cyclopentane and distilled water were used at various concentrations of D-580 from 0 to 2.81 wt%. The rise times of PUF/Closite30B/Phosphate composites blown with distilled water were faster than those blown with cyclopentane by 30%. The composites blown with cyclopentane had spherical-shape cells and the cell diameter was decreased with increasing D-580 wt%. While $T_g$ of the composites blown with cyclopentane linearly decreased with increasing the D-580 content, the $T_g$ of the composites blown with distilled water increased with the D-580 content. All PUF/Closite30B/Phosphate composites began to decompose from $250^{\circ}C$. The composites blown with cyclopentane showed the second thermal decomposition at temperatures higher than $500^{\circ}C$. The thermal stability of all composites increased with the D-580 content. The effect of D-580 on the thermal stability of the composites was measured higher at the composites blown with distilled water.

• Elastomers and Composites
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• v.46 no.2
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• pp.158-163
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• 2011

Rigid polyurethane foam (PUF) was synthesized with different contents of aliphatic polyester polyol, aromatic polyester polyol and aliphatic polyether polyol to know change of properties under sea water. UTM(universal testing machine), DSC(differential scanning calorimetry), hardness meter and FT-IR(Fourier transform spectroscopy) were used to study the PUF`s physical properties under sea water. Compressive strength and hardness of PUF decreased with increasing the content of aromatic polyester polyol under sea water as aging. According to the results of IR spectral analysis, reduction of urethane and urea peak was found and allophanate and biuret peak increased. Although glass transition temperature of PUF increased, mechanical properties of PUF decreased under sea water, because PUF gets brittle when crosslink density increase.

• KOREAN POULTRY JOURNAL
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• v.46 no.4
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• pp.112-115
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• 2014

국내 계사를 살펴보면 우레탄 또는 스티로폼을 거의 사용하고 있다. 오랜 시간이 지나면서 계사의 부식과 쥐의 영향으로 단열재 내부가 파괴되고 있는 상황이다. 하지만 최근 설립된 위드팜이 뿌리는 단열재를 출시하면서 계사의 신축 및 리모델링시 저비용으로 고효율을 기대할 수 있게 됐다. 질석과 펄라이트로 만든 뿌리는 단열재는 불연기능으로 화재예방, 단열기능으로 여름철 고온스트레스 예방, 쥐의 단열재 파괴 예방이 가능해 계사 환경 개선에 큰 도움을 주고 생산성에도 영향을 끼친다. 이번호에는 당당하게 축산업에 뛰어든 신입 축산업체인 위드팜(대표 김재국)을 소개코자 한다.