• Journal of the Korean Chemical Society
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• v.38 no.9
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• pp.621-627
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• 1994

Two crystal structures of dehydrated, $Ag^{+}$ and $Ca^{2+}$-exchanged zeolite A treated at $250^{\circ}C$ with 0.15 torr of Cs vapor have been determined by single-crystal X-ray diffraction technique in the cubic space group $Pm{\bar\3m$ at $21(1)^{\circ}C$ (a = 12.344(2) $\AA$ and 12.304(2) $\AA$). Their structures were refined to the final error indices, R (weighted), of 0.091 with 180 reflections, and 0.093 with 179 reflections, respectively, for which I > $3\sigma(I).$ In each structure, Cs species are found at four different crystallographic sites: 3 $Cs^{+}$ ions per unit cell are located at 8-ring centers, ca. 6.81∼7.14 $Cs^{+}$ ions are found on opposite 6-rings on threefold axes in the large cavity, ca. 1.93∼2.03 $Cs^{+}$ ions are found on threefold axes in the sodalite unit, and 0.53∼0.66 $Cs^{+}$ ions lie on opposite 4-rings. Also, ca. 4.12∼4.27 Ag atoms are located near the center of the large cavity. In these structures, excess cesium atoms in a unit cell are associated with other $Cs^{+}$ ions on a single threefold axis to form the linear cationic cluster $(Cs_4)^{3+}$. By blocking 8-rings, the $Cs^{+}$ ions may have prevented silver atoms from migrating out of the structure. The Ag atoms are likely to have formed hexasilver clusters at the centers of the large cavities. Each hexasilver cluster is stabilized by coordination to 14 $Cs^{+}$ ions.

• Korean Journal of Remote Sensing
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• v.18 no.4
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• pp.209-220
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• 2002

We carried out studies on SAR image intensity and interferometric phase over oyster sea farms. Strong backscattering was observed in amplitude images, and that was considered as a radar signal double bouncing from horizontal bars. These sea farming structures are not visible in satellite optical images except IKONOS image, so that it demonstrates the value of radar remote sensing as an effective tool in support of sea farm detection. The intensity of the image is sensitive to system parameters including wavelength, polarization, and look direction, but does not correlate to tide height. We found that the strongest backscattering can be obtained by L-band HH-polarization with a look direction perpendicular to the horizontal bar. We also succeeded in generating 21 coherent JERS-1 SAR interferometric pairs over the oyster farms. The general trend of the fringe rate of the interferometric phases appeared to be governed by altitude of ambiguity. The general trend was modeled by an inverse function and removed to have a residual phase. The residual phase showed a linear relation with the tide height. The results demonstrate for the first time that SAR can possibly be used to estimate sea level. However, the r.m.s. error of a regression line is 11.7 cm, and that is so far too large to make reliable assessments of sea level in practical applications. Further studies is required to improve the accuracy specifically using multi-polarization SAR data.

• Korean Journal of Remote Sensing
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• v.15 no.1
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• pp.9-20
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• 1999

The use of climatic information is essential in the industial society. More specialized weather servies are required to perform better industrial acivities including agriculture. Especially, crop models require daily weather data of crop growing area or cropping zones, where routine weather observations are rare. Estimates of the spatial distribution of daily climates might complement the low density of standard weather observation stations. This study was conducted to estimate the spatial distribution of daily minimum and maximum temperatures in Korean Peninsula. A topoclimatological technique was first applied to produce reasonable estimates of monthly climatic normals based on 1km $\times$ 1km grid cell over study area. Harmonic analysis method was then adopted to convert the monthly climatic normals into daily climatic normals. The daily temperatures for each grid cell were derived from a spatial interpolation procedure based on inverse-distance weighting of the observed deviation from the climatic normals at the nearest 4 standard weather stations. Data collected from more than 300 automatic weather systems were then used to validate the final estimates on several dates in 1997. Final step to confirm accuracy of the estimated temperature fields was comparing the distribution pattern with the brightness temperature fields derived from NOAA/AVHRR. Results show that differences between the estimated and the observed temperatures at 20 randomly selected automatic weather systems(AWS) range from -3.$0^{\circ}C$ to + 2.5$^{\circ}C$ in daily maximum, and from -1.8$^{\circ}C$ to + 2.2$^{\circ}C$ in daily minimum temperature. The estimation errors, RMSE, calculated from the data collected at about 300 AWS range from $1.5^{\circ}C$ to 2.5$^{\circ}C$ for daily maximum/minimum temperatures.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.486-490
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• 2017

도심지에서의 침수피해는 이상홍수 및 국지성 호우 시 우수관거 시설기준 미달, 펌프장 등 배수시설이 설치되지 않아 하천의 계획홍수위보다 제내지의 지반고가 낮은 저지대 지역에서 많이 발생하고 있다. 특히, 내수침수의 경우는 외수에 따른 범람보다는 국민의 재산과 인명피해에 직접적인 영향을 미치므로 침수피해 위험도가 높은 지역의 주민에게 그 지역의 침수빈도와 범위를 인지시키고 사전대응 능력을 향상시킬 필요가 있다. 따라서 연구의 목적으로 매년 피해가 발생한 이력이 있는 위험지구에 대해 전국단위 시군구별 침수피해 지도를 작성하여 침수심 산정과 피해액 예측할 수 있는 기초자료로 활용하고, 주민들의 신속한 대처를 통해 그들의 생명과 재산을 보호하여 재난 안전 국가 이미지 제고에 기여하고자 한다. 본 연구에서는 도심지 유출모형인 XP-SWMM을 활용하여 내수재해 위험요인에 대한 전국을 해석하는 것에 한계가 있어 풍수해저감종합계획에 수록된 XP-SWMM모의 분석 결과 값을 활용하고자 하였다. 기 수립된 전국 풍수해저감종합계획의 과거 피해 자료를 바탕으로 이상 집중호우나 태풍의 내습 시 풍수해 피해 발생 가능성이 제일 높은 지역을 연구범위 대상지역으로 선정하였다. 그 중 풍수해의 주요 원인으로서 태풍, 집중호우 및 해일로 인한 피해발생 빈도가 높은 지역이면서 하천재해 및 내수침수 피해가 많은 경기도 동두천시를 연구대상 지역으로 선정하였으며, 대상지 유역 현황과 지형정보 및 빈도별 침수심을 조사하였다. 수록된 내용에 따르면 경기도 동두천시는 우수관망의 밀도가 높은 4개 위험지구를 내수재해 발생가능성 지역으로 선정하여 10년, 20년, 30년, 50년, 100년, 200년 6개 빈도에 대해 XP-SWMM 모의를 실시하였다. 이와 같이 수록된 각 빈도에 대한 모의 결과 값을 GIS기술을 이용하여 디지털화 하고 부가적인 분석을 위한 GIS데이터화 하는 내삽법을 선정하여 침수면적 및 침수심을 산출하였다. 그러나 면적비교를 통해 모의 결과 값을 디지털화 하는 과정에서 많은 오차가 발생되는 것을 확인하였고, 이를 보완하기 위해 좌표보정 자동화 프로그램을 개발하여 이러한 문제점을 제거하여 신뢰도를 향상시켰다. 이렇게 계산된 연구 대상지역의 침수심과 침수면적을 활용하여 지도제작 표준 지침서 및 가이드라인을 제시하여 한국형 호우피해 지도제작 기술개발에 기여하고, 비구조적 대책으로서 이상홍수에 대한 위험도를 파악하여 지역별 도심침수 방지를 위한 대비체계를 구축하는 등 위험지역에 대한 사전분석 및 활용에 기초자료로 도움이 되고자 한다.

• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.606-614
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• 2019

A mixing ratio of the oil in water (O/W) emulsion of palm oil and the non-ionic surfactant (Tween-Span type) possessing different hydrophile-lipophilie balance (HLB) values was evaluated in this work. An optimum condition was determined through analysis of main and interaction effects of each quantitative factor using central composite design model-response surface methodology (CCD-RSM). Quantitative factors used by CCD-RSM were an emulsification time, emulsification speed, HLB value and amount of surfactant. On the other hand, the reaction parameters were the viscosity and mean droplet size of O/W emersion. Optimized conditions obtained from CCD-RSM were the emulsification time of 12.7 min, emulsification speed of 5,551 rpm, HLB value of 8.0 and amount of surfactant of 5.7 wt.%. Ideal experimental results under the optimized experimental condition were the viscosity of 1,551 cP and mean droplet size of 432 nm which satisfy the targeted values. The average error value from our actual experiment for verifying the conclusions was below to 2.5%. Therefore, a high favorable level could be obtained when the CCD-RSM was applied to the optimized palm oil to water emulsification.

• Journal of Korean Society of Disaster and Security
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• v.14 no.2
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• pp.13-23
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• 2021

This study intended to assess the reliability of topographic data using satellite imaging data. The topographical data using actual instrumentation data and satellite image data were established and applied to the rainfall-leak model, S-RAT, and the topographical data and outflow data were compared and analyzed. The actual measurement data were collected from the Water Resources Management Information System (WAMIS), and satellite image data were collected from MODIS observation sensors mounted on Terra satellites. The areas subject to analysis were selected for two rivers with more than 80% mountainous areas in the Han River basin and one river basin with more than 7% urban areas. According to the analysis, the difference between instrumentation data and satellite image data was up to 50% for peak floods and up to 17% for flood totals in rivers with high mountains, but up to 13% for peak floods and up to 4% for flood totals. The biggest difference in the video data is Landuse, which shows that MODIS satellite images tend to be recognized as cities up to 60% or more in urban streams compared to WAMIS instrumentation data, but MODIS satellite images are found to be less than 5% error in forest areas.

• Journal of Korea Water Resources Association
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• v.54 no.5
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• pp.321-334
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• 2021

A fixed reflectivity-rainfall relationship approach, such as the Marshall-Palmer relationship, for an entire year and different seasons, can be problematic in cases where the relationship varies spatially and temporally throughout a region. From this perspective, this study explores the use of long-term radar reflectivity for South Korea to obtain a nationwide calibrated Z-R relationship and the associated uncertainties within a Bayesian inference framework. A calibrated spatially structured pattern in the parameters exists, particularly for the wet season and parameter for the dry season. A pronounced region of high values during the wet and dry seasons may be partially associated with storm movements in that season. Overall, the radar rainfall fields based on the proposed modeling procedure are similar to the observed rainfall fields. In contrast, the radar rainfall fields obtained from the existing Marshall-Palmer relationship show a systematic underestimation. In the event of high impact weather, it is expected that the value of national radar resources can be improved by establishing an active watershed-level hydrological analysis system.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.663-669
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• 2018

The process of extracting active ingredients from wheat sprout using ultrasound assisted method was optimized with a central composite design model. The response value of the central composite design model established the extraction yield and the total flavonoids content, main effects and interactive effects were analyzed depending on independent variables such as the extraction time, volume ratio of ethanol to ultrapure water, and ultrasonic irradiation power. The volume ratio of ethanol to ultrapure water and ultrasonic irradiation power were relatively large for the extraction yield and the extraction time was most significantly affected the total flavonoids, Considering both the extraction yield and total flavonoids content, the optimal extraction conditions were as follows: the extraction time of 17.00 min, volume ratio of ethanol to ultrapure water of 50.25 vol%, ultrasonic irradiation power of 551.70 W. In this case, the extraction yield and total flavonoids content were 28.43 wt% and $29.99{\mu}g\;QE/mL\;dw$, respectively. The actual experimental extraction yield and total flavonoids content under this condition were 8.73 wt% and $29.65{\mu}g\;QE/mL\;dw$, respectively with respective error rates of 1.05 and 1.13%.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.2
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• pp.31-43
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• 2019

In this study, polymer elastic bumps were fabricated for the flexible electronic package flip chip bonding and the viscoelastic and viscoplastic behavior of the polymer elastic bumps according to the temperature and load were analyzed using FEM and experiments. The polymer elastic bump is easy to deform by the bonding load, and it is confirmed that the bump height flatness problem is easily compensated and the stress concentration on thin chip is reduced remarkably. We also develop a spiral cap type and spoke cap type polymer elastic bump of $200{\mu}m$ diameter to complement Au metal cap crack phenomenon caused by excessive deformation of polymer elastic bump. The proposed polymer elastic bumps could reduce stress of metal wiring during bump deformation compared to metal cap bump, which is completely covered with metal wiring because the metal wiring on these bumps is partially patterned and easily deformable pattern. The spoke cap bump shows the lowest stress concentration in the metal wiring while maintaining the low contact resistance because the contact area between bump and pad was wider than that of the spiral cap bump.

• Journal of the Society of Disaster Information
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• v.15 no.2
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• pp.292-300
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• 2019

Purpose: To reduce the noise and vibration of reinforced concrete slab structures, the damping performance is to be performed experimentally after installing hollow core or filling it with liquid. Method: Using the hollow rate as an experimental variable, the damping ratio and stiffness of each test specimen at impact load are obtained to determine the difference between the damping ratio and stiffness of the numerical analysis. In addition, the damping effects are reviewed by comparing the difference in the damping ratio and stiffness of a test specimen filled with liquid 50% of the study. Results: Since the difference in resistance between a specimen with or without hollow core is 5%, it is judged that there is no structural problem, and the injection of liquid into the hollow core can increase the damping ratio, which can reduce noise or vibration. Conclusion: At less than 20% of hollow rate, there was little damping effect, and at 30%, damping effect was found. However, if liquid is injected into the hollow core of the specimen, damping rate is shown to increase, and the injection of liquid into the hollow part is believed to reduce noise or vibration.